WO2006061847A1

WO2006061847A1 - Herbal black dye used in beautifying the hair and its applications

Info

Publication number: WO2006061847A1
Application number: PCT/IN2004/000380
Authority: WO
Inventors: Palpu Pushpangadan; Mahesh Pal; Bhagwan Shankar Dixit; Ranjan Banerji; Chandana Venkateswara Rao
Original assignee: Council Of Scientific And Industrial Research
Priority date: 2004-12-10
Filing date: 2004-12-10
Publication date: 2006-06-15
Also published as: JP2008523051A; JP4546540B2

Abstract

The present invention relates to the development of a herbal black dye from natural materials comprising the extracts of Juglans regia, Indigofera tinctoria, Terminalia chebula, Acacia sinuata, Lawsonia inermis, Trigonella foenum-graecum, Sapindus mukorossi., Eclipta alba, Emblica officinalis, Acacia catechu and Piper bed e. The dye is safe, non toxic, antiallergic, anti-dandruff and free from any toxic symptoms like itching. It is dark in colour and the composition is used in a powder/cream/paste/oil form as a coloring agent in textiles, leather polishing, cosmetics and in beautifying the hair.

Description

HERBAL BLACK DYE USED IN BEAUTIFYING THE HAIR AND ITS

APPLICATIONS

FIELD OF THE INVENTION

The present invention relates black hair dye and method of preparing the same, from natural materials. The mixture of dye derived from the method of present invention can be used in coloring the hair.

BACKGROUND AND PRIOR ART OF THE INVENTION

The synthetic dye used for coloring of hair has been known for many years. Colorants are classified as being temporary or permanent. In temporary coloring the color can be washed from hair relatively easily. So called permanent coloring of hair typically involves the formulation of aromatic diamine or hydric phenols polycompounds such as para phenylene diamine on the hair fibre. But they are raising so many side effects such as skin cancer, loss or damage of hair, etc. So these synthetic dyes, which are used for coloring hair, are very toxic and thus hazards to human health as well as to the environment.

To color human hair using oxidative dye technology the hair is generally treated with mixture of oxidative hair colouring agents and an oxidizing agent hydrogen peroxide is the most commonly used oxidizing agent. However, in addition to oxidizing the oxidative coloring agents, hydrogen peroxide treatment of the hair can also solubilise and decolorize the colored melanin component in the hair, which can lead to undesirable hair qualities, such as brittleness and hair damage. Thus, it would be desirable to develop a hair coloring composition which exhibit reduced fade provides improved resistance to wash out during a daily devising regimen; can deliver substantially consistent hair color results throughout the hair, which has reduced irritant effect on skin which has reduced staining on skin, which has reduced adverse effects on the hair of the user and also to develop a convenient, eco~friendly and easy to use method for the delivery of such a hair coloring formulation to the hair.

Over the years significant efforts have been directed towards elimination of many problems associated with the dyeing of human hair. Various approaches to hair dyeing have been developed these includes direct action dyes, natural dyes and oxidative dyes. Composition of herbal dyes and hair coloring mordents can be used to deliver a variety of hair color to the hair. However, substantial improvement is needed in the areas of color saturation color development precise initial colours consistency improved wash fastness, improved hair condition and level of hair damage.

Thus there is a need for natural hair coloring composition which effectively dye the hair but avoid or reduce damage to the hair which can colour the hair effectively and avoid reduce irritation and or staining to the skin of the user.

Thus it is another object of the present invention to provide single packed hair coloring composition, which is fast action simple to use.

A method of preparing herbal dye from plant is well known natural dyes and vegetable dyes included in the coloring compositions of the present invention such as Juglans regia, lndigofera tinctoria, Terminalia chebula, Acacia sinuata, Lawsonia inermis, Trigonella foenum-graecum,

Sapindus mukorossi, Eclipta alba, Embelica officinalis, Acacia catechu and Piper betle etc dye extract. The method comprises extracting the dye using water and drying and powder form the dye that can be easily mixed with each other. The black dye prepared in this way is often used in coloring of hair. The method of obtaining dye from plant material is eco-friendly sound because water is used in the extraction. '

A brown dye of natural origin can be prepared from the rind of the ripe walnut. Such dye is described in USSR certificate no. 1784623 (1992). This dye is often used in the food -processing industry to stain confectionery products brown so that they resemble chocolate. However, this dye tends to degrade over time. This dye cannot be used in hair because it is unsuitable for cosmetic such as hair color products.

A black dye used in food products is derived from drying and refining tea leaves. Thus there exists a need for black dye produced from natural materials that may be used in wide variety of context including hair color products. There is additional need for a method of producing such a dye in high yield manner.

OBJECTS OF THE INVENTION

The primary objective of the invention is to prepare herbal black dye for coloring hair, which prevents damage hair, skin irritation and reduced staining of skin, remove dandruff and condition hair.

Another objective of the present invention is to prepare a composition that has no side effect. Yet another objective of the present invention is to prepare herbal composition with a combination of the plants, which are rich source of tannins arid can be used in skin disease.

SUMMARY OF THE INVENTION

The subject of the present invention is a hair coloring composition suitable for the coloring of human and animal hair.

According to one aspect of the present invention, there is provide a hair coloring composition comprising: a) A dye of plants Juglans regiajndigofera tinctoria, Terminalia chebula, Acacia sinuata, Lawsonia inermis, Trigonella foenum-graecum, Sapindus mukorossi Eclipta alba, Embelica officinalis, Acacia catechu and Piper be tie. b) A hair coloring mordents

Wherein the pH of each of a and b in the range of from about 2 to 5 and where in the combination mixture of a and b has a pH in range of from about 3 to 5.

It is to be understood that the percentage weight of the composition dye components here in are expressed in terms of the total composition.

According to a further aspect of the present invention, there is provided: a method of coloring hair wherein a hair coloring mixture is present in a single package and applied directly to the hair and wherein the hair coloring mixture comprises.

DETAILED DESCRIPTION OF THE INVENTION

Juglans Linn distributed in North and South America and from South Europe to east Asia. Six species are present but here Juglans regia used in the context of the present invention. The rind of unripe wild walnut is used as source material in the method of present invention. It is rich source of proteins.

Indigofera tinctoria belongs to genus of leguminous plants originally native to India, China and other tropical subtropical regions. The coloring matter is present in the leaves of the plant in the form of indigotin also known as Indigo blue.

Eclipta alba a small genus of herbs distributed in tropical and subtropical regions of the world one of mention above species occurs in India. The herb is used as tonic and skin diseases. It contains a large amount of resin and alkaloidal principal ecliptine. The herbs also contain new poly thienyl compound (alpha - terthienyl methanol) Beta - amyrin and Stigmasterol. Acacia catechu is a tropical tree- called Acacias. The brown natural dye obtained chiefly from the wood of Acacia water extracts contains mainly catechin. It is a rich source of tannin. Emblica officinalis is indigenous to a large area ranging from the Southern Himalayas of Nepal, North India to South India, Sri Lanka, Burma, Thailand, China and Malaysia . Fruits, barks and leaves are rich source of tannin. Dried pulp of unripe fruits contains 18-30% tannin. Sometimes even more (up to 35%) the fresh fruit is used for cooling, diuretic, laxative and stomachic. The fruit contains phyllemblic acid, lipids, gallic acid and emblical. The seeds also contain fixed oils (Yield 16%),

Acacia sinuata is a common, princkly scandent shrub, ocurring in tropical jungels throughout India. The pods known as shikakai, are extensively used as a detergent. A decoction of the pods relieves biliousness and acts as a purgative. It is used to remove dandruff. An ointment prepared from the ground pods is good for skin diseases. The pods yield saponins (20.6%). The alcoholic extract of the pods on acid hydrolysis gave a sapogenin, acacic acid.

Lawsonia inermis is a glabrous, much branched shrub or small tree with greyish brown bark. It is cultivated in many tropical and warm temperature regions. Large scale cultivation for the sake of the leaves which yield the dye, is confined to India, Egypt and Sudan and to some extent, Persia, Madagascar, Pakistan and Australia. Henna has long been used in India and middle East Countries for colouring- palms of hands, soles of feet, finger nails and hair. It is harmless and causes no irritation of skin. Alcoholic extracts of henna leaves show mild antibacterial activity. It gave tannin, 10.21%. the tannin content appears to be variable, a sample from Jammu and Kashmir contained 4-5% tannin. The principal colouring matter is lawsone, 2-hydroxy-l:4 naphthaquinone which present in dried leaves. Besides lawsone other constituents present in henna are gallic acid, glucose mannitol, fat resin and traces of an alkaloids. Sapindus mukorossi a deciduous tree, native of China, Japan and India found in Himalayas from Himachal Pradesh eastwards and in Assam ascending to an altitude of c. 1500 m. The tree requires deep well-drained soil for optimum development. Fruits are credited with expectorant and emetic properties and are used in the treatment of excessive salivation, epilepsy and chlorosis. They are also reported to act as fish poison. Powdered seeds are said to possess insecticidal properties. Fruit is valued for the saponin (10%) present in the pericarp which constituent up to 56.5% of the drupe. A crystalline saponin mukorosside has been isolated from the pericarp. Extract of the pericarp mixed with DDT are used as a fungicide and insecticide. Trigonella foenum-graecum is an aromatic annual 30-60 cm in tall, found wild in Kashmir, Punjab and upper Gangetic plains and widely cultivated in many parts of India. Seeds are eaten, boiled or roasted as a vegetable in dyspepsia, diarrhea, dysentery colic, enlargement of liver and spleen and chronic cough. A paste of the seeds is used as a cosmetic to keep the skin smooth and clean. Seeds contains alkaloid trigonelline, choline, saponin, essential oil, fixed oil, bitter extractive and colouring substance.

Terminalia chebula is a large tree found in the sub Himalayas tract of west Bengal, Assam. It is also found in south India. Sri Lanka Burma and Malaysia. The dried fruits give natural dyes. It is very rich source of tannin (up to 30-35%). Myrobalans are used in fever, cough, asthma, urinary diseases, piles and worms. The fruits contain about 30% of an astringent substance, which is due to characteristic principle chebulinic acid also contains tannic acid, gallic acid, resins and some natural anthraquinones.

Betelvine (Piper betle L) commonly known as Paan and is found in India. Its leaves used for chewing along with supplement. Betel leaves havemany medicinal properties. Its leaves are a source of polyphenols. Fresh juice of betel leaves is used in many ayurvedic preparations. The present invention is based on the finding particularly effective methods and products for coloring hair. The methods and products involve the use of a dyes and mordents under safe limit. Accordingly, a herbal black dye from natural materials which is coloring agent in textiles, leather polishing, cosmetics and in beautifying the hair: Ingredients wt/ wt % a dye of Juglans regia (20- 30) %, a dye oϊ Indigo f era tinctoria (10-20) % a dye of Acacia sinuata(5-\0) %, Lawsonia inermis (10-15) %, Trigonella foenum-graecum(5 -10) %, Sapindus mukorossi (2-5) % , Eclipta alba (10-15) % a dye of Acacia catechu (7-10) %, Emblica officinalis (10-15) % , Terminalia chebula (2-4) % and Piper betle (2-5) % .

An embodiment of the present invention, wherein the mordant used is of natural origin of above species.

Another embodiment of the present invention, comprising of Juglans regia, Terminalia chebula, Emblica officinalis, Acacia sinuata, Sapindus mukorossi are fruit extracts and Indigofera tinctoria, Lawsonia inermis, Trigonella foenum-graecum and Piper betle are leaf extracts. Another embodiment of the present invention, where in the dye of plants used is obtained bf extraction with water or with organic solvents like methanol, ethanol or acetone and mordant.

Yet another embodiment of the present invention, wherein the dye used may be obtained from the plant parts selected from the leaves, fruits, and rhizome or root parts.

Still another embodiment of the present invention, wherein it contains tannins and proteins.

Another embodiment of the present invention, wherein the said method comprises steps of: i. obtaining the required parts of plants materials and shade dried, ii. powdered the dried plant material to obtain a fine/ coarse powder, iii. materials are soaked in water for 15-24 hrs and boiled (85-95° C) for a time period of 30-50 minutes , iv. raw material is exhausted, concentrated and molded to suitable dye form with suitable mordents under safe limit to obtain the required composition.

Yet another embodiment of the present invention, wherein the composition causes no hair loss or damage to hair .

Still another embodiment of the present invention, wherein^' the composition is in the form of a powder, cream, paste, oil or solution

Another embodiment of the present invention, wherein the composition are nontoxic and safe.

Yet another embodiment of the present invention, wherein no synthetic dye is used.

Still another embodiment of the present invention, wherein the composition is non-irritant.

Another embodiment of the present invention, wherein the composition provides enhance lusture and texture of hair.

Yet another embodiment of the present invention, wherein the composition prevents the hair from falling out and also helps in re-growth of the hair.

Still another embodiment of the present invention, wherein the retention time of composition is more in the hair.

Another embodiment of the present invention, wherein the composition helps in removing dandruff.

Yet another embodiment of the present invention, wherein the composition may used as hair conditioner

Still another embodiment of the present invention, wherein the composition may be used for coloring hair. Another embodiment of the present invention, where in the mixture has ratio of fine powder to water of form 1 :20 to 1 :25 ratio.

Yet another embodiment of the present invention, wherein the composition has pH of from 2 to

5.

Still another embodiment of the present invention, wherein the composition is used in shoe polishing.

Another embodiment of the present invention, wherein the composition is used for leather shining.

Yet another embodiment of the present invention, wherein the composition is used in textile colouring and is non-washable from textiles.

Still another embodiment of the present invention, wherein the composition is non-sticky to the skin.

Another embodiment of the present invention, wherein the composition has no side effects on topical application.

Still another embodiment of the present invention, wherein the composition is antifungal.

Yet another embodiment of the present invention, wherein the composition is nonitching and anti-allergic.

Example 1

Juglans regia 20 (wt%), Indigofera tinctoria 15 (wt%), Eclipta alba 10 (wt%), Acacia catechu 7 (wt%), Emblica officinalis 10 (wt%), Terminalia chebula 5.0 (wt%), Piper betle 3.0 (wt%), Acacia sinuata 5 (wt%), Lawsonia inermis 10(wt%), Trigonella foenum- graecum 10 (wt%) and Sapindus mukorossi 5 (wt%).

These plant material were collected dried in shade until they contain no more than 2-3% water by mass. The shade dry plant materials crushed through electric spreder in powder form. The fine powder raw material is soaked in water for 15 hrs. After soaking for 15 hrs it is boiled at simmering point (85-95⁰C) for a time period of 30-50 minutes until the dye of raw material is exhausted to obtain liquid dye and concentrating the liquid dye in spray drying to obtain a powder. Formulating the plant dye powder of with suitable ratio without mordents to obtain the required composition. This composition is used to hair coloring. Example 2

Juglans regia 20 (wt%), Indigofera tinctoria 10 (wt%), Eclipta alba 11 (wt%), Acacia catechu 8 (wt%), Emblica officinalis 15 (wt%), Terminalia chebula 3.5 ( wt%), Piper betle

2.0 (wt%), Acacia sinuata 10 (wt%), Lawsonia inermis 10 (wt%), Trigonella foenum- graecum 5 (wt%) and Sapindus mukorossi 5 (wt%) Colouring mordent 0.5 (wt%).

These plant materials were collected dried in shade until they contain no more than 2-3% water by mass. The shade dry plant materials crushed through electric spreder in powder form. The fine powder raw material is soaked in water for 15 hrs. After soaking for 15 hrs it is boiled at simmering point (85-95° C) for a time period of 30-50 minutes until the dye of raw material is exhausted to obtain liquid dye and concentrating the liquid dye in spray drying to obtain a powder. Formulating the plant dye powder of with suitable ratio with mordents under safe limit to obtain the required composition.

This composition is very synergetic effect in the hair. In addition to color to composition increased the lusture of hair, does not cause of skin irritation and dandruff. . This powder formulation may be packaged and sold commercially for use as herbal black dye for hair or hair colour product. Example 3

Juglans regia 25 (wt%), Indigofera tinctoria 20(wt%), Eclipta alba 10 (wt%), Emblica officinalis 10 (wt%), Terminalia chebula 8.0 ( wt%), Piper betle 1.15 (wt%), Acacia sinuata 5 (wt%), Lawsonia inermis 15 (wt%), Trigonella foenum-graecum 5 (wt%) and colouring mordent 0.25 (wt%).

The powder dye may be dissolved in hot water at the certain ratio. The resulting solution is applied to the hair for 25-30 minute. The solution is then washed away with water. Example 4

Juglans regia 50 (wt%), Indigofera tinctoria 10 (wt%), EcHpta alba 15 (wt%), Emblica officinalis 10 (wt%), Terminalia chebula 14.5 (wt%), Lawsonia inermis 10 (wt%), Trigonella foenum-graecum 5 (wt%), Sapindus mukorossi 5 (wt%) and coloring mordent 0.025(wt%).

These plant materials were collected dried in shade until they contain no more than 2-3% water by mass. The shade dry plant materials crushed through electric spreder in powder form. The fine powder raw material is soaked in water for 15 hrs. After soaking for 15 hrs it is boiled at simmering point (85-95° C) for a time period of 30-50 minutes until the dye of raw material is exhausted to obtain liquid dye. The liquid dye may be diluted in 100 times of volumes of warm water and benzoic acid may be used in dye solution as a preservative.

This liquid dye also is applied in hair colouring.

Table 1: Antifungal activity of herbal black dye

Values are inhibition zone (mm)

The compostion contains Juglans regia, Indigofera tinctoria, Eclipta alba, Terminalia chebula, Acacia sinuata, Lawsonia inermis, Trigonella foenum-graecum, Sapindus mukorossi. Embelica officinalis, Acacia catechu and Piper betle. With colour mordent and the results shows better inhibition at 4mg/disc than that of griseofulvin (25mg/disc). COLOUR ANALYSIS

A microscope chromameter was used with a 0.3 mm diameter spot size samples of hair were mounted on 1 cm wide strip of white double-sided sticky tape, which was attached to a microscope slide. The sample positioning stage of the microscope was used to bring the hair fibres into focus and a measurement was taken. The samples (before & after washing) was then randomly repositioned before the next measurements and a total of 15 measurements were taken and found that the color of hair maintained up to one month.

Claims

What is claimed is:

1. A synergistic herbal composition useful as coloring agent for coloring the hair, textiles, leather polishing and as cosmetics comprising the extracts of plants of Juglans regia, Indigofera tinctoria, Terminalia chebula, Eclipta alba, Emblica officinalis, Indigofera tinctoria, Piper betle, Acacia sinuata, Lawsonia inermis, Trigonella foenum-graecum and Sapindus mukorossi.

2. A herbal composition as claimed in claim 1, wherein extracts of Juglans regia (20-30) %, a dye of Indigofera tinctoria (10-20) %a dye of Acacia sinuata,(5-lθ) % a dye of Lawsonia inermis (10-15) %, a dye of Trigonella foenum-graecum(5-l0) %, a dye of Sapindus mukorossi (2-5) % , a dye of Eclipta alba (10-15) % , a dye of Acacia catechu (7-10) % , a dye of Emblica officinalis (10-15) % , a dye of Terminalia chebula (2-4) % extract of Piper betel (2-5) % are used.

3. A composition as claimed in claim 1, comprising of Juglans regia, Terminalia chebula, Acacia sinuata, Sapindus mukorossi, Emblica officinalis are fruit extract and Indigofera tinctoria, Eclipta alba, Lawsonia inermis and Piper betle are leaf extract and Trigonella foenum-graecum is seed extract.

4. A composition as claimed in claim 1, wherein the extract used is obtained by extraction with water or with organic solvents like methanol, ethanol or acetone and mordant along with a carrier.

5. A composition as claimed in claim 1, wherein Emblica officinalis is used as mordent, which is of natural origin.

6. A composition as claimed in claim 1, wherein Acacia catechu is used as binder.

7. A composition as claimed in claim 1, where in Terminalia chebula is used for maintaining consistency of the dye.

8. A composition as claimed in claim 1, wherein the carrier used is distilled water.

9. A composition as claimed in claim 1, wherein the dye used may be obtained from the plant parts selected from the leaves, fruits, and rhizome or root parts.

10. A composition as claimed in claim 1, contains tannins and proteins.

11. A method of preparing composition as claimed in claim 1 , wherein the said method comprises steps of: a) obtaining the required parts of plants materials and shade dried, b) powdered the dried plant material to obtain a fine/ coarse powder, c) materials are soaked in water for 15-24 hrs and boiled (85-95° C) for a time period of 30-50 minutes, d) raw material is exhausted, concentrated and molded to suitable dye form with suitable mordents under safe limit to obtain the required composition.

12. A composition as claimed in claim 1, causes no hair loss or damage to hair

13. A composition as claimed in claim 1, which is in the form of a powder, cream, paste, oil or solution

14. A composition as claimed in claims 1, which are nontoxic and safe.

15. A composition as claimed in claim 1, where in no synthetic dye is used.

16. A composition as claimed in claim 1, which is non-irritant.

17. A composition as claimed in claim 1, provides enhance lusture and texture of hair.

18. A composition as claimed in claim 1, prevents the hair from falling out and also helps in re-growth of the hair.

19. A composition as claimed in claim 1, where in the retention time of is more in the hair.

20. A composition as claimed in claim 1, helps in removing dandruff.

21. A composition as claimed in claim 1, may be used as hair conditioner

22. A composition as claimed in claim 1 , may be used for coloring hair.

23. The method as claimed in claim 1, where in the mixture has ratio of fine powder to water ofform l:20 to 1:25 ratio.

24. A composition as claimed in claim 1, which has pH of from 2 to 5.

25. A composition as claimed in claim 1, which is used in shoe polishing.

26. A composition as claimed in claim 1, which is used for leather shining.

27. A composition as claimed in claim 1, which is used in textile coloring and is non- washable from textiles.

28. A composition as claimed in claim 1, which is non-sticky to the skin.

29. A composition as claimed in claim 1 has no side effects on topical application.

30. A composition as claimed in claim 1, which is antifungal.

31. A composition as claimed in claim 1, which is non itching and anti-allergic.