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WO2005090667A2 - Procede pour mettre en suspension et introduire des substances solides dans des processus haute pression - Google Patents

Procede pour mettre en suspension et introduire des substances solides dans des processus haute pression Download PDF

Info

Publication number
WO2005090667A2
WO2005090667A2 PCT/DE2005/000491 DE2005000491W WO2005090667A2 WO 2005090667 A2 WO2005090667 A2 WO 2005090667A2 DE 2005000491 W DE2005000491 W DE 2005000491W WO 2005090667 A2 WO2005090667 A2 WO 2005090667A2
Authority
WO
WIPO (PCT)
Prior art keywords
suspension
pressure
pressure process
fluid
solid
Prior art date
Application number
PCT/DE2005/000491
Other languages
German (de)
English (en)
Other versions
WO2005090667A3 (fr
Inventor
Peter NÜNNERICH
Heribert Dierkes
Michael Bork
Original Assignee
Uhde High Pressure Technologies Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uhde High Pressure Technologies Gmbh filed Critical Uhde High Pressure Technologies Gmbh
Priority to DE112005001140T priority Critical patent/DE112005001140A5/de
Priority to CN2005800082551A priority patent/CN101001988B/zh
Priority to PL05735864T priority patent/PL1725706T3/pl
Priority to CA002559316A priority patent/CA2559316A1/fr
Priority to EP05735864A priority patent/EP1725706B1/fr
Priority to US10/593,208 priority patent/US20080034509A1/en
Priority to UAA200610951A priority patent/UA83735C2/ru
Priority to ES05735864T priority patent/ES2386358T3/es
Priority to AT05735864T priority patent/ATE556168T1/de
Priority to KR1020067018903A priority patent/KR101337155B1/ko
Priority to AU2005224953A priority patent/AU2005224953A1/en
Priority to JP2007503189A priority patent/JP4917532B2/ja
Priority to SI200531554T priority patent/SI1725706T1/sl
Publication of WO2005090667A2 publication Critical patent/WO2005090667A2/fr
Publication of WO2005090667A3 publication Critical patent/WO2005090667A3/fr

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/94—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in solvents which are in the supercritical state
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00—Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/20—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
    • D06B23/205—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation for adding or mixing constituents of the treating material
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00—Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/20—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation

Definitions

  • the suspension of the solid is carried out in a completely separated suspension process at low pressure.
  • the solid is suspended in a non-critical and liquefied gas or partially dissolved.
  • the pressure in this suspension process is less than 90% of the critical pressure of the liquefied gas.
  • the entry of the suspension in the high pressure process by means of a pump.
  • DE 199 28 405 is directed to a process for dyeing a textile substrate in at least one supercritical fluid, wherein a dosing is disclosed which divides the required amount of dye for the dyeing dye on a plurality of subsets and each dye subset for so long with the supercritical fluid in contact until it is dissolved or dispersed.
  • the disclosed device provides an oscillating and two-sided piston, which is guided transversely to and through the process line of the critical fluid. This piston absorbs solid in one end position in a first bore, and in the other end position, this first bore is located in the main flow of the critical fluid, so that there the solid is washed out of the bore.
  • a second bore is filled or emptied in reverse order at the other end of the piston.
  • a disadvantage of the method presented in DE 19928405 and the device disclosed for this purpose is that the device must be designed and dimensioned for the same pressures as the main process. Furthermore, supercritical gas is trapped in the emptied and mainstream bore and guided into the filling position, so that either the same or a higher pressure must be present here or a relaxation takes place each time, which hinders the rapid filling process. that would. Another critical factor is certainly driving over a high-pressure seal with the bores guided through the piston. Damage to the sealing material and thus sealing problems are to be expected here after short periods of use. From WO 97/13915 a very common entry method for solids in ü berkritica process is described.
  • the dye is provided in a dye formulation vessel which is located in a bypass to the main process.
  • the corresponding valves are opened and the solids are entrained by means of a partial volume flow of the main process fluid.
  • a constant dosage or targeted control of the dye supply is thus not possible because the fluid-solid mixture is diluted by the inflowing process fluid.
  • all components of this by-pass method must meet the pressure and temperature requirements of the main process.
  • a method optimized in comparison with the suspension method known from WO 97/13915 is described in US Pat. No. 6,261,326. In this method, an agitator is arranged in the dye-selling vessel for dissolving or suspending the solid or pumped by means of a pump, a subset in a circle.
  • this preparation process there is a critical or an almost critical fluid state, since this preparation process from the main process, the treatment process, is supplied with supercritical fluid. As in the above-mentioned methods, this preparation method also suffers from the defect that it has to satisfy the high-pressure conditions of the main process, here called the treatment method. Furthermore, the entry of the solid, which is not shown in US Pat. No. 6,261,326, must take place via an expensive lock, or the solids feed containers must likewise be designed for the high pressure of the treatment process.
  • the object of the invention was therefore to provide a suspension and solids introduction process which operates independently and more economically from the cycle of the high-pressure process than the processes from the prior art.
  • the invention solves the problem by means of a method for suspension and
  • This process represents a suspension stage of the high pressure Process is and is formed of a suspension tank and a device for fluid circulation and supply and discharge lines.
  • the suspension container in a first step is filled with a solid and a fluid, wherein the fluid used is a liquefied gas which is in a non-critical state.
  • the solid is suspended in the fluid by means of a fluid circulation device and kept in suspension.
  • the liquid circulation device is ideally configured as a stirrer or as a pump arranged outside of the suspension container, which is connected via a suction and a pressure line to the suspension container and promotes a subset of the suspension continuously in a circle.
  • the pressure in the suspension stage is advantageously less than 90% of the critical pressure of the gas used and is ideally less than 60 bar.
  • the temperature is adjusted such that a gaseous phase is present above the liquid phase.
  • the suspension is conveyed by means of a pump in the high-pressure process.
  • a pump in the high-pressure process.
  • the fluid used for the suspension is substantially chemically identical to the process medium of the high pressure process.
  • the fluid is mixed with other substances.
  • substances are, for example, cyclic and short-chain acyclic hydrocarbons or short-chain alcohols, aldehydes or ketones, and H 2 O and mixtures of these aforementioned substances.
  • the pressure in the suspension vessel during the introduction of the suspension in the high-pressure process is kept constant in the inventive method by gas is nachge devist in gaseous state.
  • the volume flow and thus the concentration of the solid in the fluid in a constant size or variable over the conveyor - power of the pump can be adjusted.
  • the concentration in the suspension tank is substantially constant during the emptying, since the nachge deviste gas is not liquid, but is gaseous.
  • the solid is a substance to be dissolved in the high-pressure process, such as, for example, dye particles, adhesion promoters, bleaching agents, flavors, odorous substances or mixtures thereof.
  • an advantage of the invention is the fact that the solid is not dissolved as in the prior art, but only suspended and the specific solubility of the respective starting materials need not be met in the suspension stage. Rather, these substances dissolve in the introduction into the large volume flow of the main process due to the high concentration gradient directly.
  • an advantageous embodiment of the invention is that the suspension stream is set at the initiation into the high-pressure process such that the ratio of the volume flows of suspension to Hochlichreamedi- to smaller than 1:50 and ideally equal to or less than 1: 100.
  • the very low suspension flow in relation to the main process volume flow has a negligible physical influence on the main process as a rule.
  • Fig. 1 shows the suspension process with a pump as wellsstechniksum stiilzaggregat and Figure 2 shows the method with a stirrer without external Ummélznikank.
  • the suspension process 1 which is connected via the conduction path 6 with the high-pressure process 4, consisting essentially of the suspension vessel 2 and the pump 3 is formed.
  • the suspension vessel 2 is filled via the conduit 7 with liquefied gas and via the conduit 8 with the solid.
  • a liquid volume 2 a and a gas volume 2 b form in the suspension container 2.
  • a further embodiment of the method can be seen, wherein in the suspension vessel 2, a stirrer 13 is arranged, by means of which the suspension is generated and kept stable.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Pipeline Systems (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Processing Of Solid Wastes (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)

Abstract

La présente invention concerne un procédé pour mettre en suspension et introduire une substance solide dans un processus haute pression, par exemple des pigments colorés dans un processus haute pression dans lequel un liquide surcritique est utilisé comme substance de processus et une pression de plus de 150 bar règne. Selon l'invention, la mise en suspension de la substance solide est réalisée à basse pression au moyen d'un procédé de mise en suspension complètement séparé. Dans le cadre de ce procédé de mise en suspension, la substance solide est mise en suspension ou partiellement dissoute dans un gaz non critique liquéfié. La pression au cours de la mise en oeuvre de ce procédé vaut moins de 90 % de la pression critique du gaz liquéfié. L'introduction de la suspension dans le processus haute pression s'effectue au moyen d'une pompe.
PCT/DE2005/000491 2004-03-17 2005-03-16 Procede pour mettre en suspension et introduire des substances solides dans des processus haute pression WO2005090667A2 (fr)

Priority Applications (13)

Application Number Priority Date Filing Date Title
DE112005001140T DE112005001140A5 (de) 2004-03-17 2005-03-16 Verfahren zur Suspendierung und Einspeisung von Feststoffen in einen Hochdruckprozess
CN2005800082551A CN101001988B (zh) 2004-03-17 2005-03-16 固体物质悬浮和引入高压工艺中的方法
PL05735864T PL1725706T3 (pl) 2004-03-17 2005-03-16 Sposób przeprowadzania w zawiesinę i wprowadzania substancji stałych do procesu wysokociśnieniowego
CA002559316A CA2559316A1 (fr) 2004-03-17 2005-03-16 Procede pour mettre en suspension et introduire des substances solides dans des processus haute pression
EP05735864A EP1725706B1 (fr) 2004-03-17 2005-03-16 Procede pour mettre en suspension et introduire des substances solides dans des processus haute pression
US10/593,208 US20080034509A1 (en) 2004-03-17 2005-03-16 Method for Suspending and Introducing Solid Matter in a High-Pressure Process
UAA200610951A UA83735C2 (ru) 2004-03-17 2005-03-16 Способ суспендирования и введения твердых веществ в процесс высокого давления
ES05735864T ES2386358T3 (es) 2004-03-17 2005-03-16 Procedimiento para la suspensión e introducción de sustancias sólidas en un proceso de alta presión
AT05735864T ATE556168T1 (de) 2004-03-17 2005-03-16 Verfahren zur suspendierung und einspeisung von feststoffen in einen hochdruckprozess
KR1020067018903A KR101337155B1 (ko) 2004-03-17 2005-03-16 고압 공정에서 고형물을 부유시키고 주입하는 방법
AU2005224953A AU2005224953A1 (en) 2004-03-17 2005-03-16 Method for suspending and introducing solid matter in a high-pressure process
JP2007503189A JP4917532B2 (ja) 2004-03-17 2005-03-16 高圧プロセスに固体物質を懸濁および配量する方法
SI200531554T SI1725706T1 (sl) 2004-03-17 2005-03-16 Postopek za odmerjanje in vpeljevanje trdne snovi v visokotlaäśni postopek

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004013338.7 2004-03-17
DE102004013338A DE102004013338A1 (de) 2004-03-17 2004-03-17 Verfahren zur Suspendierung und Einspeisung von Feststoffen in einen Hochdruckprozeß

Publications (2)

Publication Number Publication Date
WO2005090667A2 true WO2005090667A2 (fr) 2005-09-29
WO2005090667A3 WO2005090667A3 (fr) 2005-11-24

Family

ID=34972410

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2005/000491 WO2005090667A2 (fr) 2004-03-17 2005-03-16 Procede pour mettre en suspension et introduire des substances solides dans des processus haute pression

Country Status (18)

Country Link
US (1) US20080034509A1 (fr)
EP (1) EP1725706B1 (fr)
JP (1) JP4917532B2 (fr)
KR (1) KR101337155B1 (fr)
CN (1) CN101001988B (fr)
AT (1) ATE556168T1 (fr)
AU (1) AU2005224953A1 (fr)
CA (1) CA2559316A1 (fr)
DE (2) DE102004013338A1 (fr)
ES (1) ES2386358T3 (fr)
MA (1) MA28511B1 (fr)
PL (1) PL1725706T3 (fr)
PT (1) PT1725706E (fr)
RU (1) RU2353722C2 (fr)
SI (1) SI1725706T1 (fr)
UA (1) UA83735C2 (fr)
WO (1) WO2005090667A2 (fr)
ZA (1) ZA200607729B (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004013338A1 (de) 2004-03-17 2005-10-06 Uhde High Pressure Technologies Gmbh Verfahren zur Suspendierung und Einspeisung von Feststoffen in einen Hochdruckprozeß
CN104032603A (zh) * 2014-05-16 2014-09-10 江苏美罗家用纺织品有限公司 无水低能耗新型染色工艺
US11291931B2 (en) 2014-12-15 2022-04-05 Akadeum Life Sciences, Inc. Method and system for buoyant separation
DE102018222882A1 (de) 2017-12-22 2019-06-27 Thyssenkrupp Ag Vorrichtung und Verfahren zum kontinuierlichen Hochdruckbehandeln von Schüttgut durch Extrahieren und/oder Imprägnieren sowie Verwendung
JP7189314B2 (ja) 2018-07-09 2022-12-13 アカデューム ライフ サイエンセズ，インコーポレイテッド 浮遊性粒子を処理するシステムおよび方法
EP4392158A1 (fr) 2021-08-26 2024-07-03 Akadeum Life Sciences, Inc. Procédé et système pour séparation flottante
WO2023191984A1 (fr) 2022-04-01 2023-10-05 Akadeum Life Sciences, Inc. Procédé et système de thérapie cellulaire assistée par particules flottantes
WO2024173590A1 (fr) 2023-02-14 2024-08-22 Akadeum Life Sciences, Inc. Procédé et système de séparation assistée par flottabilité partiellement ou entièrement automatisée

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997013915A1 (fr) 1995-10-06 1997-04-17 Amann & Söhne Gmbh & Co. Procede de teinture d'un substrat textile
DE19928405A1 (de) 1999-06-22 2000-12-28 Amann & Soehne Verfahren zum Färben eines textilen Substrates in mindestens einem überkritischen Fluid sowie Färbevorrichtung
US6261326B1 (en) 2000-01-13 2001-07-17 North Carolina State University Method for introducing dyes and other chemicals into a textile treatment system

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3608742A1 (de) * 1986-03-15 1987-09-17 Mtm Obermaier Gmbh & Co Kg Verfahren zum faerben von tier-, pflanzen- oder kunststoffasern
IT1197070B (it) * 1986-08-06 1988-11-25 Foscama Biomed Chim Farma Procedimento ed impianto per la produzione in continuo di fruttosio-1,6-difosfato mediante utilizzazione di lievito di birra immobilizzato
US5308648A (en) * 1992-09-30 1994-05-03 Union Carbide Chemicals & Plastics Technology Corporation Spray application of plastics additives to polymers
CZ287481B6 (en) * 1995-10-16 2000-12-13 Krupp Uhde Gmbh Dyeing process of textile substrates with above critical liquid and apparatus for making the same
SE517099E (sv) * 1996-04-17 2004-07-13 Kvaerner Pulping Tech System innefattande två pumpar för matning av en sspension till ett tryckkärl
US5938794A (en) * 1996-12-04 1999-08-17 Amann & Sohne Gmbh & Co. Method for the dyeing of yarn from a supercritical fluid
JPH10192670A (ja) * 1996-12-27 1998-07-28 Inoue Seisakusho:Kk 超臨界状態を用いた分散方法及び分散装置
US6039470A (en) * 1997-03-24 2000-03-21 Conwell; Allyn B. Particulate mixing system
JP3645417B2 (ja) * 1998-04-08 2005-05-11 三菱化学株式会社 液体の移送方法
US6621326B1 (en) * 2000-10-26 2003-09-16 Altera Corporation P-channel negative pumps
DE102004013338A1 (de) 2004-03-17 2005-10-06 Uhde High Pressure Technologies Gmbh Verfahren zur Suspendierung und Einspeisung von Feststoffen in einen Hochdruckprozeß

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997013915A1 (fr) 1995-10-06 1997-04-17 Amann & Söhne Gmbh & Co. Procede de teinture d'un substrat textile
DE19928405A1 (de) 1999-06-22 2000-12-28 Amann & Soehne Verfahren zum Färben eines textilen Substrates in mindestens einem überkritischen Fluid sowie Färbevorrichtung
US6261326B1 (en) 2000-01-13 2001-07-17 North Carolina State University Method for introducing dyes and other chemicals into a textile treatment system

Also Published As

Publication number Publication date
JP2007529692A (ja) 2007-10-25
EP1725706B1 (fr) 2012-05-02
KR20070005623A (ko) 2007-01-10
CN101001988A (zh) 2007-07-18
WO2005090667A3 (fr) 2005-11-24
DE112005001140A5 (de) 2007-05-24
AU2005224953A1 (en) 2005-09-29
UA83735C2 (ru) 2008-08-11
RU2353722C2 (ru) 2009-04-27
CN101001988B (zh) 2010-05-26
KR101337155B1 (ko) 2013-12-05
DE102004013338A1 (de) 2005-10-06
ZA200607729B (en) 2008-06-25
MA28511B1 (fr) 2007-04-03
JP4917532B2 (ja) 2012-04-18
ES2386358T3 (es) 2012-08-17
PT1725706E (pt) 2012-07-23
ATE556168T1 (de) 2012-05-15
CA2559316A1 (fr) 2005-09-29
SI1725706T1 (sl) 2012-10-30
RU2006136418A (ru) 2008-04-27
PL1725706T3 (pl) 2012-10-31
US20080034509A1 (en) 2008-02-14
EP1725706A2 (fr) 2006-11-29

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