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WO2005081327A1 - Dispositif luminescent et procede de fabrication - Google Patents

Dispositif luminescent et procede de fabrication Download PDF

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Publication number
WO2005081327A1
WO2005081327A1 PCT/CN2005/000212 CN2005000212W WO2005081327A1 WO 2005081327 A1 WO2005081327 A1 WO 2005081327A1 CN 2005000212 W CN2005000212 W CN 2005000212W WO 2005081327 A1 WO2005081327 A1 WO 2005081327A1
Authority
WO
WIPO (PCT)
Prior art keywords
light emitting
luminescent
liquid
substrate
emitting device
Prior art date
Application number
PCT/CN2005/000212
Other languages
English (en)
Inventor
Yu-Chao Wu
Wei-Yuan Cheng
Original Assignee
Hong-Yuan Technology Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hong-Yuan Technology Co., Ltd. filed Critical Hong-Yuan Technology Co., Ltd.
Priority to EP05706648A priority Critical patent/EP1721340A1/fr
Publication of WO2005081327A1 publication Critical patent/WO2005081327A1/fr

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Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80—Constructional details
    • H10H20/85—Packages
    • H10H20/851—Wavelength conversion means
    • H10H20/8511—Wavelength conversion means characterised by their material, e.g. binder
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42—Wire connectors; Manufacturing methods related thereto
    • H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481—Disposition
    • H01L2224/48151—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/48247—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a bond pad of the item
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42—Wire connectors; Manufacturing methods related thereto
    • H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481—Disposition
    • H01L2224/48151—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/48257—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a die pad of the item
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/80—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
    • H01L2224/85—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a wire connector
    • H01L2224/85909—Post-treatment of the connector or wire bonding area
    • H01L2224/8592—Applying permanent coating, e.g. protective coating
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
    • H01L2924/181—Encapsulation
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/01—Manufacture or treatment
    • H10H20/036—Manufacture or treatment of packages
    • H10H20/0361—Manufacture or treatment of packages of wavelength conversion means

Definitions

  • the invention relates to a light emitting device and fabrication method thereof, and more particularly to a luminescent powder layer for the light emitting device and fabrication method thereof.
  • LEDs Light emitting diodes
  • the luminescent principle of LED is as follows. A voltage is applied to a diode to drive an electron and hole combination. The combination releases light from the diode. Furthermore, phosphors can be added into the LED to tune the luminescent wavelength (color) and luminescent intensity of the light.
  • White LEDs can be used in the lighting field.
  • One is single chip LED.
  • This LED uses a single LED chip and phosphors to obtain white light.
  • a white LED can use a blue LED chip and yellow phosphors or use a UV LED chip, blue, green and red phosphors to obtain a white LED.
  • Another white LED uses a multiple chip LED.
  • This LED uses a plurality of LED chips and phosphors to obtain white light.
  • a white LED can use blue, green and red LED chips to obtain white LED.
  • the multiple chips LED has a plurality of LED chips, wherein have different driving voltages, luminescent intensity, temperature characteristics and lifetime. Thus, the LED design is more complicated and has higher cost. Accordingly, the single chip LED is more practical.
  • the simpler structure of the single chip LED uses single LED chip and phosphors to obtain white light.
  • the LED comprises a pair of electrodes 10, electrically contacting a lead frame 11.
  • LED 12, as GaN, is disposed in the lead frame 11, adhesive 13, comprising epoxy or gel, is provided in the lead frame 11 covering the LED 12.
  • Phosphors 14, comprising YAG, are dispersed in the adhesive 13.
  • the LED is packaged by package materials 15.
  • the YAG is mixed into the resin then coated on the blue GaN LED chip. This method, contrary, is time and material inefficiently, and the LED luminescent efficiency and uniformity decrease due to the resin absorption and the bad YAG dispersion.
  • U.S. Patent No. 6,642,618 disclosed that the phosphors are mixed into the glass layer to prevent the humidity insertion.
  • the YAG may not be well mixed, so that the LED luminescent efficiency and uniformity may decrease.
  • U.S. Patent No. 6,576,488 and U.S. Patent No. 6,686,581 disclosed that the phosphors structure is formed on the LED chip surface by electrophoresis.
  • the phosphor powders must be conversed to gel via charges and then formed by electrical field by applying voltage.
  • a conductive plate must be added on the LED chip surface to attract phosphors to adhere thereto.
  • U.S. Patent No. 6,650,044 disclosed that the phosphor structure is formed on the LED chip surface by a screen printing method.
  • the stencil is fabricated first, and solidifying agent most be added to the phosphor powders to solidify the phosphor powders on the LED chip surface.
  • U.S. Patent No. 6,650,044 disclosed a LED structure by the above-mentioned technology.
  • Taiwanese Application No. 90,104,862 disclosed that the luminescent material is adhered to the semiconductor device by adhesive.
  • the phosphors structure is formed on the LED chip surface by adhesive or electrophoresis only.
  • embodiments of the invention provide a light emitting diode device and fabrication method thereof.
  • the invention provides another method for placing the phosphor layer on the LED chip surface and addresses the phosphor powders and the adhesive mixture issue.
  • Embodiments of the invention provide a light emitting device, comprising, a light emitting semiconductor device, and a luminescent powder layer on an optical path of the light emitting semiconductor device. At least part of the luminescent powder layer is coagulated and free of adhesive material.
  • Embodiments of the invention additionally provide a method of fabricating the light emitting device.
  • the method comprises providing a light emitting semiconductor device, positioning a plurality of luminescent particles at the optical path of the light emitting semiconductor device, and reducing the distance between the luminescent particles to enhance the molecular attraction between the luminescent particles.
  • the luminescent particles are then coagulated to form a luminescent powder layer by molecular attraction.
  • FIG. 1 is a cross-section showing the convention LED structure.
  • FIG. 2A is a cross-section showing an embodiment of a LED structure.
  • FIG. 2B is a cross-section showing another embodiment of a LED structure.
  • FIG. 3A is a cross-section showing a further embodiment of a LED structure.
  • FIG. 3B is a cross-section showing yet another embodiment of a LED structure.
  • FIG. 4A is a cross-section showing an embodiment of a LED package structure.
  • FIG. 4B is a cross-section showing another embodiment of a LED package structure.
  • FIG. 5 is a cross-section showing a further embodiment of a LED package structure.
  • FIG. 6A is a cross-section showing an embodiment of a LED package structure with a first passivation.
  • FIG. 6B is a cross-section showing an embodiment of a LED package structure with a second passivation.
  • FIG. 7 is a cross-section showing an embodiment of a light source structure.
  • FIG. 8 A is a cross-section showing an embodiment of a display device.
  • FIG. 8B is a cross-section showing another embodiment of a display device.
  • FIG. 9 is a scheme showing an embodiment of a fabrication system for the light source device.
  • the embodiments disclose a LED device fabrication method for positioning a plurality of luminescent particles at the optical path of a substrate and reducing the distance between the luminescent particles to enhance the molecular attraction between the luminescent particles.
  • the luminescent particles are coagulated to a luminescent powder layer by molecular attraction.
  • one embodiment comprises the steps following: dispersing a plurality of luminescent particles in a liquid to form a mixture; positioning a substrate in the mixture for a period, until the luminescent particles deposit on the substrate; and removing the liquid to coagulate the luminescent particles on the substrate and adhere the luminescent particles to the substrate.
  • the luminescent particle density is higher than the liquid density for the luminescent particle deposition.
  • the luminescent particle density is about 0.001 ⁇ 1 g/ml, preferably 0.01 ⁇ 0.15 g/ml.
  • the luminescent particle size is about 0.1 ⁇ 100 ⁇ m.
  • the phosphor average particle size is about 3—13 ⁇ m.
  • the nano-scale luminescent particles may be used in the present embodiment.
  • the luminescent particles are barely soluble or insoluble in the liquid.
  • the substrate may be a light emitting semiconductor device, such as a
  • LED chip or layers consisting of the LED chip.
  • FIG. 2 is a LED cross-section of the invention.
  • the LED comprises substrate 20 and luminescent powder layer 21.
  • the luminescent powder layer 21 is directly adhered on the substrate 20.
  • the luminescent powder layer 21 is free of epoxy, glue, or similar.
  • the passivation layer 22 can also be formed on the luminescent powder layer 21 to protect the luminescent powder layer 21.
  • the passivation layer 22 can be a polymer layer.
  • FIG. 3 A is another LED cross section of the invention.
  • the LED comprises the LED chip 30 and the luminescent powder layer 35.
  • the LED chip 30 comprises substrate 31, a plurality of semiconductor layers 32 and the conductive layer 33.
  • the conductive layer 33 may be conductive glass layer, such as an ITO layer.
  • the plurality of semiconductor layers 32 may be two layers or more than two layers. In this case, the plurality of semiconductor layers 32 are two layers, the first semiconductor layer 32a and the second semiconductor layer 32b, in the FIG. 3 A.
  • the luminescent powder layer 35 may be adhered on the substrate 31 surface directly.
  • the emitting powder layer 35 also may be adhered on either the plurality of semiconductor layer 32 surfaces or the conductive layer surface, such as on the first semiconductor layer 32a surface, the second semiconductor layer 32b surface or the conductive layer 33 surface.
  • the luminescent powder layer 35 only consists of luminescent powders, free from any adhesive, such as epoxy or glue, etc.
  • FIG. 3B is another LED cross-section of the invention. The LED structure is similar to the LED in FIG. 3A. The difference is that the emitting powder layer 35 is provided on bottom surface of the substrate 31. This LED structure may be used in the flip chip fabrication.
  • the luminescent powder layer 21 and 35 may be phosphors, such as sulfide phosphors or non-sulfide phosphors.
  • the sulfide phosphors may be covered by a coating film, such as organic polymer coating film, to prevent environmental factors, such as humidity and oxygen.
  • the non-sulfide phosphors may be YAG, TAG or any other phosphor.
  • a passivation may be formed on the luminescent powder layer to avoid external influence and contamination.
  • the passivation may be organic polymer materials.
  • a light emitting device comprises the light emitting semiconductor device 100 and the luminescent powder layer 130.
  • the light emitting semiconductor device 100 may be chip or wafer.
  • the light emitting semiconductor device 100 is the wafer 110 with a plurality of chips 120.
  • the wafer 110 may be separated into an optical path zone OP and a non-optical path zone NOP.
  • the luminescent powder layer 130 is adhered on the surface of the chip 120 or the optical path zone OP. At least a portion, the main portion or the entire the luminescent powder layer 130 is coagulated and free of adhesive.
  • the luminescent powder layer 130 consists of phosphors, and is coagulated by intermolecular attraction. Thus, the luminescent powders do not comprise adhesive, such as resin, organic polymer, solidify materials, or glass gel.
  • the first passivation layer 140 is formed on the luminescent powder layer 130 to avoid scraping, and the passivation 140 at least covers the top surface of luminescent powder layer 130.
  • the second passivation 150 at least covers the first passivation 140 and the luminescent powder layer 130, and may cover the chip 120.
  • the thickness of the second passivation 150 may be higher than the first passivation 140.
  • first passivation layer 140 may be a stress buffer layer to avoid damage to the powder layer in subsequent thermal treatments.
  • the stress buffer layer comprises softer materials, such as silicon gel.
  • the second passivation 150 is a layer comprising harder material, such as epoxy, to avoid scraping or crushing.
  • the luminescent powders comprise sulfide phosphors and non-sulfide phosphors, the non-sulfide phosphors are used in the present embodiment.
  • the embodiments of the light emitting semiconductor device are shown in FI 3Aand FIG. 3B. Light Emitting Package Structure
  • FIG. 4A is the cross section of the light emitting package structure of the invention.
  • the light emitting semiconductor device is LED 40.
  • the LED as shown in FIG. 2 is put in the lead frame 41, the lead frame 41 contacts a pair of electrodes 42 electrically.
  • the lead frame 41, substrate 20 and the luminescent powder layer 21 are packaged by the package materials 43.
  • the passivation 22 may be formed on the luminescent powder layer 21 to protect the luminescent powder layer 21.
  • the passivation 22 may comprise a polymer layer or epoxy.
  • FIG. 5 is the cross section of another light emitting package structure of the invention.
  • the LED as shown in FIG. 3 A is disposed in the lead frame 51, the lead frame 51 contacts a pair of electrodes 52 electrically.
  • the light emitting chip 30 and the luminescent powder layer 35 are packaged by package materials 53.
  • the light emitting device of the invention may be used in the other package structures, such as flip chip structure.
  • the light emitting device 40 (50) electrically contacts the circuit board L to form the light source 200.
  • Back Light Module
  • the light source 200 is disposed under the module body 210 or on the module body 210 sidewall to output light.
  • FIGS. 8 A and 8B show a display element 300.
  • the light source or the back light module provides the light source to the display element 300 to form a display device.
  • the present embodiment discloses a fabrication system for an emitting device.
  • the fabrication system comprises a container 950; a disposal device 940 for disposing a substrate 960 into the container 950; a liquid supply device 910 for infusing liquid 980 to the container 950 and the liquid 980 is higher than the substrate 960; a stirring device 920 for mixing a plurality of light emitting powder and the liquid 980 to form a mixture, and the liquid 980 is optionally free of adhesive; a liquid discharge device 930 for removing the liquid 980 after the luminescent powders are deposited on the substrate 960. The luminescent powders are coagulated and adhered on the substrate 960 to form the luminescent powder layer 970. Fabrication Method for Light Emitting Device
  • the present embodiment provides a light emitting semiconductor device, as shown in the FIG. 6B.
  • the plurality of the luminescent powders are disposed on the optical path of the light emitting semiconductor device, such as on the surface of chip 120.
  • the distance of the luminescent powders are decreased to enhance the intermolecular attraction of the luminescent powders to coagulate the luminescent powders to form the luminescent powder layer 130.
  • the luminescent powder layer 130 forming steps are as follows: a plurality of the luminescent powders is mixed with a liquid. The plurality of the luminescent powders is then positioned on the optical path of the semiconductor chip or wafer 120.
  • the liquid is removed to coagulate the luminescent powders to a luminescent powder layer.
  • the liquid comprises water or volatile solvents and does not comprise epoxy or glue.
  • the volatile solvents comprise the group consisting of ethers, alcohols and ketones, such as ether, methanol, ethanol or acetone.
  • the light emitting semiconductor chip or wafer is put into a container 950 containing the liquid 980, and the luminescent powders are dispersed in the liquid to form a mixture.
  • the luminescent powder depositing time may optionally increase.
  • the height of the liquid 980 is higher than the semiconductor chip or wafer 960, so that the luminescent powders can be deposited on the semiconductor chip or wafer 960.
  • the height of the liquid 980 is about 3.5-6 times the height of the semiconductor chip or wafer 960.
  • the liquid removing step may be a baking step.
  • the baking step comprises a baking temperature to remove the liquid. Agitation caused by the baking temperature is controlled to not affect the arrangement of the luminescent particles on the light emitting semiconductor chip or wafer.
  • the baking temperature is typically higher than the room temperature.
  • the baking temperature is about 40-300 ° C .
  • the ethanol baking temperature is about 80 ° C .
  • the baking step may comprise multiple steps.
  • the liquid is removed at a first temperature and a second temperature.
  • the liquid removal step further is executed before the baking step.
  • the liquid removal step may comprise a drainage step or a pumping step.
  • a plurality of luminescent powders are mixed with a liquid.
  • the luminescent powders are then deposited on the optical path zone OP and the non-optical path zone NOP of the semiconductor wafer.
  • the luminescent powders are coagulated to a luminescent powder layer.
  • a first passivation layer 140 is formed to protect the luminescent powder layer 130 on the optical path zone OP of the semiconductor wafer, as shown in FIG. 6A.
  • the luminescent powder layer on the non-optical path zone NOP of the semiconductor wafer is washed or removed, the luminescent powder layer on the optical path zone OP of the semiconductor wafer is protected by the passivation layer 140.
  • a second passivation 150 may be formed to cover the first passivation layer 140 and the luminescent powder layer.
  • the following illustrates the LED fabrication by the fabrication system for emitting device.
  • the luminescent powders are put into the liquid, and the density of luminescent powders are higher than the density of the liquid, and the luminescent powders are insoluble or have low solubility in the liquid, and the luminescent powders are stable in the liquid and have no chemical reaction with the liquid.
  • the luminescent powders are well mixed with the liquid by a stirring bar or ultrasonic agitation to form a mixture.
  • the luminescent powders may be phosphors, and the phosphors may be sulfide phosphors or non-sulfide phosphors.
  • the sulfide phosphors further may be coated by a coating film, such as organic polymer coating film, to prevent the environmental factors, such as humidity and oxygen.
  • the non-sulfide phosphors may be YAG, TAG or any other phosphors.
  • a substrate is put in the mixture for a period of time, and the height of the mixture must be higher than the substrate top surface of at least 10 ⁇ m. Then the luminescent powders deposit on the substrate by gravity naturally. Thus, the density of the luminescent powders must be higher than the liquid, or the deposition will not occur.
  • the particle size of the luminescent powders are typically 0.1-100 ⁇ m. If the particles are too small, the deposition time will be too long and the output would decrease. If the particles are too big, the uniformity of the luminescent powder layer will decrease.
  • the concentration of the luminescent powders and the liquid is about 0.001-1 g/ml, preferably 0.01-15 g/ml. If the concentration is too high, the luminescent powders are wasted or the luminescent powder layer will be too thick. If the concentration is too low, the deposition time will be too long and the luminescent powder layer will be too thin.
  • the liquid is removed by baking, drainage and/or pumping to form a luminescent powder layer on the substrate.
  • the liquid removing step must not agitate the luminescent powder layer, or the ideal luminescent powder layer can not be obtained.
  • the baking temperature may be 40-300 °C . If the baking temperature is too low, the baking time would be too long or the liquid is difficult to dry. If the baking temperature is too high, the substrate and/or the luminescent powders can be spoiled, and the luminescent powder layer can be agitated.
  • the liquid is removed, the distance between the luminescent powders decrease, and the luminescent powder layer is formed by the intermolecular force, such as Van der Waal force.
  • the baking step may comprise multiple baking steps, such as a first baking step and a second baking step.
  • the baking temperature may be lower than the liquid boiling point to prevent voids from forming on the luminescent powder layer surface.
  • the baking temperature may be higher to dry all the liquid and lower than the substrate or the luminescent powder spoiling temperature, 300 ° C for example.
  • a passivation layer may be formed on the luminescent powder layer by a coating method.
  • the passivation layer may be organic polymer.
  • the luminescent powder layer will not be formed.
  • the luminescent powders are soluble in the liquid, if the mixture is over-saturated, the invention will still work.
  • the overdose luminescent powder method increases the cost. Otherwise, if the luminescent powders are unstable in the liquid or have a chemical reaction with the liquid, the luminescent powders will deteriorate or decompose.
  • the liquid preferably is insoluble, barely soluble, stable and has no chemical reaction with the luminescent powders.
  • the liquid may be water, alcohols, ketones and/or ethers.
  • the alcohols may be ethanol, the ketons may be acetone, the ethers may be ether.
  • the substrate may be an LED chip or any layer of the LED chip, in other words, the luminescent powder layer is formed on any surface of the LED chip.
  • the following examples provide the water and ethanol as the liquid.
  • YAG phosphors produced by Nichia Co. were put in water to form a mixture by ultrasonic agitation.
  • GaN chip was put in the mixture for about 20 min for the YAG phosphors deposition.
  • the mixture surface was higher than the GaN chip top surface, so that the YAG phosphors deposited on the GaN chip.
  • the water was evaporated at about 50 ° C for a period, and then dried at about 200 ° C to dry all the water and coagulate the YAG phosphors.
  • a vacuum process may be processing to increase the water removing rate.
  • YAG phosphors produced by Nichia Co. were put in ethanol to form a mixture via ultrasonic agitation. GaN chip was put in the mixture and stayed about 20 min for the YAG phosphors deposition. The mixture surface was higher than the GaN chip top surface, so that the YAG phosphors deposited on the GaN chip.
  • the ethanol was evaporated at about 80 ° C for a period, then dried at about 150°C to dry all the ethanol and coagulate the YAG phosphors. In the ethanol removing step, a vacuum process may be processing to increase the ethanol removing rate.
  • LED measurement data, CIE Coordinates and Brightness are given in the following.
  • the LEDs are fabricated by the conventional method where the phosphor is mixed with resin and the inventive method, and use GaN LED chip and YAG phosphors.
  • the driving conditions are as follows:
  • LEDs of the examples emit white and brighter light. Accordingly, the light intensity of the LEDs that are fabricated by the invention and excited by the longer wavelength (lower energy) is close to the light intensity of the LEDs that are fabricated by the known and excited by the shorter wavelength (larger energy). It shows the LEDs of the invention have a better optical-electrical transfer rate.
  • the luminescent powder layer of the invention is adhered in or on the light emitting semiconductor device directly free of any medium, such as epoxy or glue, so the applied energy is not wasted by the medium and the light emitting device has higher emission efficiency.
  • the luminescent powder layer of the invention is fabricated by the direct adhesion method, and not mixed with the resin and than coated no the light emitting device. Thus the fabrication method of the invention is simpler and can enhance the output.
  • the luminescent powder layer of the invention is fabricated by the direct adhesion method, not by mixing with the resin then coating the light emitting device, thus non-uniformity of the luminescent powder in the medium dose not occur.
  • the luminescent powder layer of the invention is fabricated by the direct adhesion method, when this fabrication fails, the luminescent powder layer can be reworked by a brushing method, for example. So the rework is very easy and the cost is low. While the invention has been described by way of example and in terms of preferred embodiment, it is to be understood that the invention is not limited thereto.

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Abstract

L'invention concerne un procédé de fabrication de dispositif luminescent : fourniture d'un dispositif luminescent à semi-conducteur ; positionnement de plusieurs particules luminescentes au trajet optique de ce dispositif ; et réduction de la distance entre les particules luminescentes pour améliorer l'attraction moléculaire entre les particules, puis coagulation des particules en une couche de poudre luminescente par l'attraction moléculaire.
PCT/CN2005/000212 2004-02-23 2005-02-23 Dispositif luminescent et procede de fabrication WO2005081327A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP05706648A EP1721340A1 (fr) 2004-02-23 2005-02-23 Dispositif luminescent et procede de fabrication

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN200410004550 2004-02-23
CN200410004550.7 2004-02-23

Publications (1)

Publication Number Publication Date
WO2005081327A1 true WO2005081327A1 (fr) 2005-09-01

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EP (1) EP1721340A1 (fr)
CN (1) CN101270864A (fr)
WO (1) WO2005081327A1 (fr)

Cited By (2)

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US7989823B2 (en) 2006-06-08 2011-08-02 Hong-Yuan Technology Co., Ltd. Light emitting system, light emitting apparatus and forming method thereof
CN102945915A (zh) * 2012-10-22 2013-02-27 厦门多彩光电子科技有限公司 一种led荧光粉涂覆工艺

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US6576488B2 (en) * 2001-06-11 2003-06-10 Lumileds Lighting U.S., Llc Using electrophoresis to produce a conformally coated phosphor-converted light emitting semiconductor
US6642652B2 (en) * 2001-06-11 2003-11-04 Lumileds Lighting U.S., Llc Phosphor-converted light emitting device

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CN1411614A (zh) * 2000-03-03 2003-04-16 奥斯兰姆奥普托半导体有限责任公司 制造具有发光转换元件的发光半导体的方法
US6576488B2 (en) * 2001-06-11 2003-06-10 Lumileds Lighting U.S., Llc Using electrophoresis to produce a conformally coated phosphor-converted light emitting semiconductor
US6642652B2 (en) * 2001-06-11 2003-11-04 Lumileds Lighting U.S., Llc Phosphor-converted light emitting device

Cited By (2)

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Publication number Priority date Publication date Assignee Title
US7989823B2 (en) 2006-06-08 2011-08-02 Hong-Yuan Technology Co., Ltd. Light emitting system, light emitting apparatus and forming method thereof
CN102945915A (zh) * 2012-10-22 2013-02-27 厦门多彩光电子科技有限公司 一种led荧光粉涂覆工艺

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