WO2007091998A3 - Method and apparatus for pre-concentration of volatile compounds of explosives and taggants in explosives for subsequent detection by ion mobility spectrometry - Google Patents
Method and apparatus for pre-concentration of volatile compounds of explosives and taggants in explosives for subsequent detection by ion mobility spectrometry Download PDFInfo
- Publication number
- WO2007091998A3 WO2007091998A3 PCT/US2006/004074 US2006004074W WO2007091998A3 WO 2007091998 A3 WO2007091998 A3 WO 2007091998A3 US 2006004074 W US2006004074 W US 2006004074W WO 2007091998 A3 WO2007091998 A3 WO 2007091998A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- explosives
- taggants
- detection
- interface
- concentration
- Prior art date
Links
- 238000001514 detection method Methods 0.000 title abstract 5
- 239000002360 explosive Substances 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title 1
- 238000001871 ion mobility spectroscopy Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000004094 preconcentration Methods 0.000 title 1
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 abstract 2
- RMBFBMJGBANMMK-UHFFFAOYSA-N 2,4-dinitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O RMBFBMJGBANMMK-UHFFFAOYSA-N 0.000 abstract 2
- PLAZTCDQAHEYBI-UHFFFAOYSA-N 2-nitrotoluene Chemical compound CC1=CC=CC=C1[N+]([O-])=O PLAZTCDQAHEYBI-UHFFFAOYSA-N 0.000 abstract 2
- ZPTVNYMJQHSSEA-UHFFFAOYSA-N 4-nitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1 ZPTVNYMJQHSSEA-UHFFFAOYSA-N 0.000 abstract 2
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 abstract 2
- 239000000026 Pentaerythritol tetranitrate Substances 0.000 abstract 2
- 229960004321 pentaerithrityl tetranitrate Drugs 0.000 abstract 2
- XTRDKALNCIHHNI-UHFFFAOYSA-N 2,6-dinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=CC=C1[N+]([O-])=O XTRDKALNCIHHNI-UHFFFAOYSA-N 0.000 abstract 1
- YWSPWKXREVSQCA-UHFFFAOYSA-N 4,5-dimethoxy-2-nitrobenzaldehyde Chemical compound COC1=CC(C=O)=C([N+]([O-])=O)C=C1OC YWSPWKXREVSQCA-UHFFFAOYSA-N 0.000 abstract 1
- 239000000020 Nitrocellulose Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- DWCLXOREGBLXTD-UHFFFAOYSA-N dmdnb Chemical compound [O-][N+](=O)C(C)(C)C(C)(C)[N+]([O-])=O DWCLXOREGBLXTD-UHFFFAOYSA-N 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 238000002470 solid-phase micro-extraction Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/40—Concentrating samples
- G01N1/405—Concentrating samples by adsorption or absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y15/00—Nanotechnology for interacting, sensing or actuating, e.g. quantum dots as markers in protein assays or molecular motors
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/22—Devices for withdrawing samples in the gaseous state
- G01N1/2202—Devices for withdrawing samples in the gaseous state involving separation of sample components during sampling
- G01N1/2214—Devices for withdrawing samples in the gaseous state involving separation of sample components during sampling by sorption
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Biomedical Technology (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
An interface that couples SPME to IMS has been constructed and evaluated for the detection of the following detection taggants: 2-nitrotoluene (2-NT), 4-nitrotoluene (4-NT), and 2,3-dimethyl-2,3-dinitrobutane (DMNB). The interface was also evaluated for the following common explosives: smokeless powder (nitrocellulose, NC), 2,4-dinitrotoluene (2,4-DNT), 2,6-dinotrotoluene (2,6-DNT), 2,4,6-trinitrotoluene (2,4,6-TNT), hexahydro-l,3,54rinitro-s-triazine (RDX), and pentaerythritol tetranitrate (PETN). The resultant SPME-IMS interface was found to extract volatile constituent chemicals and detection taggants in explosives from a headspace for subsequent detection in a simple, rapid, sensitive, and inexpensive manner.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/630,559 US20090309016A1 (en) | 2005-02-02 | 2006-02-02 | Method and apparatus for Detecting Explosives |
| US12/135,954 US8668873B2 (en) | 2005-02-02 | 2008-06-09 | Method and apparatus for extraction, detection, and characterization of vapors from explosives, taggants in explosives, controlled substances, and biohazards |
| US14/203,491 US9412573B2 (en) | 2005-02-02 | 2014-03-10 | Method and apparatus for extraction, detection, and characterization of vapors from explosives, taggants in explosives, controlled substances, and biohazards |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64946405P | 2005-02-02 | 2005-02-02 | |
| US60/649,464 | 2005-02-02 |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/630,559 A-371-Of-International US20090309016A1 (en) | 2005-02-02 | 2006-02-02 | Method and apparatus for Detecting Explosives |
| US12/135,954 Continuation-In-Part US8668873B2 (en) | 2005-02-02 | 2008-06-09 | Method and apparatus for extraction, detection, and characterization of vapors from explosives, taggants in explosives, controlled substances, and biohazards |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2007091998A2 WO2007091998A2 (en) | 2007-08-16 |
| WO2007091998A3 true WO2007091998A3 (en) | 2008-02-14 |
Family
ID=38345577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2006/004074 WO2007091998A2 (en) | 2005-02-02 | 2006-02-02 | Method and apparatus for pre-concentration of volatile compounds of explosives and taggants in explosives for subsequent detection by ion mobility spectrometry |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US20090309016A1 (en) |
| WO (1) | WO2007091998A2 (en) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2415120C2 (en) * | 2009-05-04 | 2011-03-27 | Федеральное государственное унитарное предприятие "Государственный научно-исследовательский институт "Кристалл" | Marked emulsion explosive compound (versions) |
| CN102568994B (en) | 2010-12-31 | 2014-08-06 | 同方威视技术股份有限公司 | Sample introduction device for ion mobility spectrometer, use method of sample introduction device and ion mobility spectrometer |
| US9057712B1 (en) | 2011-10-27 | 2015-06-16 | Copilot Ventures Fund Iii Llc | Methods of delivery of encapsulated perfluorocarbon taggants |
| US9267866B2 (en) * | 2013-03-13 | 2016-02-23 | The Florida International University Board Of Trustees | Capillary microextractor of volatiles (CMV) |
| TWI488215B (en) * | 2013-11-28 | 2015-06-11 | Univ Nat Sun Yat Sen | Multi solid phase thermal desorption ionization device, mass spectrometer, and method for mass spectrometry |
| WO2016054585A1 (en) * | 2014-10-02 | 2016-04-07 | Brigham Young University | Autonomous ambient air sampling system for monitoring semi- volatile/non-volatile organic compounds |
| RU2602557C1 (en) * | 2015-05-29 | 2016-11-20 | Федеральное Казенное Предприятие "Бийский Олеумный Завод" | Mixed explosive composition |
| US12251991B2 (en) | 2020-08-20 | 2025-03-18 | Denso International America, Inc. | Humidity control for olfaction sensors |
| US11760170B2 (en) | 2020-08-20 | 2023-09-19 | Denso International America, Inc. | Olfaction sensor preservation systems and methods |
| US12269315B2 (en) | 2020-08-20 | 2025-04-08 | Denso International America, Inc. | Systems and methods for measuring and managing odor brought into rental vehicles |
| US11881093B2 (en) | 2020-08-20 | 2024-01-23 | Denso International America, Inc. | Systems and methods for identifying smoking in vehicles |
| US11636870B2 (en) | 2020-08-20 | 2023-04-25 | Denso International America, Inc. | Smoking cessation systems and methods |
| US11932080B2 (en) | 2020-08-20 | 2024-03-19 | Denso International America, Inc. | Diagnostic and recirculation control systems and methods |
| US11813926B2 (en) | 2020-08-20 | 2023-11-14 | Denso International America, Inc. | Binding agent and olfaction sensor |
| US11828210B2 (en) | 2020-08-20 | 2023-11-28 | Denso International America, Inc. | Diagnostic systems and methods of vehicles using olfaction |
| US11760169B2 (en) | 2020-08-20 | 2023-09-19 | Denso International America, Inc. | Particulate control systems and methods for olfaction sensors |
| US12017506B2 (en) | 2020-08-20 | 2024-06-25 | Denso International America, Inc. | Passenger cabin air control systems and methods |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5083019A (en) * | 1990-08-21 | 1992-01-21 | Environmental Technologies Group, Inc. | Preconcentrator for ion mobility spectrometer |
| US20020098594A1 (en) * | 1999-03-26 | 2002-07-25 | Gerstel Systemtechnik Gmbh & Co. Kg | Method for solid-phase microextraction and analysis, and a collector for this method |
| US6656738B1 (en) * | 1999-11-17 | 2003-12-02 | Bae Systems Integrated Defense Solutions Inc. | Internal heater for preconcentrator |
| US20040248319A1 (en) * | 2003-05-28 | 2004-12-09 | Belyakov Vladimir V. | Pulsed vapor desorber |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000056429A1 (en) * | 1999-03-22 | 2000-09-28 | Analytica Of Branford, Inc. | Direct flow injection analysis nebulization electrospray and apci mass spectrometry |
-
2006
- 2006-02-02 WO PCT/US2006/004074 patent/WO2007091998A2/en active Application Filing
- 2006-02-02 US US11/630,559 patent/US20090309016A1/en not_active Abandoned
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5083019A (en) * | 1990-08-21 | 1992-01-21 | Environmental Technologies Group, Inc. | Preconcentrator for ion mobility spectrometer |
| US20020098594A1 (en) * | 1999-03-26 | 2002-07-25 | Gerstel Systemtechnik Gmbh & Co. Kg | Method for solid-phase microextraction and analysis, and a collector for this method |
| US6656738B1 (en) * | 1999-11-17 | 2003-12-02 | Bae Systems Integrated Defense Solutions Inc. | Internal heater for preconcentrator |
| US20040248319A1 (en) * | 2003-05-28 | 2004-12-09 | Belyakov Vladimir V. | Pulsed vapor desorber |
Non-Patent Citations (1)
| Title |
|---|
| EWING, R.G. ET AL.: "A critical review of ion mobility spectrometrey for the detection of explosives and explosive related compounds", TALANTA, vol. 54, 10 May 2001 (2001-05-10), pages 515 - 529, XP002460372 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007091998A2 (en) | 2007-08-16 |
| US20090309016A1 (en) | 2009-12-17 |
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