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WO2006101999A3 - Modification de la rheologie d'interpolymeres d'ethylene/alpha-olefines et particules produites a partir de ceux-ci - Google Patents

Modification de la rheologie d'interpolymeres d'ethylene/alpha-olefines et particules produites a partir de ceux-ci Download PDF

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Publication number
WO2006101999A3
WO2006101999A3 PCT/US2006/009559 US2006009559W WO2006101999A3 WO 2006101999 A3 WO2006101999 A3 WO 2006101999A3 US 2006009559 W US2006009559 W US 2006009559W WO 2006101999 A3 WO2006101999 A3 WO 2006101999A3
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WO
WIPO (PCT)
Prior art keywords
ethylene
block
interpolymers
interpolymer
olefins
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Application number
PCT/US2006/009559
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English (en)
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WO2006101999A2 (fr
WO2006101999A8 (fr
Inventor
Yunwa Wilson Cheung
Felipe Martinez
Pankaj P Gupta
Original Assignee
Dow Global Technologies Inc
Yunwa Wilson Cheung
Felipe Martinez
Pankaj P Gupta
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority claimed from PCT/US2005/008917 external-priority patent/WO2005090427A2/fr
Priority to EP06748412.1A priority Critical patent/EP1858971B1/fr
Priority to JP2008502056A priority patent/JP5231985B2/ja
Priority to AU2006227458A priority patent/AU2006227458A1/en
Priority to CN2006800083811A priority patent/CN101351498B/zh
Application filed by Dow Global Technologies Inc, Yunwa Wilson Cheung, Felipe Martinez, Pankaj P Gupta filed Critical Dow Global Technologies Inc
Priority to MX2007011317A priority patent/MX2007011317A/es
Priority to BRPI0609850-9A priority patent/BRPI0609850B1/pt
Priority to KR1020077021048A priority patent/KR101243003B1/ko
Priority to CA002601337A priority patent/CA2601337A1/fr
Priority to BR122017015865-1A priority patent/BR122017015865B1/pt
Publication of WO2006101999A2 publication Critical patent/WO2006101999A2/fr
Publication of WO2006101999A3 publication Critical patent/WO2006101999A3/fr
Publication of WO2006101999A8 publication Critical patent/WO2006101999A8/fr

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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F295/00—Macromolecular compounds obtained by polymerisation using successively different catalyst types without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
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    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
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    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C08F297/086—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene the block polymer contains at least three blocks
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
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    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Gasket Seals (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

Une modification de la rhéologie d'un interpolymère d'éthylène/α-oléfines est obtenue par un mélange de l'interpolymère avec au moins une polyoléfine ramifiée. Les polyoléfines peuvent être des homopolymères ou des interpolymères et avoir un indice de ramification inférieur à 1. L'interpolymère d'éthylène/α-oléfines est un copolymère séquencé ayant au moins un bloc dur et au moins un bloc mou. Le bloc mou comprend une quantité supérieure de comonomères par rapport au bloc dur. L'interpolymère séquencé présente un certain nombre de caractéristiques uniques ici décrites. L'interpolymère d'éthylène/α-oléfines à rhéologie modifiée, c'est-à-dire, les mélanges polymères obtenus, peut être extrudé ou moulé en de nombreux articles utiles tels que des films, des feuilles, des profilés, des joints, des mousses, etc.
PCT/US2006/009559 2005-03-17 2006-03-15 Modification de la rheologie d'interpolymeres d'ethylene/alpha-olefines et particules produites a partir de ceux-ci WO2006101999A2 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
BR122017015865-1A BR122017015865B1 (pt) 2005-03-17 2006-03-15 Mistura polimérica, perfil, gaxeta, espuma e artigo termoformado
CA002601337A CA2601337A1 (fr) 2005-03-17 2006-03-15 Modification de la rheologie d'interpolymeres d'ethylene/alpha-olefines et particules produites a partir de ceux-ci
JP2008502056A JP5231985B2 (ja) 2005-03-17 2006-03-15 エチレン／α−オレフィンの共重合体およびそれらから製造される製品のレオロジー改良
AU2006227458A AU2006227458A1 (en) 2005-03-17 2006-03-15 Rheology modification of interpolymers of ethylene/alpha-olefins and articles made therefrom
CN2006800083811A CN101351498B (zh) 2005-03-17 2006-03-15 乙烯/α-烯烃共聚体的流变改性体及由其制造的制品
EP06748412.1A EP1858971B1 (fr) 2005-03-17 2006-03-15 Modification de la rheologie d'interpolymeres d'ethylene/alpha-olefines et particules produites a partir de ceux-ci
MX2007011317A MX2007011317A (es) 2005-03-17 2006-03-15 Modificacion de la reologia de interpolimeros de etileno/alfa-olefinas, y articulos hechos a partir de los mismos.
BRPI0609850-9A BRPI0609850B1 (pt) 2005-03-17 2006-03-15 Mistura polimérica, perfil, gaxeta, espuma e artigo termoformado
KR1020077021048A KR101243003B1 (ko) 2005-03-17 2006-03-15 에틸렌/α-올레핀의 혼성중합체의 유변성 개질 및 그로부터제조한 성형품

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
USPCT/US2005/008917 2005-03-17
PCT/US2005/008917 WO2005090427A2 (fr) 2004-03-17 2005-03-17 Composition de catalyseur comportant un agent de transfert pour la formation de copolymere d'ethylene multibloc
US71803605P 2005-09-16 2005-09-16
US60/718,036 2005-09-16

Publications (3)

Publication Number Publication Date
WO2006101999A2 WO2006101999A2 (fr) 2006-09-28
WO2006101999A3 true WO2006101999A3 (fr) 2007-08-23
WO2006101999A8 WO2006101999A8 (fr) 2007-10-04

Family

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PCT/US2006/009559 WO2006101999A2 (fr) 2005-03-17 2006-03-15 Modification de la rheologie d'interpolymeres d'ethylene/alpha-olefines et particules produites a partir de ceux-ci

Country Status (13)

Country Link
EP (1) EP1858971B1 (fr)
JP (1) JP5231985B2 (fr)
KR (1) KR101243003B1 (fr)
CN (1) CN101351498B (fr)
AR (1) AR054239A1 (fr)
AU (1) AU2006227458A1 (fr)
BR (2) BRPI0609850B1 (fr)
CA (1) CA2601337A1 (fr)
MX (1) MX2007011317A (fr)
RU (1) RU2007134416A (fr)
SG (1) SG160420A1 (fr)
TW (1) TWI374149B (fr)
WO (1) WO2006101999A2 (fr)

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BR122018013747B1 (pt) 2007-04-24 2021-10-26 Dow Global Technologies Inc Artigo termoformado
EP2000504A1 (fr) * 2007-06-08 2008-12-10 Borealis Technology Oy Composition polymère dotée d'une grande résistance aux chocs et d'un point de fusion élevé
WO2010039628A2 (fr) * 2008-10-03 2010-04-08 Dow Global Technologies Inc. Mélange de polymères avec des interpolymères d’éthylène/d’α-oléfine
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US8653196B2 (en) * 2010-01-11 2014-02-18 Dow Global Technologies, Llc Method for preparing polyethylene with high melt strength
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TW200640957A (en) 2006-12-01
KR101243003B1 (ko) 2013-03-12
EP1858971B1 (fr) 2019-04-24
TWI374149B (en) 2012-10-11
BR122017015865B1 (pt) 2019-10-01
AR054239A1 (es) 2007-06-13
BRPI0609850A2 (pt) 2010-05-04
EP1858971A2 (fr) 2007-11-28
SG160420A1 (en) 2010-04-29
RU2007134416A (ru) 2009-03-20
CN101351498A (zh) 2009-01-21
AU2006227458A1 (en) 2006-09-28
JP2008537563A (ja) 2008-09-18
JP5231985B2 (ja) 2013-07-10
KR20070120107A (ko) 2007-12-21
CN101351498B (zh) 2011-10-26
WO2006101999A8 (fr) 2007-10-04
MX2007011317A (es) 2007-11-07
CA2601337A1 (fr) 2006-09-28
BRPI0609850B1 (pt) 2022-09-27

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