WO2006067929A1 - 積層セラミック電子部品およびその製造方法 - Google Patents
積層セラミック電子部品およびその製造方法 Download PDFInfo
- Publication number
- WO2006067929A1 WO2006067929A1 PCT/JP2005/021544 JP2005021544W WO2006067929A1 WO 2006067929 A1 WO2006067929 A1 WO 2006067929A1 JP 2005021544 W JP2005021544 W JP 2005021544W WO 2006067929 A1 WO2006067929 A1 WO 2006067929A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- land
- via hole
- ceramic
- sheet
- electronic component
- Prior art date
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 69
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 238000000034 method Methods 0.000 title abstract description 7
- 239000004020 conductor Substances 0.000 claims abstract description 45
- 238000010030 laminating Methods 0.000 claims description 3
- 238000007650 screen-printing Methods 0.000 abstract description 10
- 239000011229 interlayer Substances 0.000 abstract description 3
- 238000011156 evaluation Methods 0.000 description 8
- 238000007639 printing Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007606 doctor blade method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/11—Printed elements for providing electric connections to or between printed circuits
- H05K1/115—Via connections; Lands around holes or via connections
- H05K1/116—Lands, clearance holes or other lay-out details concerning the surrounding of a via
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/30—Stacked capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F17/00—Fixed inductances of the signal type
- H01F17/0006—Printed inductances
- H01F17/0013—Printed inductances with stacked layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/06—Solid dielectrics
- H01G4/08—Inorganic dielectrics
- H01G4/12—Ceramic dielectrics
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F17/00—Fixed inductances of the signal type
- H01F17/0006—Printed inductances
- H01F17/0013—Printed inductances with stacked layers
- H01F2017/002—Details of via holes for interconnecting the layers
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0306—Inorganic insulating substrates, e.g. ceramic, glass
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/16—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor
- H05K1/165—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor incorporating printed inductors
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/09372—Pads and lands
- H05K2201/09454—Inner lands, i.e. lands around via or plated through-hole in internal layer of multilayer PCB
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/4038—Through-connections; Vertical interconnect access [VIA] connections
- H05K3/4053—Through-connections; Vertical interconnect access [VIA] connections by thick-film techniques
- H05K3/4061—Through-connections; Vertical interconnect access [VIA] connections by thick-film techniques for via connections in inorganic insulating substrates
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
- H05K3/4614—Manufacturing multilayer circuits by laminating two or more circuit boards the electrical connections between the circuit boards being made during lamination
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
- H05K3/4626—Manufacturing multilayer circuits by laminating two or more circuit boards characterised by the insulating layers or materials
- H05K3/4629—Manufacturing multilayer circuits by laminating two or more circuit boards characterised by the insulating layers or materials laminating inorganic sheets comprising printed circuits, e.g. green ceramic sheets
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
Definitions
- the present invention relates to a multilayer ceramic electronic component, and more particularly to a multilayer ceramic electronic component such as an inductor and an impedance element, and a manufacturing method thereof.
- Patent Document 1 Conventionally, as this type of multilayer ceramic electronic component, one described in Patent Document 1 is known. This electronic component forms a spiral coil by laminating ceramic sheets provided with coil forming conductors and sequentially connecting pads (lands) formed at the ends of the coil forming conductors through via holes. is doing.
- a coil-forming conductor 51 is formed on the surface of a ceramic sheet 50 having via-holes formed thereon by screen printing, and at the same time, the via-holes are filled with a conductive paste to form via-holes.
- Form 60 The coil forming conductor 51 has a first land 51a provided with a via hole 60 for indirect layer connection and a second land 5 lb for receiving the via hole 60.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2004-87596
- an object of the present invention is to provide a multilayer ceramic electronic component capable of satisfying both proper filling of via holes and prevention of blurring of lands without lining the ceramic sheet with a carrier film, and a method for manufacturing the same. It is in.
- a multilayer ceramic electronic component includes a plurality of ceramic sheets each having an internal conductor pattern having a first land at one end and a second land at the other end.
- the via hole is filled with a conductor.
- One land is provided to cover the via hole, and the first land provided on one ceramic sheet and the second land provided on the other ceramic sheet are provided on one ceramic sheet.
- the second land is larger than the first land and is electrically connected through a via hole.
- the second land extends from a projection area of the first land to a projection area of the internal conductor pattern.
- the area of the second land is preferably 1.10-2.25 times that of the first land.
- a method for manufacturing a multilayer ceramic electronic component according to the present invention includes an internal conductor pattern having a first land on one end and a second land on the other end on the surface of a ceramic sheet in which a hole for a via hole is formed.
- the conductor is printed so that the first land covers the via hole, the via hole is filled with the conductor, the first land provided in one ceramic sheet, and the other land.
- a plurality of ceramic sheets are connected so as to be electrically connected to the second land provided in the ceramic sheet through the via hole provided in the first ceramic sheet. And obtaining a laminate by stacking, wherein the second land is larger than the first land.
- the ceramic sheet in which the via hole is formed is preferably filled with a conductor at the same time as printing the internal conductor pattern without the backing by the carrier film.
- the discharge amount of the conductive paste for forming the second land is reduced. As a result, it is possible to achieve both the proper filling of via holes and the prevention of blurring of the second land. As a result, a multilayer ceramic electronic component with excellent reliability and productivity can be obtained.
- the second land is prevented from being scraped and the electrostatic discharge failure is reliably suppressed. At the same time, misalignment can be prevented. Also, by making it 2.25 times or less, the decrease in inductance value can be suppressed.
- FIG. 1 is an exploded perspective view showing one embodiment of a multilayer ceramic electronic component according to the present invention.
- FIG. 2 is a plan view showing the internal conductor pattern shown in FIG.
- FIG. 3 is a cross-sectional view showing the main part of the laminated state of the multilayer ceramic electronic component shown in FIG.
- FIG. 5 is a plan view showing a modification of the internal conductor pattern shown in FIG.
- FIG. 6 is a plan view showing an internal conductor pattern of a conventional multilayer ceramic electronic component.
- FIG. 7 is an explanatory view showing a conventional method for manufacturing a multilayer ceramic electronic component.
- FIG. 8 is an explanatory view showing another method for manufacturing a conventional multilayer ceramic electronic component.
- the multilayer inductor 1 includes a ceramic green sheet 2 provided with coil conductor patterns 3 to 7, lead electrodes 8, 9 and via holes 15, respectively, and a ceramic green for an outer layer not provided with a conductor pattern in advance. It consists of a sheet 2a.
- Ceramic green sheets 2 and 2a were manufactured by the following method. Ferrite raw powder Various raw powders such as Ni 0, CuO, ZnO, and Fe O are wet-mixed with a ball mill etc.
- the obtained ferrite powder was dispersed in a solvent to prepare a ceramic slurry, which was molded by a doctor blade method to obtain a long ceramic green sheet. This long ceramic green sheet was punched out to a predetermined size, and a via hole was formed as necessary to produce a ceramic green sheet 2.
- the coil conductor patterns 3 to 7 and the lead electrodes 8 and 9 are formed on each ceramic green sheet 2 by screen printing, and at the same time, the via hole is filled with the conductive paste, and the via hole is formed. 15 is formed.
- the direction of the squeegee is, for example, the direction shown in Fig. 2 with respect to the coil conductor pattern.
- the ceramic green sheet 2 in which the via hole is formed has the via hole 15 formed at the same time as the coil conductor patterns 3 to 7 and the like are printed without the backing by the carrier film.
- the surface of the ceramic green sheet 2 shown in FIG. 2 is printed with a conductive paste so that the first land 4a covers the via hole, and the conductive paste is placed in the via hole. Filled. Therefore, the coil conductor pattern 4 has two types of lands at both ends, that is, a first land 4a provided with via holes 15 for interlayer connection and a second land 4b receiving via holes 15. The diameter of the second land 4b is formed larger than the diameter of the first land 4a.
- the coil conductor patterns 3 to 7 include two types of lands, that is, first lands 3a to 6a provided with via holes 15 for interlayer connection and second lands 4b to 7b receiving the via holes 15. Have.
- the diameters of the second lands 4b to 7b are larger than the diameters of the first lands 3a to 6a.
- the lead portion of the coil conductor pattern 3 is connected to a lead electrode 8 formed on the left side of the sheet 2.
- the lead portion of the coil conductor pattern 7 is connected to a lead electrode 9 formed on the right side of the sheet 2.
- Each ceramic green sheet 2 is stacked, and further, ceramic multilayer sheets 2a for outer layers are arranged on the upper and lower sides, and then pressed with lOOOOkgfZcm 2 to form a laminate block.
- the coil conductor patterns 3 to 7 are electrically connected through the via holes 15 to form a spiral coil.
- the conductive pattern is connected to the first land 4a provided on the sheet 2 (x) and the second land 5b provided on the lower sheet 2 (y). It is in an electrically connected state via a via hole 15 provided in the sheet 2 (x).
- the laminate block is cut into a predetermined size, it is degreased and fired integrally at 870 ° C. Thus, the laminate 20 shown in FIG. 4 is obtained.
- a conductive paste is applied to both ends of the laminate 20 and baked at 850 ° C., thereby forming the external electrodes 21 and 22.
- the external electrode 21 is electrically connected to the extraction electrode 8
- the external electrode 22 is electrically connected to the extraction electrode 9.
- the second lands 4b, 5b, 6b, and 7b that receive the via holes 15 that are liable to be blurred during screen printing are made larger in shape.
- the discharge amount of the conductive paste for forming the lands 4b to 7b is increased. Therefore, even if the filling amount of the conductive paste in the via hole is optimized by matching the screen printing conditions with the first lands 3a to 6a formed at the positions where the via hole is provided, The lands 4b to 7b of 2 are less likely to be damaged. That is, it is possible to achieve both the proper filling of the via hole 15 and the prevention of the second land 4b to 7b from becoming dirty. As a result, a multilayer inductor 1 excellent in reliability and productivity can be obtained.
- Table 1 is a table showing the results (Example 1) of evaluating the obtained multilayer inductor 1.
- the diameter of the via hole 15 is 160 / zm
- the diameter of the first lands 3a, 4a, 5a, 6a is 200 ⁇
- the second lands 4b, 5b, 6b, 7b are 240 m.
- it also shows the evaluation results of the conventional multilayer inductor having the coin conductor pattern 51 shown in FIG.
- the first land 51a provided with the via hole 60 of the conventional multilayer inductor and the second land 51b receiving the via hole 60 are both 200 m (Comparative Example 1) and 240 m (comparison).
- Example 2 Comparative Example 1 and 240 m (comparison).
- the inductance value is the average value of 30 samples, and the electrostatic discharge test is performed by applying a discharge gun to the number of samples 30 positive and negative 10 times each at a time of 0.lsec. This is the number of failures when contact discharge is performed.
- the maximum stacking misalignment was obtained by enlarging the vertical section of the stacking inductor with a microscope and conducting structural analysis.
- Comparative Example 1 when the cause of the failure in the electrostatic discharge test was investigated, it was found that the cause was a printing defect (printing blur) of the second land 51b. In addition, the reason for the large stacking misalignment in Comparative Example 2 was investigated. As a result, too much conductive paste was filled into the via hole for printing, and the conductive paste protruded from the back of the ceramic green sheet, resulting in stacking. I noticed that there was a gap.
- the diameter of the second land 34b is made substantially equal to the diameter of the first land 34a, and the second land 34b is projected from the projection area of the first land to the coil conductor pattern.
- a coil conductor pattern 34 extending in the projected area may be used.
- the planar shape of the spiral coil formed by the coil conductor pattern is the same as that of the conventional multilayer inductor, and the area inside the coil does not change, so the inductance value does not change the high-frequency characteristics. .
- Table 2 shows the results of evaluation of the multilayer inductor having the coil conductor pattern 34 shown in FIG.
- Example 10 is a table showing Example 2.
- a conductive paste having a viscosity of lOOPa's was screen-printed using a printing plate having an opening rate of 60%.
- Table 2 shows the evaluation results of the laminated inductor 1 having the coil conductor pattern 4 shown in FIG. 2 (Example 1) and the coil conductor pattern 51 shown in FIG. Have The evaluation results of the conventional multilayer inductor (Comparative Example 1) are also shown.
- Table 3 shows the evaluation results of Samples 1 to 7 in which the diameters (areas) of the first land and the second land are changed.
- the content of the evaluation test is the same as the test in Tables 1 and 2 above.
- Samples 1 to 5 were manufactured by changing the diameter of the second land to 205, 2 10, 220, 300, 320 / z m with respect to the diameter of the first land of 200 m.
- Samples 2 to 4 passed the electrostatic test, and the amount of stacking misalignment is also small.
- sample 1 area ratio 1.05
- a printing defect printing shading
- the electrostatic discharge test was rejected.
- sample 5 area ratio 2.56), the inductance value decreased as the second land increased.
- Samples 6 and 7 were manufactured by making the diameter of the first land different from 220 and 215 m with respect to the diameter of the second land of 220 ⁇ m. While favorable evaluation was obtained for Sample 6, in Sample 7, the stacking deviation was large due to the large amount of conductive paste filled in the via hole formed in the first land.
- the present invention provides multilayer ceramic electronic devices such as inductors and impedance elements. It is useful for parts and manufacturing methods thereof, and is particularly excellent in that it can achieve both proper filling of via holes and prevention of land scum without backing a ceramic sheet with a carrier film.
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Coils Or Transformers For Communication (AREA)
- Manufacturing Cores, Coils, And Magnets (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/596,097 US20090139759A1 (en) | 2004-12-20 | 2005-11-24 | Laminated ceramic electronic component and manufacturing method therefor |
JP2006548737A JP4432973B2 (ja) | 2004-12-20 | 2005-11-24 | 積層セラミック電子部品の製造方法 |
CN2005800015985A CN1906715B (zh) | 2004-12-20 | 2005-11-24 | 层压陶瓷电子元件及其制造方法 |
TW094141890A TW200636769A (en) | 2004-12-20 | 2005-11-29 | Laminated ceramic electronic component and method for manufacturing same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004367863 | 2004-12-20 | ||
JP2004-367863 | 2004-12-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006067929A1 true WO2006067929A1 (ja) | 2006-06-29 |
Family
ID=36601534
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2005/021544 WO2006067929A1 (ja) | 2004-12-20 | 2005-11-24 | 積層セラミック電子部品およびその製造方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20090139759A1 (ja) |
JP (1) | JP4432973B2 (ja) |
KR (1) | KR100810524B1 (ja) |
CN (1) | CN1906715B (ja) |
TW (1) | TW200636769A (ja) |
WO (1) | WO2006067929A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009212255A (ja) * | 2008-03-04 | 2009-09-17 | Tdk Corp | コイル部品及びその製造方法 |
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TWI394030B (zh) * | 2006-12-22 | 2013-04-21 | Foxconn Tech Co Ltd | 散熱模組及採用該散熱模組之電子裝置 |
CN101207972B (zh) * | 2006-12-22 | 2010-05-19 | 鸿富锦精密工业(深圳)有限公司 | 一种电路板及使用其的感光装置 |
DE102012005831A1 (de) * | 2012-03-22 | 2013-09-26 | Giesecke & Devrient Gmbh | Substrat für einen portablen Datenträger |
CN103387388B (zh) * | 2012-05-07 | 2015-08-26 | 深圳振华富电子有限公司 | 铁氧体材料、小型大电流叠层片式宽频磁珠和其制备方法 |
JP6030512B2 (ja) * | 2013-07-09 | 2016-11-24 | 東光株式会社 | 積層型電子部品 |
DE102014112365A1 (de) * | 2014-08-28 | 2016-03-03 | Epcos Ag | Verfahren zur Herstellung eines Mehrschichtsubstrats und Mehrschichtsubstrat |
US10432152B2 (en) * | 2015-05-22 | 2019-10-01 | Nxp Usa, Inc. | RF amplifier output circuit device with integrated current path, and methods of manufacture thereof |
CN107452463B (zh) | 2016-05-31 | 2021-04-02 | 太阳诱电株式会社 | 线圈部件 |
CN109103001A (zh) * | 2018-10-10 | 2018-12-28 | 深圳市麦捷微电子科技股份有限公司 | 一种新型结构叠层片式电感器 |
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- 2005-11-24 KR KR1020067008455A patent/KR100810524B1/ko not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
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US20090139759A1 (en) | 2009-06-04 |
KR100810524B1 (ko) | 2008-03-10 |
CN1906715A (zh) | 2007-01-31 |
JPWO2006067929A1 (ja) | 2008-06-12 |
CN1906715B (zh) | 2010-06-16 |
KR20060104996A (ko) | 2006-10-09 |
TWI339848B (ja) | 2011-04-01 |
TW200636769A (en) | 2006-10-16 |
JP4432973B2 (ja) | 2010-03-17 |
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