WO2006108364A1 - Textiles contenant au moins une couche de nanofibres polymeriques et procede de production de celle-ci par filage electrostatique a partir de la solution polymerique - Google Patents
Textiles contenant au moins une couche de nanofibres polymeriques et procede de production de celle-ci par filage electrostatique a partir de la solution polymerique Download PDFInfo
- Publication number
- WO2006108364A1 WO2006108364A1 PCT/CZ2006/000018 CZ2006000018W WO2006108364A1 WO 2006108364 A1 WO2006108364 A1 WO 2006108364A1 CZ 2006000018 W CZ2006000018 W CZ 2006000018W WO 2006108364 A1 WO2006108364 A1 WO 2006108364A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- nanofibres
- polymer
- spinning
- low molecular
- created
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 73
- 238000010041 electrostatic spinning Methods 0.000 title claims abstract description 34
- 239000004753 textile Substances 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims description 18
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 78
- 239000002245 particle Substances 0.000 claims abstract description 43
- 238000009987 spinning Methods 0.000 claims abstract description 40
- 230000005684 electric field Effects 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 39
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 38
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 25
- 229910052709 silver Inorganic materials 0.000 claims description 25
- 239000004332 silver Substances 0.000 claims description 25
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 19
- 239000013543 active substance Substances 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 14
- 230000009467 reduction Effects 0.000 claims description 13
- 239000000975 dye Substances 0.000 claims description 7
- 150000002739 metals Chemical class 0.000 claims description 7
- 239000002121 nanofiber Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 4
- 239000002923 metal particle Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 description 59
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000000845 anti-microbial effect Effects 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 239000002105 nanoparticle Substances 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 206010052428 Wound Diseases 0.000 description 3
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000013528 metallic particle Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000035876 healing Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241001076388 Fimbria Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 230000000721 bacterilogical effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 150000001455 metallic ions Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
- D01D5/0038—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by solvent evaporation, i.e. dry electro-spinning
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/603—Including strand or fiber material precoated with other than free metal or alloy
- Y10T442/607—Strand or fiber material is synthetic polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
- Y10T442/614—Strand or fiber material specified as having microdimensions [i.e., microfiber]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/654—Including a free metal or alloy constituent
- Y10T442/658—Particulate free metal or alloy constituent
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Mechanical Engineering (AREA)
- Nanotechnology (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Artificial Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Nonwoven Fabrics (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Woven Fabrics (AREA)
Abstract
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2006233443A AU2006233443A1 (en) | 2005-04-11 | 2006-04-10 | Textiles containing at least one layer of polymeric nanofibres and method of production of the layer of polymeric nanofibres from the polymer solution through electrostatic spinning |
EA200702132A EA012635B1 (ru) | 2005-04-11 | 2006-04-10 | Способ изготовления слоя нановолокон |
US11/911,134 US20080207076A1 (en) | 2005-04-11 | 2006-04-10 | Textiles Containing at Least One Layer of Polymeric Nanofibres and Method of Production of the Layer of Polymeric Nanofibres From the Polymer Solution Through Electrostatic Spinning |
CA 2602450 CA2602450A1 (fr) | 2005-04-11 | 2006-04-10 | Textiles contenant au moins une couche de nanofibres polymeriques et procede de production de celle-ci par filage electrostatique a partir de la solution polymerique |
EP20060722445 EP1869232A1 (fr) | 2005-04-11 | 2006-04-10 | Textiles contenant au moins une couche de nanofibres polymeriques et procede de production de celle-ci par filage electrostatique a partir de la solution polymerique |
JP2008505721A JP2008536022A (ja) | 2005-04-11 | 2006-04-10 | 少なくとも重合体のナノ繊維の一層を含んでいる織物及び重合体溶液から静電紡糸により重合体のナノ繊維の層を製造する方法 |
CN2006800210179A CN101198728B (zh) | 2005-04-11 | 2006-04-10 | 包含至少一层聚合物纳米纤维的纺织品以及通过静电纺丝由聚合物溶液制备聚合物纳米纤维层的方法 |
HK08110829A HK1118872A1 (en) | 2005-04-11 | 2008-09-29 | Textiles containing at least one layer of polymeric nanofibres and method of production of the layer of polymeric nanofibres from the polymer solution through electrostatic spinning |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CZ20050225A CZ300797B6 (cs) | 2005-04-11 | 2005-04-11 | Textilie obsahující alespon jednu vrstvu polymerních nanovláken a zpusob výroby vrstvy polymerních nanovláken z roztoku polymeru elektrostatickým zvláknováním |
CZPV2005-225 | 2005-04-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006108364A1 true WO2006108364A1 (fr) | 2006-10-19 |
Family
ID=36676579
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CZ2006/000018 WO2006108364A1 (fr) | 2005-04-11 | 2006-04-10 | Textiles contenant au moins une couche de nanofibres polymeriques et procede de production de celle-ci par filage electrostatique a partir de la solution polymerique |
Country Status (12)
Country | Link |
---|---|
US (1) | US20080207076A1 (fr) |
EP (1) | EP1869232A1 (fr) |
JP (1) | JP2008536022A (fr) |
KR (1) | KR20080005549A (fr) |
CN (1) | CN101198728B (fr) |
AU (1) | AU2006233443A1 (fr) |
CA (1) | CA2602450A1 (fr) |
CZ (1) | CZ300797B6 (fr) |
EA (1) | EA012635B1 (fr) |
HK (1) | HK1118872A1 (fr) |
TW (1) | TW200702502A (fr) |
WO (1) | WO2006108364A1 (fr) |
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WO2008049250A1 (fr) * | 2006-10-23 | 2008-05-02 | Schoeller Textil Ag | Fibres polymères électrofilées microbicides comprenant des nanoparticules de polyéthylène imine pour applications textiles |
WO2008149248A3 (fr) * | 2007-06-08 | 2009-04-09 | Kimberly Clark Co | Procédés d'application d'agents de bien-être de la peau à une bande de nontissé à travers des nanofibres d'électrofilature |
EP2070728A1 (fr) | 2007-12-15 | 2009-06-17 | The Goodyear Tire & Rubber Company | Pneu avec un composant contenant une nano-fibre polymérique |
EP1888331A4 (fr) * | 2005-06-07 | 2009-07-08 | Univ Akron | Structures de nanofibres pour le support de materiaux biologiques |
WO2009141633A3 (fr) * | 2008-05-23 | 2010-01-21 | Convatec Technologies Inc. | Nanofibres de polysaccharides ayant des propriétés antimicrobiennes |
JPWO2008111609A1 (ja) * | 2007-03-14 | 2010-06-24 | 日東紡績株式会社 | シリカ繊維の製造方法 |
JP2010526941A (ja) * | 2007-04-11 | 2010-08-05 | ナショナル ユニヴァーシティー オブ シンガポール | 化学的物質および生物学的物質の除染用の繊維 |
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US7815427B2 (en) | 2007-11-20 | 2010-10-19 | Clarcor, Inc. | Apparatus and method for reducing solvent loss for electro-spinning of fine fibers |
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US7967588B2 (en) | 2007-11-20 | 2011-06-28 | Clarcor Inc. | Fine fiber electro-spinning equipment, filter media systems and methods |
WO2012052535A1 (fr) | 2010-10-21 | 2012-04-26 | Hi Tech Textile Holding Gmbh | Procédé et dispositif de fabrication d'un non-tissé composite |
US8715828B2 (en) | 2008-08-29 | 2014-05-06 | Dow Corning Corporation | Emulsion of metallized particles comprising a compound having a pendant Si-H group |
US9101860B2 (en) | 2007-11-20 | 2015-08-11 | Clarcor Inc. | Filtration medias, fine fibers under 100 nanometers, and methods |
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US9547011B2 (en) | 2013-03-14 | 2017-01-17 | Tricol Biomedical, Inc. | Biocompatible and bioabsorbable derivatized chitosan compositions |
US9731966B2 (en) | 2010-02-26 | 2017-08-15 | Clarcor Inc. | Non-pleated tubular depth filter having fine fiber filtration media |
WO2017218692A1 (fr) * | 2016-06-14 | 2017-12-21 | California Institute Of Technology | Nanofibres décorées avec des nanoparticules et leurs procédés de fabrication |
EP3288600A4 (fr) * | 2015-04-28 | 2019-01-02 | ConvaTec Technologies Inc. | Nanofibres antibactériennes |
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WO2008049250A1 (fr) * | 2006-10-23 | 2008-05-02 | Schoeller Textil Ag | Fibres polymères électrofilées microbicides comprenant des nanoparticules de polyéthylène imine pour applications textiles |
JPWO2008111609A1 (ja) * | 2007-03-14 | 2010-06-24 | 日東紡績株式会社 | シリカ繊維の製造方法 |
EP2133451A4 (fr) * | 2007-04-03 | 2011-06-08 | Nisshin Spinning | Nanofibre antibactérienne |
US9090995B2 (en) | 2007-04-03 | 2015-07-28 | Nisshinbo Holdings, Inc. | Process of making an antibacterial nanofiber |
JP2010526941A (ja) * | 2007-04-11 | 2010-08-05 | ナショナル ユニヴァーシティー オブ シンガポール | 化学的物質および生物学的物質の除染用の繊維 |
WO2008149248A3 (fr) * | 2007-06-08 | 2009-04-09 | Kimberly Clark Co | Procédés d'application d'agents de bien-être de la peau à une bande de nontissé à travers des nanofibres d'électrofilature |
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US8715828B2 (en) | 2008-08-29 | 2014-05-06 | Dow Corning Corporation | Emulsion of metallized particles comprising a compound having a pendant Si-H group |
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Also Published As
Publication number | Publication date |
---|---|
CZ2005225A3 (cs) | 2006-11-15 |
CA2602450A1 (fr) | 2006-10-19 |
KR20080005549A (ko) | 2008-01-14 |
EP1869232A1 (fr) | 2007-12-26 |
CZ300797B6 (cs) | 2009-08-12 |
HK1118872A1 (en) | 2009-02-20 |
TW200702502A (en) | 2007-01-16 |
CN101198728B (zh) | 2010-09-08 |
US20080207076A1 (en) | 2008-08-28 |
CN101198728A (zh) | 2008-06-11 |
EA012635B1 (ru) | 2009-12-30 |
JP2008536022A (ja) | 2008-09-04 |
AU2006233443A1 (en) | 2006-10-19 |
EA200702132A1 (ru) | 2008-08-29 |
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