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WO2008034204A3 - Growth of carbon nanotubes using metal-free nanoparticles - Google Patents

Growth of carbon nanotubes using metal-free nanoparticles Download PDF

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Publication number
WO2008034204A3
WO2008034204A3 PCT/BE2007/000109 BE2007000109W WO2008034204A3 WO 2008034204 A3 WO2008034204 A3 WO 2008034204A3 BE 2007000109 W BE2007000109 W BE 2007000109W WO 2008034204 A3 WO2008034204 A3 WO 2008034204A3
Authority
WO
WIPO (PCT)
Prior art keywords
metal
carbon nanotubes
growth
nanoparticles
free nanoparticles
Prior art date
Application number
PCT/BE2007/000109
Other languages
French (fr)
Other versions
WO2008034204A2 (en
Inventor
Caroline Whelan
Santiago Cruz Esconjauregui
Original Assignee
Imec Inter Uni Micro Electr
Nanocyl Sa
Caroline Whelan
Santiago Cruz Esconjauregui
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imec Inter Uni Micro Electr, Nanocyl Sa, Caroline Whelan, Santiago Cruz Esconjauregui filed Critical Imec Inter Uni Micro Electr
Priority to EP07815688A priority Critical patent/EP2069234A2/en
Priority to JP2009528558A priority patent/JP2010504268A/en
Priority to US12/441,132 priority patent/US20100047152A1/en
Publication of WO2008034204A2 publication Critical patent/WO2008034204A2/en
Publication of WO2008034204A3 publication Critical patent/WO2008034204A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/22—Carbides
    • B01J27/224—Silicon carbide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Catalysts (AREA)

Abstract

The present invention provides a method for forming at least one carbon nanotube (16) by using metal-free catalyst nanoparticles (14), for example Si or Ge comprising nanoparticles. The method uses the step of decomposing a carbon source gas to form carbon fragments which then recombine at the metal-free catalyst nanoparticles (14) to grow carbon nanotubes (16). The method according to embodiments of the invention leads to carbon nanotubes (16) which do not comprise metal impurities.
PCT/BE2007/000109 2006-09-21 2007-09-21 Growth of carbon nanotubes using metal-free nanoparticles WO2008034204A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP07815688A EP2069234A2 (en) 2006-09-21 2007-09-21 Growth of carbon nanotubes using metal-free nanoparticles
JP2009528558A JP2010504268A (en) 2006-09-21 2007-09-21 Growth of carbon nanotubes using metal-free nanoparticles
US12/441,132 US20100047152A1 (en) 2006-09-21 2007-09-21 Growth of carbon nanotubes using metal-free nanoparticles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US84655806P 2006-09-21 2006-09-21
US60/846,558 2006-09-21

Publications (2)

Publication Number Publication Date
WO2008034204A2 WO2008034204A2 (en) 2008-03-27
WO2008034204A3 true WO2008034204A3 (en) 2008-11-27

Family

ID=39200861

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/BE2007/000109 WO2008034204A2 (en) 2006-09-21 2007-09-21 Growth of carbon nanotubes using metal-free nanoparticles

Country Status (4)

Country Link
US (1) US20100047152A1 (en)
EP (1) EP2069234A2 (en)
JP (1) JP2010504268A (en)
WO (1) WO2008034204A2 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2937895A1 (en) * 2008-11-04 2010-05-07 Commissariat Energie Atomique MOLD COMPRISING A NANOSTRUCTURED SURFACE FOR MAKING NANOSTRUCTURED POLYMERIC PARTS AND METHOD FOR MANUFACTURING SUCH A MOLD
BR112012002233A2 (en) * 2009-07-31 2019-09-24 Massachustts Institute Of Tech systems and methods related to the formation of carbon based nanostructures.
EP2504278A2 (en) * 2009-11-25 2012-10-03 Massachusetts Institute of Technology Systems and methods for enhancing growth of carbon-based nanostructures
US9663368B2 (en) 2010-10-28 2017-05-30 Massachusetts Institute Of Technology Carbon-based nanostructure formation using large scale active growth structures
US20130072077A1 (en) 2011-09-21 2013-03-21 Massachusetts Institute Of Technology Systems and methods for growth of nanostructures on substrates, including substrates comprising fibers
JP6091237B2 (en) * 2012-02-13 2017-03-08 国立大学法人大阪大学 High purity carbon nanotube, method for producing the same, and transparent conductive film using the same
ES2663666T3 (en) 2013-02-28 2018-04-16 N12 Technologies, Inc. Nanostructure film cartridge based dispensing
US9586823B2 (en) 2013-03-15 2017-03-07 Seerstone Llc Systems for producing solid carbon by reducing carbon oxides
WO2014151138A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Reactors, systems, and methods for forming solid products
US10115844B2 (en) 2013-03-15 2018-10-30 Seerstone Llc Electrodes comprising nanostructured carbon
EP3113880A4 (en) * 2013-03-15 2018-05-16 Seerstone LLC Carbon oxide reduction with intermetallic and carbide catalysts
EP3114077A4 (en) 2013-03-15 2017-12-27 Seerstone LLC Methods of producing hydrogen and solid carbon
WO2018022999A1 (en) 2016-07-28 2018-02-01 Seerstone Llc. Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same
CN113213454B (en) * 2021-04-21 2022-06-24 温州大学 Method for preparing single-walled carbon nanotubes with graphene as catalyst

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040101468A1 (en) * 2002-11-21 2004-05-27 Liang Liu Carbon nanotube array and method for forming same
WO2006061599A2 (en) * 2004-12-07 2006-06-15 University Of Southampton Method of manufacturing carbon nanotubes

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7132161B2 (en) * 1999-06-14 2006-11-07 Energy Science Laboratories, Inc. Fiber adhesive material
GB0226590D0 (en) * 2002-11-14 2002-12-24 Univ Cambridge Tech Method for producing carbon nanotubes and/or nanofibres
US20050207964A1 (en) * 2004-03-22 2005-09-22 Dojin Kim Method for synthesizing carbon nanotubes

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040101468A1 (en) * 2002-11-21 2004-05-27 Liang Liu Carbon nanotube array and method for forming same
WO2006061599A2 (en) * 2004-12-07 2006-06-15 University Of Southampton Method of manufacturing carbon nanotubes

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
D. TAGAKI, H. HIBINO, S. SUZUKI, Y. KOBAYASHI, Y. HOMMA: "Carbon Nanotube Growth from Semiconductor Nanoparticles", NANO LETTERS, vol. 7, no. 8, 19 July 2007 (2007-07-19), pages 2272 - 2275, XP002497374 *
M. H. RÜMMELI, C. KRAMBERGER, A. GRÜNEIS, P. AYALA, T. GEMMING, B. BÜCHNER, T. PICHLER, CHEMISTRY OF MATERIALS, vol. 19, no. 17, 27 July 2007 (2007-07-27), pages 4105 - 4107, XP002497375 *
UCHINO T ET AL: "Ge-catalyzed Vapour-Liquid-Solid growth of Carbon Nanotubes", SOLID-STATE DEVICE RESEARCH CONFERENCE, 2006. ESSDERC 2006. PROCEEDING OF THE 36TH EUROPEAN, IEEE, PI, 1 September 2006 (2006-09-01), pages 214 - 217, XP031047031, ISBN: 978-1-4244-0301-1 *

Also Published As

Publication number Publication date
US20100047152A1 (en) 2010-02-25
EP2069234A2 (en) 2009-06-17
JP2010504268A (en) 2010-02-12
WO2008034204A2 (en) 2008-03-27

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