+

WO2007066310A2 - Recipient comprenant une etiquette dans le moule placee a proximite d’une topographie de surface - Google Patents

Recipient comprenant une etiquette dans le moule placee a proximite d’une topographie de surface Download PDF

Info

Publication number
WO2007066310A2
WO2007066310A2 PCT/IB2006/054664 IB2006054664W WO2007066310A2 WO 2007066310 A2 WO2007066310 A2 WO 2007066310A2 IB 2006054664 W IB2006054664 W IB 2006054664W WO 2007066310 A2 WO2007066310 A2 WO 2007066310A2
Authority
WO
WIPO (PCT)
Prior art keywords
container
mold label
copolymers
polyethylene
mold
Prior art date
Application number
PCT/IB2006/054664
Other languages
English (en)
Other versions
WO2007066310A3 (fr
Inventor
Roberto Escobosa
Paul Owen Nutley
Michael Dean Mccutchan
Dean Arthur Zimmerman
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to EP06832146A priority Critical patent/EP1957374A2/fr
Publication of WO2007066310A2 publication Critical patent/WO2007066310A2/fr
Publication of WO2007066310A3 publication Critical patent/WO2007066310A3/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00—Details of bottles or jars not otherwise provided for
    • B65D23/08—Coverings or external coatings
    • B65D23/0842—Sheets or tubes applied around the bottle with or without subsequent folding operations
    • B65D23/0864—Applied in mould
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00—Details of bottles or jars not otherwise provided for
    • B65D23/10—Handles
    • B65D23/102—Gripping means formed in the walls, e.g. roughening, cavities, projections
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/04—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps to be fastened or secured by the material of the label itself, e.g. by thermo-adhesion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/24—Lining or labelling
    • B29C2049/2412—Lining or labelling outside the article
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/24—Lining or labelling
    • B29C2049/2414—Linings or labels, e.g. specific geometry, multi-layered or material
    • B29C2049/24302—Label materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/24—Lining or labelling
    • B29C2049/2464—Means for verifying or keeping the position of the lining or label, e.g. sensors, or attachment on mould wall
    • B29C2049/2466—Means for verifying or keeping the position of the lining or label, e.g. sensors, or attachment on mould wall using electrostatic force
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/24—Lining or labelling
    • B29C2049/2464—Means for verifying or keeping the position of the lining or label, e.g. sensors, or attachment on mould wall
    • B29C2049/2472—Means for verifying or keeping the position of the lining or label, e.g. sensors, or attachment on mould wall using vacuum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B29K2023/0608—PE, i.e. polyethylene characterised by its density
    • B29K2023/0625—LLDPE, i.e. linear low density polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B29K2023/0608—PE, i.e. polyethylene characterised by its density
    • B29K2023/0633—LDPE, i.e. low density polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B29K2023/0608—PE, i.e. polyethylene characterised by its density
    • B29K2023/0641—MDPE, i.e. medium density polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B29K2023/0608—PE, i.e. polyethylene characterised by its density
    • B29K2023/065—HDPE, i.e. high density polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/08—Copolymers of ethylene
    • B29K2023/083—EVA, i.e. ethylene vinyl acetate copolymer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10—Polymers of propylene
    • B29K2023/12—PP, i.e. polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06—PVC, i.e. polyvinylchloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/04—Polyesters derived from hydroxycarboxylic acids
    • B29K2067/046—PLA, i.e. polylactic acid or polylactide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2203/00—Decoration means, markings, information elements, contents indicators
    • B65D2203/02—Labels
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

Definitions

  • the present invention relates to a container for liquid compositions comprising a surface topography, a reservoir comprising a liquid composition and an in-mold label positioned proximate to the surface topography thereby increasing the resilience of the container.
  • Liquid composition such as shampoos, conditioners, bodywash, in-shower moisturizers, lotions, detergents, toothpaste, ketchup and the like are commonly packaged in blow molded containers.
  • Consumers desire a container from which it is easy to dispense the contents.
  • dispensing is effected by the geometry of the container, orientation (e.g., inverted containers also known as "tottles"), material, orifice design and thickness of the container.
  • orientation e.g., inverted containers also known as "tottles”
  • material e.g., inverted containers also known as "tottles”
  • thickness of the container e.g., a high degree of resilience is desirable as consumers often need to squeeze the container several times to dispense enough product.
  • An increase in thickness of the squeezable wall may result in an increase of the resilience, and said wall may reform its shape quicker.
  • Labels are commonly comprised on these containers for decoration purposes and to provide information to the user, such as the composition's formula, or the method of use. Labels also may improve the intrinsic properties of containers, such as the deformation characteristics and restorative capability after squeezing.
  • in-mold label One type of label that is used is an in-mold label.
  • the most common process for in-mold labeling is blow molding.
  • In-mold labeling during production of containers by blow molding is known in the prior art.
  • a label is laid in the opened blow mold, usually by a robot, in such a way that the printed outside of the label is in contact with the mold wall, and the unprinted inside faces the blow molding to be shaped.
  • the still- molten surface of the polymer composition comes into close contact with the label and bonds thereto to give a label ed container.
  • the label is either, particularly in the case of simple in-label shapes, supplied in roll form and cut to size at the blow-molding machine ("cut in place") or, in the case of more complex label shapes, cut to size in advance and away from the blow-molding machine, stacked and later segregated from the stack at the blow-molding machine (cut & stack process) and introduced individually into the respective blow mold.
  • Films made from thermoplastics have recently increasingly been used for the in-mold labeling of containers.
  • the films which are suitable for a use of this type have to have a selected property profile in order to ensure that the in-mold label 6 and mold nestle against one another in a flat and bubble-free manner and for the label to properly bond to the container.
  • Known labels result in bubbles and wrinkles if there is surface texture present such as a ridge on the face of the container. Bubbles and other optical defects occur more often in containers that have surface topographies with high degree of curvature and when the labels are thinner than 4.5 mils.
  • the object of the present invention was to provide an inexpensive method of decorating highly curved or texturized surfaces through an in-mold label that also helps to improve the resilience of a container comprising a liquid composition.
  • the object on which the invention is achieved is by the use of a film comprising at least one layer selected from the group consisting of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene- acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof having a thickness of at least 4.5 mils.
  • the present invention is directed to a container for liquid compositions comprising a reservoir comprising a liquid composition, a surface topography, and an in-mold label positioned proximate to the surface topography.
  • the surface topography selected from the group consisting of ridges, valleys, a grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography.
  • the in-mold label has a thickness of at least 4.5 mils.
  • the in-mold label is comprised of a material selected from the group consisting of polyethylene, copolymers of polyethyene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene- acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof.
  • the present invention also includes a method of increasing resiliency in containers for liquid compositions.
  • FIG. 1 illustrates a perspective view of the container of the present invention is a bottle.
  • FIG. 2 illustrates a perspective view of the container of the present invention is a tottle.
  • ambient conditions refers to surrounding conditions at one (1) atmosphere of pressure, 50% relative humidity, and 25°C.
  • bottle as used herein, is a hollow rigid or semi-rigid container having a comparatively narrow dispensing end (neck or mouth). The dispensing end (neck or mouth) is typically the end where the bottle's contents is filled into and dispensed from.
  • liquid composition refers to the compositions of the present invention, wherein the compositions are intended to include, but are not limited to, compositions for topical application to the skin, hair, teeth, body, surfaces, and fabric fibers.
  • Such compositions can include, but are not limited to, shampoos, conditioners, tooth cleansers, hair styling products, cleaners, soaps, cosmetics, foundations, antiperspirants, deodorants, lotions, creams, ointments, kitchen and bathroom cleansers, floor cleansers, dishwashing liquid, fabric softener, laundry detergent, fabric freshener, snacks, beverages, combinations thereof, and the like.
  • mapping refers to a striped design with a veined and/or mottled appearance similar to marble.
  • phase refers to a homogeneous, physically distinct, and mechanically separable portion of matter present in a non-homogeneous physical-chemical system.
  • the phases herein are compositions with different colors.
  • the phases comprise the same chemical compositions but with different colorants.
  • compositions of the present invention refers to the compositions of the present invention, wherein the compositions are intended to include compositions for topical application to the skin or hair.
  • Such personal care compositions can include, but are not limited to, shampoos, conditioners, hair styling products, cleansers, soaps, cosmetics, foundations, anti-perspirants, deodorants, lotions, creams, ointments, combinations thereof, and the like.
  • a personal care composition comprises at least two phases that are present within the container as distinct layers or "stripes.”
  • the stripes may be relatively uniform and even across the dimension of the package.
  • the layers may be uneven, i.e. wavy, or may be non-uniform in dimension.
  • the stripes do not necessarily extend across the entire dimension of the package.
  • the "stripe' can comprise various geometric patterns, various colors and, or glitter or pearlescence, providing that the concentration of said alternative forms visually distinct bands or regions.
  • surface topography selected from the group consisting of ridges, valleys, a grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography.
  • tottle refers to a bottle which rests on neck or mouth which its contents are filled in and dispensed from, but it is also the end upon which the bottle is intended to rest or sit upon (e.g., the bottle's base) for storage by the consumer and/or for display on the store shelf (this bottle is referred to herein as a "tottle”).
  • the closure on a tottle is flat or concave, such that the tottle, when stored, rests on the closure.
  • the closure can be, for example, a cap, flip-top, screw-on, screw-on flip-top cap, etc.
  • compositions in the package or upon being dispensed that display visually different phases. These different phases are either distinctively separate or partially mixed as long as the multiple phase composition remains visible to the naked eye.
  • the present invention is directed towards a container 2 for compositions as shown in FIG. 1 and FIG. 2.
  • the container has a dispensing end 10 and a non-dispensing end 12.
  • the dispensing end has a closure 14.
  • the container 2 is a bottle 16 with a flat closure 14.
  • the container 2 is a tottle 18.
  • a clear or opaque container 2 is used.
  • the container 2 is made from a polyolefin, such as polypropylene, polyethylene (e.g., linear low density, low density, medium density, high density, copolymers such as ethylene, vinyl, and acetate), polyethylene terephthalate and co-polymers, and nylon.
  • the container 2 is a bottle 16 that is filled from the dispensing end 10.
  • the closure 14 on a tottle 18 is flat or concave, such that the tottle, when stored, rests on the closure.
  • the closure 14 can be, for example, a cap, flip-top, screw-on, screw-on flip-top cap, , etc.
  • a tottle 18 can be a preferred container 2. If a tottle 18 is used, the personal care composition can be stored with the end from which it was filled facing downward. This avoids the need to tip the container 2 over to dispense product upon each usage by the consumer, thus eliminating the movement of air bubble(s) through the length of the product in the package upon each usage occasion by the consumer. Movement of air bubble(s) through the length of the product is undesirable from an aesthetic standpoint, as this can disrupt the attractive appearance of a product having visually distinct phases. This loss of product attractiveness undesirably detracts from the consumer's enjoyment of the product.
  • the container 2 is a bottlel ⁇ that can stand on either end in an upright position.
  • the container 2 comprises a reservoir 4 containing a liquid composition and an in-mold label 6.
  • the in-mold label 6 has a thickness of at least 4.5 mils; the in-mold label 6 comprising a film selected from the group of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene- acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof.
  • Types of polyethylenes include high density polyethylene (HDPE), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE).
  • Copolymers of polyethylene include polyethylene copolymers such as ethylene vinyl acetate (EVA) or ethylene.
  • the in-mold labeling process consists of placing an in-mold label 6 in an open mold in which the in-mold label 6 is held in place by vacuum, electrostatic or other means. The mold is closed and the molten plastic is forced into the mold. In-mold labeling can be done using injection or blow molding, however blow molding is the preferred process. In blow molding, air is introduced into the mold cavity which forces the molten resin in contact with the in-mold label 6 which fuses to the container 2.
  • in-mold labeling produces excellent aesthetics as the in-mold label 6 fuses with the container 2 during the molding process. With a clear in-mold label 6, the appearance can often be similar to printing on the container 2. Printing onto a curved surface can be very difficult and requires an additional step. Printing onto a plastic surface can result in scuffing or smearing which is undesirable. With in-mold labeling, no additional printing or labeling step is required thus making it a very efficient process.
  • Blow molded containers 2 can be made from polyethylene and polyethylene copolymers including high density polyethylene (HDPE), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), polyamide resins, ionomer resins, polyvinylchloride, ethylene vinyl acetate (EVA), polyester (PET) and polyester copolymers, polypropylene (PP and mixtures thereof.
  • HDPE high density polyethylene
  • MDPE medium density polyethylene
  • LDPE low density polyethylene
  • LLDPE linear low density polyethylene
  • polyamide resins polyamide resins
  • ionomer resins polyvinylchloride
  • EVA ethylene vinyl acetate
  • PET polyester copolymers
  • PP polypropylene
  • in-mold labeling is that it can be difficult for an in-mold label 6 to be placed over a surface topography with high curvature such as a ridge or valley as air can become trapped underneath the in-mold label 6 which is not desirable for consumers especially when a "no-label" look is desired. Also, the surface topography can make the label material fold on itself upon blowing of the container thereby creating an undesirable wrinkle or crease.
  • the present invention overcomes these limitations by using a thick in-mold label 6 that is capable of being applied in-mold without entrapment of air and which is not as susceptible to wrinkling or creasing.
  • in-mold labels 6 are placed on containers 2 with smooth surfaces. It was previously difficult to use in-mold labels 6 in on a surface topography 20 or especially if that surface topography comprises a transition from a concavity to a convexity 22 or a transition from a convexity to a concavity 22 on the container 2.
  • the present invention is directed towards an in- mold label 6 of sufficient thickness that is placed over a surface topography.
  • the containers 2 of the present invention may be any shape known in the art. Most preferred are generally oval containers.
  • the containers 2 used in one of the embodiments of the present invention have at least one surface topography 20 selected from the group consisting of ridges, valleys, grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography.
  • the surface topography 20 on the container 2 is typically positioned proximate to or on or covered by the in-mold label 6.
  • the in-mold label 6 is at least 4.5 mils in thickness.
  • the in-mold label 6 has a thickness ranging from about 4.5 mils to about 40 mils, preferably from about 6 mils to 12 mils, even more preferably from about 8 mils to 12 mils, even more preferably from about 10 mils to about 12 mils, even more preferably from about 8 mils to 20 mils; with a maximum of 40 mils.
  • a thick in-mold label 6 provides additional benefits in terms of resistance to squeezing, as the fused material becomes a structural part of the container thus improving its resilience and allowing for easier dispensing of fluids.
  • the in-mold label 6 may be made by techniques known in the art. The primary process is film extrusion. The in-mold label 6 may consist of one layer or multiple layers. A common process for producing in-mold label 6 s is co extrusion whereby the heat seal layer consists of a resin with a lower melting point than the printing surface in order to avoid any distortion. Another common process for producing in-mold labels 6 is by laminating two or more separate films with an adhesive or tie layer between each film. The in-mold label 6 may contain additional layers of paper or foil.
  • the in-mold label 6 is pre-printed/decorated before being placed in the mold using processes known in the art. Decoration may include foil, inks, paper, holograms or other techniques. Secondary labels such as coupons or instructions could also be attached.
  • the in- mold label 6 of the present invention may be multilayered having an inner layer and at least one outer layer. In some embodiments, the inner layer and the outer layer may have different melting points. In some embodiments, the inner layer may have a lower melting point that the outer layer.
  • the inner layer of the in-mold label is preferably heat sealable.
  • the film according to the invention can have three layers and can comprise co extruded layers including the base layer and at least one top layer on both sides. If desired, two-layered, four-layered, five-layered or more layered embodiments are also possible.
  • the film is preferably comprised of a polyolefin, preferably a propylene polymer, and optionally fillers and further additives in effective amounts in each case.
  • the film material is a polypropylene/polyethylene co- extruded film with an EVA adhesive layer.
  • propylene polymers comprise about 70% by weight of the material and 30% by weight of the material is polyethylene.
  • Preferred polyolefins are propylene polymers. These propylene polymers comprise from 90 to 100% by weight, preferably from 95 to 100% by weight, in particular from 98 to 100% by weight, of propylene units, and have a melting point of 120 0 C.
  • propylene polymers for the base layer, with isotactic propylene homopolymer being particularly preferred.
  • the stated percentages by weight are based on the respective polymer.
  • propylene polymer Also suitable is a mixture of said propylene homopolymers and/or copolymers and/or terpolymers with other polyolefins, in particular made from monomers having from 2 to 6 carbon atoms, where the mixture comprises at least 50% by weight, in particular at least 75% by weight, of propylene polymer.
  • Suitable other polyolefins in the polymer mixture are polyethylenes, in particular HDPE, MDPE, LDPE, VLDPE and LLDPE, where the proportion of these polyolefins is in each case not in excess of 15% by weight, based on the polymer mixture.
  • the inner surface, inner layer that comes into contact with the molten resin must be capable of forming a seal with the container 2 such that it does not easily come off.
  • the inner layer should be capable of melting at the temperature of the molten resin that is used to form the container 2.
  • the inner layer should be a heat seal layer.
  • the inner layer can be an adhesive layer.
  • the inner layer is preferably comprised of EVA or LDPE.
  • the in-mold label 6 is pre-printed/decorated before being placed in the mold using processes known in the art.
  • Decoration may include foil, inks, paper, holograms or other techniques. Secondary labels such as coupons or instructions could also be attached.
  • the outer layer of the multilayered film generally comprises at least 70% by weight, preferably from 75 to less than 100% by weight, in particular from 90 to 98% by weight, of a propylene polymer and in general antiblocking agents and stabilizers and, if desired, further conventional additives, such as lubricants, for example fatty acid amides or siloxanes, in effective amounts in each case. Preference is given to embodiments of the outer layer which comprise fatty acid amides. The above data in % by weight are based on the weight of the top layer.
  • the propylene polymer of the outer layer is preferably a copolymer of propylene and ethylene or propylene and butylene or propylene and another olefin having from 5 to 10 carbon atoms. Also suitable for the purposes of the invention are terpolymers of ethylene and propylene and butylene or ethylene and propylene and another olefin having from 5 to 10 carbon atoms. It is also possible to employ mixtures or blends of two or more of said copolymers and terpolymers.
  • ethylene-propylene copolymers and ethylene- propylenebutylene terpolymers preference is given to ethylene-propylene copolymers and ethylene- propylenebutylene terpolymers, in particular random ethylene-propylene copolymers having an ethylene content of from 2 to 10% by weight, preferably from 5 to 8% by weight, or random ethylene- propylene- 1 -butylene terpolymers having an ethylene content of from 1 to 10% by weight, preferably from 2 to 6% by weight, and a 1 -butylene content of from 3 to 20% by weight, preferably from 8 to 10% by weight, in each case based on the weight of the copolymer or terpolymer.
  • PP, OPP or BOPP films are corona- or flame- treated on one side, preferably on the outer layer, in order to anchor printing inks, metal layers or adhesives to be applied.
  • the opposite, inner layer usually remains untreated.
  • the in-mold label 6 film according to the invention proved to be particularly simple and reliable to segregate in an embodiment with corona- or flame- pretreatment on both sides.
  • the in-mold label thickness is at least 4.5 mils. In a preferred embodiment the in-mold label thickness is 7.75 mils. In a preferred embodiment the film used to make the label is FasClear® 8SFC in-mold film from Avery Dennison.
  • the in-mold labeling process consists of placing an in-mold label 6 in an open mold in which the in-mold label 6 is held in place by vacuum, electrostatic or other means. The mold is closed and the molten plastic is forced into the mold. In-mold labeling can be done using injection or blow molding, however blow molding is the preferred process. In blow molding, air is introduced into the mold cavity which forces the molten resin in contact with the in-mold label 6 which fuses to the container 2.
  • the container 2 of the present invention is typically formed by blow-molding.
  • the present invention also comprises a method of increasing resiliency of a container for liquid compositions.
  • the method comprises manufacturing a container for a liquid composition comprising a reservoir comprising a liquid composition, a surface topography selected from the group consisting of ridges, valleys, a grooves, dimples, depressions, bumps, convexity, concavity, ribs, protrusions, curves, raised surfaces or other surface topography.
  • the method comprises positioning an in-mold label proximate to said surface topography.
  • the in-mold label has a thickness of at least 4.5 mils.
  • the in-mold label is comprised of a material selected from the group consisting of polyethylene, copolymers of polyethylene, polypropylene, copolymers of polypropylene, nylon, polyester, copolymers of polyester, polylactic acid, cellophane, polyvinyl chloride, ionomers, ethylene- acrylic acid copolymers, metallocene polyethylene, metallocene polypropylene, and mixtures thereof.
  • the liquid composition of the present invention can be selected from the group consisting of personal care composition, cosmetic compositions, detergent compositions, medicaments, and foodstuffs.
  • suitable liquid compositions can include shampoos, conditioners, foundations, washes, soaps, and the like.
  • the liquid compositions used to in making the personal care compositions herein have substantially the same density and/or rheology.
  • suitable examples of compositions that can be used herein include, but are not limited to, U.S. Pat No. 4,159,028, issued June 26, 1979, in the name of Barker et al.: U.S. Pat. No. 4,335,103, issued June 15, 1982, in the name of Barker et al.; U.S. Pat. No. 6,245,344, issued June 12, 2001 in the name of Thibiant et al.; US Pat. No. 6,367,519, issued April 9, 2002, in the name of Thibiant et al.; US Pat. No. 6,516,838, issued February 11, 2003, in the name of Thibiant et al.
  • At least two liquid compositions are used that are physically distinct, preferably visually distinct.
  • the visually distinct phases are of a different color.
  • one or more phases can comprise a dye, pigment, pearlescent agent, lake, coloring, or mixtures thereof.
  • Colorants useful in the present invention can be, for example, selected from the group consisting of Red 30 Low Iron, FD&C Red 40 AL Lake, D&C Red Lake Blend of Lake 27 & Lake 30, FD&C Yellow 5 Al Lake, FD&C Yellow 6 Al Lake, FD&C Yellow 5 Lake, FD&C Blue #1 AL Lake, Ko wet Titanium Dioxide, D&C Red 30 Talc Lake, D&C Red 6 Barium Lake, D&C Red 7 Calcium Lake, D&C Red 34 Calcium Lake, D&C Red 30 AL lake, D&C Red 27 AL lake, D&C Yellow 10 AL lake, D&C Red 21 AL Lake, Yellow Iron Oxide, D&C Red 30 Lake, Octocir Yellow 6 AL Lake, Octocir Yellow 5 AL Lake, D&C Red 28 Lake, D&C Orange 5 Zirc Al Lake, Cos Red Oxide BC, Cos Iron Oxide Red BC, Cos Iron oxide Black BC, Cos Iron Oxide Yellow, Cos Iron Oxide Brown, Cos Iron Oxide Yellow BC, Euroxide Red Unsteril
  • the personal care composition comprises at least two physically distinct phases.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)

Abstract

La présente invention concerne un récipient pour compositions liquides comprenant un réservoir comprenant une composition liquide, une topographie de surface et une étiquette dans le moule placée à proximité de la topographie de surface de façon à améliorer la résilience du récipient. La topographie de surface est choisie dans le groupe constitué par des arêtes, des sillons, des cannelures, des encoches, des dépressions, des bosses, une convexité, une concavité, des nervures, des saillies, des courbes, des surfaces montantes ou toute autre topographie de surface. L’étiquette dans le moule a une épaisseur d’au moins 4,5 mils ; l’étiquette dans le moule étant faite à partir d'un matériau choisi dans le groupe constitué par le polyéthylène, des copolymères de polyéthylène, le polypropylène, des copolymères de polypropylène, le nylon, le polyester, des copolymères du polyester, le poly(acide lactique), la cellophane, le poly(chlorure de vinyle), des ionomères, des copolymères d’éthylène et d’acide acrylique, un métallocène polyéthylène, un métallocène polypropylène et leurs mélanges.
PCT/IB2006/054664 2005-12-08 2006-12-07 Recipient comprenant une etiquette dans le moule placee a proximite d’une topographie de surface WO2007066310A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP06832146A EP1957374A2 (fr) 2005-12-08 2006-12-07 Recipient comprenant une etiquette dans le moule placee a proximite d une topographie de surface

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US74873305P 2005-12-08 2005-12-08
US60/748,733 2005-12-08

Publications (2)

Publication Number Publication Date
WO2007066310A2 true WO2007066310A2 (fr) 2007-06-14
WO2007066310A3 WO2007066310A3 (fr) 2007-08-16

Family

ID=38007270

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2006/054664 WO2007066310A2 (fr) 2005-12-08 2006-12-07 Recipient comprenant une etiquette dans le moule placee a proximite d’une topographie de surface

Country Status (4)

Country Link
US (1) US20070163990A1 (fr)
EP (1) EP1957374A2 (fr)
CN (1) CN101326106A (fr)
WO (1) WO2007066310A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014119552A1 (fr) * 2013-01-31 2014-08-07 花王株式会社 Récipient à bouteille
WO2016162003A1 (fr) * 2015-04-06 2016-10-13 Kiefel Gmbh Procédé servant à combiner un étiquetage dans le moule et un estampage d'un produit d'emballage, ainsi qu'installation servant à combiner un étiquetage dans le moule et un estampage d'un produit d'emballage

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1874408A1 (fr) * 2005-04-13 2008-01-09 The Procter and Gamble Company Compositions de nettoyage pour l'hygiene personnelle douces, structurees et multiphasees
US7820609B2 (en) 2005-04-13 2010-10-26 The Procter & Gamble Company Mild, structured, multi-phase personal cleansing compositions comprising density modifiers
US20070167338A1 (en) * 2006-01-09 2007-07-19 Mchugh Colin M Multiphase personal care compositions comprising beads
US8104616B2 (en) 2006-02-11 2012-01-31 The Procter & Gamble Company Clamshell package for holding and displaying consumer products
US8153144B2 (en) 2006-02-28 2012-04-10 The Proctor & Gamble Company Stable multiphase composition comprising alkylamphoacetate
US20090028809A1 (en) * 2007-07-27 2009-01-29 Jonathan Robert Cetti Personal care article for sequentially dispensing compositions with variable concentrations of hydrophobic benefit materials
US20090028808A1 (en) * 2007-07-27 2009-01-29 The Procter & Gamble Company Personal care article for sequentially dispensing compositions with variable concentrations of partitioned benefit or suspended benefit agents
USD609104S1 (en) 2008-09-05 2010-02-02 Dart Industries, Inc. Bottle
US20100237068A1 (en) * 2009-03-17 2010-09-23 Rubbermaid Incorporated Container With In-Molded Exposed Panel
USD624422S1 (en) * 2009-12-03 2010-09-28 Plastipak Packaging, Inc. Container body portion
TW201121793A (en) * 2009-12-30 2011-07-01 Sipix Chemical Inc Decorated device and fabricating method thereof
EP2468643A1 (fr) * 2010-12-23 2012-06-27 KPSS-Kao Professional Salon Services GmbH Récipient doté d'une surface texturée étiquetée
USD667729S1 (en) 2011-03-07 2012-09-25 The Procter & Gamble Company Bottle
JP2016518292A (ja) * 2013-05-17 2016-06-23 ネステク ソシエテ アノニム 消費可能製品用のパッケージ及びその使用方法
MX381295B (es) * 2014-08-27 2025-03-12 Colgate Palmolive Co Botella con hueco para dedos.
CA3083367A1 (fr) * 2017-12-14 2019-06-20 Csp Technologies, Inc. Recipient a couvercle presentant une surface interne en polymere fluore et procedes de fabrication associes
CN109501419A (zh) * 2018-10-30 2019-03-22 上海海顺新型药用包装材料股份有限公司 模内标签复合膜

Family Cites Families (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2438091A (en) * 1943-09-06 1948-03-16 American Cyanamid Co Aspartic acid esters and their preparation
US2798053A (en) * 1952-09-03 1957-07-02 Goodrich Co B F Carboxylic polymers
LU67772A1 (fr) * 1973-06-08 1975-03-06
US4335103A (en) * 1977-03-28 1982-06-15 Almay, Inc. Multiphase cosmetic composition
US4159028A (en) * 1977-03-28 1979-06-26 Almay, Inc. Method of forming and containerizing a multiphase cosmetic composition
US4263363A (en) * 1979-12-20 1981-04-21 Colgate-Palmolive Company Emulsion-containing absorbent article having improved water holding capacity
US4387090A (en) * 1980-12-22 1983-06-07 The Procter & Gamble Company Hair conditioning compositions
GB2100126B (en) * 1981-06-11 1984-08-01 Colgate Palmolive Co A dentifrice
US4518578A (en) * 1983-05-16 1985-05-21 Colgate-Palmolive Company Dentifrice composition containing visually clear pigment-colored stripe
US4509949A (en) * 1983-06-13 1985-04-09 The B. F. Goodrich Company Water thickening agents consisting of copolymers of crosslinked acrylic acids and esters
USRE34584E (en) * 1984-11-09 1994-04-12 The Procter & Gamble Company Shampoo compositions
GB8713263D0 (en) * 1987-06-05 1987-07-08 Unilever Plc Spheroidal silica
EP0496433B1 (fr) * 1987-10-22 1999-03-24 The Procter & Gamble Company Compositions photoprotectrices contenant des agents chélatants
CA1340219C (fr) * 1988-04-06 1998-12-15 Tadahiko Katsura Contenant marque et procede de fabrication
JPH0670736B2 (ja) * 1989-01-11 1994-09-07 東洋製罐株式会社 型内ラベル貼着用ラベル及びラベル付プラスチック容器
US4899877A (en) * 1989-02-13 1990-02-13 Bares Group Packaging of tools
US5087445A (en) * 1989-09-08 1992-02-11 Richardson-Vicks, Inc. Photoprotection compositions having reduced dermal irritation
DD300443A5 (de) * 1989-09-13 1992-06-11 Exxon Chemical Patents Inc Heissschmelzklebstoff
US5635171A (en) * 1990-12-21 1997-06-03 L'oreal Cosmetic or pharmaceutical composition in the form of a rigid gel, particularly for containing inclusions therein
DE4207722A1 (de) * 1991-05-28 1992-12-03 Merck Patent Gmbh Oberflaechenmodifizierte plaettchenfoermige pigmente mit verbessertem aufruehrverhalten
JP2710258B2 (ja) * 1991-10-09 1998-02-10 東洋製罐株式会社 インモールドラベルを有するブロー成形ボトル
US5248495A (en) * 1992-04-16 1993-09-28 The Procter & Gamble Company Post foaming shaving gel composition
CA2096505C (fr) * 1992-05-21 1999-09-21 Robert Stanley Lee Composition exfoliante
JP2589932B2 (ja) * 1992-06-15 1997-03-12 インターナショナル・ビジネス・マシーンズ・コーポレイション 装置の割り当てのグローバルな最適化方法とシステム
FR2694494B1 (fr) * 1992-08-05 1994-09-30 Rhone Poulenc Chimie Composition cosmétique contenant en suspension des particules non hydrosolubles.
GB9223439D0 (en) * 1992-11-09 1992-12-23 Unilever Plc Washing composition
DE69429822T2 (de) * 1993-11-12 2002-11-28 The Procter & Gamble Company, Cincinnati Abschuppende zusammensetzung von salicylsäure und zwitterionischen verbindungen
US5451396A (en) * 1993-11-17 1995-09-19 S. C. Johnson & Son, Inc. Shaving compositions
GB9414573D0 (en) * 1994-07-19 1994-09-07 Unilever Plc Detergent composition
GB9414574D0 (en) * 1994-07-19 1994-09-07 Unilever Plc Detergent composition
BR9607609A (pt) * 1995-02-15 1998-06-09 Procter & Gamble Composição líquida ara limpeza da pele de formação de espuma de intensidade estável e conjunto de banho de asseio do corpo
US6080707A (en) * 1995-02-15 2000-06-27 The Procter & Gamble Company Crystalline hydroxy waxes as oil in water stabilizers for skin cleansing liquid composition
EP0839023B1 (fr) * 1995-08-07 2003-04-09 Unilever Plc Composition liquide de nettoyage comprenant un structurant induisant une phase lamellaire soluble
JPH09230791A (ja) * 1996-02-22 1997-09-05 Kao Corp 熱活性型ラベル及びラベル付き成形体の製造方法
US5935561A (en) * 1996-03-27 1999-08-10 Procter & Gamble Company Conditioning shampoo compositions containing select hair conditioning agents
US5932203A (en) * 1996-03-27 1999-08-03 Proctor & Gamble Company Conditioning shampoo compositions containing select hair conditioning esters
EP0936899A4 (fr) * 1996-06-27 2002-01-02 Procter & Gamble Compositions cosmetiques
US6194364B1 (en) * 1996-09-23 2001-02-27 The Procter & Gamble Company Liquid personal cleansing compositions which contain soluble oils and soluble synthetic surfactants
US5947335A (en) * 1996-10-15 1999-09-07 Lever Brothers Company Dual compartment package
US5929019A (en) * 1997-01-30 1999-07-27 Lever Brothers Company, Division Of Conopco, Inc. Cleansing composition with separately dispensed cleansing base and benefit base wherein benefit base also comprises surfactant
US5965501A (en) * 1997-03-28 1999-10-12 Lever Brothers Company, Division Of Conopco, Inc. Personal washing bar compositions comprising emollient rich phase/stripe
TW505521B (en) * 1997-06-25 2002-10-11 Kao Corp Hair cosmetics
JP2001519376A (ja) * 1997-10-14 2001-10-23 ザ、プロクター、エンド、ギャンブル、カンパニー 中間鎖分岐界面活性剤を含んでなるパーソナルクレンジング組成物
EP0916334A1 (fr) * 1997-11-07 1999-05-19 Unilever Plc Composition detergente
FR2780644B1 (fr) * 1998-07-03 2001-07-20 Oreal Composition cosmetique ou dermatologique sous forme d'une dispersion d'une phase huileuse et d'une phase aqueuse, stabilisee a l'aide de particules de gel cubique
GB9827614D0 (en) * 1998-12-15 1999-02-10 Unilever Plc Detergent composition
US6362156B1 (en) * 1998-12-16 2002-03-26 Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. Pourable transparent/translucent liquid detergent composition with suspended particles
US6051541A (en) * 1998-12-16 2000-04-18 Unilever Home & Personal Care, Division Of Conopco, Inc. Process for preparing pourable, transparent/translucent liquid detergent with continuous suspending system
US6176395B1 (en) * 1999-04-21 2001-01-23 Pechiney Plastic Packaging, Inc. Dual dispense container
US6176391B1 (en) * 1999-06-21 2001-01-23 Oddzon, Inc. Message providing candy dispenser
US6245344B1 (en) * 1999-07-28 2001-06-12 Patrick Thibiant Enhanced spiral compositions
US6516838B2 (en) * 1999-07-28 2003-02-11 Patrick Thibiant Apparatus and process for forming novel spiral compositions
US6533873B1 (en) * 1999-09-10 2003-03-18 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Suspending clear cleansing formulation
JP4557193B2 (ja) * 1999-10-05 2010-10-06 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング 高配向性薄片状顔料およびその製造方法
US6268322B1 (en) * 1999-10-22 2001-07-31 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Dual chamber cleansing system, comprising multiple emulsion
US6271187B1 (en) * 1999-12-01 2001-08-07 Ecolab Inc. Hand soap concentrate, use solution and method for modifying a hand soap concentrate
US6213166B1 (en) * 2000-01-12 2001-04-10 Patrick Thibiant Apparatus and process for forming novel spiral compositions
US6383999B1 (en) * 2000-02-10 2002-05-07 Unilever Home & Personal Care Usa. Division Of Conopco, Inc. Personal washing bar having adjacent emollient rich and emollient poor phases
US6534457B2 (en) * 2000-03-20 2003-03-18 Unilever Home And Personal Care Usa, Division Of Conopco, Inc. Extrudable multiphase composition comprising lamellar phase inducing structurant in each phase
US6534456B2 (en) * 2000-03-20 2003-03-18 Unilever Home And Personal Care Usa, Division Of Conopco, Inc. Extrudable multiphase composition comprising a lamellar phase and an isotropic phase
CN1424901A (zh) * 2000-04-17 2003-06-18 宝洁公司 相分离的漂洗型毛发染色/清洁产品
US6245323B1 (en) * 2000-05-26 2001-06-12 Engelhard Corporation Bonded metal hydroxide-organic composite polymer films on particulate substrates
US6429177B1 (en) * 2000-08-22 2002-08-06 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Separating multi-phase personal wash composition in a transparent or translucent package
FR2814677B1 (fr) * 2000-10-03 2003-04-18 Oreal Composition cosmetique a phase continue hydrophile comprenant un pigment goniochromatique multicouche et son utilisation en maquillage
GB0026473D0 (en) * 2000-10-30 2000-12-13 Unilever Plc Shear gel compositions
IL156047A0 (en) * 2000-12-06 2003-12-23 Trespaphan Gmbh Label film with improved adhesion
US6395691B1 (en) * 2001-02-28 2002-05-28 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Personal wash compositions containing particle-in-oil dispersion
US6682726B2 (en) * 2001-04-30 2004-01-27 The Gillette Company Self-foaming shaving lotion
US7192598B2 (en) * 2001-05-17 2007-03-20 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Wet-skin treatment compositions
US6923975B2 (en) * 2001-05-17 2005-08-02 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Method of enhanced moisture or reduced drying using wet-skin treatment compositions
EP1432782B1 (fr) * 2001-08-02 2006-10-11 Unilever Plc Traitement pour substrats
GB0119831D0 (en) * 2001-08-14 2001-10-10 Unilever Plc Dual compartment packaged cosmetic composition
DE10200724A1 (de) * 2002-01-11 2003-07-24 Clariant Gmbh Dreiphasensysteme
US6673755B2 (en) * 2002-01-16 2004-01-06 The Procter & Gamble Company Personal cleansing compositions containing cleansing and skin active phases separated by one or more packaging barriers
MX260183B (es) * 2002-02-08 2008-09-02 Procter & Gamble Composiciones acondicionadoras de la piel que se retiran por enjuague.
ES2193875B2 (es) * 2002-04-09 2005-03-01 Laboratorios Del Dr. Esteve, S.A. Derivados de benzoxazinona, su preparacion y su aplicacion como medicamentos.
US20030211069A1 (en) * 2002-05-09 2003-11-13 The Procter & Gamble Company Rinsable skin conditioning compositions
US6664217B1 (en) * 2002-07-18 2003-12-16 Unilever Home & Personal Care, Usa Division Of Conopco, Inc. Toilet bar having simultaneous exfoliating and moisturizing properties
US6787511B2 (en) * 2002-08-14 2004-09-07 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Biphasic composition induced by polydextrose
US6780826B2 (en) * 2002-09-11 2004-08-24 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Oil-containing personal wash compositions or emulsions comprising particles of high refractive index and defined thickness, geometry and size
US6759376B2 (en) * 2002-09-11 2004-07-06 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Oil-containing personal wash liquid compositions or emulsions comprising particles of high refractive index and defined thickness, geometry and size
CA2495084C (fr) * 2002-09-20 2013-02-19 The Procter & Gamble Company Compositions de demaquillage a liquides rayes contenant une phase de nettoyage et une phase d'agrement separees
CA2502760C (fr) * 2002-11-04 2010-05-04 The Procter & Gamble Company Compositions pour hygiene personnelle liquides striees contenant une phase de nettoyage et une phase active distincte a stabilite accrue
US7514131B2 (en) * 2002-11-22 2009-04-07 Yupo Corporation In-mold label with separable part
US20050100570A1 (en) * 2003-05-08 2005-05-12 The Procter & Gamble Company Multi-phase personal care composition
US6929678B2 (en) * 2003-05-19 2005-08-16 Teledyne Tekmar Company Purge and trap concentrator with improved drying
BRPI0412732A (pt) * 2003-07-22 2006-09-26 Rhodia composição de tensoativo estruturado, composição para cuidados pessoais e composição de tensoativo aquosa
US20050143269A1 (en) * 2003-12-24 2005-06-30 Wei Karl S. Multi-phase personal cleansing compositions comprising a lathering cleansing phase and a non-lathering structured aqueous phase
US20050139574A1 (en) * 2003-12-30 2005-06-30 Unilever Home & Personal Care Usa Bottle with soft feel handle
US6903057B1 (en) * 2004-05-19 2005-06-07 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Personal product liquid cleansers stabilized with starch structuring system
US8623341B2 (en) * 2004-07-02 2014-01-07 The Procter & Gamble Company Personal care compositions containing cationically modified starch and an anionic surfactant system
US20060102654A1 (en) * 2004-07-23 2006-05-18 Seys Andrew C Multiple dispenser container
US7678754B2 (en) * 2004-11-01 2010-03-16 Shell Oil Company System and method for cleaning and/or treating surfaces of objects
US8147853B2 (en) * 2005-02-15 2012-04-03 The Procter & Gamble Company Personal care compositions containing hydrophobically modified non-platelet particles
US7527077B2 (en) * 2005-02-25 2009-05-05 The Procter & Gamble Company Multi-phase personal care compositions, processes for making and providing, and articles of commerce
US7820609B2 (en) * 2005-04-13 2010-10-26 The Procter & Gamble Company Mild, structured, multi-phase personal cleansing compositions comprising density modifiers
EP1874408A1 (fr) * 2005-04-13 2008-01-09 The Procter and Gamble Company Compositions de nettoyage pour l'hygiene personnelle douces, structurees et multiphasees
US20070167338A1 (en) * 2006-01-09 2007-07-19 Mchugh Colin M Multiphase personal care compositions comprising beads
US8104616B2 (en) * 2006-02-11 2012-01-31 The Procter & Gamble Company Clamshell package for holding and displaying consumer products

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014119552A1 (fr) * 2013-01-31 2014-08-07 花王株式会社 Récipient à bouteille
WO2016162003A1 (fr) * 2015-04-06 2016-10-13 Kiefel Gmbh Procédé servant à combiner un étiquetage dans le moule et un estampage d'un produit d'emballage, ainsi qu'installation servant à combiner un étiquetage dans le moule et un estampage d'un produit d'emballage

Also Published As

Publication number Publication date
US20070163990A1 (en) 2007-07-19
CN101326106A (zh) 2008-12-17
EP1957374A2 (fr) 2008-08-20
WO2007066310A3 (fr) 2007-08-16

Similar Documents

Publication Publication Date Title
US20070163990A1 (en) Container comprising an in-mold label positioned proximate to a surface topography
JP7442649B2 (ja) 色のグラデーションを有するブロー成形多層物品
AU2010224411C1 (en) Container with enhanced display
US11814208B2 (en) Blow molded article with visual effects
KR101262467B1 (ko) 개량된 파지부를 갖는 오버몰딩된 용기 및 그 제조 방법
CA2568588C (fr) Emballage pour des articles de soins personnels comportant une etiquette thermoretractable
JP2007521990A (ja) ２つ又はそれ以上の材料で作製されたプリフォーム及びこれらを得るための方法
US20130292287A1 (en) Flexible Containers Having a Decoration Panel
CN112867674B (zh) 吹塑多层制品
US20050139574A1 (en) Bottle with soft feel handle
WO2016206611A1 (fr) Article présentant différentes surfaces texturées
WO2002072441A1 (fr) Procede de formation d'un manchon retractable pour une bouteille avec poignee
BRPI0410670B1 (pt) frasco
WO2012085042A1 (fr) Récipient ayant une surface texturée étiquetée
MX2008007331A (en) A container comprising an in-mold label positioned proximate to a surface topography
JP7482679B2 (ja) ラミネートチューブ用積層体
JP5002879B2 (ja) 多層ブロー成形ボトル
CN106687382A (zh) 抗划伤性和防污性优异的塑料容器
US20230294887A1 (en) Cap of a package suitable for storing personal health care products
US20230294886A1 (en) Cap of a package suitable for storing personal health care products
JP2019066582A (ja) 熱収縮性筒状ラベル
JP3676519B2 (ja) 遮光性ラベル付き容器
MXPA06008667A (en) Preforms made of two or more materials and processes for obtaining them
JPH0535247U (ja) インモールドラベルを有する軟質のブロー成形ボトル

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200680046211.2

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2006832146

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: MX/a/2008/007331

Country of ref document: MX

NENP Non-entry into the national phase

Ref country code: DE

WWP Wipo information: published in national office

Ref document number: 2006832146

Country of ref document: EP

点击 这是indexloc提供的php浏览器服务，不要输入任何密码和下载