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WO2008110590A1 - Compositions détergentes liquides de lessive - Google Patents

Compositions détergentes liquides de lessive Download PDF

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Publication number
WO2008110590A1
WO2008110590A1 PCT/EP2008/052978 EP2008052978W WO2008110590A1 WO 2008110590 A1 WO2008110590 A1 WO 2008110590A1 EP 2008052978 W EP2008052978 W EP 2008052978W WO 2008110590 A1 WO2008110590 A1 WO 2008110590A1
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WO
WIPO (PCT)
Prior art keywords
composition
liquid
fragrance
waxy
composition according
Prior art date
Application number
PCT/EP2008/052978
Other languages
English (en)
Inventor
Serge Creutz
Lorry Deklippel
Stephane Ugazio
Original Assignee
Dow Corning Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Corning Corporation filed Critical Dow Corning Corporation
Publication of WO2008110590A1 publication Critical patent/WO2008110590A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3734—Cyclic silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions

Definitions

  • This invention relates to the incorporation of fragrance compositions in liquid cleansing surfactant compositions.
  • the invention is particularly applicable to liquid laundry detergent compositions like fabric washing compositions, but can also be used in other surfactant-containing compositions including personal care cleansing compositions such as hair shampoo or shower gel.
  • fragrances are frequently incorporated in detergents to give a pleasant odour during use of the cleaning product and to mask the inherent smell of the soap or other surfactant present in the cleaning product.
  • the fragrances are generally complex mixtures of fragrant compounds of varying volatility. Upon storage in a detergent composition, perfumes and fragrances can be altered through interactions and/or reactions with the other components of the composition. Due to their volatile nature, the fragrant compounds tend to be dissipated with time, particularly the most volatile compounds which are often associated with perceived freshness.
  • WO-A-01/25389 describes a domestic care product comprising a fragrance particle, where the particle comprises a fragrance composition and a silicone polymer having a melting point of at least 10 0 C, and at least 20% of the silicone atoms in the silicone polymer have a substituent of 16 carbon atoms or more.
  • WO-A-03/082356 describes an emulsion comprising a disperse phase which is a blend of a fragrance composition and a waxy hydrophobic material having a melting point in the rangel 0-200 C dispersed in a continuous phase comprising an aqueous solution of concentration at least 0.1 M of a salt capable of ionic disassociation in water.
  • the protected fragrance composition can be produced in powdered form for blending with a solid cleaning product such as a powder detergent.
  • a solid cleaning product such as a powder detergent.
  • a fragrance containing emulsion can be dispersed in the liquid cleaning product.
  • WO-A-2004/084844 describes the use of a waxy silicone material to control release of an active material, selected from fragrances, sunscreens, vitamins, drugs, biocides, pest repellents, catalysts and cooling agents, from a cleaning composition, personal care product, household care product or textile treatment composition, wherein the waxy silicone material is a cyclopolysiloxane.
  • a liquid surfactant containing composition such as a laundry detergent composition according to the present invention contains a polymeric cationic material and a fragrance composition blended with a waxy silicone material, whereby the polymeric cationic material improves the efficiency of deposition of the fragrance composition blend on the fabric being washed and the waxy silicone material improves the long lasting effect of the fragrance.
  • a material is said to be waxy when its melting point is within or close to the working temperature, for example a melting point in the range 10 to 200C.
  • a waxy material even if formed of a mixture of different compounds such as a polymer usually is, has a true melting point i.e. a sharp melting point or melts in a low range of temperature instead of a melting zone trough a wide range of temperature.
  • the melting point preferably refers to the temperature whereby he complete mixture has melted.
  • a waxy material can be formed of a mixture of a waxy compound with a liquid compound.
  • a silicone material is a material containing at least one silicon-containing compound, preferably a polysiloxane compound, preferably a polydiorganopolysiloxane compound.
  • a waxy silicone compound can for example comprise a hydrophobic polysiloxane compound.
  • the polysiloxane compound contains at least one substituent comprising at least 12 carbon atoms preferably at least 16 carbon atoms.
  • the substituent preferably contains a hydrocarbon chain.
  • the polyorganosiloxane compound has at least one substituent which is a long chain containing an alkyl group.
  • a process according to one aspect of the invention for preparing a liquid detergent composition for fabric washing comprises adding to a liquid detergent surfactant composition a polymeric cationic material and an emulsion of a fragrance composition blended with a waxy silicone material.
  • a detergent composition is a composition able to clean surfaces. It contains a surfactant compound, for example a cationic compound.
  • a liquid detergent composition is typically based on one or more active organic detergent surfactant of the anionic, cationic, non-ionic or amphoteric type, or mixtures thereof.
  • Suitable anionic organic detergent surfactants are alkali metal soaps of higher fatty acids, alkyl aryl sulphonates, for example sodium dodecyl benzene sulphonate, long chain (fatty) alcohol sulphates, olefin sulphates and sulphonates, sulphated monoglycerides, sulphated esters, sulphonated or sulphated ethoxylated alcohols, sulpho-succinates, alkane sulphonates, phosphate esters, alkyl isethionates, alkyl taurates and alkyl sarcosinates.
  • Suitable cationic organic detergent surfactants are alkylamine salts, quaternary ammonium salts, sulphonium salts and phosphonium salts.
  • Suitable non-ionic organic surfactants are condensates of ethylene oxide with a long chain (fatty) alcohol or fatty acid, condensates of ethylene oxide with an amine or an amide, condensation products of ethylene and propylene oxides, sucrose esters, fluorosurfactants, fatty acid alkylol amides and fatty amine oxides.
  • Suitable amphoteric organic detergent surfactants are imidazoline compounds, alkylaminoacid salts and betaines.
  • the liquid laundry detergent composition usually contains water as diluent.
  • the fragrance composition may be solid or liquid and may be a single fragrant compound, or a natural scented oil, or may be a mixture of fragrant compounds and/or natural oils.
  • natural oils and fragrant compounds particularly suitable for laundry detergent compositions are described in WO-A-01/25389.
  • Further examples include the damascones, for example 1-2,6,6-trimethyl-3-cyclohexenyl-2-buten-1-one (delta- damascone), and 3-(4-t-butylphenyl)-2-methylpropanal (lilial).
  • the waxy silicone material is generally a polysiloxane containing at least one hydrocarbon substituent having 12 or more carbon atoms.
  • the waxy silicone material is a cyclopolysiloxane, although linear polysiloxane waxes can be used.
  • linear polysiloxane waxes can be used.
  • waxy cyclopolysiloxanes tend to be more miscible with fragrance compounds than linear polysiloxane waxes are. Therefore, waxy cyclopolysiloxanes are preferred.
  • the waxy polysiloxane preferably comprises methyl alkyl siloxane units ((CH3)(R')SiO2/2), where R' is a long chain alkyl group having 12 or more, preferably 16 to 100 carbon atoms.
  • R' is a long chain alkyl group having 12 or more, preferably 16 to 100 carbon atoms.
  • the long chain alkyl group R' can optionally be substituted by polar substituents such as amino, amido, alcohol, alkoxy, or ester groups.
  • All the siloxane units of the waxy polysiloxane may be such methyl alkyl siloxane units, (this may be preferred if the waxy polysiloxane is a cyclopolysiloxane) or the waxy polysiloxane may additionally contain dimethyl siloxane units or units of the formula ((CH 3 )(R")SiC>2/2) where R" is an alkyl group having 1-1 1 carbon atoms, for example ethyl, a cycloalkyl group such as 2-cyclohexylethyl, a haloalkyl group or an aromatic group.
  • the methyl group of the above siloxane units could be replaced by ethyl or another lower alkyl group if desired.
  • the cyclopolysiloxane is preferably a cyclotetrasiloxane or cyclopentasiloxane or a mixture thereof.
  • the waxy polysiloxane preferably has a melting point in the range 10-200 0 C, most preferably 30 to 8O 0 C.
  • waxy cyclopolysiloxane contains aromatic groups, for example aryl groups attached directly to Si such as phenyl, or aralkyl groups comprising phenyl or substituted phenyl groups attached to silicone through an alkylene linkage, in addition to long chain alkyl groups.
  • Waxy cyclopolysiloxanes containing aralkyl groups that is, silicon-bonded substituents of the formula X-Ph, wherein X denotes a divalent aliphatic organic group bonded to silicon through a carbon atom and Ph denotes an optionally substituted aromatic group, are particularly preferred, for example 2-phenylpropyl, benzyl, 2- phenylethyl or 2-(t-butylphenyl)ethyl.
  • Such aralkyl groups may for example be present in 10 to 80 %, preferably 20 to 50% of the siloxane units of the waxy cyclopolysiloxane, usually as methyl aralkyl siloxane units.
  • the waxy polysiloxane can be mixed with a liquid silicone, for example a polydiorganosiloxane, a branched liquid polysiloxane, a silicone polyether copolymer or an aminopolysiloxane.
  • a liquid silicone for example a polydiorganosiloxane, a branched liquid polysiloxane, a silicone polyether copolymer or an aminopolysiloxane.
  • Particularly preferred liquid polysiloxanes are those containing aryl, for example phenyl, or aralkyl, for example benzyl, 2-phenylethyl or 2-phenylpropyl groups in addition to alkyl groups such as methyl.
  • the liquid polydiorganosiloxane can be linear or cyclic; cyclic siloxanes such as tetra(2-phenylpropyl)- tetramethylcyclotetrasiloxane may be preferred.
  • the liquid polysiloxane can contain functional groups, for example it can contain hydroxyl groups such as terminal silanol groups in a linear polydiorganosiloxane such as polydimethylsiloxane, alkoxy groups such as methoxy, ethoxy or propoxy bonded to silicon, or amino, amido, alcohol or alkoxy groups substituted in an organic group bonded to silicon.
  • the waxy hydrophobic mixture of the waxy polysiloxane and the liquid silicone is preferably a solid, for example it preferably has a melting point in the range 10-200 0 C, but can alternatively be a viscous liquid.
  • the liquid silicone can for example be used at up to 100% or even higher based on the weight of the wax, such as up to 200 or 300%, particularly if the blend of wax and liquid silicone is solid at 1 O 0 C, although the liquid silicone if used is preferably present at 1 to 60%, most preferably 10 to 30%, based on the weight of wax.
  • An organic liquid for example liquid paraffin or a naphthenic oil, can be used alternatively or additionally if it is compatible with the blend of fragrance and waxy polysiloxane.
  • the polymeric cationic material can be a natural or synthetic polymer substituted by cationic groups such as quaternary ammonium groups, or can be an addition polymer or condensation polymer of a polymerisable material containing cationic groups.
  • the polymeric cationic material can be a polysaccharide such as cellulose or a cellulose ether, guar, starch or xanthan gum substituted by quaternary ammonium groups.
  • Examples include the polymers sold under the Trade Marks 'Jaguar C13-S', which is a guar hydroxypropyltrimethylammonium chloride, 'Jaguar C14-S', which is another quaternary ammonium derivative of guar, 'Cosmedia C261 ', which is a guar hydroxypropyltrimethylammonium chloride, and 'JR-400', which is a cellulose ether with a [2- hydroxy-3-(trimethylammonio)propyl]- ⁇ -hydroxy-polyoxyethylene chloride.
  • Preferred examples of cationic addition polymers include polymers of a diallyl dimethyl ammonium salt, for example a halide such as the chloride, which generally contain N,N-dimethylimidazolinium salt units, for example homopolymers of diallyl dimethyl ammonium chloride or the copolymers with acrylamide sold under the Trade Marks 'Merquat 550', 'Merquat S', 'Merquat 740' and 'Merquat 2200'.
  • a diallyl dimethyl ammonium salt for example a halide such as the chloride, which generally contain N,N-dimethylimidazolinium salt units
  • cationic addition polymers are polymers of methacrylamidopropyl trimethyl ammonium salts or methacryloxyethyl trimethyl ammonium salts, such as polymers of a halide salt such as chloride or of a methylsulphate salt, for example copolymers with acrylic esters such as methyl acrylate, methyl methacrylate or ethyl acrylate.
  • the polymeric cationic material can be premixed with the blend of fragrance composition and waxy silicone material but is preferably added separately to the liquid laundry detergent composition.
  • the polymeric cationic material is generally present at 0.01 to 1% by weight of the liquid laundry detergent composition, for example at 0.02 to 0.5%.
  • the blend of fragrance and waxy polysiloxane is preferably added as an emulsion to the liquid laundry detergent composition.
  • An emulsion can conveniently be formed by melting the blend of fragrance and waxy polysiloxane, and liquid silicone if used, and emulsifying it in the continuous phase using at least one surfactant.
  • the surfactant is preferably immiscible with the said blend.
  • the surfactant is preferably an anionic surfactant.
  • anionic organic surfactants include alkali metal soaps of higher fatty acids, alkyl aryl sulphonates, long chain (fatty) alcohol sulphates, olefin sulphates and sulphonates, sulphated monoglycerides, sulphated esters, sulphonated ethoxylated alcohols, sulphosuccinates, alkane sulphonates, phosphate esters, alkyl isethionates, alkyl taurates and/or alkyl sarcosinates.
  • Deposition of the fragrance blend on the fabric is also improved when the blend of fragrance and waxy polysiloxane is added as a nonionic emulsion.
  • nonionic organic surfactants include condensates of ethylene oxide with a long chain (fatty) alcohol or fatty acid, condensates of ethylene oxide with an amine or an amide, condensation products of ethylene and propylene oxides, and sucrose esters. Mixtures of anionic and non-ionic surfactants can be used.
  • An emulsion can alternatively be made by emulsifying the waxy polysiloxane in the absence of the fragrance.
  • the fragrance can be post-added to the emulsion, which is then heated above the melting point of the waxy polysiloxane and left standing at this temperature, allowing the fragrance to diffuse within the hydrophobic waxy polysiloxane droplet.
  • Deposition of the fragrance blend on other substrates is also improved when the blend of fragrance and waxy polysiloxane is added as an anionic or nonionic emulsion, for example deposition on hair from a shampoo or deposition on skin from a shower gel.
  • the invention thus includes a liquid surfactant composition
  • a liquid surfactant composition comprising a cleansing surfactant, a polymeric cationic material and an anionic or non-ionic emulsion of a fragrance composition blended with a waxy silicone material.
  • a process for preparing a liquid surfactant composition comprises adding to a liquid cleansing surfactant composition a polymeric cationic material and an anionic or nonionic emulsion of a fragrance composition blended with a waxy silicone material.
  • the polymeric cationic material can be added to the emulsion of the fragrance composition with waxy silicone but preferably, the polymeric cationic material is added to the liquid cleansing surfactant.
  • a polymeric cationic material is added to the liquid cleansing surfactant composition.
  • the anionic or nonionic emulsion of a fragrance composition blended with a waxy silicone material is added to the liquid cleansing composition obtained in the first step.
  • the liquid laundry detergent compositions of the invention may contain one or more additional ingredients selected from solvents, alkanolamines, pH adjusting agents, opacifiers, perfumes, dyes, colour stabilisers, bactericides, brighteners, soil release agents and softening agents.
  • the liquid laundry detergent compositions of the invention as well as washing fabrics clean, deliver fragrance to the fabrics with longevity of fragrance effect.
  • the polymeric cationic material helps the blend of fragrance composition and waxy silicone material to deposit effectively on fabrics being washed, for example fabrics made of textile fibers such as cotton, wool, silk, nylon, and the like.
  • the waxy silicone material can also provide fabric softening benefits.
  • the invention is illustrated by the following Examples, in which parts and percentages are by weight.
  • An aqueous thickening solution was prepared by dispersing 8.9 g xanthan gum (sold under the trade mark Keltrol RD) and 24.5 g hydroxyethylcellulose (sold under the trade mark Natrosol 250 LR) in 962.3 g of demineralised water 4.2 g Kathon CG (Trade Mark) biocide was then added.
  • a cyclopolysiloxane wax was made by reacting an olefin mixture of C26-C45 chain length with tetramethylcyclotetrasiloxane. 84.6 g of the above thickening solution, 28.8 g of Maranil Paste A 55 (trade mark) sodium C 1 0- 1 3 n-alkylbenzenesulphonate, 108.7 g of the cyclopolysiloxane wax, and 5.4 g of Dow Corning BF20+ (trade mark) antifoam emulsion were loaded in a stirred reactor and heated to 8O 0 C. 28.4 g of damascone fragrance was then added. After 20 minutes, the heating was stopped.
  • a liquid detergent composition was made from 75% water, 17.7% Maranil Paste A, 55, 7.3% Dehydol LT7 (trade mark) ethoxylated C 12 - 1 8 alcohols and 0.1% of a polymeric cationic material as deposition aid polymer.
  • the polymers used were Example 1 Jaguar C14-S: Guar Hydroxypropyl Trimonium Chloride, a quaternary ammonium derivative of guar (from Rhodia), CAS Number: 65497-29-2
  • Example 2 Merquat 550 diallyl dimethyl ammonium chloride acrylamide copolymer
  • Example 5 Jaguar C13-S quaternary ammonium derivative of guar (from Rhodia), similar to Jaguar C-14-S.
  • examples 1 to 4 12.8% of the emulsion of encapsulated fragrance particles was added to each detergent composition to give a concentration of 0.75% damascone fragrance in each composition.
  • a liquid detergent composition containing 0.75% non-encapsulated damascone with no polymeric cationic material was used.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

L'invention porte sur une composition tension-active liquide pour nettoyer une surface. Cette composition comprend un agent tensioactif de nettoyage, une matière cationique polymère et une émulsion anionique ou non ionique d'une composition de parfum mélangée avec une matière de silicone cireuse. La composition est, de préférence, une composition détergente liquide pour le lavage de tissu. Elle peut conférer un parfum de longue durée au tissu lavé.
PCT/EP2008/052978 2007-03-14 2008-03-13 Compositions détergentes liquides de lessive WO2008110590A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0704871.3 2007-03-14
GB0704871A GB0704871D0 (en) 2007-03-14 2007-03-14 Liquid laundry detergent compositions

Publications (1)

Publication Number Publication Date
WO2008110590A1 true WO2008110590A1 (fr) 2008-09-18

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Cited By (14)

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KR100996262B1 (ko) 2008-12-23 2010-11-24 에이케이켐텍 주식회사 4급 암모늄계 양이온 계면활성제 및 이의 제조방법
WO2010115781A3 (fr) * 2009-03-31 2010-12-16 Dow Corning Corporation Compositions d'organopolysiloxane contenant une substance active
US8597624B2 (en) 2009-03-31 2013-12-03 Dow Corning Corporation Organopolysiloxane emulsions and their production
US8623958B2 (en) 2009-03-10 2014-01-07 Dow Corning Toray Co. Ltd. Oil-in-water silicone emulsion composition
US9029428B2 (en) 2010-07-02 2015-05-12 Dow Corning Toray Co., Ltd. Oil-in-water silicone emulsion composition
WO2015144053A1 (fr) * 2014-03-26 2015-10-01 The Procter & Gamble Company Compositions de nettoyage contenant des polymères cationiques dans un système tensioactif enrichi en aes
WO2015143995A1 (fr) * 2014-03-26 2015-10-01 The Procter & Gamble Company Compositions de nettoyage contenant des polymères cationiques, et leurs procédés de fabrication et d'utilisation
WO2016074537A1 (fr) * 2014-11-11 2016-05-19 The Procter & Gamble Company Compositions détergente ou nettoyante à profil moussant amélioré
EP3031892A1 (fr) 2014-12-12 2016-06-15 The Procter and Gamble Company Procédé de fabrication d'un bien de consommation contenant une composition d'administration de bénéfice
EP3031893A1 (fr) 2014-12-12 2016-06-15 The Procter and Gamble Company Procédé de fabrication d'un bien de consommation contenant une composition d'administration de bénéfice
CN105980539A (zh) * 2014-02-14 2016-09-28 隆萨有限公司 衣料用液体洗衣清洁剂组合物
US9719059B2 (en) 2014-12-12 2017-08-01 The Procter & Gamble Company Lamellar phase-containing laundry detergent in a multi-compartment water-soluble pouch
US9840682B2 (en) 2014-11-11 2017-12-12 The Procter & Gamble Company Cleaning compositions with improved sudsing profile comprising a cationic polymer and silicone mixture
US9976105B2 (en) 2006-10-10 2018-05-22 Dow Silicones Corporation Silicone polymer emulsions

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WO2003082356A2 (fr) * 2002-04-03 2003-10-09 Dow Corning Corporation Emulsions
US20040072719A1 (en) * 2002-10-10 2004-04-15 Bennett Sydney William Encapsulated fragrance chemicals
WO2004084844A2 (fr) * 2003-03-27 2004-10-07 Dow Corning Corporation Compositions a liberation controlee
WO2006012767A1 (fr) * 2004-08-04 2006-02-09 Givaudan Sa Composition comprenant un parfum dissous dans une huile de silicone

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US20030022799A1 (en) * 2001-07-27 2003-01-30 Alvarado Robert M. A shampoo foaming composition which comprises an alkyl ether sulfate, a sorbitan derivative, a betaine, an alkylamido alkylamine, an alkoxylated carboxylic acid, and an organic salt
WO2003082356A2 (fr) * 2002-04-03 2003-10-09 Dow Corning Corporation Emulsions
US20040072719A1 (en) * 2002-10-10 2004-04-15 Bennett Sydney William Encapsulated fragrance chemicals
WO2004084844A2 (fr) * 2003-03-27 2004-10-07 Dow Corning Corporation Compositions a liberation controlee
WO2006012767A1 (fr) * 2004-08-04 2006-02-09 Givaudan Sa Composition comprenant un parfum dissous dans une huile de silicone

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9976105B2 (en) 2006-10-10 2018-05-22 Dow Silicones Corporation Silicone polymer emulsions
KR100996262B1 (ko) 2008-12-23 2010-11-24 에이케이켐텍 주식회사 4급 암모늄계 양이온 계면활성제 및 이의 제조방법
US8623958B2 (en) 2009-03-10 2014-01-07 Dow Corning Toray Co. Ltd. Oil-in-water silicone emulsion composition
WO2010115781A3 (fr) * 2009-03-31 2010-12-16 Dow Corning Corporation Compositions d'organopolysiloxane contenant une substance active
CN102361629A (zh) * 2009-03-31 2012-02-22 道康宁公司 包含活性物质的有机聚硅氧烷组合物
US8580729B2 (en) 2009-03-31 2013-11-12 Dow Corning Corporation Organopolysiloxane compositions containing an active material
US8597624B2 (en) 2009-03-31 2013-12-03 Dow Corning Corporation Organopolysiloxane emulsions and their production
CN104069025A (zh) * 2009-03-31 2014-10-01 道康宁公司 包含活性物质的有机聚硅氧烷组合物
US9029428B2 (en) 2010-07-02 2015-05-12 Dow Corning Toray Co., Ltd. Oil-in-water silicone emulsion composition
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WO2016094599A1 (fr) 2014-12-12 2016-06-16 The Procter & Gamble Company Procédé de fabrication d'un produit de type bien de consommation comprenant une composition destinée à administrer un bénéfice
EP3031892A1 (fr) 2014-12-12 2016-06-15 The Procter and Gamble Company Procédé de fabrication d'un bien de consommation contenant une composition d'administration de bénéfice

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