WO2006055999A1 - Procede et dispositif de production d'eau a teneur accrue en oxygene - Google Patents
Procede et dispositif de production d'eau a teneur accrue en oxygene Download PDFInfo
- Publication number
- WO2006055999A1 WO2006055999A1 PCT/AT2005/000474 AT2005000474W WO2006055999A1 WO 2006055999 A1 WO2006055999 A1 WO 2006055999A1 AT 2005000474 W AT2005000474 W AT 2005000474W WO 2006055999 A1 WO2006055999 A1 WO 2006055999A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oxygen
- water
- electrolyte
- column
- activated
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 151
- 239000001301 oxygen Substances 0.000 title claims abstract description 141
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 141
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims description 64
- 238000004519 manufacturing process Methods 0.000 title description 7
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 239000003792 electrolyte Substances 0.000 claims abstract description 21
- 150000002926 oxygen Chemical class 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 10
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 7
- 238000012856 packing Methods 0.000 claims abstract description 6
- 230000004913 activation Effects 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 230000005855 radiation Effects 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims 4
- 239000008187 granular material Substances 0.000 claims 3
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 238000001228 spectrum Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 7
- 230000003993 interaction Effects 0.000 abstract description 4
- 230000009471 action Effects 0.000 abstract description 3
- 238000005868 electrolysis reaction Methods 0.000 abstract description 3
- 230000000638 stimulation Effects 0.000 abstract 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 137
- 244000005700 microbiome Species 0.000 description 26
- 239000012190 activator Substances 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 239000008151 electrolyte solution Substances 0.000 description 11
- 229910001882 dioxygen Inorganic materials 0.000 description 9
- 241001465754 Metazoa Species 0.000 description 8
- 229920006395 saturated elastomer Polymers 0.000 description 7
- 230000007423 decrease Effects 0.000 description 6
- 241000700159 Rattus Species 0.000 description 5
- 230000004071 biological effect Effects 0.000 description 5
- 239000003651 drinking water Substances 0.000 description 5
- 235000020188 drinking water Nutrition 0.000 description 5
- 238000009738 saturating Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000010171 animal model Methods 0.000 description 4
- 230000031018 biological processes and functions Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 210000001035 gastrointestinal tract Anatomy 0.000 description 4
- 230000008092 positive effect Effects 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 244000005706 microflora Species 0.000 description 3
- 150000003254 radicals Chemical group 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 230000001850 reproductive effect Effects 0.000 description 3
- -1 singlet oxygen Chemical compound 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 238000002560 therapeutic procedure Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 230000032823 cell division Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000029087 digestion Effects 0.000 description 2
- 230000001079 digestive effect Effects 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 238000011534 incubation Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 230000003340 mental effect Effects 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 239000008239 natural water Substances 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- BQAVIHWBOOGDHK-VTSJMVTISA-N C[C@@H]1C(C2)C2OCC1 Chemical compound C[C@@H]1C(C2)C2OCC1 BQAVIHWBOOGDHK-VTSJMVTISA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 208000018522 Gastrointestinal disease Diseases 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000006701 autoxidation reaction Methods 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000004663 cell proliferation Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 239000002384 drinking water standard Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012737 fresh medium Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-M hydroperoxide group Chemical group [O-]O MHAJPDPJQMAIIY-UHFFFAOYSA-M 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 210000000936 intestine Anatomy 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 239000002855 microbicide agent Substances 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 238000012543 microbiological analysis Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000009456 molecular mechanism Effects 0.000 description 1
- 231100000219 mutagenic Toxicity 0.000 description 1
- 230000003505 mutagenic effect Effects 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 230000001706 oxygenating effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000009304 pastoral farming Methods 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000001575 pathological effect Effects 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000009374 poultry farming Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011321 prophylaxis Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/52—Adding ingredients
- A23L2/54—Mixing with gases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B5/00—Water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
- C02F1/36—Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/4608—Treatment of water, waste water, or sewage by electrochemical methods using electrical discharges
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46152—Electrodes characterised by the shape or form
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/026—Treating water for medical or cosmetic purposes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4612—Controlling or monitoring
- C02F2201/46125—Electrical variables
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4618—Supplying or removing reactants or electrolyte
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4619—Supplying gas to the electrolyte
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
- C02F2305/023—Reactive oxygen species, singlet oxygen, OH radical
Definitions
- the invention relates to a method for producing water with increased oxygen content, including its activated forms, having the features of the introductory part of claim 1.
- the invention further relates to an apparatus for carrying out the method for producing water with increased oxygen content, including its activated forms.
- US Pat. No. 4,549,969 A describes a process for increasing the oxygen content in aquarium water.
- a hollow rod is introduced into the aquarium, in which an aqueous solution of hydroperoxide (its concentration is in the range of 0.1-5%) is included.
- the rod part immersed in the container with the oxygenating water has pores.
- the outer surface of the rod member is covered with a substance which catalyzes the decomposition of hydroperoxide in water and in oxygen: manganese dioxide, Fe 2 O 3 , nickel oxide.
- Oxygen produced in the aquarium dissolves better in the water than would be the case if pure oxygen were added to the water.
- oxygen is supplied "in statu nascendi".
- Singlet oxygen is an excited form of molecular oxygen (O 2 ), which in turn represents the usual form of oxygen found in the air or in water, and is also called triplet oxygen.
- Singlet oxygen forms in a series of chemical reactions involving, for example, oxygen radicals and peroxy compounds.
- singlet oxygen also arises from ordinary tri- Oxygen in contact with special colors, so-called photody- namic colors, with light of a certain wavelength.
- the singlet oxygen is a strong oxidant and readily enters into various chemical reactions, especially with water.
- JP 1228591 A describes a method in which air is irradiated intensively with ultraviolet radiation in the wavelength ranges from 150 nm to 180 nm and from 200 nm to 300 nm.
- the irradiation in these wavelength ranges contributes to the formation of ozone in the oxygen contained in the air. Ozone splits instantly, forming atomic oxygen. The oxygen thus formed is introduced into water, which is intended to become active.
- both active oxygen is introduced into it, not only in the form of singlet oxygen, but also in its other active forms, such as the hydroperoxide radical, the ozone, higher peroxides of the types H 2 O 3 and H 2 O 4 and their radical forms and other oxygen species, as well as the fact that a significantly increased, relatively balanced concentration of molecular oxygen is produced in the water, which activates in the decay reactions of these high energy particles becomes, whereby they are reproduced.
- This method and the apparatuses allow to obtain water with a content of 50-60 mg oxygen / liter.
- the disadvantages of this method are that the content of oxygen is expensive and that it drops rapidly during storage under normal conditions.
- oxygen-saturated water produced by the above methods quickly loses dissolved oxygen at atmospheric pressure and its level remains within the dynamic equilibrium of the water-luff system, ie, in the range of 6 to 14 mg / 1 at room temperature.
- the object of the invention is to provide a process for producing oxygen-enriched liquids, in particular water enriched with both active and molecular oxygen (hereinafter referred to as "oxywater”), and also a process for carrying out the process To provide a suitable device, with the stable and highly effective, oxygenated water can be obtained to provide.
- oxygen-enriched liquids in particular water enriched with both active and molecular oxygen (hereinafter referred to as "oxywater”)
- Oxygen and its active forms primarily refer to the saturation of drinking water, water for water therapies, use of saturated water in industry and agriculture as well as saturating polluted plant and household water.
- the saturation of other liquids with oxygen and its active forms to optionally transfer active oxygen to other liquids and gases is also contemplated within the scope of the invention.
- the pure oxygen prior to introduction into the liquid, the pure oxygen is activated, whereby it is converted into various active forms and at the same time moistened, which promotes stabilization of these forms until they enter the liquid;
- the packing are preferably made of silicate material
- the saturation of a liquid (water) with active oxygen occurs at a temperature of the liquid and the surrounding air in the range of room temperature and an overpressure of about 0.2 - 2 kPa.
- Clathrates are three-dimensional, closed structures whose scaffolds are made up of water molecules that are bound together by hydrogen bonds, and that have spaces on the inside where space-sized particles of molecular dimensions, especially active oxygen forms, can be accommodated.
- the activation of the oxygen in the device described below and the incorporation of active oxygen into the water ensure an efficient realization of the physical-chemical processes, in which the activation of the oxygen and the stabilization of the activated oxygen before the time of its dissolution in the water and after its introduction into the water.
- FIG. 1 shows schematically a system for saturating water with oxygen
- FIG. 2 shows a detail of the device from FIG. 1
- FIG. 3 shows a diagram of the dynamics of saturation of water with activated oxygen.
- the activation of oxygen takes place in a device according to Fig. 1 and 2 .
- Oxygen from bottles 4 (purity: 99.9%) is controlled by a control organ 9, passed through an activator 8 ("plasma memotron" in FIG. 2). From the activator 8, active oxygen enters a separator 2.
- the activator 8 is supplied with electrical energy from a power supply 5, which can also serve as a control unit.
- the operating voltage of the power supply 5 is for example 220 V, that of the activator 8 between 110 and 220 V.
- the current is set between 2 and 30 amps.
- the ratio between the amount of electrolytic solution and gaseous oxygen in the activator 8 is 1:10 to 1: 150 liters.
- the temperature of the mixture of electrolyte solution and oxygen in the activator 8 is at stable operating conditions 30 to 90 ° C.
- the process parameters to be observed in the oxygen activation are selected and set taking into account the requirements for the amount and content of oxygen and its active forms in the water.
- the nature of the electrolyte solution, its constituents and the concentration of electrolytes in the solution are also chosen taking into account the requirements of the final finished product. For example, in the production of drinking water with an average content of oxygen and its active forms of 25-35 mg / 1, an alkaline electrolyte having a basic substance content of the order of 4% is used.
- the electrolyte solution is prepared in advance and supplied from a reservoir 2a.
- composition of the usable electrolyte solution according to the invention is the following:
- alkaline electrolyte containing alkaline substance e.g. Sodium hydroxide (NaOH) of water 4 +/- 1%.
- the plant parts contained in the part marked "sector A" in FIG. 1 serve to produce activated oxygen.
- Domrachev GA Selivanovskii DA, Didenculov IN, Rodigin Yu.L., Stunzhas PA: Temperature dependence of efficiency of sonolysis and intensity of solonuminescence of water, Zhurnal Fizicheskoi Himii., 2001, 75 (2), pp. 363-368).
- the parts of the plant contained in the part labeled "sector B" of Fig. 1 serve to saturate a liquid (in the example: water) with oxygen and its active forms.
- a well For enriching / saturating natural water from a well (well, spring) is used, which corresponds to drinking water standards.
- the cleaning is carried out in a two-stage filter 6.
- the purified, clarified and possibly sterilized by UV irradiation 12 water is collected in a container 3 and conveyed from the container 3 with a pump 7 in the upper part of the column 1.
- the ratio of the flows of water: oxygen is 80: 1.
- the absorption temperature is equal to the ambient temperature.
- the control and regulation of the functions of the oxygen activation and water saturation sections A and B can be done with a computer controlled system.
- Activation of oxygen is accomplished using the equipment portions of the apparatus of sector "A" in FIG. 1, notably the activator 8 shown in greater detail in FIG.
- Activator 8 (plasma motorotron) is designed and manufactured according to the planned performance of the plant.
- a typical plasma chemotron has a hollow plastic housing 11 in the bottom of which a hollow, metallic cathode 13 is mounted. Through the cavity in the cathode 13 electrolyte solution is passed from the separator 2 in the activator 8, whereby the cathode 13 is cooled.
- the anode 12 is spaced around the cathode 13 and perforated. From an annular manifold 14, the oxygen from the bottles 4 is supplied, escaping oxygen is uniformly distributed from the perforated anode 12 in the reaction zone.
- the level of electrolyte solution in the housing 11 is controlled by means of overflow 20 via an opening 21 in the housing 11 or via a device. Instead of the overflow, an (arbitrarily designed) other device for regulating the liquid level can also be provided.
- the reliability of the activator 8 is ensured by switching off current to the cathode 13 and the anode 12 when in the housing 11 no more electrolyte solution is present.
- the operating voltage of the power supply 5 is up to 220 V, that of the
- Activator 8 between 110 V and 220 V.
- the current is set from 2 to 30 amps.
- the relationship between the flows of Electrolyte solution and the gaseous oxygen is 1:10 to 1: 150 liters.
- the temperature of the active mixture is 30 to 90 ° C under stable operating conditions.
- the process parameters to be observed during oxygen activation are determined by the requirements for the amount and content of oxygen and its active forms in the water.
- Electrolyte solution and gaseous oxygen 1:50 liters
- oxygen-enriched water obtainable according to the present invention.
- water obtainable according to the invention has special properties, that it exerts an unusual influence on microorganisms which come into contact with it, that it has a favorable effect on physical endurance and that it affects the De - Reduced pressivity of laboratory animals (rats).
- microorganisms To determine whether microorganisms are present in the water, it is applied to a Petri dish with a standard agar medium and incubated for one day at an optimal temperature for cell proliferation, after which the number of colonies is counted.
- the microorganisms of artesian water and water obtainable according to the invention have formed colonies only after two to three days, i. much later than microorganisms from ordinary water.
- the microorganisms from water obtainable according to the invention have formed very small colonies whose dimensions are smaller than those of artesian water. This shows a very low reproductive capacity of the microorganisms living in these waters, but especially in the water obtainable according to the invention. Even in water obtainable according to the invention, which was stored in closed bottles for one year and in which the content of microorganisms was markedly higher than in fresh water obtainable in accordance with the invention, the reproductive capacity of the microorganisms remained at a low level.
- the small size of the colonies is related to the fact that the number of cells in them is smaller by one to two orders of magnitude, depending on how long the colonies had time to grow than in the cultures of the control cells. In other words, the rate of division of the microorganisms rapidly decreases after contact with water obtainable according to the invention.
- the modification of the reproductive properties of the cells of the coli bacterium under the action of water obtainable according to the invention can explain the positive effect of a regular consumption of this water on the digestive apparatus.
- the microorganisms colonizing the gastrointestinal tract of humans and animals play a very important role in normal physiology. They ensure that the digestive processes run efficiently and provide the organism with many biologically active substances (vitamins, regulatory molecules) that the organism itself does not produce or does not produce in sufficient quantities.
- the microorganisms normally living in the intestine only fulfill their functions in the time between cell divisions. Too high a rate of division of the microbial cells in the gastrointestinal tract is usually associated with pathological phenomena and is accompanied by the negative symptoms.
- the "oxy" water obtainable according to the invention is an advantageous agent for the prophylaxis and therapy of gastrointestinal diseases.
- water obtainable according to the invention normalizes the biological activity of microorganisms without killing them, which has a favorable effect on the digestion and also on other physiological processes in the human organism.
- the oxygen content in an opened bottle of water obtainable according to the invention is from two to three times the oxygen content in artesian water and other pure water which are in equilibrium with the air.
- the composition of the salts, the pH and the redox potential of this water make it possible to count it as drinking water of the highest quality.
- the oxygen content in water obtainable according to the invention decreases and gradually reaches an equilibrium concentration, this process proceeding rapidly when stirring. Consequently, one can explain the above-described biological properties of the water, in particular its influence on the Kolibakterienzellen, especially when stirring the Incubationsproben, not only with an increased oxygen content in the water.
- Water obtainable according to the invention in comparison with conventional drinking water, has a considerably higher energy activity, which is responsible for its particular biological properties.
- the water produced by the process according to the invention (“oxy- Water ”) may have the following properties, among others.
- Water obtainable according to the invention has a bacteriostatic effect on intestinal and other microflora, without having pronounced antibiotic properties.
- Water obtainable according to the invention has a favorable effect on the physical and mental endurance of laboratory animals.
- the mechanism of biological activity of water obtainable according to the invention is given by its capacity for oxygen activation and autoxidation.
- oxygen is generated by interaction with the active oxygen produced during the electrolysis, by excitation under the action of the various energy sources. gieformen that occur when current is passed through the electrolyzer (in particular sound energy and light energy), activated.
- the active oxygen is stabilized in the water clathrates and this moist gas mixture is brought into contact in a countercurrent column with the liquid to be oxygenated, wherein the liquid to be enriched, the Gegenstromkolon- ne, which contains a silicate-containing material as filler, from top to bottom and the activated oxygen flows through the countercurrent column from bottom to top.
- the liquid to be enriched is passed through the column several times until the desired degree of oxygen enrichment has been achieved.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05811876A EP1819640A1 (fr) | 2004-11-29 | 2005-11-24 | Procede et dispositif de production d'eau a teneur accrue en oxygene |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT20022004 | 2004-11-29 | ||
ATA2002/2004 | 2004-11-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006055999A1 true WO2006055999A1 (fr) | 2006-06-01 |
Family
ID=35709366
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AT2005/000474 WO2006055999A1 (fr) | 2004-11-29 | 2005-11-24 | Procede et dispositif de production d'eau a teneur accrue en oxygene |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP1819640A1 (fr) |
WO (1) | WO2006055999A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013114150A1 (fr) | 2012-02-02 | 2013-08-08 | Potemkin Alexander | Installation de conversion de substances de départ hydrocarbonées en combustible gazeux et liquide et chémotron à plasma destiné à cette installation |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2704542A1 (fr) * | 1993-04-29 | 1994-11-04 | Coteau Holding Sa | Procédé de traitement des eaux. |
US5685994A (en) * | 1994-10-20 | 1997-11-11 | Johnson; Dennis E. J. | Method for water treatment and purification using gas ion plasma source and disinfectant metal ion complexes |
EP1022256A2 (fr) * | 1999-01-19 | 2000-07-26 | ECO Naturforschungs- und Technologie Gesellschaft mbH | Dispositif et procédé pour enrichir l'eau, en particulier avec de l'oxygène |
DE10014833A1 (de) * | 2000-03-24 | 2001-10-04 | Luwatec Gmbh Luft Und Wasserte | Verfahren zur Aufbereitung von mechanisch, organisch und/oder biologisch verunreinigtem Wasser |
US6478949B1 (en) * | 1996-10-31 | 2002-11-12 | H2O Technologies, Ltd. | Method and apparatus for increasing the oxygen content of water |
US20030133354A1 (en) * | 2000-04-27 | 2003-07-17 | Denis-Michel Ledoux | Treatment of fluids |
-
2005
- 2005-11-24 WO PCT/AT2005/000474 patent/WO2006055999A1/fr active Application Filing
- 2005-11-24 EP EP05811876A patent/EP1819640A1/fr not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2704542A1 (fr) * | 1993-04-29 | 1994-11-04 | Coteau Holding Sa | Procédé de traitement des eaux. |
US5685994A (en) * | 1994-10-20 | 1997-11-11 | Johnson; Dennis E. J. | Method for water treatment and purification using gas ion plasma source and disinfectant metal ion complexes |
US6478949B1 (en) * | 1996-10-31 | 2002-11-12 | H2O Technologies, Ltd. | Method and apparatus for increasing the oxygen content of water |
EP1022256A2 (fr) * | 1999-01-19 | 2000-07-26 | ECO Naturforschungs- und Technologie Gesellschaft mbH | Dispositif et procédé pour enrichir l'eau, en particulier avec de l'oxygène |
DE10014833A1 (de) * | 2000-03-24 | 2001-10-04 | Luwatec Gmbh Luft Und Wasserte | Verfahren zur Aufbereitung von mechanisch, organisch und/oder biologisch verunreinigtem Wasser |
US20030133354A1 (en) * | 2000-04-27 | 2003-07-17 | Denis-Michel Ledoux | Treatment of fluids |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013114150A1 (fr) | 2012-02-02 | 2013-08-08 | Potemkin Alexander | Installation de conversion de substances de départ hydrocarbonées en combustible gazeux et liquide et chémotron à plasma destiné à cette installation |
Also Published As
Publication number | Publication date |
---|---|
EP1819640A1 (fr) | 2007-08-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0237793B1 (fr) | Procédé et dispositif pour le traitement des eaux de piscine et de baignoire à l'aide de chlore et d'ozone | |
DE60216962T2 (de) | Einrichtung unf Verfahren zur Behandlung von Wasser in einem Aquakultursystem | |
EP2146580A2 (fr) | Agent de desinfection a base de solutions aqueuses contenant de l'acide hypochlorique (hocl), procede de production et utilisation associes | |
DE3603900A1 (de) | Trinkwasserreinigungseinrichtung | |
DE102006035629A1 (de) | Verfahren zum Reformieren von Wasser und Wasser-Reformierer | |
WO2013022142A1 (fr) | Appareil pour la production d'eau hydrogénée fonctionnelle | |
DE2629081A1 (de) | Germizides mittel | |
EP2475622A1 (fr) | Purification continue d'une eau d'élevage peuplée d'animaux aquatiques et/ou de plantes aquatiques | |
DE2822818C2 (fr) | ||
EP2152324A2 (fr) | Procédé de protection phytosanitaire pour la lutte contre les parasites des plantes à l'aide de radicaux oxydants produits par voie électrolytique, de la lumière uv-c et de la technologie de pulvérisation électrostatique assistée par air | |
WO1984003274A1 (fr) | Procede de fabrication d'une solution aqueuse modifiee de chlorite, la solution produite par la suite et son utilisation | |
DE3403631C2 (fr) | ||
DE2941742A1 (de) | Kombiniertes jod-uv-desinfektionsverfahren fuer wasser | |
DE102008015068A1 (de) | Elektrodiaphragmalyse | |
WO1982003381A1 (fr) | Procede pour la preparation de corps moules pour l'aseptisation de l'eau et de solutions aqueuses | |
DE2606660C2 (de) | Verfahren zum Herstellen einer wäßrigen Suspension von Bakterien | |
DE4038099C2 (fr) | ||
DE60101333T2 (de) | Verfahren zur behandlung von stickstoff- und/oder phosphor- und/oder organischen stoffen- und/oder schwermetalle enhaltendem abwasser | |
DE60128342T2 (de) | Verwendung von ozonierten lösungen von tetrasilber tetraoxide | |
WO2006055999A1 (fr) | Procede et dispositif de production d'eau a teneur accrue en oxygene | |
AT8452U1 (de) | Verfahren und vorrichtung zum herstellen von wasser mit erhöhtem sauerstoffgehalt | |
DE2133563A1 (de) | Verfahren und Vorrichtung zur Sauer Stoffanreicherung und Ozonisierung von BSB haltigem Abwasser | |
DE2425319A1 (de) | System zum reinigen und sterilisieren von wasser | |
WO2011120701A1 (fr) | Solution à base aqueuse activée électrochimiquement et utilisation de la solution | |
CH644087A5 (en) | Process and agent for maintaining the sterility of water and aqueous solutions |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 2005811876 Country of ref document: EP |
|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KM KN KP KR KZ LC LK LR LS LT LU LV LY MA MD MG MK MN MW MX MZ NA NG NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU LV MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWP | Wipo information: published in national office |
Ref document number: 2005811876 Country of ref document: EP |