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WO2005023975A1 - Agent cosmetique a phases multiples pour laver les cheveux et nettoyer la peau - Google Patents

Agent cosmetique a phases multiples pour laver les cheveux et nettoyer la peau Download PDF

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Publication number
WO2005023975A1
WO2005023975A1 PCT/EP2004/009511 EP2004009511W WO2005023975A1 WO 2005023975 A1 WO2005023975 A1 WO 2005023975A1 EP 2004009511 W EP2004009511 W EP 2004009511W WO 2005023975 A1 WO2005023975 A1 WO 2005023975A1
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WO
WIPO (PCT)
Prior art keywords
composition according
weight
salt
amount
acid
Prior art date
Application number
PCT/EP2004/009511
Other languages
German (de)
English (en)
Inventor
Matthias Hloucha
Kerstin Dorn
Lars Jung
Gabriele Weser
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10341023A external-priority patent/DE10341023A1/de
Priority claimed from DE2003154213 external-priority patent/DE10354213A1/de
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Publication of WO2005023975A1 publication Critical patent/WO2005023975A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/03—Liquid compositions with two or more distinct layers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines

Definitions

  • the present invention relates to a composition comprising at least two aqueous phases and its use as a personal care and / or body cleanser, in particular for cleaning skin and hair, especially as a shower bath, shampoo, bubble bath, liquid soap, make-up remover or facial cleanser.
  • compositions which form two or more phases, in particular for use as agents for body care and / or cleaning.
  • Various compositions have already been described in this connection.
  • WO 02/15849 describes a two-phase aqueous system which contains between 5 and 35% by weight detergents, between 1 and 12% by weight thickener, between 4 and 20% by weight polyalkylene glycol and a salt selected from the group consisting of Contains alkali or alkaline earth sulfate, bisulfate, carbonate or bicarbonate.
  • a salt selected from the group consisting of Contains alkali or alkaline earth sulfate, bisulfate, carbonate or bicarbonate.
  • the amount of salt used is between 10 and 25% by weight.
  • EP 0175485 describes two-phase aqueous systems which are based on the use of complexing agents. However, their use is problematic and should be avoided if possible.
  • No. 6,180,587 describes the use of a two-phase aqueous system in which a copolymer of acrylic acid and maleic acid and an alkoxy sulfate are used. This system is based on a combination of polyacid and anionic surfactant.
  • JP 06033410 and JP 62263297 describe two-phase systems in which anionic surfactants are used in combination with polyacrylates or polyamides.
  • WO 00/61716 describes multi-phase preparations which contain at least one dissolved surface-active compound, at least one dissolved polymer compound and at least one water-soluble, mono- or polyhydric alcohol having 2-9 C atoms.
  • the object of the present invention was to provide two-phase or multi-phase aqueous compositions, with at least two visually separated phases, which are advantageous compared to the multi-phase aqueous compositions described in the prior art, in particular those which are used for personal care and / or cleaning can be used, for example by being more environmentally friendly or cheaper, giving a better skin feel, better foaming enable or enable a faster phase separation than the multiphase aqueous systems described in the prior art.
  • aqueous compositions can advantageously be used as multi-phase systems for personal care and cleaning, which comprise the following components: a) at least one nonionic and / or at least one amphoteric surfactant in an amount of 0.1-25% by weight.
  • % preferably in an amount of 1-15% by weight
  • the information here relates to the overall system.
  • the various phases of the multiphase system, which are at rest, can have a different composition.
  • any mixture of nonionic and amphoteric surfactants can be contained in the composition.
  • the agent according to the invention contains no amphoteric surfactants.
  • the nonionic surfactant is preferably in an amount of 0.1-15% by weight, particularly preferably 0.5-8% by weight, especially in an amount of 2-4 or 4-6% by weight. , each based on the total weight, contained in the agent according to the invention.
  • the agent according to the invention contains no nonionic surfactants.
  • the amphoteric surfactant is preferably in an amount of 0.1-15% by weight, particularly preferably 0.5 - 8 wt .-%, especially in an amount of 2-6 or 4-6 wt .-%, contained in the agent according to the invention.
  • nonionic surfactants are preferably present in an amount of 0.1-15% by weight, particularly preferably 0.5-8% by weight, especially in one Amount of 4-6% by weight and the amphoteric surfactants preferably in an amount of 0.1 to 20% by weight, preferably 0.5 to 7.5% by weight and in particular 1 to 5% by weight. % contain.
  • composition according to the invention is distinguished by the fact that it represents a multiphase system which comprises at least two visually separated aqueous phases, which are preferably both clear. These are advantageously two aqueous phases; no oil phase is formed. This has the advantage that the user does not feel greasy on the skin.
  • the volume ratio of the different phases of the multiphase composition according to the invention can have any value.
  • the volume ratio can in particular be between 95: 5 and 5:95.
  • a value between 70:30 and 30:70 is preferred here.
  • phase separation can be seen after twelve hours, preferably after six hours, particularly preferably within one hour after shaking.
  • composition is also preferably characterized by a good feeling on the skin, particularly since the use of high amounts of salt is dispensed with can be. Further advantages of the composition according to the invention are preferably good foam formation and good skin tolerance.
  • the sum of the amount of salt and the amount of polar organic compound in the composition according to the invention is preferably between 5 and 20% by weight.
  • the present invention furthermore relates to a process for producing a composition according to the invention, the aforementioned components of the composition according to the invention being mixed with one another in the amounts stated.
  • the present invention furthermore relates to the use of a composition according to the invention as a body care and / or body cleaning agent, the body care and / or body cleaning agent being in particular a shower bath, shampoo, foam bath, a liquid soap, a make-up remover or can be a facial cleanser.
  • Nonionic surfactants contain z as a hydrophilic group.
  • B a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether group. Examples of such compounds are: C8-C22-alkyl mono- and oligoglycosides and their ethoxylated analogues,
  • Preferred nonionic surfactants are alkyl polyglycosides of the general formula RO- (S) x .
  • the alkyl radical R here preferably contains 6 to 22 carbon atoms and can be either linear or branched. Primary linear and methyl-branched aliphatic radicals are preferred. Examples of such alkyl radicals are 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. 1-Octyl, 1-decyl, 1-lauryl, 1-myristyl are particularly preferred.
  • the alkyl polyglycosides which can be used according to the invention can contain, for example, only a homogeneous alkyl radical R, in particular a C ⁇ -, C-io-, C ⁇ 2 -, C - or Ci 6 - alkyl group.
  • a homogeneous alkyl radical R in particular a C ⁇ -, C-io-, C ⁇ 2 -, C - or Ci 6 - alkyl group.
  • these compounds are made from natural fats and oils or mineral oils.
  • the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the respective working up of these compounds.
  • R consists essentially of C ⁇ and C ⁇ Q alkyl groups, essentially of C ⁇ - ur
  • d C ⁇ -Alkyl phenomenon consists essentially of Cß- to C- j g -alkyl groups or essentially from C ⁇ - D ' s C- j g -alkyl groups.
  • Any mono- or oligosaccharides can be used as the sugar building block S.
  • Sugar with 5 or 6 carbon atoms and the corresponding oligosaccharides are usually used.
  • sugars are glucose, fructose, galactose, arabinose, ribose, xylose, lyxose, allose, old rose, mannose, gulose, idose, talose and sucrose.
  • Preferred sugar building blocks are Glucose, fructose, galactose, arabinose and sucrose; Glucose is particularly preferred. In particular, it can be alkyl glucosides which are available under the trade names APG600 and Plantacare®1200UP and / or under the INCI name Lauryl Glucoside.
  • alkyl polyglycosides which can be used according to the invention contain on average 1.1 to 5 sugar units. Alkyl polyglycosides with x values of 1.1 to 1.6 are preferred. Alkyl glycosides in which x is 1.1 to 1.4 are very particularly preferred.
  • amphoteric surfactants also includes the group of surfactants known to the person skilled in the art as zwitterionic surfactants.
  • Suitable amphoteric or zwitterionic surfactants which can be used according to the invention contain a basic and an acidic group, which form an inner salt.
  • the cationic group is in particular a quaternary ammonium group, but it can also be, for example, a phosphonium, imidazolium or sulfonium group.
  • the anionic group is in particular a carboxylate or sulfonate group, but it can also be a phosphonate or sulfate group, for example.
  • amphoteric surfactants which can preferably be used according to the invention are compounds of the general formula (I)
  • R 1 is preferably an aliphatic or aromatic hydrophobic, optionally substituted group
  • R 2 and R 3 independently of one another are preferably hydrogen or a short, optionally substituted alkyl group, and where R 2 and R 3 can also be linked to one another
  • R 4 is preferably an optionally substituted alkylene or polyalkoxy group
  • X is preferably a carboxylate or Sulfonate group stands.
  • amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines.
  • betaine compounds of the formula (II) are used as amphoteric surfactants,
  • R 1 is an alkyl radical with 8 to 25, preferably 10 to 21 carbon atoms, which is optionally interrupted by heteroatoms or heteroatom groups
  • R 2 and R 3 are identical or different alkyl radicals with 1 to 3 carbon atoms.
  • C 1 -C 18 -Alkyldimethylcarboxymethylbetaine, C 1 -C 4 -alkylamido propyldimethylcarboxymethylbetaine and cocoamidopropylbetaine are preferred.
  • Sulfobetaines are also preferred.
  • a sulfonate group is the anionic group instead of the carboxy group.
  • Bis (hydroxyethyl) sulfobetaine and cocoamidopropyl sulfobetaine are particularly suitable.
  • betaines and / or sulfobetaines can generally be used, as described, for example, in US Pat. No. 2,082,275, US Pat. No. 2,702,279 or US Pat. No. 2,255,082. salts
  • a salt or a mixture of several salts is contained in the composition according to the invention as a further component.
  • the salt preferably contains inorganic salts and / or salts of organic acids, in particular from the group of the alkali metal, alkaline earth metal and ammonium salts of sulfuric acid, hydrohalic acids and organic acids, and mixtures thereof, in particular sodium chloride, sodium sulfate, magnesium sulfate, sodium citrate , Potassium citrate, and sodium lactate.
  • Organic acids in particular polyvalent organic acids, especially di-, tri- and tetracarboxylic acids and / or salts of higher polycarboxylic acids, that is to say, for example, of organic acids which are linked to one another via functional groups, such as iminodisuccinic acid, are particularly preferred.
  • the organic acids can also carry further functional groups.
  • the organic acids comprise 4 to 8 carbon atoms and 2 to 4 carboxylate groups, which may in particular be oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, malic acid, tartaric acid, citric acid or iminodisuccinic acid.
  • Citrates, the salts of citric acid, and iminodisuccinates, the salts of iminodisuccinic acid are particularly preferred.
  • the salt of organic acid, and in particular citric acid and / or iminodisuccinic acid can be, for example, a sodium, potassium or ammonium salt.
  • the salt of citric acid and / or the salt of iminodisuccinic acid is preferably in the composition in an amount between 0.1 and 10% by weight, particularly preferably between 1 and 8% by weight, especially between 2 and 5 or 4 and 7 % By weight.
  • Suitable polar organic compounds which may be included in the compositions of this invention are for example selected from the group consisting of mono- and polyhydric alcohols, in particular mono- and divalent C 2 - 6 alkanols, particularly n-propanol, i-propanol or 1, 6-hexanediol, and esters of organic acids and ethers, in particular triethyl citrate and also, for example, also di-n-octyl ether, decyl oleate, Glycerol monooleate and / or glycerol monolaurate.
  • mono- and polyhydric alcohols in particular mono- and divalent C 2 - 6 alkanols, particularly n-propanol, i-propanol or 1, 6-hexanediol
  • esters of organic acids and ethers in particular triethyl citrate and also, for example, also di-n-octyl ether, decyl oleate
  • esters in particular C- ⁇ - 4 alkyl esters, polyvalent organic acids, especially organic acids, the total of 4 to 8 carbon atoms and 2 to 4 carboxylate groups include, where the acids may also be mono- or polysubstituted can be, in particular by hydroxyl groups, with triethyl citrate being very particularly preferred as the ester of the organic acid.
  • The% by weight ratio between polar organic compound and salt is preferably between 0.1 and 10, particularly preferably between 0.2 and 7, in particular when triethyl citrate is used as the polar organic compound and a salt of citric acid and / or iminodisuccinic acid as the salt is used.
  • Suitable water-soluble polymers are all water or aqueous surfactant solutions at 20 ° C. in amounts of at least 0.5% by weight of natural or synthetic high-molecular substances with recurring structural elements.
  • Natural polymers are understood to be water-soluble polysaccharides or the water-soluble derivatives of water-insoluble polysaccharides.
  • Suitable natural polymers are e.g. Starch, guar, cellulose ethers, especially methyl celluloses or hydroxyethyl celluloses, and carboxymethyl celluloses.
  • Suitable synthetic polymer compounds are e.g.
  • water-soluble copolymers of acrylic acid, acrylamide, vinyl pyrrolidone and other water-soluble monomers with non-water-soluble comonomers are polymer compounds in the sense of the present invention suitable.
  • Polymer compounds selected from polyethylene glycols, polypropylene glycols and polyvinylpyrrolidine with molecular weights of more than 1000 D are preferably suitable for the preparation of the preparations according to the invention.
  • the amounts of polymer compounds required for segregation depend on the type and molecular weight of the polymer compound, it generally applies that the required amounts the lower the higher the Molecular weight of the polymer compound is.
  • the upper limit of the content of polymer compounds should be chosen so that the preparation does not gel and separation is not hindered by the toughness of the phases.
  • the polymer is polyethylene glycol (PEG), in particular PEG with a molecular weight greater than or equal to 3000 g / mol (D), especially greater than or equal to 6000 g / mol (D), in particular greater than or equal to 10,000 g / mol (D).
  • PEG polyethylene glycol
  • D polyethylene glycol
  • The% by weight ratio between polar organic compound and water-soluble polymer is preferably between 0.1 and 10, particularly preferably between 0.2 and 4.5 or between 4 and 7, in particular if the polar organic compound is triethyl citrate is.
  • compositions may also contain anionic surfactants.
  • these are preferably in an amount between 0 and 30% by weight, particularly preferably in an amount between 0.7 and 20% by weight.
  • % especially in an amount between 5 and 15 wt .-% or 10 and 20 wt .-%, contain.
  • Suitable anionic surfactants in compositions according to the invention are all anionic surface-active substances suitable for use on the human body. These are characterized by a hydrophilic anionic group such as. B. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 10 to 22 carbon atoms.
  • a hydrophilic anionic group such as. B. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 10 to 22 carbon atoms.
  • glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups can be contained in the molecule.
  • Suitable anionic surfactants each in the form of the sodium, potassium, magnesium and ammonium and the mono-, di- and trialkanolammonium salts with 2 or 3 carbon atoms in the alkanol group: linear fatty acids with 10 to 22 carbon atoms Atoms (soaps), Amide ether carboxylates of the formula [R-NH (-CH2-CH 2 -0) n-CH2-COO] mZ, in which R is a linear or branched, saturated or unsaturated acyl radical having 2 to 29 carbon atoms, n is an integer of 1 to 10, m represents the numbers 1 or 2 and Z represents a cation from the group of the alkali or alkaline earth metals, acyl sarcosides with 10 to 18 C atoms in the acyl group, acyl taurides with 10 to 18 C atoms in the acyl group, Acyl isothionates with 10 to 18 carbon atoms in the acyl group,
  • Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids with 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule, and sulfosuccinic acid and dialkyl esters with 8 to 18 carbon atoms in the alkyl group and sulfosuccinic acid mono-alkyl polyoxyethyl ester with 8 to 18 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups.
  • the anionic surfactant is a fatty alcohol ether sulfate, in particular sodium lauryl ether sulfate (SLES), also known under the trade name TEXAPON®N70 (Cognis).
  • SLES includes C 12 -C 4 alkyl groups, two ethoxy groups and a sulfate group.
  • composition according to the invention can contain further constituents, in particular those which are customary for a personal care product and / or cleaning agent, in particular those such as those for a personal care product and / or body cleaning product, in particular for cleaning skin and hair, especially for a shower bath , a shampoo, a bubble bath, a liquid soap, a make-up remover and / or for a facial cleanser.
  • these can in particular be selected from the group consisting of buffer salts, perfumes, preservatives, care substances, cosmetic or dermatological active substances, complexing agents, antioxidants and dyes.
  • hydrophobically modified polymers and / or heavy metal salts and / or oils can also be present in small amounts.
  • the dyes which can be used according to the invention include, for example, the water-soluble dye dyes bluel (Cl 42090), green3 (Cl 42053), green ⁇ (Cl 61570), green ⁇ (Cl 59040), yellow ⁇ (Cl 19140), yellowö (Cl 15985), yellowlO (Cl 47005), red4 (Cl 14700), red33 (Cl 17200) red40 (Cl 16035).
  • Cl stands for "Color Index”.
  • the dyes are listed, for example, in the reference work of the German Research Foundation (DFG) entitled “Cosmetic Colorants", 3rd edition, VCH Verlagsgesellschaft mbH, D-6940 Weinheim, 1991, ISBN 3-527-27020-5.
  • DFG German Research Foundation
  • Cationic polymers and cationic surfactants are suitable as care substances.
  • care substances according to the invention preferably cationic polymers may be selected from the following group are used: - quaternized cellulose derivatives, such as are available under the names of Celquat ® (National Starch) and polymer Ucare JR ® (Amerchol) commercially.
  • the compounds Celquat ® H 100, Celquat ® L 200 and Polymer Ucare JR ® 400 are preferred quaternized cellulose derivatives, - Cationic guar derivatives, in particular those sold under the tradename Cosmedia ® guar (Cognis) and Jaguar ® (Rhodia) Products , - Polymer Dimethyldiallylammoniumsalze and their copolymers with esters and amides of acrylic acid and methacrylic acid.

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Abstract

L'invention concerne une composition comprenant au moins deux phases aqueuses, ainsi que son utilisation comme agent de soins corporels et/ou d'agent de lavage corporel, notamment pour nettoyer la peau et laver les cheveux, avant tout comme produit de douche, shampooing, bain moussant, savon liquide, démaquillant ou comme produit nettoyant pour le visage.
PCT/EP2004/009511 2003-09-03 2004-08-26 Agent cosmetique a phases multiples pour laver les cheveux et nettoyer la peau WO2005023975A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10341023A DE10341023A1 (de) 2003-09-03 2003-09-03 Mehrphasiges kosmetisches Mittel zur Haar- und Hautreinigung
DE10341023.6 2003-09-03
DE10354213.2 2003-11-20
DE2003154213 DE10354213A1 (de) 2003-11-20 2003-11-20 Mehrphasiges kosmetisches Mittel zur Haar- und Hautreinigung

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WO2005023975A1 true WO2005023975A1 (fr) 2005-03-17

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FR2918068A1 (fr) * 2007-06-26 2009-01-02 Agence Internationale De L Emb Procede et composition pour colorer les eaux de bassins de bains et/ou de baignades.
US20160310369A1 (en) * 2015-04-23 2016-10-27 The Procter & Gamble Company Low Viscosity Hair Care Composition
WO2017012738A1 (fr) * 2015-07-20 2017-01-26 Beiersdorf Ag Produits à deux phases miscibles de manière réversible et pouvant être à nouveau dissociés
US9949914B2 (en) 2015-04-23 2018-04-24 The Procter & Gamble Company Low viscosity hair care composition
US9949901B2 (en) 2015-04-23 2018-04-24 The Procter & Gamble Company Low viscosity hair care composition
WO2018089394A1 (fr) * 2016-11-08 2018-05-17 Colgate-Palmolive Company Compositions de soins bucco-dentaires
US10311575B2 (en) 2016-03-23 2019-06-04 The Procter And Gamble Company Imaging method for determining stray fibers
EP3530722A1 (fr) * 2016-10-19 2019-08-28 Shiseido Company, Ltd. Composition d'agent nettoyant
US10426713B2 (en) 2017-10-10 2019-10-01 The Procter And Gamble Company Method of treating hair or skin with a personal care composition in a foam form
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US11224567B2 (en) 2017-06-06 2022-01-18 The Procter And Gamble Company Hair compositions comprising a cationic polymer/silicone mixture providing improved in-use wet feel
US11291616B2 (en) 2015-04-23 2022-04-05 The Procter And Gamble Company Delivery of surfactant soluble anti-dandruff agent
US11318073B2 (en) 2018-06-29 2022-05-03 The Procter And Gamble Company Low surfactant aerosol antidandruff composition
US11446217B2 (en) 2016-03-03 2022-09-20 The Procter & Gamble Company Aerosol antidandruff composition
US11679065B2 (en) 2020-02-27 2023-06-20 The Procter & Gamble Company Compositions with sulfur having enhanced efficacy and aesthetics
US11679073B2 (en) 2017-06-06 2023-06-20 The Procter & Gamble Company Hair compositions providing improved in-use wet feel
US11771635B2 (en) 2021-05-14 2023-10-03 The Procter & Gamble Company Shampoo composition
US11819474B2 (en) 2020-12-04 2023-11-21 The Procter & Gamble Company Hair care compositions comprising malodor reduction materials
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US11986543B2 (en) 2021-06-01 2024-05-21 The Procter & Gamble Company Rinse-off compositions with a surfactant system that is substantially free of sulfate-based surfactants
US12226505B2 (en) 2018-10-25 2025-02-18 The Procter & Gamble Company Compositions having enhanced deposition of surfactant-soluble anti-dandruff agents

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US6180587B1 (en) * 1999-09-28 2001-01-30 Colgate Palmolive Company Multiple phase compositions
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WO2009016283A3 (fr) * 2007-06-26 2009-08-20 Agence Internationale De L Emb Procede et composition pour colorer les eaux de bassins de bains et/ou de baignades
FR2918068A1 (fr) * 2007-06-26 2009-01-02 Agence Internationale De L Emb Procede et composition pour colorer les eaux de bassins de bains et/ou de baignades.
US11291616B2 (en) 2015-04-23 2022-04-05 The Procter And Gamble Company Delivery of surfactant soluble anti-dandruff agent
US20160310369A1 (en) * 2015-04-23 2016-10-27 The Procter & Gamble Company Low Viscosity Hair Care Composition
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WO2017012738A1 (fr) * 2015-07-20 2017-01-26 Beiersdorf Ag Produits à deux phases miscibles de manière réversible et pouvant être à nouveau dissociés
US11446217B2 (en) 2016-03-03 2022-09-20 The Procter & Gamble Company Aerosol antidandruff composition
US10311575B2 (en) 2016-03-23 2019-06-04 The Procter And Gamble Company Imaging method for determining stray fibers
US11730684B2 (en) 2016-10-19 2023-08-22 Shiseido Company, Ltd. Cleansing composition
EP3530722A1 (fr) * 2016-10-19 2019-08-28 Shiseido Company, Ltd. Composition d'agent nettoyant
EP3530722A4 (fr) * 2016-10-19 2020-06-03 Shiseido Company, Ltd. Composition d'agent nettoyant
US10441519B2 (en) 2016-10-21 2019-10-15 The Procter And Gamble Company Low viscosity hair care composition comprising a branched anionic/linear anionic surfactant mixture
US11202740B2 (en) 2016-10-21 2021-12-21 The Procter And Gamble Company Concentrated shampoo dosage of foam for providing hair care benefits
US10653590B2 (en) 2016-10-21 2020-05-19 The Procter And Gamble Company Concentrated shampoo dosage of foam for providing hair care benefits comprising an anionic/zwitterionic surfactant mixture
US10799434B2 (en) 2016-10-21 2020-10-13 The Procter & Gamble Company Concentrated shampoo dosage of foam for providing hair care benefits
US10842720B2 (en) 2016-10-21 2020-11-24 The Procter And Gamble Company Dosage of foam comprising an anionic/zwitterionic surfactant mixture
US10888505B2 (en) 2016-10-21 2021-01-12 The Procter And Gamble Company Dosage of foam for delivering consumer desired dosage volume, surfactant amount, and scalp health agent amount in an optimal formulation space
US11129783B2 (en) 2016-10-21 2021-09-28 The Procter And Gamble Plaza Stable compact shampoo products with low viscosity and viscosity reducing agent
US11141361B2 (en) 2016-10-21 2021-10-12 The Procter And Gamble Plaza Concentrated shampoo dosage of foam designating hair volume benefits
US11154467B2 (en) 2016-10-21 2021-10-26 The Procter And Gamble Plaza Concentrated shampoo dosage of foam designating hair conditioning benefits
AU2017359156B2 (en) * 2016-11-08 2020-03-19 Colgate-Palmolive Company Oral care compositions
CN109963551A (zh) * 2016-11-08 2019-07-02 高露洁-棕榄公司 口腔护理组合物
WO2018089394A1 (fr) * 2016-11-08 2018-05-17 Colgate-Palmolive Company Compositions de soins bucco-dentaires
US11679073B2 (en) 2017-06-06 2023-06-20 The Procter & Gamble Company Hair compositions providing improved in-use wet feel
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US11116704B2 (en) 2017-10-10 2021-09-14 The Procter And Gamble Company Compact shampoo composition
US10426713B2 (en) 2017-10-10 2019-10-01 The Procter And Gamble Company Method of treating hair or skin with a personal care composition in a foam form
US11116705B2 (en) 2017-10-10 2021-09-14 The Procter And Gamble Company Compact shampoo composition containing sulfate-free surfactants
US11992540B2 (en) 2017-10-10 2024-05-28 The Procter & Gamble Company Sulfate free personal cleansing composition comprising low inorganic salt
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US11607373B2 (en) 2017-10-10 2023-03-21 The Procter & Gamble Company Sulfate free clear personal cleansing composition comprising low inorganic salt
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US10912732B2 (en) 2017-12-20 2021-02-09 The Procter And Gamble Company Clear shampoo composition containing silicone polymers
US11318073B2 (en) 2018-06-29 2022-05-03 The Procter And Gamble Company Low surfactant aerosol antidandruff composition
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US11980679B2 (en) 2019-12-06 2024-05-14 The Procter & Gamble Company Sulfate free composition with enhanced deposition of scalp active
US11679065B2 (en) 2020-02-27 2023-06-20 The Procter & Gamble Company Compositions with sulfur having enhanced efficacy and aesthetics
US11819474B2 (en) 2020-12-04 2023-11-21 The Procter & Gamble Company Hair care compositions comprising malodor reduction materials
US11771635B2 (en) 2021-05-14 2023-10-03 The Procter & Gamble Company Shampoo composition
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