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WO2008123011A1 - 非水電解質二次電池用Ｌｉ－Ｎｉ複合酸化物粒子粉末及びその製造方法、並びに非水電解質二次電池 - Google Patents

非水電解質二次電池用Ｌｉ－Ｎｉ複合酸化物粒子粉末及びその製造方法、並びに非水電解質二次電池 Download PDF

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Publication number
WO2008123011A1
WO2008123011A1 PCT/JP2008/000454 JP2008000454W WO2008123011A1 WO 2008123011 A1 WO2008123011 A1 WO 2008123011A1 JP 2008000454 W JP2008000454 W JP 2008000454W WO 2008123011 A1 WO2008123011 A1 WO 2008123011A1
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Prior art keywords
nonaqueous electrolyte
electrolyte secondary
secondary battery
complex oxide
particle powder
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PCT/JP2008/000454
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English (en)
French (fr)
Inventor
Kazuhiko Kikuya
Osamu Sasaki
Teruaki Santoki
Hiroshi Yamamoto
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Toda Kogyo Corporation
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Publication date
Application filed by Toda Kogyo Corporation filed Critical Toda Kogyo Corporation
Priority to KR1020097017597A priority Critical patent/KR101403828B1/ko
Priority to CA002680192A priority patent/CA2680192A1/en
Priority to EP08720340.2A priority patent/EP2128915B1/en
Priority to ES08720340.2T priority patent/ES2584027T3/es
Priority to US12/529,809 priority patent/US8574765B2/en
Publication of WO2008123011A1 publication Critical patent/WO2008123011A1/ja

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    • C01—INORGANIC CHEMISTRY
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    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1228—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2
    • H—ELECTRICITY
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    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
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    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/50—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (MnO2)n-, e.g. Li(CoxMn1-x)O2 or Li(MyCoxMn1-x-y)O2
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    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
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    • C01G53/04—Oxides
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    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
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    • H01M4/362—Composites
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    • H—ELECTRICITY
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    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
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    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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  • Composite Materials (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)

Abstract

　充放電容量が大きく、充電時の熱安定性に優れた非水電解質二次電池用Ｌｉ－Ｎｉ複合酸化物粒子粉末を提供する。上記課題は、核となる二次粒子の組成がＬｉｘ１Ｎｉ１－ｙ１－ｚ１-w１Ｃｏｙ１Ｍｎｚ１Ｍｗ１Ｏ２（０．９≦ｘ１≦１．３、０．１≦ｙ１≦０．３、０．０≦ｚ１≦０．３、０≦ｗ１≦０．１　ＭはＡｌ、Ｆｅから選ばれる少なくとも１種の金属）であるＬｉ－Ｎｉ複合酸化物において、粒子表面に組成がＬｉｘ２Ｎｉ１－ｙ２－ｚ２－ｗ２Ｃｏｙ２Ｍｎｚ２Ｍｗ２Ｏ２（０．９≦ｘ２≦１＋ｚ２、０≦ｙ２≦０．３３、０≦ｚ２≦０．５、０≦ｗ２≦０．１　ＭはＡｌ、Ｆｅ、Ｍｇ、Ｚｒ、Ｔｉから選ばれる少なくとも１種の金属）であるＬｉ－Ｎｉ複合酸化物を被覆又は存在させた非水電解質二次電池用Ｌｉ－Ｎｉ複合酸化物粒子粉末により解決される。
PCT/JP2008/000454 2007-03-05 2008-03-05 非水電解質二次電池用Ｌｉ－Ｎｉ複合酸化物粒子粉末及びその製造方法、並びに非水電解質二次電池 WO2008123011A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
KR1020097017597A KR101403828B1 (ko) 2007-03-05 2008-03-05 비수전해질 이차 전지용 Ｌｉ-Ｎｉ 복합 산화물 입자 분말 및 그의 제조 방법 및 비수전해질 이차 전지
CA002680192A CA2680192A1 (en) 2007-03-05 2008-03-05 Li-ni composite oxide particles for non-aqueous electrolyte secondary battery, process for producing the same, and non-aqueous electrolyte secondary battery
EP08720340.2A EP2128915B1 (en) 2007-03-05 2008-03-05 Li-ni complex oxide particle powder for nonaqueous electrolyte secondary battery, method for producing the same, and nonaqueous electrolyte secondary battery
ES08720340.2T ES2584027T3 (es) 2007-03-05 2008-03-05 Polvo de partículas de óxido complejo de Li-Ni para una batería secundaria de electrolito no acuoso, procedimiento para su producción, y batería secundaria de electrolito no acuoso
US12/529,809 US8574765B2 (en) 2007-03-05 2008-03-05 Li-Ni composite oxide particles for non-aqueous electrolyte secondary battery, process for producing the same, and non-aqueous electrolyte secondary battery

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Application Number Priority Date Filing Date Title
JP2007-054861 2007-03-05
JP2007054861 2007-03-05

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WO2008123011A1 true WO2008123011A1 (ja) 2008-10-16

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US (1) US8574765B2 (ja)
EP (1) EP2128915B1 (ja)
JP (2) JP4258676B2 (ja)
KR (1) KR101403828B1 (ja)
CN (2) CN104810517B (ja)
CA (1) CA2680192A1 (ja)
ES (1) ES2584027T3 (ja)
WO (1) WO2008123011A1 (ja)

Cited By (11)

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JP2009230914A (ja) * 2008-03-19 2009-10-08 Sanyo Electric Co Ltd 非水電解質二次電池
EP2259370A3 (en) * 2009-06-05 2011-01-12 SB LiMotive Co., Ltd. Active material and positive electrode for rechargeable lithium battery and rechargeable lithium battery including the positive electrode
WO2011039132A1 (en) * 2009-09-30 2011-04-07 Solvay Sa Positive active electrode material for lithium secondary battery, process for preparing the same and lithium secondary battery
CN102339984A (zh) * 2010-07-28 2012-02-01 北京当升材料科技股份有限公司 一种多层包覆结构的球形材料的制备方法
CN102394297A (zh) * 2011-12-02 2012-03-28 湘潭大学 一种球形核壳结构复合型富锂多元正极材料及其制备方法
WO2015004856A1 (ja) * 2013-07-10 2015-01-15 株式会社Ｇｓユアサ リチウム二次電池用混合活物質、リチウム二次電池用電極、リチウム二次電池及び蓄電装置
WO2015151606A1 (ja) * 2014-03-31 2015-10-08 日立金属株式会社 リチウムイオン二次電池用正極活物質、その製造方法およびリチウムイオン二次電池
JP2015533257A (ja) * 2013-06-18 2015-11-19 エルジー・ケム・リミテッド リチウム二次電池用正極活物質及びその製造方法
WO2017056585A1 (ja) * 2015-09-30 2017-04-06 Ｎｅｃエナジーデバイス株式会社 正極活物質、正極およびリチウムイオン二次電池
US10665856B2 (en) 2014-07-31 2020-05-26 Murata Manufacturing Co., Ltd. Positive electrode active material, positive electrode, battery, battery pack, electronic device, electric vehicle, power storage device, and power system
JP2021509522A (ja) * 2017-12-29 2021-03-25 セイケム インコーポレイテッド オニウム金属酸化フッ化物前駆体を介した、Ｌｉイオンバッテリ用カソードセラミック粒子上のＬｉｍＭＯｘＦｙシェル形成

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EP2162935A1 (en) 2007-06-22 2010-03-17 Boston-Power, Inc. Cid retention device for li-ion cell
TWI502793B (zh) * 2008-09-10 2015-10-01 Toda Kogyo Corp Li-Ni composite oxide particle powder for nonaqueous electrolyte storage battery, method for producing the same, and nonaqueous electrolyte storage battery
JP4972624B2 (ja) * 2008-09-30 2012-07-11 日立ビークルエナジー株式会社 リチウム二次電池用正極材料及びそれを用いたリチウム二次電池
EP2351139B1 (en) * 2008-10-13 2013-10-09 BASF Corporation Mixed lithium nickel cobalt oxide and lithium nickel manganese cobalt oxide cathodes
JP4951638B2 (ja) * 2009-02-27 2012-06-13 株式会社日立製作所 リチウムイオン二次電池用正極材料及びそれを用いたリチウムイオン二次電池
KR101787141B1 (ko) * 2010-06-09 2017-10-18 도다 고교 가부시끼가이샤 리튬 복합 화합물 입자 분말 및 그의 제조 방법, 및 비수전해질 이차 전지
JP5549437B2 (ja) * 2010-07-08 2014-07-16 ソニー株式会社 正極活物質、非水電解質電池および正極活物質の製造方法
KR101215829B1 (ko) * 2010-07-22 2012-12-27 주식회사 에코프로 리튬 이차전지용 양극활물질의 제조방법, 그에 의하여 제조된 리튬 이차전지용 양극활물질 및 그를 이용한 리튬 이차전지
JP5830236B2 (ja) * 2010-09-29 2015-12-09 日立オートモティブシステムズ株式会社 非水電解質二次電池
EP2676312A1 (en) * 2011-02-18 2013-12-25 3M Innovative Properties Company Composite particles, methods of making the same, and articles including the same
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US9764962B2 (en) 2011-04-14 2017-09-19 Toda Kogyo Corporation Li—Ni composite oxide particles and process for producing the same, and non-aqueous electrolyte secondary battery
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JP4894969B1 (ja) 2011-06-07 2012-03-14 住友金属鉱山株式会社 ニッケルマンガン複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、ならびに、非水系電解質二次電池
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JP5971109B2 (ja) * 2011-12-20 2016-08-17 住友金属鉱山株式会社 ニッケル複合水酸化物とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および非水系電解質二次電池
JP5630593B2 (ja) 2012-06-06 2014-11-26 住友金属鉱山株式会社 ニッケル複合水酸化物、非水系電解質二次電池用正極活物質、非水系電解質二次電池、およびこれらの製造方法
JP6040392B2 (ja) * 2012-07-24 2016-12-07 株式会社田中化学研究所 複合酸化物、複合遷移金属化合物、複合酸化物の製造方法、非水電解質二次電池用の正極活物質、並びに非水電解質二次電池
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