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WO2008121338A2 - Production de nanofibres grâce à un filage par fusion - Google Patents

Production de nanofibres grâce à un filage par fusion Download PDF

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Publication number
WO2008121338A2
WO2008121338A2 PCT/US2008/004081 US2008004081W WO2008121338A2 WO 2008121338 A2 WO2008121338 A2 WO 2008121338A2 US 2008004081 W US2008004081 W US 2008004081W WO 2008121338 A2 WO2008121338 A2 WO 2008121338A2
Authority
WO
WIPO (PCT)
Prior art keywords
melt
distribution disc
nanofibers
spinning
molten polymer
Prior art date
Application number
PCT/US2008/004081
Other languages
English (en)
Other versions
WO2008121338A3 (fr
Inventor
Tao Huang
Larry R. Marshall
Jack Eugene Armantrout
Scott Yembrick
William H. Dunn
James M. O'connor
Tim Mueller
Marios Avgousti
Mark David Wetzel
Original Assignee
E. I. Du Pont De Nemours And Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by E. I. Du Pont De Nemours And Company filed Critical E. I. Du Pont De Nemours And Company
Priority to KR1020097022684A priority Critical patent/KR101519169B1/ko
Priority to CN2008800173840A priority patent/CN101755081B/zh
Priority to BRPI0807306-6A2A priority patent/BRPI0807306A2/pt
Priority to JP2010501009A priority patent/JP5394368B2/ja
Priority to EP08727205.0A priority patent/EP2129816B1/fr
Priority to EP12181094.9A priority patent/EP2527503B1/fr
Publication of WO2008121338A2 publication Critical patent/WO2008121338A2/fr
Publication of WO2008121338A3 publication Critical patent/WO2008121338A3/fr

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/18—Formation of filaments, threads, or the like by means of rotating spinnerets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/0007—Electro-spinning
    • D01D5/0015—Electro-spinning characterised by the initial state of the material
    • D01D5/0023—Electro-spinning characterised by the initial state of the material the material being a polymer melt
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D01D5/098—Melt spinning methods with simultaneous stretching
    • D01D5/0985—Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
    • Y10T442/184—Nonwoven scrim
    • Y10T442/186—Comprising a composite fiber

Definitions

  • This invention relates to a melt spinning process for forming fibers and fibrous webs.
  • very fine fibers can be made and collected into a fibrous web useful for selective barrier end uses such as in the fields of air and liquid filtration, flame retardancy, biomedical, battery and capacitor separators, biofuel membranes, cosmetic facial masks, biomedical applications, such as, hemostasis, wound dressings and healing, vascular grafts, tissue scaffolds, synthetic ECM (extra cellular matrix), and sensing applications, electronic/optical textiles, EMI Shielding, and antichembio protective coatings.
  • Centrifugal atomization processes are known in the art for making metal, metal alloy and ceramics powers. Centrifugal spinning processes are known in the art for making polymer fibers, carbon pitch fibers and glass fibers, such as disclosed in U.S. Patent Nos. 3,097,085 and 2,587,710. In such processes, the centrifugal force supplied by a rotational disc or distribution disc produces enough shear to cause the material to become atomized or to form fibers.
  • centrifugal spinning has only been successfully used for the production of fibers with diameters larger than micron size. There is a growing need for very fine fibers and fibrous webs made from very fine fibers. These types of webs are useful for selective barrier end uses. Presently very fine fibers are made from melt spun "islands in the sea" cross section fibers, split films, some meltblown processes, and electrospinning. However, these processes are generally limited to making non-commercial quantities of nanofibers because of their very low throughput.
  • Electrospinning and electroblowing are processes for forming fibers with sub-micron scale diameters from polymer solutions through the action of electrostatic forces and/or shear force.
  • the fibers collected as non- woven mats have some useful properties such as high surface area-to- mass ratio, and thus have great potential in filtration, biomedical applications (such as, wound dressings, vascular grafts, tissue scaffolds), and sensing applications.
  • Spinning nanofibers directly from polymer melts would offer several advantages over solution based spinning: elimination of solvents and their concomitant recycling requirements, higher throughput, and spinning of polymers with low solvent solubility.
  • multi-component systems such as blends and composites would be more readily melt spun, because in many cases there is no common solvent for such blends.
  • productivity would increase 10-500 fold and costs would drop significantly due to elimination of solvent recovery.
  • the present invention is directed to a nanofiber forming process comprising the steps of supplying a spinning melt of at least one thermoplastic polymer to an inner spinning surface of a heated rotating distribution disc having a forward surface fiber discharge edge, issuing the spinning melt along said inner spinning surface so as to distribute the spinning melt into a thin film and toward the forward surface fiber discharge edge, and discharging separate molten polymer fibrous streams from the forward surface discharge edge to attenuate the fibrous streams to produce polymeric nanofibers that have mean fiber diameters of less than about 1,000 nm.
  • a second embodiment of the present invention is a melt spinning apparatus for making polymeric nanofibers, comprising a molten polymer supply tube having an inlet portion and an outlet portion and at least one molten polymer outlet nozzle at the outlet portion thereof, said supply tube positioned axially through said melt spinning apparatus, a spinneret comprising a rotatable molten polymer distribution disc, having an inner spinning surface inlet portion surrounding and in fluid communication with said outlet portion of said molten polymer supply tube, and an indirect heating source directed at said rotatable molten polymer distribution disc.
  • Another embodiment of the present invention is a collection of nanofibers comprising polyolefin, having mean fiber diameters of less than about 500 nm.
  • Figure 1 is a cut-away cross-sectional view of a melt spinning apparatus suitable for use in forming melt spun nanofibers according to the present invention.
  • Figure 2 is an illustration of the desired temperature profile within the fiber spinning and formation area of the melt spinning apparatus of the present invention.
  • Figure 3A is a cut-away side view
  • 3B is a top view of a molten polymer distribution disc according to the present invention.
  • Figure 4A is a scanning electron micrograph of polypropylene (PP) fibers from Example 1.
  • Figure 4B is a histogram of the fiber diameters of Example 1.
  • Figure 5A is a scanning electron micrograph of polypropylene fibers from Example 2.
  • Figure 5B is a histogram of the fiber diameters of Example 2.
  • Figure 6A is a scanning electron micrograph of polypropylene fibers from Example 3.
  • Figure 6B is a histogram of the fiber diameters of Example 3.
  • Figure 7A is a scanning electron micrograph of polypropylene fibers from Example 4.
  • Figure 7B is a histogram of the fiber diameters of Example 4.
  • Figure 8A is a scanning electron micrograph of polyethylene fibers from Example 5.
  • Figure 8B is a histogram of the fiber diameters of Example 5.
  • Capillary-based spinning uses a rotor with side nozzle holes. A polymer melt is pushed out through the side nozzle holes, and large diameter fibers are formed by centrifugal stretching, such as disclosed in U.S. Patent No. 4,937,020. Capillary-based classical centrifugal spinning is not related to the case of the present invention.
  • Another is film splitting-based spinning using a conical disc as rotor, such as disclosed in U.S. Patent No. 2,433,000. A polymer melt or solution is issued either directly onto a conical disc surface, or through nozzle holes at the bottom of the distribution disc. Film splitting-based classical centrifugal spinning is more closely related to the present invention.
  • nanofibers are formed by film splitting at the forward discharge edge of a rotating distribution disc, such as a bell cup; from a fully spread thin melt film on the inner surface of the distribution disc, with a typical film thickness in the low micron range.
  • the polymer viscosity is relatively higher than in the case of the present invention.
  • the higher the viscosity the larger the fibers which are formed.
  • the spinning melt can be spun into nanofibers without any rheology modification.
  • the spinning polymer can be plasticized, hydrolyzed or otherwise cracked to lower the viscosity.
  • a spinning melt with a viscosity between about 1 ,000 cP to about 100,000 cP is useful, even a viscosity between about 1 ,000 cP to about 50,000 cP.
  • shear disc placed downstream of the rotating distribution disc, and the polymer melt is issued through a gap between the rotating distribution disc and the shear disc, wherein the shear applied to the polymer melt causes shear thinning.
  • the shear disc also acts as a melt distribution disc, helping to form a more uniform, fully spread, thin melt film on the inner surface of the rotating polymer distribution disc.
  • the spinning melt comprises at least one polymer.
  • Any melt spinnable, fiber-forming polymer can be used.
  • Suitable polymers include thermoplastic materials comprising polyolefins, such as polyethylene polymers and copolymers, polypropylene polymers and copolymers; polyesters and co-polyesters, such as poly(ethylene terephthalate), biopolyesters, thermotropic liquid crystal polymers and PET coployesters; polyamides (nylons); polyaramids; polycarbonates; acrylics and meth-acrylics, such as poly(meth)acrylates; polystyrene-based polymers and copolymers; cellulose esters; thermoplastic cellulose; cellulosics; acrylonitrile-butadiene-styrene (ABS) resins; acetals; chlorinated polyethers; fluoropolymers, such as polychlorotrifluoroethylenes (CTFE), fluorinated-ethylene-propylene (FEP); and polyvin
  • FIG. 1 is an illustration of the cross-section view of the nanofiber melt spinning and web collection unit according to the present invention.
  • a rotating spinneret contains a rotating distribution disc 1 suitable for forming fibers from the spinning melt.
  • the distribution disc can have a concave or flat open inner spinning surface and is connected to a high speed motor (not shown) by a drive shaft 6.
  • concave we mean that the inner surface of the disc can be curved in cross-section, such as hemispherical, have the cross-section of an ellipse, a hyperbola, a parabola or can be frustoconical, or the like.
  • the melt spinning unit can optionally include a stationary shear disc 3 mounted substantially parallel to the polymer distribution disc's inner surface.
  • a spinning melt is issued along the distribution disc's inner surface, and optionally through a gap between the distribution disc inner surface and the shear disc, if present, so as to help distribute a sheared spinning polymer melt toward the forward surface of the discharge edge 2 of the distribution disc.
  • the distribution disc and shear disc are heated by an indirect, non-contact heating device 10, such as an infrared source, induction heating device or other such radiational heating source, to a temperature at or above the melting point of the polymer.
  • the spinning melt is pumped from an inlet portion of a supply tube 4, running axially through the shear disc 3, if present, toward the distribution disc 1 and exits the supply tube at an outlet portion thereof.
  • the throughput rate of the melt can be between about 0.1 cc/min to about 200 cc/min, even between about 0.1 cc/min to about 500 cc/min.
  • the rotational speed of distribution disc 1 is controlled to between about 1,000 rpm and about 100,000 rpm, even between about 5,000 rpm and about 100,000 rpm, or even between about 10,000 rpm and about 50,000 rpm.
  • the thin film splits into melt ligaments, the melt ligaments are further stretched by centrifugal force, and fibers 11 are produced from the ligaments stretching.
  • One or more hot gas (e.g. air or N 2 ) rings 5a and 5b, having hot gas nozzles disposed on the circumference thereof, can be positioned annular to the rotating distribution disc and/or the molten polymer supply tube, the nozzles being positioned so as to direct a hot gas flow toward the molten polymer ligaments, to maintain the temperature of the film splitting and ligament stretching regions above the melting point of the polymer, to maintain the ligaments in the melt state and enable further stretching into nanofibers.
  • the hot gas flow can also act to guide the fibers toward the web collector 8.
  • cooling gas e.g. air or N 2
  • the cooling gas flow further guides the nanofiber stream 11 toward the web collector 8.
  • Web collection can be enhanced by applying vacuum through the collector to pull the fibers onto the collector.
  • the web collection ring 8 in Figure 1 is a screen ring which is cooled, electrically grounded and connected to a blower (not shown) to form a vacuum collector ring.
  • the web collector 8 can be cooled with flowing cold water or dry ice.
  • a tubular web collecting screen 12 is positioned inside the web collection ring 8, and is moved vertically along the web collection ring 8 in order to form a uniform nanofibrous web.
  • a nonwoven web or other such fibrous scrim can be situated on the tubular web collecting screen 12, onto which the nanofibers can be deposited.
  • an electrostatic charge voltage potential can be applied and maintained in the spinning space between the distribution disc and the collector to improve the uniformity of the fibrous web laydown.
  • the electrostatic charge can be applied by any known in the art high voltage charging device.
  • the electrical leads from the charging device can be attached to the rotating spinneret and the collector, or if an electrode is disposed within the spinning space, to the spinneret and the electrode, or to the electrode and the collector.
  • the voltage potential applied to the spinning unit can be in the range between about 1 kV and about 150 kV.
  • the designed temperature distribution surrounding the rotating distribution disc is an important distinguishing characteristic of the present invention process from classical centrifugal spinning.
  • FIG 2 is an illustration of the designed temperature profile within the melt spinning region surrounding the rotational distribution disc 1 , in which T1 is the temperature of melt spinning zone around the rotating distribution disc, T2 is the temperature of melt threads (ligaments) 11 stretching zone, and T3 is the temperature of rapid quenching and nanofiber solidifying zone, where T1 >T2> Tm (the melting point of polymer) and T3 « Tm 1 i.e. well below the melting point of the polymer.
  • Figure 3A is a side view and Figure 3B is a top view of an example of a molten polymer distribution disc 1.
  • the distribution disc geometry can influence the formation of fibers and fiber size.
  • Diameter D of the present distribution disc is between about 10 mm and 200 mm
  • the angle ⁇ of the forward surface discharge edge is 0 degrees when the disc is flat, or between greater than 0 degrees to about 90 degrees
  • the edge of the distribution disc is optionally serrated 15 in order to form the fully spread thin film on the inner surface of the distribution disc.
  • the serration on the distribution disc edge also helps to form the more uniform nanofibers with relatively narrow fiber diameter distribution.
  • the present process can make very fine fibers, preferably continuous fibers, with a mean fiber diameter of less than about 1 ,000 nm and even between about 100 nm to about 500 nm.
  • the fibers can be collected onto a fibrous web or scrim.
  • the collector can be conductive for creating an electrical field between it and the rotary spinneret or an electrode disposed downstream of the spinneret.
  • the collector can also be porous to allow the use of a vacuum device to pull the hot and/or cooling gases away from the fibers and help pin the fibers to the collector to make the fibrous web.
  • a scrim material can be placed on the collector to collect the fiber directly onto the scrim thereby making a composite material.
  • a nonwoven web or other porous scrim material such as a spunbond web, a melt blown web, a carded web or the like, can be placed on the collector and the fiber deposited onto the nonwoven web or scrim. In this way composite fabrics can be produced.
  • the process and apparatus of the present invention have been demonstrated to successfully melt spin polyolefin nanofibers, in particular polypropylene and polyethylene nanofibers.
  • the fiber size (diameter) distributions of said polyolefin nanofibers are believed to be significantly lower than heretofore known in the art polyolefin fibers.
  • U.S. Patent No. 4,397,020 discloses a radial spinning process which, while suggesting the production of sub-micron polyolefin fibers having diameters as low as 0.1 micron, exemplifies only PP fibers having diameters of 1.1 micron.
  • collections of polyolefin nanofibers having a mean fiber diameter of less than about 500 nm have been obtained, even less than or equal to about 400 nm, and the median of the fiber diameter distributions can be less than or equal to about 400 nm, or even less than 360 nm.
  • Fiber Diameter was determined as follows. Ten scanning electron microscope (SEM) images at 5,00Ox magnification were taken of each nanofiber layer sample. The diameter of more than 200, or even more than 300 clearly distinguishable nanofibers were measured from the SEM images and recorded. Defects were not included (i.e., lumps of nanofibers, polymer drops, intersections of nanofibers). The average fiber diameter for each sample was calculated and reported in nanometers (nm).
  • Example 1 Continuous fibers were made using an apparatus as illustrated in
  • the typical shear viscosity of Metocene MF650Y PP is 4.89181 Pa-sec, at the shear rate of 10,000/sec. at 400 0 F.
  • the melting point of Metocene MF650Y PP is Tm>160 °C.
  • a PRISM extruder with a gear pump was used to deliver the polymer melt to the rotating spinneret through the supply tube.
  • the pressure was set to a constant 61 psi.
  • the gear pump speed was set to a constant set point 5 and this produced a melt feed rate of about 0.8 cc/min.
  • the hot blowing air was set at a constant 30 psi.
  • the rotating polymer melt distribution disc had a concave angle of 30 degrees, without a serrated discharge edge and in the absence of a shear disc.
  • the rotation speed of the distribution disc was set to a constant 11 ,000 rpm.
  • the temperature of the spinning melt from the melt supply tube was set to 251 0 C 1 the temperature of the distribution disc was set to 260 0 C and the temperature of the blowing air was set to 220 0 C. No electrical field was used during this test.
  • Nanofibers were collected on a Reemay nonwoven collection screen that was held in place 15 inches away from the distribution disc by stainless steel sheet metal.
  • An SEM image of the fibers can be seen in Fig. 4A.
  • SEM scanning electron microscopy
  • Example 2 was prepared similarly to Example 1 , except the rotation speed of the distribution disc was set to a constant 13,630 rpm. The diameters of fibers became smaller than Example 1.
  • An SEM image of the fibers can be seen in Fig. 5A.
  • the typical shear viscosity of Metocene MF650Y PP is 5.76843 Pa-sec, at the shear rate of 10,000/sec. at 400 0 F.
  • the melting point of Metocene MF650Y PP is Tm>160 °C.
  • the distribution disc had a concave angle of 15 degrees, without a serrated discharge edge and in the presence of a stationary shear disc.
  • the rotation speed of the distribution disc was set to a constant 11 ,000 rpm.
  • the temperature of the spinning melt from the melt supply tube was set to 251 0 C, the temperature of the distribution disc was set to 270 0 C and the temperature of the blowing air was set to 220 0 C. No electrical field was used during this test.
  • Fibers were collected on a Reemay nonwoven collection screen that was held in place 15 inches away from the rotary spinning disc by stainless steel sheet metal.
  • An SEM image of the fibers can be seen in Fig. 6A.
  • SEM scanning electron microscopy
  • the typical shear viscosity of Metocene MF650Y PP is 9.45317 Pa-sec, at the shear rate of 10,000/sec. at 400 0 F.
  • the melting point of Metocene MF650Y PP is Tm>160 °C.
  • the distribution disc had a concave angle of 30 degrees, without a serrated discharge edge and in the absence of shear disc.
  • the rotation speed of the distribution disc was set to a constant 11 ,000 rpm.
  • the temperature of the spinning melt from melt supply tube was set to 251 0 C, the temperature of the distribution disc was set to 260 C C and the temperature of the blowing air was set to 220 0 C. No electrical field was used during this test.
  • Fibers were collected on a Reemay nonwoven collection screen that was held in place 15 inches away from the distribution disc by stainless steel sheet metal.
  • An SEM image of the fibers can be seen in Fig. 7A.
  • Continuous fibers were made according to Example 1 , except using a polyethylene (LLDPE) injection molding resin (SURPASS® IFs932-R from NOVA Chemicals, Canada), a high melt index resin with very narrow molecular weight distribution.
  • LLDPE polyethylene
  • SURPASS® IFs932-R injection molding resin
  • a PRISM extruder with a gear pump is used for deliver melt to the distribution disc through the supply tube.
  • the pressure was set to a constant 61 psi.
  • the gear pump speed was set to a constant 10 and this produced a melt feed rate of about 1.6 cc/min.
  • the hot blowing air was set at a constant 30 psi.
  • the rotary spinning disc had a concave angle of 30 degrees, with serrated discharge edge and in presence of a stationary shear disc.
  • the rotation speed of the distribution disc was set to a constant 13,630 rpm.
  • the temperature of the spinning melt from the melt supply tube was set to 250 0 C, the temperature of the rotary spinning disc was set to 220 0 C and the temperature of the blowing air was set to 160 0 C. No electrical field was used during this test.
  • Fibers were collected on a Reemay nonwoven collection screen that was held in place 15 inches away from the distribution disc by stainless steel sheet metal.
  • An SEM image of the fibers can be seen in Fig. 8A.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Nanotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Nonwoven Fabrics (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Artificial Filaments (AREA)

Abstract

Procédé et appareil permettant d'obtenir des nanofibres grâce à un filage par fusion basé sur l'utilisation d'un disque de distribution rotatif à grande vitesse. Les fibres peuvent être rassemblées pour former une bande uniforme qui sera finalement utilisée en tant que barrière sélective. Il est possible de produire des fibres dont le diamètre moyen est inférieur à 1 000 nm.
PCT/US2008/004081 2007-03-29 2008-03-27 Production de nanofibres grâce à un filage par fusion WO2008121338A2 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
KR1020097022684A KR101519169B1 (ko) 2007-03-29 2008-03-27 용융 방사에 의한 나노섬유의 제조
CN2008800173840A CN101755081B (zh) 2007-03-29 2008-03-27 通过熔体纺丝法来制备纳米纤维
BRPI0807306-6A2A BRPI0807306A2 (pt) 2007-03-29 2008-03-27 "processo de formação de nanofibra, aparelho de fiação via sistema de fusão para a produção de nanofibras polimérica e coleta de nanofibras"
JP2010501009A JP5394368B2 (ja) 2007-03-29 2008-03-27 溶融紡糸によるナノ繊維の製造
EP08727205.0A EP2129816B1 (fr) 2007-03-29 2008-03-27 Production de nanofibres grâce à un filage par fusion
EP12181094.9A EP2527503B1 (fr) 2007-03-29 2008-03-27 Production de nanofibres grâce à un filage par fusion

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US92113507P 2007-03-29 2007-03-29
US60/921,135 2007-03-29

Publications (2)

Publication Number Publication Date
WO2008121338A2 true WO2008121338A2 (fr) 2008-10-09
WO2008121338A3 WO2008121338A3 (fr) 2009-04-16

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US (1) US8277711B2 (fr)
EP (2) EP2527503B1 (fr)
JP (1) JP5394368B2 (fr)
KR (1) KR101519169B1 (fr)
CN (2) CN102534829B (fr)
BR (1) BRPI0807306A2 (fr)
WO (1) WO2008121338A2 (fr)

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EP2257660A4 (fr) * 2008-03-17 2012-01-04 Univ Texas Procédés et appareils pour réaliser des fibres superfines
WO2013157969A1 (fr) 2012-04-17 2013-10-24 Politechnika Łodzka Matériel médical pour reconstruction de vaisseaux sanguins, son procédé de fabrication et utilisation du matériel médical pour la reconstruction de vaisseaux sanguins
US8647541B2 (en) 2011-02-07 2014-02-11 Fiberio Technology Corporation Apparatuses and methods for the simultaneous production of microfibers and nanofibers
WO2015061377A1 (fr) * 2013-10-22 2015-04-30 E. I. Du Pont De Nemours And Company Voile nanofibreux fin en polypropylène filé à l'état fondu
US9242024B2 (en) 2011-03-29 2016-01-26 University-Industry Cooperation Group Of Kyung-Hee University Et Al Three-dimensional nanofiber scaffold for tissue repair and preparation method thereof
EP3396039A4 (fr) * 2015-12-21 2019-01-09 Panasonic Intellectual Property Management Co., Ltd. Ensemble de fibres
US11408096B2 (en) 2017-09-08 2022-08-09 The Board Of Regents Of The University Of Texas System Method of producing mechanoluminescent fibers
US11427937B2 (en) 2019-02-20 2022-08-30 The Board Of Regents Of The University Of Texas System Handheld/portable apparatus for the production of microfibers, submicron fibers and nanofibers

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EP2129816B1 (fr) 2016-12-21
JP5394368B2 (ja) 2014-01-22
JP2010522835A (ja) 2010-07-08
US8277711B2 (en) 2012-10-02
US20080242171A1 (en) 2008-10-02
CN102534829A (zh) 2012-07-04
EP2527503B1 (fr) 2025-02-26
KR20090127371A (ko) 2009-12-10
BRPI0807306A2 (pt) 2014-05-20
EP2129816A2 (fr) 2009-12-09
EP2527503A1 (fr) 2012-11-28
CN102534829B (zh) 2017-04-12
CN101755081A (zh) 2010-06-23
CN101755081B (zh) 2012-10-10
KR101519169B1 (ko) 2015-05-11
WO2008121338A3 (fr) 2009-04-16

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