WO2006035339A1 - Lampe a decharge de gaz basse pression - Google Patents
Lampe a decharge de gaz basse pression Download PDFInfo
- Publication number
- WO2006035339A1 WO2006035339A1 PCT/IB2005/053056 IB2005053056W WO2006035339A1 WO 2006035339 A1 WO2006035339 A1 WO 2006035339A1 IB 2005053056 W IB2005053056 W IB 2005053056W WO 2006035339 A1 WO2006035339 A1 WO 2006035339A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas discharge
- low
- radiation
- pressure gas
- lamp
- Prior art date
Links
- 230000005855 radiation Effects 0.000 claims abstract description 83
- 229910052738 indium Inorganic materials 0.000 claims abstract description 9
- -1 oxides Chemical class 0.000 claims abstract description 9
- 230000001965 increasing effect Effects 0.000 claims abstract description 8
- 150000004770 chalcogenides Chemical class 0.000 claims abstract description 6
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052802 copper Inorganic materials 0.000 claims abstract description 4
- 239000010949 copper Substances 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 150000002259 gallium compounds Chemical class 0.000 claims abstract description 3
- 150000004820 halides Chemical class 0.000 claims abstract description 3
- 150000004678 hydrides Chemical class 0.000 claims abstract description 3
- 150000004679 hydroxides Chemical class 0.000 claims abstract description 3
- 150000002902 organometallic compounds Chemical class 0.000 claims abstract description 3
- 230000000737 periodic effect Effects 0.000 claims abstract description 3
- 229910052716 thallium Inorganic materials 0.000 claims abstract description 3
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims abstract description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- UPWPDUACHOATKO-UHFFFAOYSA-K gallium trichloride Chemical compound Cl[Ga](Cl)Cl UPWPDUACHOATKO-UHFFFAOYSA-K 0.000 claims 1
- SRVXDMYFQIODQI-UHFFFAOYSA-K gallium(iii) bromide Chemical compound Br[Ga](Br)Br SRVXDMYFQIODQI-UHFFFAOYSA-K 0.000 claims 1
- DWRNSCDYNYYYHT-UHFFFAOYSA-K gallium(iii) iodide Chemical compound I[Ga](I)I DWRNSCDYNYYYHT-UHFFFAOYSA-K 0.000 claims 1
- PSCMQHVBLHHWTO-UHFFFAOYSA-K indium(iii) chloride Chemical compound Cl[In](Cl)Cl PSCMQHVBLHHWTO-UHFFFAOYSA-K 0.000 claims 1
- JKNHZOAONLKYQL-UHFFFAOYSA-K tribromoindigane Chemical compound Br[In](Br)Br JKNHZOAONLKYQL-UHFFFAOYSA-K 0.000 claims 1
- RMUKCGUDVKEQPL-UHFFFAOYSA-K triiodoindigane Chemical compound I[In](I)I RMUKCGUDVKEQPL-UHFFFAOYSA-K 0.000 claims 1
- 239000007789 gas Substances 0.000 description 76
- KLRHPHDUDFIRKB-UHFFFAOYSA-M indium(i) bromide Chemical compound [Br-].[In+] KLRHPHDUDFIRKB-UHFFFAOYSA-M 0.000 description 16
- 238000005259 measurement Methods 0.000 description 8
- 230000008878 coupling Effects 0.000 description 7
- 238000010168 coupling process Methods 0.000 description 7
- 238000005859 coupling reaction Methods 0.000 description 7
- 239000002245 particle Substances 0.000 description 6
- 238000001228 spectrum Methods 0.000 description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000012780 transparent material Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 238000002310 reflectometry Methods 0.000 description 3
- 208000002874 Acne Vulgaris Diseases 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 230000009102 absorption Effects 0.000 description 2
- 206010000496 acne Diseases 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000001427 coherent effect Effects 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 235000013405 beer Nutrition 0.000 description 1
- 229910001423 beryllium ion Inorganic materials 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000009103 reabsorption Effects 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/70—Lamps with low-pressure unconstricted discharge having a cold pressure < 400 Torr
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/30—Vessels; Containers
- H01J61/35—Vessels; Containers provided with coatings on the walls thereof; Selection of materials for the coatings
Definitions
- the invention relates to a low-pressure gas discharge lamp that comprises at least a gas-discharge vessel containing a gas filling, and components for producing and maintaining a low-pressure gas discharge.
- charge carriers which are particularly electrons but may also be ions
- charge carriers are accelerated in the gas discharge vessel, by an electrical field between the electrodes of the lamp, in such a way that they collide with the gas atoms or molecules in the gas filling. These collisions excite the gas filling and ionize it. When the atoms or molecules return to their ground state, atomic or molecular radiation is emitted.
- the generation of light in conventional low-pressure gas discharge lamps, i.e. particularly in lamps that contain mercury in the gas filling is accomplished essentially by means of atomic radiation.
- radiation density is a measure of the value of the intensity of the radiation in a wavelength range, which range may be situated both in the region of the wavelength spectrum that is visible to the human eye and in the one that is not.
- Low-pressure gas discharge lamps have also been described in which it is particularly molecular radiation that is emitted, such for example as in EP 1 187 173 A2 or EP l 187 174 A2.
- the low-pressure gas discharge lamp that is described in EP 1 187 173 A2 is fitted with a gas discharge vessel that contains a copper-containing gas filling and a buffer gas, and with components for producing and maintaining a low-pressure gas discharge.
- a low-pressure gas discharge lamp that is fitted with a gas discharge vessel that contains an indium-containing gas filling and a buffer gas.
- higher radiation densities are required for the molecular radiation that is emitted.
- the object of the invention is achieved by a low-pressure gas discharge lamp having the features claimed in claim 1.
- the low-pressure gas discharge lamp according to the invention comprises at least a gas discharge vessel that contains a gas filling having a copper, indium, thallium or gallium compound selected from the group consisting of the halides, oxides, chalcogenides, hydroxides, hydrides, or the organometallic compounds, or the tin halides, or the chalcogenides of the main group 4 of the periodic table, or mixtures thereof, and that contains a buffer gas, and components for producing and maintaining a low-pressure gas discharge, the gas discharge vessel having at least one region that serves primarily as an exit opening for the molecular radiation of a predetermined wavelength range and a predetermined radiation density that is emitted, which radiation density, when the lamp is operating, is increased in comparison with the radiation density at the other regions of the discharge vessel at which radiation can, in principle, emerge.
- a gas discharge vessel that contains a gas filling having a copper, indium, thallium or gallium compound selected from the group consisting of the halides, oxide
- lamps according to the invention can thus be excited and operated by means of internal or external lamp electrodes or entirely without electrodes.
- the lamp When the lamp is operated by external electrodes (electrical field is coupled in), it is generally operated by means of capacitive coupling; the possibilities when there are no electrodes are, in particular, inductive operation (coupling of the magnetic field) or microwave operation (coupling of the electromagnetic field).
- Components for producing and maintaining within the meaning of the invention are components that are known for applications and modes of operation of this kind, such as internal and external electrodes. These components may in turn comprise a plurality of components or parts.
- the lamp according to the invention may be used in particular for tanning purposes and for treating acne, using in particular the directly emitted UV radiation for this, and for general lighting applications, particularly if the radiation from the molecules is in the visible range of the spectrum.
- Other preferred fields of application are as an aperture lamp (with or without phosphors), particularly for general lighting applications, and as a lamp in devices for office automation (OA), e.g. copying machines and color scanners, or for the background lighting of displays, e.g. liquid crystal displays.
- the shape of the aperture which is preferably in the form of a rectangular slot. Shapes such as, for example, wavy lines or letters come within the scope of the invention.
- this low-pressure gas discharge lamp had, in particular, a gas discharge vessel of quartz glass that was of cylindrical geometry and had a diameter of approximately 25 mm and a length of approximately 250 mm.
- the gas discharge vessel also contained a gas filling having indium halides (InBr).
- InBr indium halides
- the measurements on the first measuring set-up were made radially relative to the longitudinal axis of the gas discharge vessel, i.e. the measurements of the radiation emitted took place at right angles to the surface of the cylindrical gas discharge vessel, or in other words were what is termed side-on.
- this measured spectrum from the first measuring set-up i.e. the dependence of the radiation density on the particular wavelength, is represented by the broken line.
- the spectrum that can be seen in Fig. 1 is characterized in particular by the excursions of the band emission of the InBr molecule between approximately 355 nm and approximately 390 nm and of the band emissions of atomic indium at approximately 451 nm, 410 nm, 326 nm and 304 nm.
- the measurements on the second measuring set-up took place under similar conditions but axially in relation to the longitudinal axis of the gas discharge vessel, i.e. the measurement of the radiation emitted was made along the longitudinal axis of the cylindrical gas discharge vessel.
- this unexpected, measured effect can be used to deliberately increase the radiation density with preset operating and geometrical parameters - without any increase in the power to the lamp. This is done by exploiting the molecular radiation in selected wavelength ranges for this purpose, which radiation can, if required, be increased still further by making suitable provisions (e.g. back reflection in the gas discharge. This is successfully achieved particularly in a case where the molecular radiation from the gas discharge space is emitted by only a small part of the surface of the lamp.
- the increase that is possible in the radiation density as compared with the radiation density when no additional measures are taken is dependent, as well as on geometrical factors, in particularly on the form of radiating molecule used.
- the radiation density S that can be achieved is generally proportional to the particle density of the radiating species and on the effective path length L eff over which this radiation is built up through the discharge volume along the beam to the eye. As long as the self-absorption of the emitted radiation from the radiating species (from the molecules N m0 ⁇ in this case) is small, the radiation density S is linearly dependent on the particle density N mo i and the effective path length L e fr:
- This maximum molecule density N_max mo i at which in increase in radiation density is, in principle, still possible can be defined as a function of molecular parameters such as, amongst others, the transition probability A ba n d of the molecule band being considered and the latter's width of emission ⁇ band, and as a function of geometrical factors such as, in particular, the "simple absorption length x abS " (e.g. the radius of a cylindrical discharge vessel) and the mean number of back reflections n r , by for example:
- O.I The effective spectral filling factor
- the above formula can be derived from studies of radiation absorbance (Beer's law) and from certain specific properties of molecule absorbance. In the formula, the reflectance of the reflecting layers is assumed to be of an idealized form, i.e. to be 100%. This formula for the maximum molecule densities is used for the purposes of the invention to give a limiting density value for the effect described (increase in the density of non-coherent radiation). The range within which the increase in radiation density is linear with the number of reflections is the density range in which the effect gives the greatest benefit and is thus preferred.
- the following equation is thus suitable for densities N mo i less than N_lin mo i:
- S Radiation density from the lamp when steps are taken to increase the radiation density (e.g. an aperture)
- S 0 Radiation density from the lamp when no steps are taken to increase the radiation density
- n r Mean number of back reflections
- the lamp according to the invention may, in principle be equipped, and then operated as well, with internal and/or external electrodes.
- a further alternative is for the discharge vessel to be produced from optically transparent material only at the end-faces.
- the diffusely reflecting layer may also, if desired, be applied to the outside of the gas discharge vessel.
- a further alternative is, when the diffusely reflecting layer is applied on the inside, for the gas discharge vessel to be produced from optically transparent material only at the points where the aperture is situated.
- the object of the invention is also achieved by a lighting unit having at least one low-pressure gas discharge lamp as claimed in claims 1 to 10.
- the lighting unit according to the invention having at least one low-pressure gas discharge lamp may be used in particular for tanning purposes and for treating acne, using in particular the directly emitted UV radiation for this, and for general lighting applications, particularly if the radiation from the molecules is in the visible range of the spectrum.
- Other preferred fields of application are as an aperture lamp unit with or without phosphors, particularly for general lighting applications, and as a lamp in devices for office automation (OA), e.g. copying machines and color scanners, or for the background lighting of displays, e.g. liquid crystal displays.
- OA office automation
- Fig. 2 is a schematic side view of a low-pressure gas discharge lamp and a measuring set-up (for head-on measurement).
- Fig. 3 is a schematic view in section through a cylindrical gas discharge lamp.
- the present low-pressure gas discharge lamp 1 provided with a measuring set-up (for head-on measurement) is, as can be seen in Fig. 2, arranged in an electrical heating oven 8.
- the measuring device 7 is arranged approximately on the longitudinal axis of the lamp 1 and is spaced away from an end-face of the lamp 1.
- the low-pressure gas discharge lamp 1 has a gas discharge vessel 2 of quartz glass that is of cylindrical, tubular geometry and has a diameter of approximately 25 cm and a length of approximately 250 mm (length of lamp: L; inside diameter of lamp: d; L » d).
- the inside diameter of the gas discharge vessel is approximately 24 cm.
- the hermetically sealed gas discharge vessel 2 contains, as well as a normal buffer gas such as argon, a gas filling containing indium halides (InBr).
- the low-pressure gas discharge lamp 1 is operated in a normal manner by means of capacitive coupling.
- a normal diffusely reflecting coating 5 which in particular does not allow any molecular radiation to pass through.
- the two end- faces act as exit openings 4 for the molecular radiation that is emitted, particularly in the predetermined wavelength range from 355 nm to 390 nm.
- To the outer surface of the ends may be applied a normal layer of phosphor 6 that in particular causes UV radiation to be converted into visible radiation, and in this specific case into white light.
- the lamp according to the invention may, in principle, be equipped, and then operated as well, with internal and/or external electrodes.
- a further alternative is for the discharge vessel to be produced from optically transparent material only at the end-faces.
- FIG. 3 A further preferred embodiment is shown schematically in Fig. 3. What is shown is a section through a cylindrical gas discharge lamp, namely a section at the center of the tubular lamp 1. Not shown are the provisions that are made, which are shown in Fig. 1 , to bring the gas discharge vessel 2 to a temperature at its coldest point of, for example, 218 0 C. This can for example be done by a heating oven, as in the case of the first embodiment, or by an outer enclosing tube provided with conventional heat-reflecting layers.
- the low-pressure gas discharge lamp 1 shown has a gas discharge vessel 2 of quartz glass that is of cylindrical, tubular geometry and has a diameter of approximately 25 cm and a length of approximately 250 mm.
- the hermetically sealed gas discharge vessel 2 contains, as well as a normal buffer gas such as argon, a gas filling containing indium halides (InBr).
- the low-pressure gas discharge lamp 1 is operated in a normal manner by means of capacitive coupling. Except in the region that is marked as the aperture 9, there is applied to the inside surface a diffusely reflecting coating 5 that in particular does not allow molecular radiation to pass through.
- the aperture 9 acts as an exit opening 4 for the molecular radiation, particularly in the predetermined wavelength range from 355 nm to 390 nm, that is emitted.
- the diffusely reflecting layer 5 may also, if desired, be applied to the outside of the gas discharge vessel 2.
- a further alternative is, when the diffusely reflecting layer 5 is applied on the inside, for the gas discharge vessel 2 to be produced from optically transparent material only at the points where the aperture 9 is situated.
- a normal phosphor layer may, in addition, be applied to the aperture 9, which layer in particular causes the UV radiation from 355 nm to 390 nm to be converted into visible radiation, and in this specific case into white light.
- the lamp according to the invention may, in principle be equipped, and then operated as well, with internal and/or external electrodes.
Landscapes
- Discharge Lamp (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04104722.6 | 2004-09-28 | ||
EP04104722 | 2004-09-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006035339A1 true WO2006035339A1 (fr) | 2006-04-06 |
Family
ID=35432079
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2005/053056 WO2006035339A1 (fr) | 2004-09-28 | 2005-09-19 | Lampe a decharge de gaz basse pression |
Country Status (1)
Country | Link |
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WO (1) | WO2006035339A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GR1006103B (el) * | 2007-08-21 | 2008-10-15 | Σπυριδων Κιτσινελης | Λαμπτηρας βασισμενος σε σωληνα εκκενωσης χαμηλης πιεσης ατμων αλογονιδιων του αλουμινιου και γαλλιου |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4140385A (en) * | 1976-03-22 | 1979-02-20 | Xerox Corporation | Low pressure metal or metal halide lamps for photocopying applications |
US5903091A (en) * | 1996-05-31 | 1999-05-11 | Fusion Lighting, Inc. | Lamp method and apparatus using multiple reflections |
EP1178518A1 (fr) * | 2000-07-31 | 2002-02-06 | Secretary of Agency of Industrial Science and Technology | Dispositif émetteur de lumière |
US20020180359A1 (en) * | 2000-12-19 | 2002-12-05 | Kirkpatrick Douglas A. | Discharge lamp with indium and erbium fill |
US20030001505A1 (en) * | 2001-06-15 | 2003-01-02 | Scholl Robert Peter | Low-pressure gas discharge lamp with a mercury-free gas filling |
-
2005
- 2005-09-19 WO PCT/IB2005/053056 patent/WO2006035339A1/fr active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4140385A (en) * | 1976-03-22 | 1979-02-20 | Xerox Corporation | Low pressure metal or metal halide lamps for photocopying applications |
US5903091A (en) * | 1996-05-31 | 1999-05-11 | Fusion Lighting, Inc. | Lamp method and apparatus using multiple reflections |
EP1178518A1 (fr) * | 2000-07-31 | 2002-02-06 | Secretary of Agency of Industrial Science and Technology | Dispositif émetteur de lumière |
US20020180359A1 (en) * | 2000-12-19 | 2002-12-05 | Kirkpatrick Douglas A. | Discharge lamp with indium and erbium fill |
US20030001505A1 (en) * | 2001-06-15 | 2003-01-02 | Scholl Robert Peter | Low-pressure gas discharge lamp with a mercury-free gas filling |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GR1006103B (el) * | 2007-08-21 | 2008-10-15 | Σπυριδων Κιτσινελης | Λαμπτηρας βασισμενος σε σωληνα εκκενωσης χαμηλης πιεσης ατμων αλογονιδιων του αλουμινιου και γαλλιου |
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