WO2007114256A1 - Organic electroluminescence multicolor display panel - Google Patents
Organic electroluminescence multicolor display panel Download PDFInfo
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- WO2007114256A1 WO2007114256A1 PCT/JP2007/056875 JP2007056875W WO2007114256A1 WO 2007114256 A1 WO2007114256 A1 WO 2007114256A1 JP 2007056875 W JP2007056875 W JP 2007056875W WO 2007114256 A1 WO2007114256 A1 WO 2007114256A1
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- WIPO (PCT)
- Prior art keywords
- organic
- layer
- display panel
- organic electroluminescent
- multicolor display
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- 238000005401 electroluminescence Methods 0.000 title claims abstract description 10
- 239000000758 substrate Substances 0.000 claims abstract description 54
- 238000000149 argon plasma sintering Methods 0.000 claims abstract description 53
- 239000011368 organic material Substances 0.000 claims abstract description 52
- 239000003086 colorant Substances 0.000 claims abstract description 11
- 230000000694 effects Effects 0.000 claims abstract description 9
- 239000010408 film Substances 0.000 claims description 36
- 239000002245 particle Substances 0.000 claims description 35
- 238000002347 injection Methods 0.000 claims description 11
- 239000007924 injection Substances 0.000 claims description 11
- 230000005525 hole transport Effects 0.000 claims description 10
- 230000004888 barrier function Effects 0.000 claims description 8
- 239000010409 thin film Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 230000001747 exhibiting effect Effects 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 153
- 239000000463 material Substances 0.000 description 15
- 239000011521 glass Substances 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000007789 sealing Methods 0.000 description 9
- 150000002894 organic compounds Chemical class 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
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- 238000007740 vapor deposition Methods 0.000 description 4
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- 238000005259 measurement Methods 0.000 description 3
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- 238000002834 transmittance Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XBIUWALDKXACEA-UHFFFAOYSA-N 3-[bis(2,4-dioxopentan-3-yl)alumanyl]pentane-2,4-dione Chemical compound CC(=O)C(C(C)=O)[Al](C(C(C)=O)C(C)=O)C(C(C)=O)C(C)=O XBIUWALDKXACEA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
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- 230000031700 light absorption Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000000560 X-ray reflectometry Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
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- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
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- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/875—Arrangements for extracting light from the devices
- H10K59/877—Arrangements for extracting light from the devices comprising scattering means
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/875—Arrangements for extracting light from the devices
- H10K59/876—Arrangements for extracting light from the devices comprising a resonant cavity structure, e.g. Bragg reflector pair
Definitions
- the present invention uses an organic compound exhibiting electroluminescence (hereinafter also referred to as EL) that emits light by current injection, and includes an organic EL layer that is made of an organic EL material.
- EL organic compound exhibiting electroluminescence
- the present invention relates to an organic EL multicolor display panel that also has multiple elements.
- an organic EL element using an organic compound material is a current injection type element having diode characteristics, and emits light with a luminance corresponding to the amount of current.
- a display panel has been developed by arranging multiple organic EL elements that emit two or more colors in a matrix.
- each of the organic EL elements includes a transparent anode as a first electrode, a plurality of organic material layers including an organic light emitting layer, and a metal negative electrode as a second electrode on a glass substrate as a display surface (observer side). It has a structure in which poles are sequentially stacked (bottom emission type).
- a hole transporting functional layer hole injection layer, hole transporting layer
- an electron transporting functional layer electron injection layer, electron transporting layer on the cathode side.
- a top emission type organic EL display panel is also known in which the display surface is reversed and the first electrode is a metal electrode and the second electrode is a transparent electrode.
- the one that emits light from the opposite side of the substrate is the top emission type organic EL panel and the one that emits light from the substrate side is the bottom emission type organic EL panel and the one that is opposite the substrate side and the substrate side.
- An organic EL element in which the thickness of the ITO anode and the plurality of organic material layers is variously set so that the desired wavelength of the light obtained from the organic light-emitting layer becomes a peak wavelength is a multicolor light-emitting display panel (full-color, multi-color).
- a multicolor light-emitting display panel full-color, multi-color.
- This OLED multicolor display panel In the channel, a transparent electrode 3 made of an anode such as ITO, a hole transport layer 42 made of an organic compound material, and organic light emitting layers 43B, 43, which are sequentially laminated on a transparent substrate 2 made of glass or the like.
- each individual organic EL element is a structure in which the surface of the glass substrate is roughened (see Patent Document 1), and scattering particles are dispersed in a binder polymer.
- Patent Document 2 A structure (refer to Patent Document 2) is proposed!
- a region where reflection and refraction angle are disturbed with respect to light emitted from the light emitting element is provided, and the region is composed of a scattering layer containing fine particles and a binder.
- Patent Document 1 Japanese Patent Laid-Open No. 9-63767
- Patent Document 2 Japanese Patent Publication No. 03Z026357
- the thickness of the transparent anode and the plurality of organic material layers is emitted so that the desired wavelength of light obtained from the organic light emitting layer becomes the peak wavelength for each organic EL element.
- Each color is set separately. Since the film thickness of the organic material layer changes for each luminescent color, even with the same organic material, a vapor deposition device is also required for each luminescent color, requiring a film formation process that coats the organic material with a shadow mask, which is complicated. Become.
- the present invention provides an example of providing an organic EL multicolor display panel that is easy to manufacture.
- the organic EL multicolor display panel of the present invention includes a substrate and a plurality of organic EL elements arranged on the substrate and exhibiting two or more colors of emitted light, each of the organic EL elements being on the substrate side
- An organic EL multicolor display panel comprising an organic material layer and a second electrode, disposed on the side from which the emitted light is extracted so that the emitted light is transmitted in common to the plurality of organic EL elements.
- a light scattering layer having a light scattering effect.
- the feature that the optical interference effect is greatly reduced by the presence of the light scattering structure is fully activated, and the material / film thickness between the light scattering structure and the light emitting layer is reduced.
- a structure in which the material thickness between the light emitting layer and the reflective electrode is aligned regardless of the emission color is possible.
- each luminescent color is a commonly used material, it can be formed at once without separately coating the organic film for each color. This reduces the number of vapor deposition devices, eliminates the need for mask alignment with high-definition pixels, and improves the material utilization effect.
- FIG. 1 is a schematic partial cross-sectional view showing an organic EL multicolor display panel.
- FIG. 2 is a schematic partial sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
- FIG. 3 is a schematic partial cross-sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
- FIG. 4 is a schematic partial sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
- FIG. 5 is a schematic partial sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
- FIG. 6 is a schematic partial sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
- FIG. 7 is a schematic partial sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
- an organic EL multicolor display panel in which a hole transport layer is formed of a common organic compound material as an organic material layer regardless of the emission color.
- FIG. 2 is a schematic partially enlarged cross-sectional view of an organic EL multicolor display panel.
- This organic EL multicolor display panel also has a plurality of organic EL element powers, and each organic EL element is sequentially laminated on a substrate 12 (for example, a transparent substrate such as glass), and the first electrode 13 (for example, ITO or the like).
- An electron transport layer (common layer) 44) made of an organic compound material and a second electrode 15 also serve as a force.
- a sealing film (not shown) made of SiN or the like is formed on the second electrode 15.
- Each organic EL element is shielded from the outside air.
- the transparent electrode 3 and the metal electrode 5 each having a parallel striping force are orthogonal to each other, and each organic EL element is arranged in parallel at the intersection.
- the organic light-emitting layers 43B, 43G, and 43R that are separately and separately laminated have different organic compound material powers that exhibit blue, green, and red with different emission colors when current is applied.
- the organic EL multicolor display panel is composed of a set of organic EL elements of blue, green and red light emission colors as one pixel, for example, in a matrix arrangement of these plural pixels.
- the hole transport layer (common layer) 42 is a common layer having a continuous constant film thickness that has the same material force as that of the adjacent organic EL element.
- the organic material layer 4 includes the hole transport layer and the electron transport layer disposed on the opposite sides with respect to the organic light emitting layers 43B, 43G, and 43R. One of them may be provided as the organic material layer 4 common layer. Furthermore, the organic material layer 4 can be provided with a hole injection layer and an electron injection layer arranged outside the hole transport layer and the electron transport layer (not shown) with respect to the organic light emitting layers 43B, 43G, and 43R, respectively. Also, at least one of them can be provided depending on the layer form.
- the organic material layer 4 common layer has the same film thickness even if it corresponds to different emission colors. That is, in the organic EL element, the organic light emitting layers 43B, 43G, and 43R have the same film thickness as the organic material layer 4 up to the electrodes.
- the light scattering layer 6 having a light scattering effect with a uniform film thickness extracts emitted light so that the emitted light is transmitted in common to the plurality of organic EL elements of the organic light emitting layers 43B, 43G, and 43R. In other words, it is commonly disposed between the first electrode 13 on the substrate 12 side and the substrate 12.
- the light scattering layer 6 has a light scattering rate of 30% or more.
- scattering rate (parallel light transmittance without light scattering layer, parallel light transmittance with light scattering layer) / (parallel light transmittance without light scattering layer). Therefore, the first electrode 13 and the organic material layer 4 of the organic EL element can be formed with a constant film thickness by the light scattering layer 6 without changing the film thickness.
- the organic EL multicolor display panel includes the substrate 12 and a plurality of organic EL elements arranged on the substrate 12 and exhibiting two or more emission colors, and each of the organic EL elements is a substrate 12 side cover.
- the first electrode 13 transparent electrode
- the organic material layer 4 hole transport layer, electron transport layer, etc.
- the second electrode. 15 metal electrode
- the light scattering layer 6 is disposed between the first electrode 13 and the substrate 12 close to the substrate 12 of the organic EL element, and the first electrode 13 and the substrate 12 are transmissive.
- the substrate 12 side force is also a bottom emission type because the emitted light is taken out.
- the organic material layers 4 from the first electrode 13 to the organic light emitting layers 43B, 43G, and 43R are respectively laminated in common to a plurality of organic EL elements and have the same film thickness.
- the organic material layer 4 from the second electrode 15 to the organic light emitting layers 43B, 43G, and 43R is shared by multiple organic EL devices. Laminated and have the same film thickness.
- the absolute value of the refractive index difference between any two adjacent layers in the organic material layer 4 is 0.25 or less.
- the transparent electrode, the charge injection layer, and the charge transport layer are in contact with each other in this order, and the refractive index of each layer of the organic material layer 4 is the charge injection layer:
- nl and the charge transport layer: n2 it is desirable to reduce the refractive index step so that the relationship satisfies the relationship I nl-n2 I ⁇ 0.25 in the wavelength region of 450 to 630 nm.
- the organic EL multicolor display panel is not limited to the bottom emission type.
- the light scattering layer 6 is formed on the main surface of the second electrode 15 far from the substrate 12 opposite to the organic material layer 4 of the organic EL element, and is transmitted through the second electrode 15.
- the second electrode 15 side force may be a top emission type from which emitted light is extracted.
- a sealing plate 16 may be overlaid on the light scattering layer 6 and fixed to the substrate with a spacer (not shown) to block each organic EL element from the outside air. .
- the light scattering layer 6 is a substrate on the side opposite to the organic material layer 4 of the organic EL element. Force placed on the main surface side of the second electrode 15 far from 12
- the sealing plate 16 has a spacer (not shown) in order to have a sealed air layer (hollow) on the second electrode 15.
- the light scattering layer 6 may be formed on the inner surface of the sealing plate 16. Further, the inner surface of the sealing plate 16 can be attached to the inner side of the light scattering layer 6 with an adhesive or the like without providing a hollow.
- An example of the light scattering layer 6 is a scattering particle-containing film in which scattering particles are dispersed in a resin.
- the scattering particles preferably have a particle size of 0.1-1 ⁇ m.
- the scattering particles are silica, titanium, alumina, etc., for example, preferably TiO.
- the organic EL multicolor display panel may be a bottom emission type in which the light scattering layers 6 are provided on both sides of the substrate 12 as shown in FIG.
- the first electrode 13 and the second electrode 15 are made transmissive, so that the substrate 12 side and the substrate side It is also possible to use a transparent organic EL panel type that extracts light to both the sealing plate 16 on the opposite side.
- Layer Can
- the low refractive index layer has a refractive index of 1.3 or less, more preferably 1.2 or less.
- the low refractive index layer preferably contains silica.
- a gas barrier disposed on the outside of the first electrode 13 with respect to the organic material layer 4 on the organic EL multicolor display panel. Can be provided.
- the gas nolia layer is a laminate of a polymer thin film and an inorganic thin film, or a high molecular thin film or an inorganic thin film.
- the light scattering layer 6 is provided. It can be a rough surface interface constituting the rough surface.
- the substrate 12 and the sealing plate 16 are ground glass, and the rough surface is used as the interface.
- the rough surface interface preferably has an average roughness Ra that satisfies the relationship d> 5 XRa (where d is the distance between the light-scattering layer 6 and the organic light-emitting layers 43B, 43G, and 43R).
- Ra (arithmetic mean roughness) is the roughness curve force.
- the length of the measurement length is extracted in the direction of the average line, the X-axis is the direction of the average line of the extracted part, and the direction of the vertical magnification is the y-axis.
- the average roughness R a is preferably in the range of lnm to l ⁇ m.
- the organic material layer 4 is arranged outside the light scattering layer 6 so as to divide a plurality of organic EL elements, and A light absorption layer having a light absorption effect can be provided.
- the light scattering layer 6 with respect to the organic material layer 4 so as to increase the color purity of light emitted from a plurality of organic EL elements.
- a color filter disposed on the outside can be provided.
- the organic EL multicolor display panel of the above-described embodiment by utilizing the feature that the influence of optical interference can be reduced by the light scattering structure, the material commonly used for each emission color can be reduced. By aligning the film thickness, the common organic material layer can be formed simultaneously without being separately applied. Panels such as full-color type with two colors, full-color type with two colors, and area power color type, and driving methods such as active drive or passive drive are selected. An organic EL panel with two or more light-emitting pixels on one panel It is effective for.
- Example l Glass substrate Z Low refractive index layer Z Scattered particle-containing film Z Transparent electrode ( ⁇ ) Z Organic light emitting layer, Reflective electrode (Al) t An organic EL panel composed of ⁇ ⁇ was prepared.
- MS51 tetramethoxysilane oligomer 25% by weight, n-butyl alcohol 30% by weight, demineralized water 15% by weight, and ethanol 30% by weight were mixed with an acid catalyst ( A small amount of aluminum acetylacetonate) was added. The mixture was stirred at 60 ° C for 3 hours and left to mature for 1 week.
- MS 51 tetramethoxysilane oligomer 30% by weight manufactured by Mitsubishi Chemical Corporation, 50% by weight of propyl alcohol, 8% by weight of demineralized water, and 12% by weight of methanol were mixed with an acid catalyst ( A small amount of aluminum acetylacetonate) and further particles containing tantalum particles with an average particle size of 20 Onm (60% weight particle size is 150-250 nm) in butyl alcohol. The dispersion was previously dispersed so that the weight percentage in it was 15% by weight. The mixture was stirred at 60 ° C for 3 hours and left to mature for 1 week. The weight percentage in the particle-containing layer was measured in the same manner as the particle size distribution in the film described above. The density when the matrix was a porous material was determined by determining the X-ray reflectivity or the refractive index.
- This coating solution was applied onto the above-mentioned low refractive index layer on the glass substrate with a dip coater, dried for 15 minutes, immersed in methanol for 5 minutes, pulled up, dried for 5 minutes, and then 15 minutes at 150 ° C. After heating, the mixture was further heated at 250 ° C. for 15 minutes to obtain a light scattering layer.
- a protective film was applied, peeled off after application, and a coating film was formed only on one side.
- the resulting scattering particle-containing film had a thickness of 600 nm, and a structure in which scattering particles overlapped in almost three steps was observed.
- the refractive index of the matrix portion of the light scattering layer was measured with a sopra ellipsometer and found to be 1.40 at a wavelength of 550 nm. Refractive index measurement was also performed using the prism coupler model 2010 of Metricon Inc. in the US, and the refractive index was 1.38 with a laser with a wavelength of 633 nm.
- the transmission loss light (scattering loss light) with respect to the parallel rays of the scattering particle-containing film was 52% at a wavelength of 550 ⁇ m.
- a spectrophotometer manufactured by HEURED Packard was used for the measurement, and a glass substrate before forming the coating film was used as a reference.
- ITO Indium Tin Oxide
- PC1 020 manufactured by Mitsubishi Chemical Co., Ltd.
- NPB naphthylpentylbenzidine
- A1Q3 aluminoquinoline complex, green luminescent dye
- the refractive index of the ITO layer was measured and found to be 2.04 (550 nm).
- the obtained EL element is a laminate of a glass substrate Z, a low refractive index layer, a film containing scattering particles, a transparent electrode (ITO), an organic light emitting layer, and a reflective electrode (A1).
- Example 2 Scattered particle-containing film Z glass substrate Z low refractive index layer Z scattered particle-containing film Z Transparent electrode (ITO), organic light emitting layer, reflective electrode (Al) t Organic EL A panel was made.
- ITO transparent electrode
- Al organic light emitting layer
- Al reflective electrode
- Example 1 an EL element was produced in exactly the same manner as in Example 1, except that dip coating was performed without applying a protective film on the back surface when the light scattering layer was applied.
- the obtained EL device is a laminate of a scattering particle-containing film Z glass substrate, a low refractive index layer, a scattering particle-containing film Z transparent electrode (ITO), and an organic light emitting layer Z reflecting electrode (A1).
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- Electroluminescent Light Sources (AREA)
Abstract
Description
明 細 書 Specification
有機エレクトロルミネセンス多色ディスプレイパネル 技術分野 Organic electroluminescent multicolor display panel
[0001] 本発明は、電流の注入によって発光するエレクトロルミネセンス(以下、 ELともいう) を呈する有機化合物を利用し、カゝかる有機 EL材料カゝらなる有機発光層を備えた有 機 EL素子の複数力もなる有機 EL多色ディスプレイパネルに関する。 The present invention uses an organic compound exhibiting electroluminescence (hereinafter also referred to as EL) that emits light by current injection, and includes an organic EL layer that is made of an organic EL material. The present invention relates to an organic EL multicolor display panel that also has multiple elements.
背景技術 Background art
[0002] 一般に、有機化合物材料を用いた有機 EL素子は、ダイオード特性を有する電流 注入型の素子であり、電流量に対応した輝度で発光する素子である。 2色以上の発 光色を呈する有機 EL素子の複数をマトリクス状に配列してディスプレイパネルが開 発されている。 In general, an organic EL element using an organic compound material is a current injection type element having diode characteristics, and emits light with a luminance corresponding to the amount of current. A display panel has been developed by arranging multiple organic EL elements that emit two or more colors in a matrix.
[0003] 例えば、有機 EL素子の各々は、表示面 (観察者側)としてのガラス基板上に、第 1 電極として透明陽極、有機発光層を含む複数の有機材料層、第 2電極として金属陰 極を、順次、積層した構造を有している(ボトムェミッション型)。また、有機材料層とし て、有機発光層を挟んだ機能層として、陽極側にホール輸送機能層 (ホール注入層 、ホール輸送層)、陰極側に電子輸送機能層(電子注入層、電子輸送層)が適宜設 けられる。また、表示面を逆にして、第 1電極を金属電極として第 2電極を透明電極と してトップェミッション型有機 ELディスプレイパネルも知られている。一般に、基板と 逆側から発光を得るものをトップェミッション型有機 ELパネルと ヽ、基板側から発 光を得るものをボトムェミッション型有機 ELパネルと ヽ、基板側と基板側の逆側の 両方に光を取り出す透明有機 ELパネルと ヽぅタイプもある。 [0003] For example, each of the organic EL elements includes a transparent anode as a first electrode, a plurality of organic material layers including an organic light emitting layer, and a metal negative electrode as a second electrode on a glass substrate as a display surface (observer side). It has a structure in which poles are sequentially stacked (bottom emission type). In addition, as an organic material layer, as a functional layer sandwiching an organic light emitting layer, a hole transporting functional layer (hole injection layer, hole transporting layer) on the anode side and an electron transporting functional layer (electron injection layer, electron transporting layer on the cathode side). ) Is set as appropriate. A top emission type organic EL display panel is also known in which the display surface is reversed and the first electrode is a metal electrode and the second electrode is a transparent electrode. In general, the one that emits light from the opposite side of the substrate is the top emission type organic EL panel and the one that emits light from the substrate side is the bottom emission type organic EL panel and the one that is opposite the substrate side and the substrate side. There are also a transparent OLED panel and a cocoon type that extract light from both.
[0004] 有機発光層から得られる光の所望の波長がピーク波長となるように ITO陽極及び 複数の有機材料層の厚みを種々設定した有機 EL素子を、多色発光ディスプレイパ ネル (フルカラー、マルチカラー)に適用すると、図 1に示すように、発光色の異なる画 素すなわち有機 EL素子に応じて、有機材料層 42の厚みをそれぞれ変化させる必要 がある。これは光学干渉の最適膜厚が発光色毎に異なる為、光学干渉で発光が弱ま つてしまうことを避け、発光効率を上げるためである。この有機 EL多色ディスプレイパ ネルにおいて、ガラスなどの透明基板 2上に順に積層された、 ITOなどカゝらなる陽極 の透明電極 3と、有機化合物材料カゝらなるホール輸送層 42と、有機発光層 43B、 43[0004] An organic EL element in which the thickness of the ITO anode and the plurality of organic material layers is variously set so that the desired wavelength of the light obtained from the organic light-emitting layer becomes a peak wavelength is a multicolor light-emitting display panel (full-color, multi-color). As shown in Fig. 1, it is necessary to change the thickness of the organic material layer 42 in accordance with pixels having different emission colors, that is, organic EL elements. This is because the optimum film thickness of the optical interference differs for each emission color, so that the light emission is prevented from being weakened by the optical interference and the light emission efficiency is increased. This OLED multicolor display panel In the channel, a transparent electrode 3 made of an anode such as ITO, a hole transport layer 42 made of an organic compound material, and organic light emitting layers 43B, 43, which are sequentially laminated on a transparent substrate 2 made of glass or the like.
G又は 43Rと、陰極の金属電極 5と、力 なる。 G or 43R, the metal electrode 5 of the cathode, and power.
[0005] また、発光効率、取り出し効率を高めるために個々の有機 EL素子単体の構造とし ては、ガラス基板の表面を荒らした構造 (特許文献 1参照)、バインダーポリマー中に 散乱粒子を分散させた構造 (特許文献 2参照例)などが提案されて!ヽる。 [0005] In addition, in order to increase the light emission efficiency and the extraction efficiency, the structure of each individual organic EL element is a structure in which the surface of the glass substrate is roughened (see Patent Document 1), and scattering particles are dispersed in a binder polymer. A structure (refer to Patent Document 2) is proposed!
[0006] 特許文献 1記載の有機 EL素子において、該一対の陽極及び陰極からなる電極の 外側に、かつ発光が放射される側に、高低差 0. 1 111以上0. 21 m以下の凹凸を 表面に有する透明又は半透明の基板を設けている。 [0006] In the organic EL device described in Patent Document 1, irregularities having an elevation difference of 0.1 111 or more and 0.21 m or less are formed on the outer side of the electrode composed of the pair of anode and cathode and on the side from which light emission is emitted. A transparent or translucent substrate on the surface is provided.
[0007] 特許文献 2記載の有機 EL素子において、透光性基板の少なくとも一方の表面上に[0007] In the organic EL element described in Patent Document 2, on at least one surface of the translucent substrate
、発光素子からの発光に対して反射、屈折角に乱れを生じさせる領域を設け、かかる 領域が微粒子とバインダーを含む散乱層から構成されている。 In addition, a region where reflection and refraction angle are disturbed with respect to light emitted from the light emitting element is provided, and the region is composed of a scattering layer containing fine particles and a binder.
特許文献 1:特開平 9— 63767号公報 Patent Document 1: Japanese Patent Laid-Open No. 9-63767
特許文献 2:特再 03Z026357号公報 Patent Document 2: Japanese Patent Publication No. 03Z026357
発明の開示 Disclosure of the invention
発明が解決しょうとする課題 Problems to be solved by the invention
[0008] 従来の有機 EL多色ディスプレイパネルでは、有機 EL素子ごとに、有機発光層から 得られる光の所望の波長がピーク波長となるように、透明陽極及び複数の有機材料 層の厚みを発光色ごとそれぞれ設定している。発光色毎に有機材料層の膜厚を変 えるため、同じ有機材料であっても、蒸着装置も発光色毎に必要となり、有機材料を シャドーマスクで塗り分ける成膜工程が必要となり、煩雑になる。 [0008] In the conventional organic EL multicolor display panel, the thickness of the transparent anode and the plurality of organic material layers is emitted so that the desired wavelength of light obtained from the organic light emitting layer becomes the peak wavelength for each organic EL element. Each color is set separately. Since the film thickness of the organic material layer changes for each luminescent color, even with the same organic material, a vapor deposition device is also required for each luminescent color, requiring a film formation process that coats the organic material with a shadow mask, which is complicated. Become.
[0009] しかし、先行技術では、光散乱構造の能力を十分には発揮できては 、な 、。 However, in the prior art, the ability of the light scattering structure cannot be fully exhibited.
[0010] そこで本発明は、製造が簡単な有機 EL多色ディスプレイパネルを提供することが 一例として挙げられる。 [0010] Therefore, the present invention provides an example of providing an organic EL multicolor display panel that is easy to manufacture.
課題を解決するための手段 Means for solving the problem
[0011] 本発明の有機 EL多色ディスプレイパネルは、基板と前記基板上に配置されかつ 2 色以上の発光色を呈する複数の有機 EL素子とを含み、前記有機 EL素子の各々が 前記基板側から順に積層された第 1電極、少なくとも有機発光層を含む積層された 有機材料層、及び第 2電極からなる、有機 EL多色ディスプレイパネルであって、 前記複数の有機 EL素子に共通して発光光が透過するように前記発光光が取り出 される側に配置されかつ光散乱効果を有する光散乱層を有することを特徴とする。 [0011] The organic EL multicolor display panel of the present invention includes a substrate and a plurality of organic EL elements arranged on the substrate and exhibiting two or more colors of emitted light, each of the organic EL elements being on the substrate side The first electrode laminated in order from the laminated, including at least the organic light emitting layer An organic EL multicolor display panel comprising an organic material layer and a second electrode, disposed on the side from which the emitted light is extracted so that the emitted light is transmitted in common to the plurality of organic EL elements. And a light scattering layer having a light scattering effect.
[0012] 以上の構成によれば、光散乱構造が存在することにより光学干渉の効果が大きく低 減されるという特徴を十分に活力ゝして、光散乱構造—発光層間の材料 ·膜厚や、発 光層と反射性電極の間の材料'膜厚、を発光色に関係なく揃えるという構造が可能と なる。 [0012] According to the configuration described above, the feature that the optical interference effect is greatly reduced by the presence of the light scattering structure is fully activated, and the material / film thickness between the light scattering structure and the light emitting layer is reduced. Thus, a structure in which the material thickness between the light emitting layer and the reflective electrode is aligned regardless of the emission color is possible.
[0013] つまり、各発光色、共通に使う材料であれば、色毎に有機膜を塗り分けることなぐ 一度に成膜することができる。これにより、蒸着装置の数が減らせ、高精細画素への マスク合わせも不要となり、材料の利用効果も上がる。 [0013] That is, as long as each luminescent color is a commonly used material, it can be formed at once without separately coating the organic film for each color. This reduces the number of vapor deposition devices, eliminates the need for mask alignment with high-definition pixels, and improves the material utilization effect.
図面の簡単な説明 Brief Description of Drawings
[0014] [図 1]有機 EL多色ディスプレイパネルを示す概略部分断面図である。 FIG. 1 is a schematic partial cross-sectional view showing an organic EL multicolor display panel.
[図 2]本発明による他の実施形態の有機 EL多色ディスプレイパネルを示す概略部分 断面図である。 FIG. 2 is a schematic partial sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
[図 3]本発明による他の実施形態の有機 EL多色ディスプレイパネルを示す概略部分 断面図である。 FIG. 3 is a schematic partial cross-sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
[図 4]本発明による他の実施形態の有機 EL多色ディスプレイパネルを示す概略部分 断面図である。 FIG. 4 is a schematic partial sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
[図 5]本発明による他の実施形態の有機 EL多色ディスプレイパネルを示す概略部分 断面図である。 FIG. 5 is a schematic partial sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
[図 6]本発明による他の実施形態の有機 EL多色ディスプレイパネルを示す概略部分 断面図である。 FIG. 6 is a schematic partial sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
[図 7]本発明による他の実施形態の有機 EL多色ディスプレイパネルを示す概略部分 断面図である。 FIG. 7 is a schematic partial sectional view showing an organic EL multicolor display panel according to another embodiment of the present invention.
符号の説明 Explanation of symbols
[0015] 4 有機材料層 [0015] 4 Organic material layer
6 光散乱層 6 Light scattering layer
12 基板 13 第 1電極 12 Board 13 First electrode
15 第 2電極 15 Second electrode
42 ホール輸送層 42 Hole transport layer
43B、43G、43R 有機発光層 43B, 43G, 43R organic light emitting layer
44 電子輸送層 44 Electron transport layer
発明を実施するための形態 BEST MODE FOR CARRYING OUT THE INVENTION
[0016] 本発明による有機 EL素子及びその製造方法の実施形態を図面を参照しつつ説明 する。 Embodiments of an organic EL device and a method for manufacturing the same according to the present invention will be described with reference to the drawings.
[0017] 第 1の実施形態では、有機材料層としてホール輸送層が発光色によらず共通の有 機化合物材料で形成した有機 EL多色ディスプレイパネルを説明する。 In the first embodiment, an organic EL multicolor display panel will be described in which a hole transport layer is formed of a common organic compound material as an organic material layer regardless of the emission color.
[0018] 図 2は有機 EL多色ディスプレイパネルの概略部分拡大断面図を示す。この有機 E L多色ディスプレイパネルは複数の有機 EL素子力もなり、各々の有機 EL素子は、基 板 12 (例えばガラスなどの透明基板)上に順に積層された、第 1電極 13 (例えば ITO などカゝらなる陽極の透明電極)と、有機材料層 4 (有機化合物材料カゝらなるホール輸 送層(共通層) 42や、有機化合物材料カゝらなる有機発光層 43B、 43G又は 43Rや、 有機化合物材料からなる電子輸送層(共通層) 44)と、第 2電極 15 (例えば陰極の金 属電極)と、力もなる。また、第 2電極 15の上には SiN等からなる封止膜(図示せず) FIG. 2 is a schematic partially enlarged cross-sectional view of an organic EL multicolor display panel. This organic EL multicolor display panel also has a plurality of organic EL element powers, and each organic EL element is sequentially laminated on a substrate 12 (for example, a transparent substrate such as glass), and the first electrode 13 (for example, ITO or the like). Transparent electrode of the anode) and organic material layer 4 (hole transport layer (common layer) 42 which is an organic compound material), organic light emitting layer 43B, 43G or 43R, which is an organic compound material, An electron transport layer (common layer) 44) made of an organic compound material and a second electrode 15 (for example, a metal electrode as a cathode) also serve as a force. Further, a sealing film (not shown) made of SiN or the like is formed on the second electrode 15.
4 Four
が形成されており、各有機 EL素子は外気カゝら遮断されている。それぞれが平行スト ライプ力 なる透明電極 3及び金属電極 5は互いに直交しており、それらの交点に各 有機 EL素子が並設されて 、る。 Each organic EL element is shielded from the outside air. The transparent electrode 3 and the metal electrode 5 each having a parallel striping force are orthogonal to each other, and each organic EL element is arranged in parallel at the intersection.
[0019] 独立して別個に積層された有機発光層 43B、 43G、 43Rはそれぞれ電流印加時 に異なる発光色の青、緑、赤を呈する異なる有機化合物材料力もなつている。このよ うに有機 EL多色ディスプレイパネルは、青、緑及び赤の発光色の有機 EL素子の組 を 1つの画素として、例えば、これら複数画素のマトリクス配列にて構成されている。 [0019] The organic light-emitting layers 43B, 43G, and 43R that are separately and separately laminated have different organic compound material powers that exhibit blue, green, and red with different emission colors when current is applied. In this way, the organic EL multicolor display panel is composed of a set of organic EL elements of blue, green and red light emission colors as one pixel, for example, in a matrix arrangement of these plural pixels.
[0020] ホール輸送層(共通層) 42は、隣接する有機 EL素子の同一材料力もなる連続した 一定膜厚を有する共通層である。 [0020] The hole transport layer (common layer) 42 is a common layer having a continuous constant film thickness that has the same material force as that of the adjacent organic EL element.
[0021] このように、有機材料層 4は有機発光層 43B、 43G、 43Rに関して互いに反対側に 配置されたホール輸送層及び電子輸送層を含むが、 2層タイプの場合は少なくとも 一方を有機材料層 4共通層として備えていればよい。さらに、有機材料層 4は有機発 光層 43B、 43G、 43Rに関してそれぞれホール輸送層及び電子輸送層(図示せず) の外側に配置されたホール注入層及び電子注入層を設けることができ、これらも積 層形態によって少なくとも一方を設けることができる。 As described above, the organic material layer 4 includes the hole transport layer and the electron transport layer disposed on the opposite sides with respect to the organic light emitting layers 43B, 43G, and 43R. One of them may be provided as the organic material layer 4 common layer. Furthermore, the organic material layer 4 can be provided with a hole injection layer and an electron injection layer arranged outside the hole transport layer and the electron transport layer (not shown) with respect to the organic light emitting layers 43B, 43G, and 43R, respectively. Also, at least one of them can be provided depending on the layer form.
[0022] 有機材料層 4共通層により、 ヽずれの発光色に対応しても同一膜厚を有するように なる。すなわち、有機 EL素子において、有機発光層 43B、 43G、 43R力も電極まで 有機材料層 4を同一膜厚を有する。 [0022] The organic material layer 4 common layer has the same film thickness even if it corresponds to different emission colors. That is, in the organic EL element, the organic light emitting layers 43B, 43G, and 43R have the same film thickness as the organic material layer 4 up to the electrodes.
[0023] 一様膜厚の光散乱効果を有する光散乱層 6は、有機発光層 43B、 43G、 43Rの複 数の有機 EL素子に共通して発光光が透過するように発光光が取り出される側すな わち基板 12側の第 1電極 13及び基板 12の間に、共通して、配置されている。光散 乱層 6は 30%以上の光散乱率を有する。ただし、散乱率 = (光散乱層を備えない場 合の平行光線透過率一光散乱層を備える場合の平行光線透過率) / (光散乱層を 備えない場合の平行光線透過率)である。従って、光散乱層 6によって、有機 EL素 子の第 1電極 13、有機材料層 4はその膜厚を変化させる必要はなく一定膜厚で形成 することができる。 [0023] The light scattering layer 6 having a light scattering effect with a uniform film thickness extracts emitted light so that the emitted light is transmitted in common to the plurality of organic EL elements of the organic light emitting layers 43B, 43G, and 43R. In other words, it is commonly disposed between the first electrode 13 on the substrate 12 side and the substrate 12. The light scattering layer 6 has a light scattering rate of 30% or more. However, scattering rate = (parallel light transmittance without light scattering layer, parallel light transmittance with light scattering layer) / (parallel light transmittance without light scattering layer). Therefore, the first electrode 13 and the organic material layer 4 of the organic EL element can be formed with a constant film thickness by the light scattering layer 6 without changing the film thickness.
[0024] このように、有機 EL多色ディスプレイパネルでは、複数の有機 EL素子に共通して 発光光が透過するように発光光が取り出される側に光散乱効果を有する光散乱層 6 が配置されていればよい。このように、有機 EL多色ディスプレイパネルは、基板 12と 基板 12上に配置されかつ 2色以上の発光色を呈する複数の有機 EL素子とを含み、 有機 EL素子の各々が基板 12側カゝら順に積層された第 1電極 13 (透明電極)、少なく とも有機発光層 43B、 43G、 43Rを含む積層された有機材料層 4 (ホール輸送層、電 子輸送層、 etc.)並びに第 2電極 15 (金属電極)を有する。ここで、上記例の有機 EL 多色ディスプレイパネルは、光散乱層 6が有機 EL素子の基板 12に近い第 1電極 13 及び基板 12の間に配置され、第 1電極 13及び基板 12を透過性あるものとして、基板 12側力も発光光が取り出されるので、ボトムェミッション型である。 Thus, in the organic EL multicolor display panel, the light scattering layer 6 having a light scattering effect is arranged on the side from which the emitted light is extracted so that the emitted light is transmitted in common to the plurality of organic EL elements. It only has to be. As described above, the organic EL multicolor display panel includes the substrate 12 and a plurality of organic EL elements arranged on the substrate 12 and exhibiting two or more emission colors, and each of the organic EL elements is a substrate 12 side cover. The first electrode 13 (transparent electrode), the organic material layer 4 (hole transport layer, electron transport layer, etc.) including at least the organic light emitting layers 43B, 43G, 43R, and the second electrode. 15 (metal electrode). Here, in the organic EL multicolor display panel of the above example, the light scattering layer 6 is disposed between the first electrode 13 and the substrate 12 close to the substrate 12 of the organic EL element, and the first electrode 13 and the substrate 12 are transmissive. As a matter of fact, the substrate 12 side force is also a bottom emission type because the emitted light is taken out.
[0025] 第 1電極 13から有機発光層 43B、 43G、 43Rまでの有機材料層4はそれぞれ複数 の有機 EL素子に共通に積層されかつ同一の膜厚を有する。第 2電極 15から有機発 光層 43B、 43G、 43Rまでの有機材料層 4はそれぞれ複数の有機 EL素子に共通に 積層されかつ同一の膜厚を有する。有機材料層 4の内の近接する何れの 2層の屈折 率差の絶対値が 0. 25以下である。すなわち、観察者側カゝら見て、透明電極、電荷 注入層、電荷輸送層が、この順で接して並んだ構造をとり、有機材料層 4の各層の屈 折率が、電荷注入層: nl、電荷輸送層: n2、とした時、その関係が、 450〜630nm の波長領域で I nl— n2 I < 0. 25という関係を満たすように、屈折率段差を小さく することが望ましい。 [0025] The organic material layers 4 from the first electrode 13 to the organic light emitting layers 43B, 43G, and 43R are respectively laminated in common to a plurality of organic EL elements and have the same film thickness. The organic material layer 4 from the second electrode 15 to the organic light emitting layers 43B, 43G, and 43R is shared by multiple organic EL devices. Laminated and have the same film thickness. The absolute value of the refractive index difference between any two adjacent layers in the organic material layer 4 is 0.25 or less. That is, as seen from the observer side, the transparent electrode, the charge injection layer, and the charge transport layer are in contact with each other in this order, and the refractive index of each layer of the organic material layer 4 is the charge injection layer: When nl and the charge transport layer: n2, it is desirable to reduce the refractive index step so that the relationship satisfies the relationship I nl-n2 I <0.25 in the wavelength region of 450 to 630 nm.
[0026] 有機 EL多色ディスプレイパネルは、ボトムェミッション型に限定されることはなく。図 3に示すように、光散乱層 6が有機 EL素子の有機材料層 4とは反対側の基板 12から 遠い第 2電極 15の主面に成膜して配置され、第 2電極 15を透過性あるものとして、第 2電極 15側力も発光光が取り出されるトップェミッション型としてもよい。また、図 4に 示すように、光散乱層 6上に封止板 16を重ねてスぺーサ(図示せず)で基板に固着 させ各有機 EL素子を外気から遮断する構造とすることもできる。 [0026] The organic EL multicolor display panel is not limited to the bottom emission type. As shown in FIG. 3, the light scattering layer 6 is formed on the main surface of the second electrode 15 far from the substrate 12 opposite to the organic material layer 4 of the organic EL element, and is transmitted through the second electrode 15. As a characteristic, the second electrode 15 side force may be a top emission type from which emitted light is extracted. Further, as shown in FIG. 4, a sealing plate 16 may be overlaid on the light scattering layer 6 and fixed to the substrate with a spacer (not shown) to block each organic EL element from the outside air. .
[0027] 有機 EL素子は外気力も遮断される他のトップェミッション型構造としては、図 5に示 すように、光散乱層 6が有機 EL素子の有機材料層 4とは反対側の基板 12から遠い 第 2電極 15の主面側に配置される力 第 2電極 15の上には密閉空気層(中空)を存 在させるために封止板 16がスぺーサ(図示せず)を介して固設されており、光散乱層 6が封止板 16の内面に成膜されてもよい。また、中空を設けずに、封止板 16の内面 光散乱層 6側を接着剤などを介して貼り付けることもできる。 [0027] As another top emission type structure in which the organic EL element is also shielded from external air force, as shown in FIG. 5, the light scattering layer 6 is a substrate on the side opposite to the organic material layer 4 of the organic EL element. Force placed on the main surface side of the second electrode 15 far from 12 The sealing plate 16 has a spacer (not shown) in order to have a sealed air layer (hollow) on the second electrode 15. The light scattering layer 6 may be formed on the inner surface of the sealing plate 16. Further, the inner surface of the sealing plate 16 can be attached to the inner side of the light scattering layer 6 with an adhesive or the like without providing a hollow.
[0028] 光散乱層 6の一例は散乱粒子が榭脂中に分散した散乱粒子含有膜である。散乱 粒子は 0. 1〜1 μ mの粒径を有することが好ましい。また、散乱粒子はシリカ、チタ- ァ、アルミナなどであり、例えば TiOであることが好ましい。 [0028] An example of the light scattering layer 6 is a scattering particle-containing film in which scattering particles are dispersed in a resin. The scattering particles preferably have a particle size of 0.1-1 μm. Further, the scattering particles are silica, titanium, alumina, etc., for example, preferably TiO.
[0029] さらに、有機 EL多色ディスプレイパネルは、図 6に示すように、基板 12の両側に光 散乱層 6を設けたボトムェミッション型とすることもできる。 Furthermore, the organic EL multicolor display panel may be a bottom emission type in which the light scattering layers 6 are provided on both sides of the substrate 12 as shown in FIG.
[0030] さらにまた、図 7に示すように、光散乱層 6付きの封止板 16で封止するとともに、第 1 電極 13及び第 2電極 15に透過性をもたせ、基板 12側と基板側の逆側の封止板 16 との両方に光を取り出す透明有機 ELパネルタイプとすることもできる。 Furthermore, as shown in FIG. 7, while sealing with a sealing plate 16 with a light scattering layer 6, the first electrode 13 and the second electrode 15 are made transmissive, so that the substrate 12 side and the substrate side It is also possible to use a transparent organic EL panel type that extracts light to both the sealing plate 16 on the opposite side.
[0031] 他の実施形態としては、図 2〜図 7に示した構造にカ卩えて、有機 EL多色ディスプレ ィパネルに、有機材料層 4に関して光散乱層 6の外側に配置された低屈折率層を設 けることができる。低屈折率層は 1. 3以下更に好ましくは 1. 2以下の屈折率を有する 。低屈折率層はシリカを含むことが好ましい。 [0031] As another embodiment, a low refractive index disposed outside the light scattering layer 6 with respect to the organic material layer 4 in the organic EL multicolor display panel in addition to the structure shown in FIGS. Layer Can The low refractive index layer has a refractive index of 1.3 or less, more preferably 1.2 or less. The low refractive index layer preferably contains silica.
[0032] さらに、他の実施形態としては、図 2〜図 7に示した構造に加えて、有機 EL多色デ イスプレイパネルに、有機材料層 4に関して第 1電極 13の外側に配置されたガスバリ ァ層を設けることができる。ガスノリア層は高分子薄膜及び無機薄膜の積層又は高 分子薄膜若しくは無機薄膜である。 Furthermore, as another embodiment, in addition to the structures shown in FIGS. 2 to 7, a gas barrier disposed on the outside of the first electrode 13 with respect to the organic material layer 4 on the organic EL multicolor display panel. Can be provided. The gas nolia layer is a laminate of a polymer thin film and an inorganic thin film, or a high molecular thin film or an inorganic thin film.
[0033] またさらに、他の実施形態としては、図 2〜図 7に示した構造における光散乱層 6の 散乱粒子が榭脂中に分散した散乱粒子含有膜に代えて、光散乱層 6を粗面を構成 する粗面界面とすることができる。この場合、基板 12や封止板 16をスリガラスとしてそ の表面の粗面を界面とする。粗面界面は d> 5 XRaの関係(ただし dは光散乱層 6と 有機発光層 43B、 43G、 43Rとの間の距離)を満たす平均粗さ Raを有することが好 ましい。 Ra (算術平均粗さ)とは、粗さ曲線力 その平均線の方向に測定長さの部分 を抜き取り、この抜き取り部分の平均線の方向に X軸、縦倍率の方向^ y軸とし、粗さ 曲線を y=f (x)で表したとき与えられる Raの値を長さで表したものをいう。平均粗さ R aが lnm〜l μ mの範囲に入ることが好ましい。 Furthermore, as another embodiment, instead of the scattering particle-containing film in which the scattering particles of the light scattering layer 6 in the structure shown in FIGS. 2 to 7 are dispersed in the resin, the light scattering layer 6 is provided. It can be a rough surface interface constituting the rough surface. In this case, the substrate 12 and the sealing plate 16 are ground glass, and the rough surface is used as the interface. The rough surface interface preferably has an average roughness Ra that satisfies the relationship d> 5 XRa (where d is the distance between the light-scattering layer 6 and the organic light-emitting layers 43B, 43G, and 43R). Ra (arithmetic mean roughness) is the roughness curve force. The length of the measurement length is extracted in the direction of the average line, the X-axis is the direction of the average line of the extracted part, and the direction of the vertical magnification is the y-axis. The length of the Ra value given when the curve is expressed as y = f (x). The average roughness R a is preferably in the range of lnm to l μm.
[0034] さらに、他の実施形態としては、図 2〜図 7に示した構造に加えて、複数の有機 EL 素子を分割するように有機材料層 4に関して光散乱層 6の外側に配置されかつ光吸 収効果を有する光吸収層を備えることができる。 Furthermore, as another embodiment, in addition to the structure shown in FIGS. 2 to 7, the organic material layer 4 is arranged outside the light scattering layer 6 so as to divide a plurality of organic EL elements, and A light absorption layer having a light absorption effect can be provided.
[0035] また、他の実施形態としては、図 2〜図 7に示した構造に加えて、複数の有機 EL素 子からの発光の色純度を高めるように有機材料層 4に関して光散乱層 6の外側に配 置されたカラーフィルタを備えることができる。 [0035] As another embodiment, in addition to the structures shown in Figs. 2 to 7, the light scattering layer 6 with respect to the organic material layer 4 so as to increase the color purity of light emitted from a plurality of organic EL elements. A color filter disposed on the outside can be provided.
[0036] 以上のように、上記実施形態の有機 EL多色ディスプレイパネルによれば、光散乱 構造により光学干渉の影響を減らすことができるという特徴を活かし、各発光色に共 通に用いる材料の膜厚をそろえることにより、共通の有機材料層は塗り分けることなく 、同時に成膜できる。 3色塗り分けフルカラー型、 2色塗り分けフルカラー型、エリア力 ラー型などのパネルや、アクティブ駆動又はパッシブ駆動など駆動方式は選ばな 、 1 パネル上に 2色以上の発光画素をもつ有機 ELパネルに有効である。 [0036] As described above, according to the organic EL multicolor display panel of the above-described embodiment, by utilizing the feature that the influence of optical interference can be reduced by the light scattering structure, the material commonly used for each emission color can be reduced. By aligning the film thickness, the common organic material layer can be formed simultaneously without being separately applied. Panels such as full-color type with two colors, full-color type with two colors, and area power color type, and driving methods such as active drive or passive drive are selected. An organic EL panel with two or more light-emitting pixels on one panel It is effective for.
[0037] 以下に、上記実施形態を含め種々の有機 EL多色ディスプレイパネル構造を表に まとめると以下のものが挙げられる。ボトムェミッション及びトップェミッション型有機 E L多色ディスプレイパネル構造を主に示してある力 基板両方に光を取り出す透明有 機 ELパネルタイプの場合は、ボトムェミッション型とトップェミッション型とを、第 1及び 2電極に挟まれた有機材料層を中心として組合せれば構成できる。なお、下表中() 内に記載の部材はある場合と無い場合の両方の構造が可能であるという態様を示す [表 1] [0037] In the table below, various organic EL multicolor display panel structures including the above-described embodiment are listed. In summary, the following are listed. The bottom emission and top emission type organic EL multicolor display panel structure is mainly shown. Transparent organic light that extracts light to both substrates. In the case of the EL panel type, the bottom emission type and the top emission type are It can be constructed by combining the organic material layers sandwiched between the first and second electrodes. In addition, in the table below, () shows a mode in which the members listed in () can be structured with and without them [Table 1]
ボトムェミッション Bottom emission
透^ 透明 反射 構造 散乱層 基板 散乱層 第 1電極 有機材料層 第 2電極 Transparent Transparent Reflective structure Scattering layer Substrate Scattering layer First electrode Organic material layer Second electrode
1 ― 基板 (低屈折率層) 散乱粒子含有層 (ガスバリア層) 第 1電極 有機材料層 第 2電極1 ― Substrate (low refractive index layer) Scattered particle containing layer (gas barrier layer) First electrode Organic material layer Second electrode
2 ― 基板 ― 粗面界面 (ガスバリア層) 第 1電極 有機材料層 第 2電極2-Substrate-Rough surface interface (gas barrier layer) First electrode Organic material layer Second electrode
3 散乱粒子含有層 基板 (低屈折率層) 散乱粒子含有層 (ガスバリア層) 第 1電極 有機材料層 第 2電極3 Scattered particle-containing layer Substrate (low refractive index layer) Scattered particle-containing layer (gas barrier layer) First electrode Organic material layer Second electrode
4 散乱粒子含有層 基板 ― 粗面界面 (ガスバリア層) 有機材料層 4 Scattered particle-containing layer Substrate-rough surface interface (gas barrier layer) Organic material layer
5 粗面界面 基板 (低屈折率層) 散乱粒子含有層 (ガスバリア層) 第 1電極 有機材料層 第 2電極 5 Rough surface interface Substrate (low refractive index layer) Scattered particle containing layer (gas barrier layer) First electrode Organic material layer Second electrode
6 粗面界面 基板 ― 粗面界面 (ガスバリア層) 第 1電極 有機材料層 第 2電極 6 Rough surface interface Substrate-rough surface interface (gas barrier layer) First electrode Organic material layer Second electrode
CM トップェミッション cm Top emission
実施例 Example
[0040] (実施例 l):ガラス基板 Z低屈折率層 Z散乱粒子含有膜 Z透明電極 (ιτο) Z有 機発光層,反射電極 (Al) t ヽぅ構成の有機 ELパネルを作製した。 Example l: Glass substrate Z Low refractive index layer Z Scattered particle-containing film Z Transparent electrode (ιτο) Z Organic light emitting layer, Reflective electrode (Al) t An organic EL panel composed of ヽ ぅ was prepared.
[0041] 旭硝子 (株)製無アルカリガラス AN100よりなる厚さ 0. 7mm、 75mm角のガラス基 板を中性洗剤中で 30分程超音波洗浄し、純水でフロー洗浄し、 60°Cオーブン中で 乾燥した。 [0041] Asahi Glass Co., Ltd. Alkali-free glass AN100-thickness 0.7mm, 75mm square glass substrate was ultrasonically cleaned in neutral detergent for about 30 minutes, flow washed with pure water, 60 ° C Dried in the oven.
[0042] 一方、三菱化学 (株)製 MS51 (テトラメトキシシランのオリゴマー) 25重量%、 n—ブ チルアルコール 30重量%、脱塩水 15重量%、及びエタノール 30重量%の液に、酸 触媒 (アルミァセチルァセトナート)を少量加えた。この混合液を 60°Cで 3時間攪拌し 1週間放置して熟成した。 On the other hand, MS51 (tetramethoxysilane oligomer) 25% by weight, n-butyl alcohol 30% by weight, demineralized water 15% by weight, and ethanol 30% by weight were mixed with an acid catalyst ( A small amount of aluminum acetylacetonate) was added. The mixture was stirred at 60 ° C for 3 hours and left to mature for 1 week.
[0043] これを上述のガラス基板上にスピンコ一ターで塗布し、 15分乾燥後、メタノール中 に 5分浸漬、引き上げて 5分乾燥後、 150°Cで 15分加熱して、さらに 250°Cで 15分 加熱して、低屈折率層を形成した。得られた低屈折率層の厚さは 300nmであった。 ソプラ社のエリプソメーターでこの低屈折率層のマトリクス部分の屈折率を測定したと ころ、波長 550nmにおいて 1. 3であった。また米国メトリコン社のプリズムカプラーモ デル 2010を用いて波長 633nmのレーザーで屈折率を測定したところ、屈折率は 1 . 3であった。 [0043] This was coated on the above glass substrate with a spin coater, dried for 15 minutes, dipped in methanol for 5 minutes, pulled up, dried for 5 minutes, heated at 150 ° C for 15 minutes, and further heated to 250 ° A low refractive index layer was formed by heating at C for 15 minutes. The thickness of the obtained low refractive index layer was 300 nm. When the refractive index of the matrix portion of this low refractive index layer was measured with a sopra ellipsometer, it was 1.3 at a wavelength of 550 nm. Further, when the refractive index was measured with a 633 nm laser using a prism coupler model 2010 manufactured by Metricon Inc., the refractive index was 1.3.
[0044] 次に、三菱化学 (株)製 MS 51 (テトラメトキシシランのオリゴマー) 30重量%、プチ ルアルコール 50重量%、脱塩水 8重量%、及びメタノール 12重量%の液に、酸触媒 (アルミァセチルァセトナート)を少量カ卩え、さらにブチルアルコール中に平均粒径 20 Onmのチタ-ァ粒子(60%重量粒子径は 150〜250nm)をでき上がった粒子含有 浸み出し光拡散層中の重量百分率で 15重量%となるように予め分散させた。この混 合液を 60°Cで 3時間攪拌し 1週間放置して熟成した。粒子含有層中の重量百分率 は前述の膜中の粒度分布を求めるのと同様の方法で実施した。マトリクスが多孔体で ある場合の密度は X線反射率を求めることまたは屈折率を求めることから実施した。 [0044] Next, MS 51 (tetramethoxysilane oligomer) 30% by weight manufactured by Mitsubishi Chemical Corporation, 50% by weight of propyl alcohol, 8% by weight of demineralized water, and 12% by weight of methanol were mixed with an acid catalyst ( A small amount of aluminum acetylacetonate) and further particles containing tantalum particles with an average particle size of 20 Onm (60% weight particle size is 150-250 nm) in butyl alcohol. The dispersion was previously dispersed so that the weight percentage in it was 15% by weight. The mixture was stirred at 60 ° C for 3 hours and left to mature for 1 week. The weight percentage in the particle-containing layer was measured in the same manner as the particle size distribution in the film described above. The density when the matrix was a porous material was determined by determining the X-ray reflectivity or the refractive index.
[0045] この塗布液を上述のガラス基板上の低屈折率層の上にディップコーターで塗布、 1 5分乾燥後メタノール中に 5分浸漬、引き上げて 5分乾燥後、 150°Cで 15分加熱して 、さらに 250°Cで 15分加熱して、光散乱層を得た。なおディップコート時には裏面に 保護フィルムを貼り、塗布後に剥離して、片側にのみ塗膜が形成されるようにした。 [0045] This coating solution was applied onto the above-mentioned low refractive index layer on the glass substrate with a dip coater, dried for 15 minutes, immersed in methanol for 5 minutes, pulled up, dried for 5 minutes, and then 15 minutes at 150 ° C. After heating, the mixture was further heated at 250 ° C. for 15 minutes to obtain a light scattering layer. In addition, on the back side during dip coating A protective film was applied, peeled off after application, and a coating film was formed only on one side.
[0046] 得られた散乱粒子含有膜は厚さが 600nm、散乱粒子がほぼ 3段分に重なった構 造が観察された。 [0046] The resulting scattering particle-containing film had a thickness of 600 nm, and a structure in which scattering particles overlapped in almost three steps was observed.
[0047] ソプラ社のエリプソメーターで光散乱層のマトリクス部分の屈折率を測定したところ、 波長 550nmにおいて 1. 40であった。また米国メトリコン社のプリズムカプラーモデ ル 2010でも屈折率測定を実施したところ、波長 633nmのレーザーで屈折率は 1. 3 8であった。 The refractive index of the matrix portion of the light scattering layer was measured with a sopra ellipsometer and found to be 1.40 at a wavelength of 550 nm. Refractive index measurement was also performed using the prism coupler model 2010 of Metricon Inc. in the US, and the refractive index was 1.38 with a laser with a wavelength of 633 nm.
[0048] この散乱粒子含有膜の表面粗さをケーエルエー'テンコール社製 P— 15型を使用 して測定した。 0. 5 スキャンさせて測定したところ Ra = 8nm、 Rmax= 120nmであ つた o [0048] The surface roughness of the scattering particle-containing film was measured using P-15 type manufactured by KLA-Tencor Corporation. 0.5 Scanned and measured Ra = 8nm, Rmax = 120nm o
[0049] また散乱粒子含有膜の平行光線に対する透過ロス光 (散乱ロス光)は、波長 550η mで 52%であった。測定にはヒユーレッドパッカード社の分光光度計を用い、レファレ ンスとしては塗布膜を形成する前のガラス基板を用いた。 [0049] The transmission loss light (scattering loss light) with respect to the parallel rays of the scattering particle-containing film was 52% at a wavelength of 550 ηm. A spectrophotometer manufactured by HEURED Packard was used for the measurement, and a glass substrate before forming the coating film was used as a reference.
[0050] この散乱粒子含有膜上に ITO (インジウムティンオキサイド)を 115nm厚で常温ス ノッタして透明電極を形成し、さらに三菱ィ匕学 (株)製塗布型ホール注入材料 PC1 020 を 30nm形成後、 NPB (ナフチルペンチルベンジジン)層 45nm、 A1Q3 (アル ミキノリン錯体、緑色発光色素) 60nmを蒸着により形成し、最後に蒸着によりアルミ- ゥムの反射電極を 80nm厚さに形成した。 ITO層の屈折率を測定したところ 2. 04 (5 50nm)であった。得られた EL素子は、ガラス基板 Z低屈折率層 Z散乱粒子含有膜 Z透明電極 (ITO) Z有機発光層 Z反射電極 (A1)の積層体である。 [0050] On this scattering particle-containing film, ITO (Indium Tin Oxide) is deposited at a temperature of 115 nm at room temperature to form a transparent electrode, and then, a 30 nm thick coating-type hole injection material PC1 020 manufactured by Mitsubishi Chemical Co., Ltd. is formed. Thereafter, an NPB (naphthylpentylbenzidine) layer of 45 nm and A1Q3 (aluminoquinoline complex, green luminescent dye) of 60 nm were formed by vapor deposition, and finally an aluminum reflective electrode was formed to a thickness of 80 nm by vapor deposition. The refractive index of the ITO layer was measured and found to be 2.04 (550 nm). The obtained EL element is a laminate of a glass substrate Z, a low refractive index layer, a film containing scattering particles, a transparent electrode (ITO), an organic light emitting layer, and a reflective electrode (A1).
[0051] (実施例 2):散乱粒子含有膜 Zガラス基板 Z低屈折率層 Z散乱粒子含有膜 Z透 明電極 (ITO) ,有機発光層,反射電極 (Al) t ヽぅ構成の有機 ELパネルを作製し た。 [0051] (Example 2): Scattered particle-containing film Z glass substrate Z low refractive index layer Z scattered particle-containing film Z Transparent electrode (ITO), organic light emitting layer, reflective electrode (Al) t Organic EL A panel was made.
[0052] 実施例 1において、光散乱層の塗布の際に裏面に保護フィルムを貼らずにディップ 塗布を実施した以外は全く同様にして EL素子を作製した。得られた EL素子は、散 乱粒子含有膜 Zガラス基板,低屈折率層,散乱粒子含有膜 Z透明電極 (ITO) , 有機発光層 Z反射電極 (A1)の積層体である。 [0052] In Example 1, an EL element was produced in exactly the same manner as in Example 1, except that dip coating was performed without applying a protective film on the back surface when the light scattering layer was applied. The obtained EL device is a laminate of a scattering particle-containing film Z glass substrate, a low refractive index layer, a scattering particle-containing film Z transparent electrode (ITO), and an organic light emitting layer Z reflecting electrode (A1).
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