CROSSFLOW FILTRATION SYSTEM AND METHOD FOR MEMBRANE FOULING PREVENTION
BACKGROUND OF THE INVENTION
fθtHKE} (ϊ) Field of the Invention
002} The present invention relates to filtration of fluids, in particular,
to filtration of fluids via se ipermeabϊe membranes.
rø3} (2) Background of fee Invention
{0004J For purification of fluids, in particular, in water treatment, in
natural water treatment, in industrial and agricultural wastewater
treatment, there are widely used various meambranes. Fluid filtration
through a membrane is perforemed on "cross and flow" principle. That is,
the stream delivered by a pressure pump moves parallel with the
membrane. Part of this stream passes through the membrane. This is the
purufied fluid. The remaining part of this stream carrying impurities and
named concentrate further moves parallel with the membrane and leaves
its surface. There are known membranes for various purposes. In
particular;, membranes for removing suspended particles and large
colloids while macromolecules and dissolved solids pass through them -
this technology is named mϊcrofiltration (MF) and membranes for
macromolecular separation while dissolved salts and small molecules
pass through them, this technology is named ultrafiltratϊon (UF), and the
membranes themselves - respectively MF-membranes or UF-membranes
(see U.S. Pats. 6,197,203 and 5,132,015 or EP 0479492 AI). There are
further known membranes for removing from a fluid all dissolved salts
and inorganic molecules as well as organic molecules. Water molecules
pass f eely through them. This technology is called reverse osmosis (RO)
and membranes - RO-membranes, (see U.S. Pats. 6,604,914; 5,132,017;
5,131,277; 5,122,265; 5,096,574; and 4,814,086).
fββθSj Fluid filtration through a membrane is not perfect, as the
membranes themselves are fouled during operation both by mechanical
impurities, and by salts by deposition of foreign matter on the membrane
surface. As a result, the membrane capacity is reduced, the pressure at the
inlet to the membrane increases and the permeate quality deteriorates.
Unless measures are taken in time to clean the membrane, it is heavily
fouled or scaled and may be damaged by fluid pressure.
fOO J Measures conventionally taken for prevention of membrane
fouling or for cleaning membranes already fouled are expensive and, as a
rule, not sufficient enough. Among these we find, for example,
preliminary water treatment (see U.S. Pat. 5,034,121), which require high
capital outlays in combination with high operating costs, that is,
corresponding plants, chemicals, reagents, etc. are needed. To prevent
membrane fouling by salts or substances forming deposits or films on the
membrane surface, special expensive chemical or biological substances
are added to a filtered fluid (see U.S. Pat. Appl. 2002/0036168 Al, U.S.
Pats. 4,921,610 and 5,403,479), which cannot fully eliminate membrane
fouling and compensate their capacity reduction. Therefore, when the
membrane capacity is reduced and pressure at its inlet increases, the
membrane is washed directly on the spot of its location by chemical
solutions or blown through by gas (see U.S. Pats. 4,207,183 and
6,641,733). This process is named **CIP cleaning in place". Such methods
of membrane cleaning also cause an increase in additional costs and
creation of aggressive waterwastes. Besides, all these methods are often
not efficient enough or efficient only for a short period of time. As a
result, it is necessary to replace the used membranes by new ones,
\ W1] The main cause of foulant deposition on the membrane surface is
the inadequate turbulance of a fluid stream passing through the membrane
module due to design peculiarities of fee filtering membrane element. A
conventional diagram of a device for fluid filtration is shown in FIG. 1.
Device 1 includes a pressure pump 2, membrane module 4 wife ports : 6
- for feed entrance (F), 8 - for exit of concentrate (C) and 10 - for exit of
the permeate (P). Besides devices are known (FIG. 2) comprising a
pressure pump 2, membrane module 4 with ports: 6 -for entrance of feed
(F), 8 - for exit of concentrate (C ) and 10 - for exit of permeate (P). Part
of the concentrate stream returns to the inlet 6 of membrane module 4 to
increase the stream velocity within the membrane, which allows to slow
its fouling (see U.S. Pat. 4,961,851). There are also known devices
(FIG.3) having means for changing from time to time the direction of the
feed stream passing through membrane module 4 - in this case, valve 12,
which allows to reduce the membrane fouling (U.S. Pat. 5,690,829). At
last, there are known devices for cleaning membrane modules using
methods for vibration or ultrasonic cleaning (see U.S. Pat. 5,919,376).
{0008} A disadvantage of aforesaid devices and methods is quick
membrane fouling which causes its capacity reduction, deterioration of
permeate quality and, finally, membrane failure. Besides, the return of
part of the concentrate to membrane inlet (recirculation) requires an
increase of pressure pumps capacity, causes an increased concentration of
impurities at the membrane inlet which also increases the membrane
loading. Other methods, such as vibration or based on electric effects are
complicated, expensive and of low efficiency. Besides, they require fee
use of special membranes (see U.S. Pat. Appl. 2003 0155314, U.S. Pats.
6,241,485; 5,985,160 and 4,830,642).
{0009} (3) Description of the Prior Art
pβlO] Closest to the claimed object are devices and methods disclosed
in US Pat. 6,168,714; 6,423,230; 6,322,698 and U.S. patent application
2001/0000895.
OIII Rios, Luis et al. in U.S. Pat. 6,322,698 describe a vibratory
separation system having a drive mechanism for imparting a vibratory
motion to a membrane module to enhance filtration. The membrane
module comprises one or more filter elements secured to one another,
each having a permeable membrane. The vibratory motion imparted to
the membrane module generates a dynamic flow boundary layer at the
permeable membranes. This fluid shear boundary layer, in turn, generates
lift, thereby inhibiting fouling of the membranes.
{00I2J Aforesaid vibration system has some disadvantages: it is
complicated, expensive and is of low capacity. Besides, it also requires
the use of special membranes.
P013J Ilias, Shamsuddin et al. in U.S. Pats. 6,168,714; 6,423,230 and
U.S. Pat. Appl. 2001 0000895 describe a filtration system for a cross-
flow membrane filter which reduces the deleterious effects of
concentration polarization and membrane fouling, thereby increasing the
average transmembrane flux. The filtration system includes a feed supply
for providing a feed solution; a feed pump connected to the feed supply; a
cross-flow membrane filter connected downstream of the feed pump for
separating the feed into a permeate and a reteπtate, the cross-flow
membrane filter including at least two membrane ports and at least two
permeable outlets; a valve manifold assembly located between fee feed
pump and fee cross-flow membrane filter; and a control system for
controlling fee valve manifold to selectively reverse fee flow of fee feed
ferough the cross-flow membrane filter. Periodic reversal of the direction
of Sow of the feed stream in the membrane module, while mamtaining
the cross-flow, keeps the system in a hydrodynamically transient state
and prevents the formation of an undesirable stable boundary layer at fee
membrane surface thereby increasing fee average transmembrane flux.
{0014} A disadvantage of aforesaid device is that fee returnn of part of
the concentrate to fee membrane inlet (recirculation) requires an increase
m capacity of pressure pumps, causes increased concentration of
impurities at the membrane inlet, which also increases membrane
loading. This may finally result in reduction of membrane capacity and its
failure.
{0015} An object of the present invention is the prolongation of
membrane life by reducing the level of their fouling salination and an
increase in membrane capacity, and increasing thereby the life of the
whole filtering equipment.
{0016} Another object of the invention is a reduction of quantity of
energy and chemical substances added during the filtration process,
reduction in bacterial fouling of membranes.
{0017} Still another object of the invention is reducing the quantity of
aggressive wastes generated in fee process of filtration and enhancing the
effect of fluid demineralization.
SUMMARY OF THE INVENTION
{0018} The subject matter of the present invention is a crossflow
filtration system for prevention of foulng of the membrane surface. The
system comprises a pipe-line for feeding a fluid to be cleaned, a pressure
pump connected via a hydraulic line with fee pipe-line for feeding the
fluid to be cleaned. The system also comprises a membrane module
having an inlet connected via a pressure line wife fee pressure pump, and
two exits, the first whereof serves for removing cleaned fluid, and fee
second - for removing waste concentrate. This membrane module serves
for separating a feed stream into a fluid and concentrate containing
impurities. Besides, the system includes a pipe-line for cleaned fluid
connected with fee first exit of fee membrane module, as well as a pipe¬
line for removing waste concentrate connected with fee second exit of
this membrane module. At last, the system contains means for applying
an additional reciprocal fluid pulse to the fluid passing through the
membrane module, and pipe-lines connecting said means wife this
membrane module.
{0019} Besides aforesaid devices, the suggested system for membrane
fouling prevention is provided wife a control system controlling the
operation of the pressure pump, membrane module, means for applying
an additional reciprocal fluid pulse to fee fluid passing through fee
membrane module. This control system contains at least one
microprocessor or at least one controller.
{0020} Means for applying an additional reciprocal fluid pulse to fee
fluid passing ttøougfr the membrane may contain pressure pumps. These
may be gear-type, diaphragm, lobe or piston pumps. Each of these pumps
has an individual actuator. All pump actuators are connected wife the
control system.
{0021} In another embodiment of the suggested system means for
applying an additional reciprocal fluid pulse to fee fluid passing through
the membrane module may contain diaphragm cylinders, piston type
thrust cylinders or hydraulic cushions. Each of these diaphragm
cylinders, piston type thrust cylinders or hydraulic cushions has an
individual actuator. AH actuators of these diaphragm cylinders, piston
type thrust cylinders or hydraulic cushions are associated with fee
control system.
{0022} In still another embodiment of fee suggested system means for
applying an additional reciprocal fluid pulse to the fluid passing through
fee membrane module may contain hydraulic cylinders, in particular,
three hydraulic cylinders, the one whereof is connected with fee first exit
of the membrane module, fee second — with the second exit of the
membrane module, and the third - with the inlet of this membrane
module and with fee pressure line. AH these hydraulic cylinders may be
connected together to form a single unit. Each of the hydrualic cylinders
is provided with an individual actuator. AH actuators of the hydraulic
cylinders are associated with said control system.
{0023} And in the last embodiment of fee suggested system at least one
of the means for applying an additional reciprocal fluid pulse to the fluid
passing through the membrane module, is provided with an individual
actuator and a hydraulic control device, having an autonomous actuator,
is connected wife the input and one of the outputs of the membrane
module or with both outputs of this membrane module. This means
actuator and an autonomous actuator of the hydraulic control device are
connected wife fee contol system.
{0024} Another subject matter of the invention is a method for membrane
fouling prevention by applying an additional reciprocal fluid pulse to fee
fluid passing through the membrane via corresponding means,
substantially pressure pumps, diaphragm cylinders, piston type thrust
cylinders, hydraulic cushions or hydraulic cylinders, each of them
provided with an individual actuator associated wife fee control system.
This method comprises fee following steps: i) applying an additional
reciprocal fluid pulse to the fluid fed into fee membrane module through
fee inlet; li) applying an additional reciprocal fluid pulse to the fluid
removed from the membrane module through fee first exit; iii) applying
an additional reciprocal fluid pulse to the fluid removed from the
membrane module through the second exit and, finally, iv) repeating
steps (I), (Li), pii) in certain succession and combination until the
oscillations of fluid stream through the membrane reach the desired level.
Thereby, feere ϊs generated in the membrane module a controlled fluid
motion in all directions which prevents membrane fouling and formation
of a boundary concentrate layer on said membrane surface.
{0025} In performing fee suggested mefeod, pressure pumps, diaphragm
cylinders, piston type thrust cylinders, hydraulic cushions or hydraulic
cylinders can operate in antiphase. In this case, pressure pumps,
diaphragm cylinders, piston type thrust cylinders, hydraulic cushions or
hydraulic cylinders can generate a hydraulic wave in the fluid passing
through the membrane module.
{©026} In performing the suggested mefeod fee control system can
change the direction and velocity of streams at fee exits of pressure
pumps, diaphragm cylinders, piston type thrust cylinders, hydraulic
cushions or hydraulic cylinders. Besides, the control system can change
mutual relation of fluid streams at the exits of pressure pumps, diaphragm
cylinders, piston type thrust cylinders, hydraulic cushions or hydraulic
cylinders as to fee value, direction of these streams or their phase.
Besides, ϊt is possible to generate a mode in which only one or two
pressure pumps, diaphragm cylinders, piston type thrust cylinders,
hydraulic cushions or hydraulic cylinders can operate simultaneously.
BRIEF DESCRIPTION OF THE DRAWINGS
{0027} The invention will now be described in conjunction with the
following drawings in which like reference numerals designate like
elements and wherein:
{0028} FIG. 1 - 3 show schematic diagrams of known devices for
cleaning of fluids ( Prior Art);
{0029} FIG. 4 shows a schematic diagram of fee suggested system using
pressure pumps for applying an additional fluid pulse to fee fluid;
{0030} FIG. 5 shows a schematic diagram of the suggested system using
hydraulic cylinders for applying an additional fluid pulse to the fluid;
{0031} FIG. 6 shows a schematic diagram of the suggested system using
diaphragm cylinders for applying an additional fluid pulse to the fluid;
{0032} FIG. 7 shows a schematic diagram of fee suggested system using
hydraulic cushions for applying an additional fluid pulse to the fluid.
{0033} FIG, 8 shows a schematic diagram of the suggested system using
means for applying an additional reciprocal fluid pulse, which is provided
wife an individual actuator and a hydraulic control device with an
autonomous actuator
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
{0034} The preferred embodiments of the present invention are described
below. The inventors of fee present subject matter contemplate feat the
embodiments described herein are capable of use in the repair of other
vessels and in other procedures. Thus, it is intended feat the present
invention cover the modifications and variations of the invention,
provided they come within fee scope of the appended claims and their
equivalents.
{0035} The most preferred embodiment of an apparatus, according to the
present invention, are shown in drawing figures 4-8.
{0036} The suggested system 20 for preventing the fouling of a
membrane surface (FIG. 4) comprises a pipe-line 22 for feeding a fluid
to be cleaned, as well as a pressure pump 24 associated via a hydraulic
line wife pipe-line 22 for feeding a fluid to be cleaned and a membrane
26 enclosed in a body - membrane module 28. Membrane module 28
has an inlet 30 connected via a pressure hydraulic line 32 with pump 24,
as well as two exits, 34 and 36 respectively, fee first whereof, 34 serves
for removing the cleaned fluid, and fee second, 36 - for removing the
concentrate. Membrane 26 serves for the separation of feed into pure
fluid and concentrate containing impurities. Besides, system 20 includes a
pϊpe-Iine 38 for cleaned fluid connected wife the first exit 34 of
membrane module 28, as well as a pipe-line 40 for removing the
concentrate connected with the second exit 36 of membrane module 28.
{0037} At last, system 20 comprises means for applying a reciprocal
fluid pulse to the fluid passing through membrane 26 containing pressure
pumps, diaphragm cylinders, piston type thrust cylinders, hydraulic
cushions or hydraulic cylinders, as well as pipe-lines connecting said
means with membrane module 28.
{0038} In fee first embodiment of suggested system 20 means for
applying an additional reciprocal fluid pulse to the fluid passing through
membrane 26 located in membrane module 28 contain pressure pumps,
42, 44, 46 respectively (FΪG.4). There may be gear-type, diaphragm, lobe
or piston pumps. Each of these pumps is provided with an individual
actuator, 48, 50 and 52 respectively. All actuators 48, 50 and 52 of pumps
42, 44, 46 are associated with fee control system controlling fee operation
of pump 24, membrane 26 and membrane module 28, means for applying
an additional reciprocal fluid pulse to fee fluid passing through the
membrane, in this embodiment - 42, 44, 46. This control system contains
at least one microprocessor 54 (FIG, 4) or at least one controller 56 (FIG.
5).
{0039} In the second embodiment of suggested system 20 (FIG.5) means
for applying an additional reciprocal fluid pulse to the fluid passing
through membrane 26 contain hydraulic cylinders, in particular, three
hydraulic cylinders 66, 68, 70, one whereof 68 is connected with the first
exit 34 of membrane module 28, the second 70 — with the second exit 36
of membrane module 28, and fee third 66 - with inlet 30 of membrane
module 28 and with pressure line 32. AH these hydraulic cylinders 66, 68
and 70 may be connected together to form a single unit. Each of hydraulic
cylinders 66, 68 and 70 has an individual actuator, 72, 74 and 76
respectively. AH actuators 72, 74 and 76 of hydraulic cylinders 66, 68,
and 70 are associated wife said control system 54 (56).
{0040} In the third embodiment of suggested system 20 (FΪG.6) means
for applying an additional reciprocal fluid pulse to fee fluid passing
through membrane 26 contain diaphragm cylinders, in particular, three
diaphragm cylinders 78, 80, 82, one whereof 80 is connected wife the
first exit 34 of membrane module 28, the second 82 - with the second
exit 36 of membrane module 28, and the third 78 - with inlet 30 of
membrane module 28 and with pressure line 32, AH these diaphragm
cylinders 78, 80 and 82 may be connected together to form a single unit.
Each of diaphragm cylinders 78, 80 and 82 is provided with an individual
actuator, 84, 86 and 88 respectively. AH actuators 84, 86 and 88 of
diaphragm cylinders 78, 80 and 82 are associated with said control
system 54 (56).
{0041} In fee fourth embodiment of suggested system 20 (FIG.7) means
for applying an additional reciprocal fluid pulse to fee fluid passing
through membrane 26 contain hydraulic cushions (or piston type thrust
cylinders), in particular, three hydraulic cushions (or piston type thrust
cylinders) 90, 92, 94, one whereof, 92 is connected with the first exit 34
of membrane module 28, the second 94 - with fee second exit 36 of
membrane module 28, and the third, 90 - with inlet 30 of membrane
module 28 and wife pressure line 32. AH these hydraulic cushions (or
piston type thrust cylinders) 90, 92 and 94 may be connected together to
form a single unit. Each of hydraulic cushions (or piston type thrust
cylinders) 90, 92 and 94 is provided wife an individual actuator, 96, 98
and 100 respectively. AH actuators 96, 98 and 100 of hydrauKc cushions
90, 92, 94 are associated wife said control system 54 (56).
{0042} And in the last embodiment of suggested system 20 (FIG. 8), the
means for applying an additional reciprocal fluid pulse to fee fluid
passing through membrane 26 located in membrane module 28 contain
pressure pumps, 102, 104, 106, 108 respectively (FIG.8). These may be
gear-type, diaphragm, lobe or piston pumps. Each of these pumps Is
provided wife an individual actuator, 110, 112, 114 and 116 respectively.
The pressure pump 108 has an individual actuator 116 and an individual
hydraulic control device 118 with an autonomous actuator 120. AH
actuators 110, 112, 114 and 116 of pumps 102, 104, 106, 108 as well as
an individual hydraulic control device 118 with its autonomous actuator
120, are associated with fee control system 54 (56) controlling the
operation of pump 24, membrane 26 and membrane module 28, means
for applying an additional reciprocal fluid pulse to fee fluid passing
through fee membrane, in this embodiment - pumps 102, 104, 106, 108.
This control system contains at least one microprocessor 54 (FIG. 8) or
at least one controller 56.
{0043} Suggested system 20 operates in accordance wife fee suggested
mefeod for membrane 26 fouling prevention.
{0044} The conventional system of fluid cleaning operates in a standard
mode by delivering fluid via pressure pump 2 (FIG. 1 - 3) or 24 (FIG. 4 -
8) to membrane 4 or 26. Then the fluid feat has been cleaned is removed
through a corrresponding exit, 10 or 34 of membrane module 28, and the
fouled eca centrate - through another exit of membrane module 28, 8 or
36 respectively.
{0045} According to the suggested method, the claimed system for
membrane 26 fouling prevention (FIG. 4 - 8) acts on fee fluid to be
cleaned by applying thereto an additional reciprocal fluid pulse via
corresponding means, substantially pressure pumps 42, 44, 46, 102, 104,
106, 108 hydraulic cylinders, 66, 68, 70 respectively. The same occurs
when diaphragm cylinders 78, 80, 82, as well as hydraulic cushions 90,
92, 94 or piston type thrust cylinders are used. The method comprises the
following steps: ϊ) applying an additional reciprocal fluid pulse to the
fluid fed to membrane module 28 through inlet 30; H) applying an
additional reciprocal fluid pulse to the fluid removed from membrane
module 28 through first exit 34; Hi) applying an additional reciprocal
fluid pulse to the fluid removed from membrame module 28 through
second exit 36, and, at last, iv) repeating steps (i), (ϋ), (in) in certain
succession and predetermined combination until oscillations of fluid
stream through membrane 26 reach fee desired level and fee control
system - microprocessor 54 or central controller 56 issue a corresponding
signal (FIG. 4 - 8). Thereby, in membrane module 28 there is excited a
controlled reciprocal movement of fluid through membrane 26 in aH
directions, which prevents its fouling and, in particular, prevents the
formation of a boundary concentrate layer on the surface of membrane
26.
{0046} In performing the suggested mefeod, pressure pumps 42, 44, 46 ,
hydraulic cylinders 66, 68, 70, diaphragm cylinders 78, 80, 82 or
hydraulic cushions (or piston type thrust cylinders) 90, 92, 94 can operate
in antiphase. In this case, pressure pumps 42, 44, 46, hydraulic cylinders
66, 68, 70, diaphragm cylmders 78, 80, 82 or hydraulic cushions (piston
type thrust cylinders) 90, 92, 94 may excite a hydraulic wave in the
liquid passing through membrane 26.
{0047} In performing the suggested method, the hydraulic control device
118 changes fee direction and velocity of stream, its value and pressure. In this case, the additional pressure pump 108 can create an additional
fluid stream, which changes its value and direction and is imposed on the
basic fluid stream in membrane module 28, changing its direction and
value and so applying an additional reciprocal fluid pulse to the fluid fed
to the membrane module 26. The additional pressure pump 108 with a
hydraulic control device 118 Is controlled by actuators 116, 120 and
control system 54 (56) together or separate of the basic pump 24 and
other pumps 102, 104, 106 in definite consecutivϊty and in definite
predesigned pulse combination.
{0048} In performing fee suggested method, the control system -
microprocessor 54 or controller 56 can change the direction and velocity
of streams at fee outlets of pumps 42, 44, 46, 102, 104, 106, 108
hydraulic cylinders 66, 68, 70, diaphreagπi cylinders 78, 80, 82 or
hydraulic cushions (piston type thrust cylinders) 90, 92, 94. Besides, the
control system can change the mutual relation of fluid streams at the
outlets of pumps 42, 44, 46, 102, 104, 106, 108 hydraulic cylinders 66,
68, 70, diaphragm cylinders 78, 80, 82 or hydraulic cushions (piston type
thrust cylinders) 90, 92, 94 as to fee value, direction of these streams or
their phase.
{0049} Application of system 1, as well as performing, on fee basis of
this system, new and improved method of membrane 26 fouling
prevention allows to solve fee problem of increasing fee life of
membranes 26 and their capacity. Besides, it increases fee life of filtering
equipment and reduces capital outlays for this equipment.
Simultaneously, there is reduced fee quantity of aggressive wastes
generated in fluid filtration process. At last, It reduces fee consumption of
energy and chemical substances in the process of fluid filtration.
{0050} While this invention has been described in conjunction with
specific embodiment thereof, it is evident that many alternatives,
modifications and variations will be apparent to those skHIed in fee art.
Accordingly, the preferred embodiments of the invention as set forth
herein are intended to be illustrative, not limiting. Various changes may
be made without departing from fee spirit and scope of the invention as
defined in the following claims.