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WO2005095550A1 - Procede de production de combustible pour moteur - Google Patents

Procede de production de combustible pour moteur Download PDF

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Publication number
WO2005095550A1
WO2005095550A1 PCT/RU2005/000137 RU2005000137W WO2005095550A1 WO 2005095550 A1 WO2005095550 A1 WO 2005095550A1 RU 2005000137 W RU2005000137 W RU 2005000137W WO 2005095550 A1 WO2005095550 A1 WO 2005095550A1
Authority
WO
WIPO (PCT)
Prior art keywords
ζδμ
πρi
zsm
φρaκtsii
uglevοdοροdοv
Prior art date
Application number
PCT/RU2005/000137
Other languages
English (en)
Russian (ru)
Inventor
Oleg Vladimirovich Kihtyanin
Gennady Viktorovich Echevsky
Sergei Petrovich Kildyashev
Evgeny Gennadyevich Kodenev
Dmitrii Grigoryevich Aksenov
Oleg Vladimirovich Klimov
Original Assignee
Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdeleniya Rossiiskoi Akademii Nauk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdeleniya Rossiiskoi Akademii Nauk filed Critical Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdeleniya Rossiiskoi Akademii Nauk
Priority to EA200501396A priority Critical patent/EA007773B1/ru
Priority to UAA200512854A priority patent/UA81166C2/uk
Publication of WO2005095550A1 publication Critical patent/WO2005095550A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/88—Ferrosilicates; Ferroaluminosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil

Definitions

  • Diesel fuel is intended for fast diesel engines of land equipment.
  • One of the main operating indicators of diesel fuel is its low-temperature properties, which are used to switch on the power to the engines. Comply with the operating conditions, they distinguish between a few diesel engines:
  • the applied temperature and the temperature of the off-air are higher than 0 ° ⁇ ; - winter, applied temperature and temperature of minus 20 ° ⁇ (with a temperature of setting ⁇ minus 35 ° ⁇ ) or applied temperature and temperature of minus 30 ° ⁇ (with a temperature of minus 45 ° ⁇ );
  • diesel fuel with a high content of oil has a significantly higher stagnation temperature than diesel fuel with a low content of carbohydrate.
  • ⁇ dna ⁇ for mn ⁇ gi ⁇ ⁇ lima ⁇ iches ⁇ i ⁇ ⁇ ay ⁇ n ⁇ v ⁇ azyvae ⁇ sya ne ⁇ b ⁇ dimym is ⁇ lz ⁇ va ⁇ diesel ⁇ liva with improved ⁇ em ⁇ e ⁇ a ⁇ u ⁇ nymi ⁇ a ⁇ a ⁇ e ⁇ is ⁇ i ⁇ ami, ⁇ ye would ⁇ zv ⁇ lyali ⁇ livu ⁇ s ⁇ ava ⁇ sya in zhid ⁇ m s ⁇ s ⁇ yanii ⁇ i ⁇ chen niz ⁇ i ⁇ ⁇ em ⁇ e ⁇ a ⁇ u ⁇ a ⁇ without s ⁇ etsialn ⁇ g ⁇ vneshneg ⁇ ⁇ az ⁇ g ⁇ eva.
  • the main reactions of the conversion of n-paraffins are hydrocracking and hydromerization. Izves ⁇ ny mn ⁇ zhes ⁇ v ⁇ ⁇ tsess ⁇ v ⁇ ev ⁇ ascheniya ⁇ a ⁇ a ⁇ in ⁇ v, ⁇ sn ⁇ vanny ⁇ on gid ⁇ e ⁇ inge n- ⁇ a ⁇ a ⁇ in ⁇ v with is ⁇ lz ⁇ vaniem tse ⁇ li ⁇ ny ⁇ ⁇ a ⁇ aliza ⁇ v, imeyuschi ⁇ ⁇ azme ⁇ ⁇ , ⁇ y ⁇ zv ⁇ lyae ⁇ ⁇ zhdenie n- ⁇ a ⁇ a ⁇ in ⁇ v, n ⁇ ⁇ e ⁇ ya ⁇ s ⁇ vue ⁇ d ⁇ s ⁇ u ⁇ u for ⁇ azve ⁇ vlenny ⁇ ⁇ a ⁇ a ⁇ in ⁇ v, and tsi ⁇ l ⁇ a ⁇ a ⁇ in ⁇ v a ⁇ ma ⁇ iches ⁇ i ⁇ uglev ⁇ d ⁇ d ⁇ v.
  • ⁇ ⁇ sn ⁇ vn ⁇ m for e ⁇ y purpose is ⁇ lzuyu ⁇ tse ⁇ li ⁇ y sleduyuschi ⁇ s ⁇ u ⁇ u ⁇ ny ⁇ ⁇ i ⁇ v: ⁇ 8 ⁇ -5 ⁇ Z ⁇ -11, ⁇ 8 ⁇ -12, ⁇ 8 ⁇ -23, ⁇ 8 ⁇ -35 and ⁇ -38 and ⁇ tsessy, ⁇ sn ⁇ vannye on is ⁇ lz ⁇ vanii e ⁇ i ⁇ tse ⁇ li ⁇ v in ⁇ ev ⁇ aschenii ⁇ a ⁇ a ⁇ in ⁇ v, ⁇ isany in ⁇ yade patents (Pat.
  • ne ⁇ b ⁇ dim ⁇ s ⁇ is ⁇ lz ⁇ vaniya v ⁇ d ⁇ da.
  • the closest to the claimed method of receiving diesel fuel with a low temperature of plugging is the method of receiving the fuel, described in Pa. ⁇ ⁇ ° 2216569, ⁇ 35/095, 11/20/2003.
  • the process of producing gasoline and diesel fuel is supplied at a temperature of 250-500 ° C, the pressure is not more than 2.5 b ⁇ lee 10 hr "1, and in ⁇ aches ⁇ ve ⁇ a ⁇ aliza ⁇ v is ⁇ lzuyu ⁇ tse ⁇ li ⁇ y or alyum ⁇ s ⁇ a ⁇ y tse ⁇ li ⁇ n ⁇ g ⁇ s ⁇ eniya.
  • the task is solved by the process of processing of carbon dioxide of an original diesel fraction em ⁇ e ⁇ a ⁇ u ⁇ y ⁇ i ⁇ eniya not higher than 360 C ⁇ u ⁇ em ⁇ n ⁇ a ⁇ i ⁇ vaniya u ⁇ azann ⁇ y ⁇ a ⁇ tsii with ⁇ ve ⁇ dym ⁇ is ⁇ ym ⁇ a ⁇ aliza ⁇ m, ⁇ edva ⁇ i ⁇ eln ⁇ ⁇ b ⁇ ab ⁇ annym ⁇ as ⁇ v ⁇ m ⁇ ganiches ⁇ y lib ⁇ ne ⁇ ganiches ⁇ y ⁇ isl ⁇ y, ⁇ i ⁇ em ⁇ e ⁇ a ⁇ u ⁇ a ⁇ ⁇ ea ⁇ tsii least 200 ° C and a pressure at 3.0 b ⁇ lee ⁇ Pa, mass ⁇ vy ⁇ ⁇ as ⁇ da ⁇ mixture uglev ⁇ d ⁇ d ⁇ v not b ⁇ lee 20 h "1 .
  • ⁇ ⁇ aches ⁇ ve ⁇ is ⁇ g ⁇ ⁇ a ⁇ aliza ⁇ a is ⁇ lzuyu ⁇ tse ⁇ li ⁇ alyum ⁇ sili ⁇ a ⁇ n ⁇ g ⁇ , gall ⁇ sili ⁇ a ⁇ n ⁇ g ⁇ , gall ⁇ alyum ⁇ sili ⁇ a ⁇ n ⁇ g ⁇ , zhelez ⁇ alyum ⁇ sili ⁇ a ⁇ n ⁇ g ⁇ , ⁇ malyum ⁇ sili ⁇ a ⁇ n ⁇ g ⁇ s ⁇ s ⁇ ava, vyb ⁇ anny of ⁇ yada ⁇ -5, ⁇ 8 ⁇ -11, ⁇ 8 ⁇ -12, ⁇ 8 ⁇ -22, ⁇ -23, ⁇ -35, ⁇ -48 m ⁇ deni ⁇ , ⁇ .
  • ⁇ ⁇ aches ⁇ ve is ⁇ dn ⁇ g ⁇ ma ⁇ e ⁇ iala for ⁇ ig ⁇ vleniya ⁇ a ⁇ aliza ⁇ a is ⁇ lzuyu ⁇ ⁇ din of tse ⁇ li ⁇ v, vyb ⁇ anny of ⁇ yada: alyum ⁇ sili ⁇ a ⁇ y, gall ⁇ sili ⁇ a ⁇ y, gall ⁇ alyum ⁇ sili ⁇ a ⁇ y, zhelez ⁇ alyum ⁇ sili ⁇ a ⁇ y, ⁇ malyum ⁇ sili ⁇ a ⁇ y s ⁇ s ⁇ u ⁇ u ⁇ y ⁇ -5, ⁇ -11, ⁇ 8 ⁇ -12, ⁇ -22, ⁇ -23, ⁇ 8 ⁇ -35 , ⁇ 8 ⁇ -48, morning, ⁇ .
  • the original goal is to process the products of organic or non-organic acids.
  • the obtained catalysts dry and incinerate at temperatures no higher than 600 ° ⁇ .
  • the original material is pre-treated with acid, and additionally it can be processed by metal compounds.
  • the yield of hydrocarbon diesel fraction is 86 wt. %
  • the plant for filling the diesel fraction is minus 55 ° ⁇ .
  • Example 10 After 3 hours after the start of the reaction, the yield of diesel hydrocarbons calculated on the basis of the given raw material was 92 wt. % The plant for filling the diesel fraction is minus 40 ° ⁇ .
  • Example 10 30 g of a powder of alumina silicate is a part of the industrial system ⁇ -35, which is consumed in the presence of a sulphate solution. The sample obtained dries at temperatures of up to 0 ° C, calcines at temperatures of 550 ° C, after which they prepare a fraction of 0.2-0.8 mm.
  • the sample obtained dries at a temperature of up to 0 ° C, an incandescent of 550 ° C, after which a fraction of 0.2-0.8 mm is prepared.
  • the yield of diesel hydrocarbons calculated on the basis of the given raw material was 93 wt. %
  • the plant for filling the diesel fraction is minus 53 ° ⁇ .
  • a comparable method is known to be inconsequential to the fact that diesel is at a low power supply.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

Cette invention concerne un procédé de production de combustible pour moteur, principalement de combustible diesel à faible point de solidification, à partir d'hydrocarbures de fraction diesel, lequel procédé consiste à transformer des hydrocarbures dont la température d'ébullition est comprise entre 160 et 360 °C en présence d'un catalyseur poreux à une température d'au moins 200 °C et une pression n'excédant pas 3 MPa en introduisant ces hydrocarbures de fraction diesel dans un réacteur qui comprend une couche fixe de catalyseur. On utilise comme catalyseur une zéolithe de composition aluminosilicate, galloaluminosilicate, gallosilicate, ferroaluminosilicate ou chromoaluminosilicate sélectionnée parmi ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, ZSM-35, ZSM- 48, mordénite et BETA et préalablement traitée au moyen d'une solution d'acides organiques ou inorganiques. Cette invention permet d'accroître le rendement du combustible diesel.
PCT/RU2005/000137 2004-04-01 2005-03-28 Procede de production de combustible pour moteur WO2005095550A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EA200501396A EA007773B1 (ru) 2004-04-01 2005-03-28 Способ получения моторного топлива
UAA200512854A UA81166C2 (en) 2004-04-01 2005-03-28 Method for motor fuel producing

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2004109994 2004-04-01
RU2004109994/04A RU2261266C1 (ru) 2004-04-01 2004-04-01 Способ получения дизельного топлива

Publications (1)

Publication Number Publication Date
WO2005095550A1 true WO2005095550A1 (fr) 2005-10-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2005/000137 WO2005095550A1 (fr) 2004-04-01 2005-03-28 Procede de production de combustible pour moteur

Country Status (4)

Country Link
EA (1) EA007773B1 (fr)
RU (1) RU2261266C1 (fr)
UA (1) UA81166C2 (fr)
WO (1) WO2005095550A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008014920A2 (fr) * 2006-08-01 2008-02-07 Universidad Politecnica De Valencia Craquage catalytique de composés organiques au moyen de zéolite itq-33

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2681949C1 (ru) * 2018-12-13 2019-03-14 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) Способ приготовления катализатора и способ получения дизельного топлива с использованием этого катализатора

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4229282A (en) * 1979-04-27 1980-10-21 Mobil Oil Corporation Catalytic dewaxing of hydrocarbon oils
US4419220A (en) * 1982-05-18 1983-12-06 Mobil Oil Corporation Catalytic dewaxing process
RU2216569C1 (ru) * 2002-10-30 2003-11-20 Институт катализа им. Г.К.Борескова СО РАН Способ получения моторных топлив (варианты)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4743354A (en) * 1979-10-15 1988-05-10 Union Oil Company Of California Process for producing a product hydrocarbon having a reduced content of normal paraffins
RU2141503C1 (ru) * 1999-04-16 1999-11-20 Кастерин Владимир Николаевич Способ получения низкозастывающих нефтепродуктов

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4229282A (en) * 1979-04-27 1980-10-21 Mobil Oil Corporation Catalytic dewaxing of hydrocarbon oils
US4419220A (en) * 1982-05-18 1983-12-06 Mobil Oil Corporation Catalytic dewaxing process
RU2216569C1 (ru) * 2002-10-30 2003-11-20 Институт катализа им. Г.К.Борескова СО РАН Способ получения моторных топлив (варианты)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008014920A2 (fr) * 2006-08-01 2008-02-07 Universidad Politecnica De Valencia Craquage catalytique de composés organiques au moyen de zéolite itq-33
WO2008014920A3 (fr) * 2006-08-01 2008-04-10 Univ Valencia Politecnica Craquage catalytique de composés organiques au moyen de zéolite itq-33

Also Published As

Publication number Publication date
RU2261266C1 (ru) 2005-09-27
UA81166C2 (en) 2007-12-10
EA007773B1 (ru) 2007-02-27
EA200501396A1 (ru) 2006-04-28

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