+

WO2008033130A1 - Compositions d'additifs servant à corriger un surdosage d'additifs de conductivité dans des combustibles dérivés du pétrole - Google Patents

Compositions d'additifs servant à corriger un surdosage d'additifs de conductivité dans des combustibles dérivés du pétrole Download PDF

Info

Publication number
WO2008033130A1
WO2008033130A1 PCT/US2006/035589 US2006035589W WO2008033130A1 WO 2008033130 A1 WO2008033130 A1 WO 2008033130A1 US 2006035589 W US2006035589 W US 2006035589W WO 2008033130 A1 WO2008033130 A1 WO 2008033130A1
Authority
WO
WIPO (PCT)
Prior art keywords
fuel
conductivity
additive
oil composition
additives
Prior art date
Application number
PCT/US2006/035589
Other languages
English (en)
Inventor
Cenk Burgazli
Jr. Cyrus P. Henry
Original Assignee
Innospec Fuel Specialties Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Innospec Fuel Specialties Llc filed Critical Innospec Fuel Specialties Llc
Priority to PCT/US2006/035589 priority Critical patent/WO2008033130A1/fr
Priority to PCT/US2006/037255 priority patent/WO2008033145A2/fr
Publication of WO2008033130A1 publication Critical patent/WO2008033130A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C10L1/1883—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom polycarboxylic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1963—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof mono-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/20—Organic compounds containing halogen
    • C10L1/206—Organic compounds containing halogen macromolecular compounds
    • C10L1/207—Organic compounds containing halogen macromolecular compounds containing halogen with or without hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/224—Amides; Imides carboxylic acid amides, imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C10L1/2362—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing nitrile groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C10L1/2364—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing amide and/or imide groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431—Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437—Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2462—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds
    • C10L1/2475—Organic compounds containing sulfur, selenium and/or tellurium macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon to carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C10L1/2633—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond)
    • C10L1/2658—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond) amine salts

Definitions

  • This invention relates generally to fuel oil compositions, and particularly relates to additives which can be utilized to correct excessive conductivity in hydrocarbon fuels.
  • the invention further relates to a method of using such compositions.
  • ULS Ultra Low Sulfur
  • Fuel electrostatics is the ability of a hydrocarbon to transport or dissipate charge accumulated in the material. Fuel electrostatics directly affects the probability of an incident (fire or explosion) due to Static Discharge Ignitions (SDI). The real risk associated with SDI is a paramount safety concern for the fuel industry.
  • Electrostatics It is widely known that electrostatic charges can be frictionally transferred between two dissimilar, nonconductive materials. When this occurs, the electrostatic charge thus created appears at the surfaces of the contacting materials. The magnitude of the generated charge is dependent upon the nature of and, more particularly, the respective conductivity of each material. The potential for electrostatic ignition and explosion is probably at its greatest during product handling, transfer, and transportation. Electrostatic charging is known to occur during solvent or fuel pumping operations. In such operations, the flow of low conductivity liquid through conduits with high surface area or through "fine” filters combined with the disintegration of a liquid column and splashing during high speed tank loading can result in static charging. Such static charging can result in electrical discharge (spark) with catastrophic potential in highly flammable environments.
  • Organic liquids such as distillate fuels (diesel, gasoline, jet fuel, turbine fuels, home heating fuels, and kerosene) and relatively contaminant free light hydrocarbon oils (organic solvents and cleaning fluids) are inherently poor conductors. Static charge accumulates in these fluids because electric charge moves very slowly through these liquids and can take a considerable time to reach a surface which is grounded. Until the charge is dissipated, a high surface-voltage potential can be achieved which can create an incendiary spark, resulting in an ignition or an explosion.
  • distillate fuels diesel, gasoline, jet fuel, turbine fuels, home heating fuels, and kerosene
  • organic solvents and cleaning fluids organic solvents and cleaning fluids
  • Hydro treating is a process by which hydrogen, under pressure, in the presence of a catalyst, reacts with sulfur compounds in the fuel to form hydrogen sulfide gas and a hydrocarbon.
  • hydro treating to reduce sulfur content results not only in the removal of sulfur from the fuel but also the removal of other polar compounds which normally increase the conductivity characteristics of the fuel.
  • a non-hydro treated fuel has conductivity in the range of 10 to about 30 pS/m 2
  • a hydro treated fuel (below 15 ppm limit) is normally below 1 pS/m 2
  • Conductivity below ⁇ 3 pS/m greatly increases the risk of catastrophic electrostatic ignition.
  • Static Dissipaters / Conductivity Improvers In order to correct the detrimental effects of hydro treating, refineries and fuel handlers are routinely utilizing Static Dissipaters / Conductivity Improvers. These additives when used properly minimize the risk of electrostatic ignition in hydrocarbon fuels and solvents. There is a great wealth of knowledge and experience regarding the use of Static Dissipaters / Conductivity Improver additives (ASTM D - 4865 Standard Guide for Generation and Dissipation of Static Electricity in Petroleum Fuel Systems, and API Recommended Practice 2003 - Protection against Ignition Arising Out Of Static, Lightening, and Spray Currents; the entire teachings of which are incorporated herein by reference). The diversity of additives which have been patented and utilized in the fuel industry exemplifies the importance of risk associated with ignition due to static discharge.
  • the present invention is directed to compositions and methods for correcting fuel oil compositions having excess conductivity.
  • the oil compositions can comprise a Petroleum Based Component, a Conductivity Additive and a Conductivity Correcting Additive.
  • additional additives can be utilized with the conductivity correcting additive added such as: (a) low temperature operability / cold flow additives, (b) corrosion inhibitors, (c) cetane improvers, (d) detergents, (e) lubricity improvers, (f) dyes and markers, (g) anti-icing additives, (h) demulsifiers/anti haze additives, (i) antioxidants, Q) metal deactivators, (k) biocides, and (1) thermal stabilizers
  • the invention further describes a method of using such compositions formulations.
  • Fig. 1 is a graphical representation of the effect of lubricity additives on Stadis ® 425 conductivity response.
  • Fig. 2 is a graphical representation of the effect of lubricity additives on T 3514 conductivity response.
  • the present invention is directed to fuel oil compositions, comprising a Petroleum Based Component, a Conductivity Additive, and a Conductivity Correcting Additive to correct excess fuel Conductivity.
  • suitable Conductivity Correcting Additive compositions and methods directed toward the utilization of these Conductivity Correcting Additive composition are disclosed herein.
  • Petroleum Based Component is a hydrocarbon derived from refining petroleum or as a product of Fischer-Tropsch processes (well known to those skilled in the art).
  • the hydrocarbon may also be a solvent.
  • the fuel products are commonly referred to as Petroleum Distillate Fuels.
  • Petroleum Distillate Fuels encompass a range of distillate fuel types. These distillate fuels are used in a variety of applications, including automotive diesel engines and in non on- road applications under both varying and relatively constant speed and load conditions.
  • Petroleum Distillate Fuel oils can comprise atmospheric or vacuum distillates.
  • the distillate fuel can contain cracked gas oil or a blend of any proportion of straight run, thermally or catalytically cracked distillates.
  • the distillate fuel in many cases can be subjected to further processing such hydrogen-treatment or other processes to improve fuel properties.
  • the material can be described as a gasoline or middle distillate fuel oil.
  • Gasoline is a low boiling mixture of aliphatic, olefmic, and aromatic hydrocarbons, and optionally, alcohols or other oxygenated components. Typically, the mixture boils in the range from about room temperature up to about 225 ° C.
  • Middle distillates can be utilized as a fuel for locomotion in motor vehicles, air planes, ships and boats as burner fuel in home heating and power generation and as fuel in multi purpose stationary diesel engines.
  • Engine fuel oils and burner fuel oils generally have flash points greater than 38 ° C.
  • Middle distillate fuels are higher boiling mixtures of aliphatic, olefinic, and aromatic hydrocarbons and other polar and non-polar compounds having a boiling point up to about 350 ° C.
  • Middle distillate fuels generally include, but are not limited to, kerosene, jet fuels, and various diesel fuels.
  • Diesel fuels encompass Grades No. 1 -Diesel, 2-Diesel, 4-Diesel Grades (light and heavy), Grade 5 (light and heavy), and Grade 6 residual fuels.
  • Middle distillates specifications are described in ASTM D-975, for automotive applications (the entire teaching of which is incorporated herein by reference), and ASTM D-396, for burner applications (the entire teaching of which is incorporated herein by reference).
  • Jet fuels for aviation are designated by such terms as JP -4, JP-5, JP-7, JP-8, Jet A, Jet A-I. JP-4 and JP-5.
  • the Jet fuels are defined by U.S. military specification MIL-T-5624-N, the entire teaching of which is incorporated herein by reference and JP-8 is defined by U.S. Military Specification MIL-T83133-D the entire teaching of which is incorporated herein by reference.
  • Jet A, Jet A-I and Jet B are defined by ASTM specification D- 1655 and Def. Stan. 91 91 the entire teachings of which are incorporated herein by reference.
  • Static Dissipaters Static Dissipaters (SD), Conductivity Improver (CI), or Anti Stats (AS) are defined as any chemical species which are either present or added to fuels to increase the conductivity or the rate of charge dissipation in such fuels.
  • SD Static Dissipaters
  • CI Conductivity Improver
  • AS Anti Stats
  • Static Dissipaters / Conductivity Improver additives which have been patented and can be utilized as part of this invention are described as having components derived from the chemical families that include: aliphatic amines-fluorinated polyolefins
  • alpha-olefin-sulfone copolymer class — polysulphone and quaternary ammonium salt U.S. Pat. No. 3,811,848
  • polysulphone and quaternary ammonium salt amine/epichlorhydrin adduct dinonylnaphthylsulphonic acid U.S. Pat. No. 3,917,466
  • copolymer of an alkyl vinyl monomer and a cationic vinyl monomer U.S. Pat. No.
  • alpha-olefin-maleic anhydride copolymer class U.S. Pat. No. 3,677,725;
  • Conductivity Additives can also become mandated by current ballot actions in ASTM.
  • the ballot proposes to modify ASTM D-975 (on road Diesel specification) to require conductivity additives to meet a minimum conductivity of 50 pS/m at time of use in all ground fuels.
  • the new specification can also impose an upper limit on fuel conductivity.
  • the gauges utilized to measure volumes in bulk fuel tanks can be affected by the conductivity of the fuel. Many of these volume measuring instruments take into consideration the dielectric constant of the fuel when measuring fuel tank volumes. The effect of an over conductive fuel can impede the function of these devices resulting in erroneous volume readings and possible over filling of fuel tanks. For the reasons described, it would be very beneficial to be able to correct problems associated with fuels having excessive levels of conductivity.
  • the present invention describes the use of fuel additives specifically matched to alleviate or correct excess conductivity in fuels.
  • the conductivity control is achieved by the use of Conductivity Correcting Additives.
  • the Conductivity Correcting Additives can have a retarding affect on the conductivity enhancement by fuel conductivity additives.
  • the present invention utilizes additive chemistries which on their own perform to meet their intended purpose, but when combined in the desired manner allow for the diminishment of excess conductivity in the fuel without adversely affecting other fuel properties.
  • the invention utilizes the unexpected interaction between Conductivity Correcting Additives and Conductivity Additives to correct high levels of conductivity in fuels.
  • Suitable compositions that can serve as a Conductivity Correcting Additive are components derived from chemical families that include: long chain fatty acid, derivatives of such fatty acids include, but not limited to, salts (both mineral and organic), amides and esters; polymeric analogs of organic acids known as dimer / trimer acids, derivatives of such polymeric analogs include, but not limited to, salts (both mineral and organic), amides and esters; and poly and alkyl amines (which are generally known as "filming amines”) and their derivatives such as amides, salts, and oxyalkylates.
  • R 1 can be alkyl - linear, branched, saturated, unsaturated, C 1-40 , aromatic, cyclic, polycyclic;
  • R 2 can be alkyl - linear, branched, saturated, unsaturated, C 1-40 , aromatic, cyclic, polycyclic, H, or analogs of R 3 - NH 2 or R 3 -OH;
  • R 3 can be alkyl - linear, branched, saturated, unsaturated, C M0 , aromatic, cyclic, polycyclic, repeating units based on ethylene, propylene or butylene oxide, or repeating units based on ethylene, propylene or butylene aziridine;
  • R 4 can be alkyl - linear, branched, saturated, unsaturated, C 1-40 , aromatic, cyclic, polycyclic, H, R 3 -OH, alcohol, ester, or an acid;
  • X can be O, NH, NR 1 , S, or P; Y can be 1 - 6; and
  • Z can be organic functional groups ( H, alcohols, aldehydes, ketones, acids, esters, amides, amines, imides, ester amines, amido amines, imido amines, imidazolines, carbamates, ureas, imines, and enamines) present on the R 1 hydrocarbon backbone.
  • organic functional groups H, alcohols, aldehydes, ketones, acids, esters, amides, amines, imides, ester amines, amido amines, imido amines, imidazolines, carbamates, ureas, imines, and enamines
  • Conductivity Correcting Additive a condensate product of an alcohol amine and an organic acid, and alkoxylates of dimerized trimerized fatty acids.
  • a C 18 fatty acid however, other chain length fatty acids (C 8 - C 22 ) are also applicable.
  • the alcohol amine depicted is ethanol amine, although other alcohol amines such as di ethanol amine and tri ethanol amine can be utilized.
  • the carbon spacer instead of ethylene can be propylene or butylene. The ratio of amide to ester can vary depending of process conditions.
  • Dimerized / Trimerized fatty acids are generally described as a mixture of products derived from reactions of unsaturated fatty acids. Chemistries involved in coupling of these acids are known as 2+2, Ene, and Dials Alder reactions. These complex mixtures can subsequently be reacted with ethylene glycol or ethylene oxide to produce the desired Conductivity Correcting Additive.
  • a Conductivity Correcting Additive can address both pipeline and tank constraint issues by directly being injection either into the tanks or into a pipeline.
  • the Conductivity Correcting Additive can be handled in the customary fashion as other additives currently used in fuels.
  • a method of decreasing the conductivity of a hydrocarbon fuel or solvent by metering into the fuel, a suitable Conductivity Correcting Additive can be practiced by adding to the fuel a mixture of Conductivity Correcting Additive and conductivity additive, or by adding to the fuel in succession, the conductivity additive and the Conductivity Correcting Additive.
  • the conductivity and Conductivity Correcting Additive additives can be added in any order, and at any point in the fuel production and handling process. That is, for example, the conductivity additive can be added at a refinery and the Conductivity Correcting Additive subsequently added at a terminal or even at a fueling rack.
  • Another example is the blending of two or more fuels where one fuel contains a conductivity additive and another contains a Conductivity Correcting Additive.
  • a further example is the addition to a fuel a single or multi component formulation comprising a conductivity additive and another single or multi component formulation comprising a Conductivity Correcting Additive.
  • the Conductivity Correcting Additive in the formulation is specifically chosen to be present in the fuel oil composition in an amount effective to improve the desired fuel properties.
  • the Conductivity Correcting Additive can be added separately to the fuel in amounts from 1 to 10,000 mg/1 of fuel. It can also be added as part of a conductivity / Conductivity Correcting Additive package, or as part of another multi component package and can eventually be present in the fuel between 1 to 1000 mg/1.
  • tolutriazole and derivatives thereof; 4,5,6,7-tetrahydrobenzotriazole and 5,5'- methylenebisbenzotriazole, Mannich bases of benzotriazole or tolutriazole, e.g.
  • Low temperature oper ability / cold flow additives are used in fuels to enable users and operators to handle the fuel at temperatures below which the fuel would normally cause operational problems.
  • Distillate fuels such as diesel fuels tend to exhibit reduced flow at low temperatures due in part to formation of waxy solids in the fuel.
  • the reduced flow of the distillate fuel affects transport and use of the distillate fuels in refinery operations and internal combustion engine. This is a particular problem during the winter months and especially in northern regions where the distillates are frequently exposed to temperatures at which solid formation begins to occur in the fuel, generally known as the cloud point (ASTM D 2500) or wax appearance point (ASTM D 3117).
  • waxy solids in the fuel will in time essentially prevent the ability of the fuel to flow, thus plugging transport lines such as refinery piping and engine fuel supply lines.
  • transport lines such as refinery piping and engine fuel supply lines.
  • wax precipitation and gelation can cause the engine fuel filters to plug resulting in engine inoperability.
  • Example of Low temperature operability / cold flow marketed by Innospec Inc. of Newark, Delaware is PPD 8500.
  • Corrosion Inhibitors are a group of additives which are utilized to prevent or retard the detrimental interaction of fuel and materials present in the fuel with engine components.
  • the additives used to impart corrosion inhibition to fuels generally also function as lubricity improvers. Examples of Corrosion Inhibitors marketed by Innospec Inc. of Newark, Delaware are DCI 6A, and DCI 4A.
  • Cetane Improvers are used to improve the combustion properties of middle distillates.
  • fuel ignition in diesel engines is achieved through the heat generated by air compression, as a piston in the cylinder moves to reduce the cylinder volume during the compression stroke.
  • the air is first compressed, then the fuel is injected into the cylinder; as the fuel contacts the heated air, it vaporizes and finally begins to burn as the self-ignition temperature is reached. Additional fuel is injected during the compression stroke and the fuel burns almost instantaneously, once the initial flame has been established. Thus, a period of time elapses between the beginning of fuel injection and the appearance of a flame in the cylinder.
  • Detergents are additives which can be added to hydrocarbon fuels to prevent or reduce deposit formation, or to remove or modify formed deposits. It is commonly known that certain fuels have a propensity to form deposits which may cause fuel injectors to clog and affect fuel injector spray patterns. The alteration of fuel spray patterns may cause non uniform distribution and/or incomplete atomization of fuel resulting in poor fuel combustion. The accumulation of deposits is characterized by overall poor drivability including hard starting, stalls, rough engine idle and stumbles during acceleration. Furthermore if deposit build up is allowed to proceed unchecked, irreparable harm may result which may require replacement or non-routine maintenance. In extreme cases, irregular combustion could cause hot spots on the pistons which can resulted in total engine failure requiring a complete engine overhaul or replacement. Examples of Detergents marketed by Innospec Inc. of Newark, Delaware are DDA 350, and OMA 580.
  • Lubricity improver's increase the lubricity of the fuel, which impacts the ability of the fuel to prevent wear on contacting metal surfaces in the engine.
  • a potential detrimental result of poor lubricating ability of the fuel can be premature failure of engine components (for example, fuel injection pumps).
  • Lubricity Improvers marketed by Innospec Inc. of Newark, Delaware are OLI 9070.x, and OLI9101.X.
  • Fuel lubricity is the ability of the fuel to prevent wear on contacting metal surfaces. Certain diesel engine designs rely on fuel as a lubricant for their internal moving components. The problem of poor lubricity in these fuels is likely to be exacerbated by future engine system developments aimed at further decreasing emissions.
  • Fuel lubricity requirements can be achieved by the use of lubricity additives.
  • Dyes and Markers are materials used by the EPA (Environmental Protection Agency) and the IRS (Internal Revenue Service) to monitor and track fuels. Since 1994 the principle use for dyes in fuel is attributed to the federally mandated dying or marking of untaxed "off-road" middle distillate fuels as defined in the Code of Federal Regulations, Title 26, Part 48.4082-1(26 CFR 48.4082-1). Dyes are also used in Aviation Gasoline; Red, Blue and Yellow dyes denote octane grade in Avgas. Markers are used to identify, trace or mark petroleum products without imparting visible color to the treated product. One of the main applications for markers in fuels is in Home Heating Oil. Examples of Dyes and Markers marketed by Innospec Inc. of Newark, Delaware are Oil Red B4 and Oil Color IAR.
  • Anti-Icing Additives are mainly used in the aviation industry and in cold climates. They work by combining with any free water and lowering the freeze point of the mixture that no ice crystals are formed. Examples of Anti-Icing additives marketed by Innospec Inc. of Newark, Delaware are Dri-Tech and DEGME.
  • Demulsifiers / Anti Haze additives are mainly added to the fuel to combat cloudiness problems which maybe caused by the distribution of water in a wet fuel by dispersant used in stability packages.
  • Examples of Demulsifiers / Anti Haze additives marketed by Innospec Inc. of Newark, Delaware are DDH 10 and DDH 20.
  • Antioxidants are used to inhibit the degradation of fuels by interaction of the fuel with atmospheric oxygen. This process is known as "Oxidative Instability". The oxidation of the fuel results in the formation of alcohols, aldehydes, ketones, carboxylic acids and further reaction products of these functional groups, some of which may yield polymers. Antioxidants function mainly by interrupting free radical chain reactions thus inhibiting peroxide formation and fuel degradation. Examples of Antioxidants additives marketed by Innospec Inc. of Newark, Delaware are AO 37 and AO 29.
  • Metal Deactivators are chelating agents that form stable complexes with specific metals. Certain metals (Copper, Zinc) are very detrimental to fuel stability as they catalyze oxidation processes resulting in fuel degradation (increase in gums, polymers, color, and acidity). Examples of Metal Deactivator marketed by Innospec Inc. of Newark, Delaware is DMD.
  • Biocides are used to control microorganisms such as bacteria and fungi (yeasts, molds) which can contaminate fuels. Biological problems are generally a function of fuel system cleanliness, specifically water removal from tanks and low point in the system. Example of Biocide marketed by Innospec Inc. of Newark, Delaware is 6500.
  • Thermal Stabilizers are additives which help prevent the degradation of fuel upon exposure to elevated temperatures. Fuel during its use cycle is exposed to varying thermal stresses. These stresses are: 1) In storage - where temperatures are low to moderate, 0 to 49°C (32 to 120°F), for long periods of time, 2) In vehicle fuel systems- where temperatures are higher depending on ambient temperature and engine system, 60 to 70°C (140 to 175°F), but the fuel is subjected to these higher temperatures for shorter periods of time than in normal storage, and 3) In (or near) the engine - where temperatures reach temperatures as high as 15O 0 C (302 0 F) before injection or recycling, but for even shorter periods of time. Thermal stability additives protect the fuel uniformity / stability against these types of exposures. Examples of Thermal Stabilizers marketed by Innospec Inc. of Newark, Delaware are FOA 3 and FOA 6.
  • the invention fully discloses the use of Conductivity Correcting Additive additives to control over conductivity of fuels, by selecting and properly matching a Conductivity Correcting Additive to a conductivity additive thereby utilizing their interaction to minimize fuel conductivity in order to meet fuel or operational specifications.
  • Conductivity of the fuel is measured by using procedures outlined in ASTM D-2624 Standard Test Methods for Electrical Conductivity of Aviation and Distillate Fuels. The complete method is incorporated herein by reference.
  • Conductivity Correcting Additive Screen The base line conductivity of the fuel containing 10 mg/1 of conductivity additive was measured. The additives selected from the General Additive Survey were then dosed into a high conductivity fuel (10 mg/1 of conductivity additive) at amounts equivalent to 200 mg/1, and 400 mg/1. The conductivity of the fuel containing conductivity additive and Conductivity Correcting Additive was then evaluated.
  • Static Dissipater I (Stadis ® 425): The effect on conductivity upon combining a Conductivity Correcting Additive with Stadis ® 425 was evaluated.
  • the conductivity of the fuel with 10 mg/1 of Stadis ® 425 along with 200 and 400 mg/1 of Conductivity Correcting Additive is depicted in Figure 1.
  • Static Dissipater II (Tolad 3514): The affect on conductivity upon combining a Conductivity Correcting Additive with Tolad 3514 was evaluated. The conductivity of the fuel with 10 mg/1 of Tolad 3514 along with 200 and 400 mg/1 of Conductivity Correcting Additive is depicted in Figure 2.
  • compositions and methods disclosed and claimed herein can be manufactured and executed without undue experimentation in light of the present disclosure. While the compositions and methods of this invention have been described in terms of specific embodiments, it will be apparent to those of skill in the art that variations may be applied to the compositions and/or methods and in the steps or in the sequence of steps of the methods described herein without departing from the concept, spirit and scope of the invention. More specifically, it will be apparent that certain compositions which are chemically related can be substituted for the compositions described herein while the same or similar results would be achieved. All such similar substitutes and modifications apparent to those skilled in the art are deemed to be within the spirit, scope and concept of the invention as defined by the appended claims.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

L'invention concerne des procédés servant à corriger des compositions de combustibles ayant une conductivité excessive. Les compositions de combustibles comprennent un composant à base de pétrole, un additif de conductivité et un additif de correction de la conductivité.
PCT/US2006/035589 2006-09-12 2006-09-12 Compositions d'additifs servant à corriger un surdosage d'additifs de conductivité dans des combustibles dérivés du pétrole WO2008033130A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/US2006/035589 WO2008033130A1 (fr) 2006-09-12 2006-09-12 Compositions d'additifs servant à corriger un surdosage d'additifs de conductivité dans des combustibles dérivés du pétrole
PCT/US2006/037255 WO2008033145A2 (fr) 2006-09-12 2006-09-27 Compositions d'additifs pour corriger un traitement excessif d'additifs de conductivité dans des carburants à base de pétrole

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2006/035589 WO2008033130A1 (fr) 2006-09-12 2006-09-12 Compositions d'additifs servant à corriger un surdosage d'additifs de conductivité dans des combustibles dérivés du pétrole

Publications (1)

Publication Number Publication Date
WO2008033130A1 true WO2008033130A1 (fr) 2008-03-20

Family

ID=39184069

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US2006/035589 WO2008033130A1 (fr) 2006-09-12 2006-09-12 Compositions d'additifs servant à corriger un surdosage d'additifs de conductivité dans des combustibles dérivés du pétrole
PCT/US2006/037255 WO2008033145A2 (fr) 2006-09-12 2006-09-27 Compositions d'additifs pour corriger un traitement excessif d'additifs de conductivité dans des carburants à base de pétrole

Family Applications After (1)

Application Number Title Priority Date Filing Date
PCT/US2006/037255 WO2008033145A2 (fr) 2006-09-12 2006-09-27 Compositions d'additifs pour corriger un traitement excessif d'additifs de conductivité dans des carburants à base de pétrole

Country Status (1)

Country Link
WO (2) WO2008033130A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2609091A (en) * 2021-07-16 2023-01-25 Innospec Ltd Compositions, and methods and uses relating thereto

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2977895B1 (fr) 2011-07-12 2015-04-10 Total Raffinage Marketing Compositions d'additifs ameliorant la stabilite et les performances moteur des gazoles non routiers

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5755834A (en) * 1996-03-06 1998-05-26 Exxon Chemical Patents Inc. Low temperature enhanced distillate fuels
US6200359B1 (en) * 1998-12-23 2001-03-13 Shell Oil Company Fuel oil composition
US6383237B1 (en) * 1999-07-07 2002-05-07 Deborah A. Langer Process and apparatus for making aqueous hydrocarbon fuel compositions, and aqueous hydrocarbon fuel compositions
US6592638B2 (en) * 2000-03-16 2003-07-15 Clariant Gmbh Mixtures of carboxylic acids, their derivatives and hydroxyl-containing polymers and their use for improving the lubricating effect of oils
US6793695B2 (en) * 2000-03-16 2004-09-21 The Lubrizol Corporation Anti-static lubricity additive ultra-low sulfur diesel fuels

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7597725B2 (en) * 2002-10-04 2009-10-06 Infineum International Ltd. Additives and fuel oil compositions

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5755834A (en) * 1996-03-06 1998-05-26 Exxon Chemical Patents Inc. Low temperature enhanced distillate fuels
US6200359B1 (en) * 1998-12-23 2001-03-13 Shell Oil Company Fuel oil composition
US6383237B1 (en) * 1999-07-07 2002-05-07 Deborah A. Langer Process and apparatus for making aqueous hydrocarbon fuel compositions, and aqueous hydrocarbon fuel compositions
US6592638B2 (en) * 2000-03-16 2003-07-15 Clariant Gmbh Mixtures of carboxylic acids, their derivatives and hydroxyl-containing polymers and their use for improving the lubricating effect of oils
US6793695B2 (en) * 2000-03-16 2004-09-21 The Lubrizol Corporation Anti-static lubricity additive ultra-low sulfur diesel fuels

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2609091A (en) * 2021-07-16 2023-01-25 Innospec Ltd Compositions, and methods and uses relating thereto
GB2609091B (en) * 2021-07-16 2024-05-08 Innospec Ltd Compositions, and methods and uses relating thereto

Also Published As

Publication number Publication date
WO2008033145A2 (fr) 2008-03-20
WO2008033145A3 (fr) 2008-10-16

Similar Documents

Publication Publication Date Title
US20080163542A1 (en) Synergistic fuel composition for enhancing fuel cold flow properties
CN102149797B (zh) 具有改良的低温性能的燃料组合物
EP1328609B1 (fr) Carburants diesel a teneur en soufre ultra-faible avec additif lubrifiant anti-statique
AU2006350703B2 (en) Stabilizer compositions for blends of petroleum and renewable fuels
EP2171021B2 (fr) Utilisation d'un améliorant de la conductivité dans une composition d'hydrocarbures
AU2001247349A1 (en) Anti-static lubricity additive ultra-low sulfur diesel fuels
AU2017217783A1 (en) Fuel additives
PH12014501374B1 (en) Additive compositions that improve the lacquering resistance of superior quality diesel or biodiesel fuels
US8821594B2 (en) Synergistic additive composition for petroleum fuels
CN101735867A (zh) 用于燃料的提高电导率的添加剂
US20100146845A1 (en) Additive compositions for correcting overtreatment of conductivity additives in petroleum fuels
WO2008033130A1 (fr) Compositions d'additifs servant à corriger un surdosage d'additifs de conductivité dans des combustibles dérivés du pétrole
US6379530B1 (en) Polyisobutene substituted succinimides
WO2008054368A9 (fr) Composition de type additif synergique pour les combustibles pétroliers
KR20090045231A (ko) 석유와 재생가능한 연료의 블렌드를 위한 안정화제 조성물
Kulinowski et al. | Gasoline and Diesel Fuel Additives
EP1942175B1 (fr) Composition d'additifs

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 06814557

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 06814557

Country of ref document: EP

Kind code of ref document: A1

点击 这是indexloc提供的php浏览器服务，不要输入任何密码和下载