WO2005052199A1 - Procede de production d'un composant a matrice metallique et a renforcement par des fibres ou des particules - Google Patents
Procede de production d'un composant a matrice metallique et a renforcement par des fibres ou des particules Download PDFInfo
- Publication number
- WO2005052199A1 WO2005052199A1 PCT/EP2003/012352 EP0312352W WO2005052199A1 WO 2005052199 A1 WO2005052199 A1 WO 2005052199A1 EP 0312352 W EP0312352 W EP 0312352W WO 2005052199 A1 WO2005052199 A1 WO 2005052199A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- matrix material
- fibers
- fiber composite
- semi
- finished product
- Prior art date
Links
- 239000011159 matrix material Substances 0.000 title claims abstract description 91
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 31
- 239000002245 particle Substances 0.000 title claims abstract description 31
- 239000000835 fiber Substances 0.000 title claims description 156
- 229910052751 metal Inorganic materials 0.000 title claims description 23
- 239000002184 metal Substances 0.000 title claims description 23
- 230000002787 reinforcement Effects 0.000 title description 6
- 239000002131 composite material Substances 0.000 claims abstract description 83
- 239000000463 material Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims description 108
- 239000011265 semifinished product Substances 0.000 claims description 53
- 239000010410 layer Substances 0.000 claims description 45
- 238000000576 coating method Methods 0.000 claims description 33
- 229910045601 alloy Inorganic materials 0.000 claims description 28
- 239000000956 alloy Substances 0.000 claims description 28
- 239000011248 coating agent Substances 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 15
- 238000005507 spraying Methods 0.000 claims description 15
- 238000007751 thermal spraying Methods 0.000 claims description 12
- 230000009974 thixotropic effect Effects 0.000 claims description 12
- 239000004744 fabric Substances 0.000 claims description 11
- 239000007791 liquid phase Substances 0.000 claims description 11
- 238000003825 pressing Methods 0.000 claims description 11
- 239000012071 phase Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 238000007750 plasma spraying Methods 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 239000007789 gas Substances 0.000 claims description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 238000010891 electric arc Methods 0.000 claims description 6
- 238000001652 electrophoretic deposition Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000004804 winding Methods 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 238000009792 diffusion process Methods 0.000 claims description 4
- 230000005684 electric field Effects 0.000 claims description 4
- 238000010030 laminating Methods 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 4
- 238000007650 screen-printing Methods 0.000 claims description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 4
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 238000007786 electrostatic charging Methods 0.000 claims description 3
- 238000010285 flame spraying Methods 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 239000011241 protective layer Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 229910000838 Al alloy Inorganic materials 0.000 claims description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- 230000004888 barrier function Effects 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 2
- 150000001247 metal acetylides Chemical class 0.000 claims description 2
- 229910052863 mullite Inorganic materials 0.000 claims description 2
- 150000004767 nitrides Chemical class 0.000 claims description 2
- 239000011224 oxide ceramic Substances 0.000 claims description 2
- 229910052574 oxide ceramic Inorganic materials 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 239000011135 tin Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000011149 active material Substances 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000013615 primer Substances 0.000 claims 1
- 239000002987 primer (paints) Substances 0.000 claims 1
- 238000007493 shaping process Methods 0.000 abstract description 5
- 230000008569 process Effects 0.000 description 48
- 238000005242 forging Methods 0.000 description 9
- 239000000155 melt Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 238000000465 moulding Methods 0.000 description 6
- 239000007790 solid phase Substances 0.000 description 6
- 230000035882 stress Effects 0.000 description 6
- 238000011161 development Methods 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 238000009716 squeeze casting Methods 0.000 description 5
- 229910018125 Al-Si Inorganic materials 0.000 description 4
- 229910018520 Al—Si Inorganic materials 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 230000008595 infiltration Effects 0.000 description 4
- 238000001764 infiltration Methods 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 210000001170 unmyelinated nerve fiber Anatomy 0.000 description 2
- 229910021364 Al-Si alloy Inorganic materials 0.000 description 1
- 229910000789 Aluminium-silicon alloy Inorganic materials 0.000 description 1
- 241000132092 Aster Species 0.000 description 1
- 229910000897 Babbitt (metal) Inorganic materials 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- CAVCGVPGBKGDTG-UHFFFAOYSA-N alumanylidynemethyl(alumanylidynemethylalumanylidenemethylidene)alumane Chemical compound [Al]#C[Al]=C=[Al]C#[Al] CAVCGVPGBKGDTG-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000001513 hot isostatic pressing Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000000626 liquid-phase infiltration Methods 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 239000011156 metal matrix composite Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000009715 pressure infiltration Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
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- 239000002356 single layer Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/08—Making alloys containing metallic or non-metallic fibres or filaments by contacting the fibres or filaments with molten metal, e.g. by infiltrating the fibres or filaments placed in a mould
- C22C47/12—Infiltration or casting under mechanical pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
- B22D17/007—Semi-solid pressure die casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/14—Casting in, on, or around objects which form part of the product the objects being filamentary or particulate in form
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/12—Making non-ferrous alloys by processing in a semi-solid state, e.g. holding the alloy in the solid-liquid phase
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
Definitions
- the invention relates to a method for producing a component from a composite material (MMC) with a metallic matrix material which is reinforced by embedded fibers or particles.
- MMC composite material
- the invention further relates to such a composite material and the use of such a composite material.
- the need to save primary energy sources and reduce emissions makes the light metal material of increasing importance in automobile construction and in aerospace technology.
- MMC materials Metal Matrix Composites
- high-strength reinforcing fibers can increase the high-temperature strength and stiffness of these materials, which are insufficient for many applications.
- the manufacturing costs are to be reduced through short manufacturing cycles and the manufacture of components close to final dimensions ("net shape for ing").
- melt metallurgical and liquid phase impregnations as well as die casting techniques are generally used.
- the long reaction and contact times of molten metallic phases with the reinforcing fibers and the molding tools or surfaces result in undesirable damage.
- dissolution and precipitation processes as well as chemical interface reactions occur.
- liquid, chemically highly active light metal melts (usually aluminum) are used, so that additional protection of the fibers used is essential with a suitable protective layer.
- MMC embedded fibers or particles
- the process is intended to enable the most cost-effective and energy-saving production of components that are shaped close to production (net-shape molding).
- the Thixou molding process is basically known in the prior art for forming special alloys, in particular aluminum-based or copper-based, with which a two-phase or multi-phase region is used within a specially selected temperature range above the solidus line and below the liquidus line, in which a liquid phase share is present.
- a pronounced solidification interval of the alloy to be formed is required, ie a temperature range in which both solid and liquid phase components are present side by side (cf. FIG. 1).
- Suitable alloy with thixoidal forming has a globolithic structure that forms a solid phase skeleton and thus ensures good handling of the heated semi-finished product when it is inserted into a press mold.
- This solid phase skeleton breaks open under shear loads and thus reduces the yield stress, so that only short flow distances result in the tool and a near-net-shape deformation can be achieved.
- a first advantage is that the temperature is significantly lower than the use of melt processes or melt infiltration processes and the significantly shortened molding exercise time. In this way, it is possible to dispense with the coating of the embedded fibers or particles, since the embedded fibers are hardly damaged by the only short melting process at a relatively low temperature.
- the entire melting shop (melting furnace, alloy furnace, degassing, alloy control, casting furnace) can be dispensed with. Furthermore, due to the modified tool concept, there is significantly less recycle material that has to be melted down again before being reintroduced into the production process.
- the term “semifinished product” is understood to mean the preform, which is subsequently formed into a component by thixoui-molding within the tool.
- This semifinished product can be a prepreg which consists of a single or preferably a plurality of laminate layers, or a preform which is produced from a granulate on the basis of a pressing process.
- semi-finished products are therefore always understood to be the generic term, which includes a prepreg and other preforms prepared in some other way, which are manufactured within the tool by thixoforming to form the component.
- a prepreg is produced by laminating layers of fiber composites and matrix material in the form of sheets.
- layers of fiber composites are preferably joined alternately with the suitable sheets by lamination in order to provide the desired shape of the semi-finished product.
- the provision of the matrix material is sufficient: ials in the form of sheets, sufficiently short flow paths and yet to ensure uniform wetting of the enclosed fibers or particles.
- the sheets are provided in the form of cold-rolled sheets. This results in a fine-grained recrystallization with a globular structure due to the dislocation density induced by the cold rolling process, which has a favorable effect on the resulting properties of the component.
- a fiber composite is coated with a metallic matrix material.
- the fiber composite can be coated with the metallic matrix material by a screen printing process.
- Another method variant for coating a fiber composite with the metallic matrix material consists in an application by means of electrostatic charging.
- Another method variant for coating a fiber composite with metallic matrix material generally consists of an electrophoretic deposition (EPD) from an aqueous suspension with the support of an electric field.
- EPD electrophoretic deposition
- the fiber structure to be coated is switched to be electrically conductive as an electrode, and the charge-bearing metal powder particles are driven by the electric field onto the fiber or fabric surface as a uniform layer.
- Such a procedure is particularly suitable for fiber composites that are inherently electrically conductive, such as C fibers.
- other fibers that are not readily electrically conductive can also be processed if suitable intermediate layers are used.
- metal particles are preferably used which have a grain size with a diameter between 10 n and 100 ⁇ m, preferably with sizes between 100 nm and 10 ⁇ m.
- surface active liquid or dissolved auxiliaries enables targeted charge distributions of the solid particles in the suspension to be set, which allow concentration and field strength-dependent mass transport for layer separation. In this way, the properties of the component subsequently produced from this can be varied within wide limits and adapted to the respective requirements.
- a fiber composite is coated with the metallic matrix material by thermal spraying.
- thermal spraying Basically, atmospheric plasma spraying (APS), arc wire spraying, wire flame spraying or high-speed flame spraying are possible.
- the thermal spraying is preferably carried out by electric arc wire spraying or powder plasma spraying, in particular by atmospheric plasma spraying.
- Fiber composites with . are provided with thermally sprayed metal layers, offer the advantage of a finer-grained structure compared to the use of alternating layers of sheet metal and fiber composites. While the grain sizes of thixotropically formable Al-Si sheets are in the range of 2 to 20 ⁇ m, the dimensions of the individual phases in the thermally sprayed AlSi layer structure are in the submicrometer range due to the high cooling rate when applying layers. This enables improved impregnability of the metallic phase into the fiber structure during thixotropic forming.
- the volume ratio of matrix material to fibers in thermal spraying is preferably set between 0.3 and 8.0, in particular between 0.8 and 3.0.
- the fiber composite is preferably cooled during thermal spraying, in particular using liquid carbon dioxide.
- the fiber composite is held under tension during thermal spraying on a carrier device.
- composite materials can be produced in this way in which embedded long fibers are stressed under tensile stress without the matrix itself being previously undesirably stressed.
- the carrier device can promote the fiber composite in Allow continuously or in cyclical operation in a coating level for thermal spray coating.
- the fiber composite can be guided over a winding device.
- a spraying distance of 50 to 200 mm is maintained between the surface of the fiber composite and the nozzle outlet during coating by plasma spraying, while a spraying distance of 80 to 300 mm is maintained when coating by electric arc spraying.
- a mixture of the matrix material and short fibers is granulated or pelletized.
- fibers with a length of between 0.5 and 20 mm, preferably between 2 and 6 mm, are preferably used.
- the volume ratio of matrix material to fibers is preferably between 0.3 and 5, preferably between 1 and 2.
- a mixture of the matrix material and of powdery particles is granulated or pelletized.
- the production of granules or pellets using short fibers or powdery particles can advantageously be used to produce special graded layers or, for example, to produce bearing materials.
- the granulated or pelletized mixtures can be processed into a semi-finished product by cold pressing. If the matrix material used is sufficiently ductile, this cold pressing process can be carried out without the addition of binders. However, if there is a lack of ductility, suitable pressing aids, e.g. Paraffin added.
- the mixture produced by granulating or pelletizing is applied to a fiber composite by means of a suitable coating process.
- Thermal spraying, a screen printing process or another previously mentioned process can in turn be used for this purpose.
- At least one layer with a fiber composite made of long fibers is preferably used for the manufacture.
- long fibers are understood to mean a fiber length of at least 1 mm or an aspect ratio (ratio of length to diameter) of the fiber of at least 50, preferably of at least 100, particularly preferably of at least 150.
- the layer sequence can be varied in a suitable manner when laminating prepregs. in order to influence the properties of the component to be produced in a targeted manner.
- fiber composites made of long fibers coated with matrix material can be laminated together in a suitable manner.
- layers of matrix material in the form of sheets or foils can be inserted.
- Intermediate layers of granules or pellets can also be inserted.
- a prepreg produced by lamination is provided with an outer layer made of matrix material.
- the surface of the component produced is largely free of embedded fibers or particles.
- fiber composites can be used in a wide variety of forms to ensure certain properties of the component produced.
- fiber composites can be used as scrims made of unidirectional long fibers (UD). se ("un oven") or woven fiber composites in the form of 2D fiber composites, 3D fiber composites, in the form of knitted fabrics or knitted fabrics.
- UD unidirectional long fibers
- woven fiber composites in the form of 2D fiber composites, 3D fiber composites, in the form of knitted fabrics or knitted fabrics.
- the semi-finished product can also be produced from graded layers in order to achieve a targeted influencing of properties at particularly stressed points on the component or in preferred directions of stress. In this way, the ratio of matrix material to fibers can be specifically changed over the component cross-section.
- Aluminum alloys or copper alloys are preferably used for this purpose, in particular alloys which consist of the main components aluminum, magnesium and copper or which consist of the main components copper and tin or zinc.
- alloys are preferred as the matrix material which consist of alloys of the type AlMg4.5Mn0.4 (AA 5182), of the type AlMgSil (EN AW-6082), of the type AlSi7Mg (EN AW-356, EN-AW-357), type AlSi3 (AA 208, AA 296), type A1SÜ2 (AA 336, AA 384), type CuZn40A12 or type CuSnl3, 5A10, 3.
- the wear-reducing effect of reinforcing asters is in the foreground.
- These materials can be used in particular to produce advantageous bearing materials, for which purpose a combination with carbon fibers or articles in a modification close to graphite is suitable, since emergency running properties can be achieved in this way.
- the metallic matrix material itself is reinforced by embedded particles, which are preferably designed as oxide ceramics, as carbides, as nitrides, as metals or alloys or as tribologically active substances.
- fibers consisting of carbon, silicon carbide, aluminum oxide, mullite are used for fiber reinforcement of the MMC. Modifications of these fibers with nitrogen, titanium, boron, carbon or silicon and their compounds are also conceivable.
- fibers coated on their surface can also be used, in particular fibers provided with diffusion barrier or protective layers or fibers provided with adhesion promoter layers.
- the properties of the component to be manufactured can be adapted to the respective requirements to an even greater extent.
- Adhesion promoters improve the interfacial adhesion between embedded fibers and the metallic matrix phase.
- fibers can be embedded that are less compatible with the matrix phase used.
- Silicon carbide, silicon nitride, titanium carbide, titanium nitride, carbon or mixed phases or compounds thereof are particularly suitable for coating the fibers.
- fibers with a diameter between 0.5 and 150 ⁇ m, particularly preferably between 5 and 20 ⁇ m, are preferably used.
- the fibers can be used both as long fibers or continuous fibers and in the form of short fibers (“chopped fibers”).
- the semifinished product is heated to a specific temperature interval within which the matrix material has a defined liquid phase fraction.
- the semi-finished product is heated to a temperature between 574 and 584 ° C for thixoforming, with a liquid phase fraction between 43 and 51 percent by volume.
- the alloy AlMgSil is used, the thixoforming is heated to a temperature between 635 ° C and 645 ° C, with a liquid phase fraction between approximately 15 and 35%. provides.
- heating takes place to a temperature range between 871 ° C and 875 ° C, resulting in a liquid phase fraction between approximately 20 and 40%.
- the Thixoumformung preferably done as thixoforging within a suitable tool (die) at a controlled ram speed and Pres' skraft.
- the impact speed and pressing force are adapted to the specific process. Ram speeds of up to 800 mm / s are possible.
- the speed of impact of the upper part of the tool on the workpiece is preferably set between 10 mm / s and 300 mm / s depending on the fiber-matrix ratio used, the component complexity and the component volume.
- the tool is preferably heated to temperatures between 100 ° C and 400 ° C.
- the semi-finished product is pre-compressed in a mold for thixoforming.
- the mold used later for thixoforming is preferably used as the shape.
- the pre-compressed semifinished product can now be preheated outside the tool, which can be done inductively, in a forced-air oven with a protective gas atmosphere, with infrared emitters or with lasers, is then inserted into the tool in the preheated state and then thixotropically formed, especially thixo-forged.
- the preferred matrix materials allow the semifinished product to be heated up to the temperature necessary for thixotropic forming, while the semifinished product is still sufficiently strong, which allows the semifinished product to be handled for insertion into the mold, which can be done automatically, for example.
- the semi-finished product loses its shear strength only when the thixo forging is subsequently applied via the stamp, so that the material is formed in the shortest possible time.
- the semi-finished products are heated within the tool to a temperature above the solidus line, but below the liquidus line of the matrix material.
- the layered material can be brought into contact with the tool wall by applying a low pressure. This improves the heat transfer and thus reduces the heating-up time.
- the thixotropic forming is preferably carried out by forging.
- the thixotropically formed component is preferably cooled in a controlled manner within the tool in order to achieve a directional solidification of the metallic matrix.
- Composite materials produced in this way can preferably be used according to the invention as high-strength structural components with high-specific rigidity or with a high specific modulus of elasticity, which are shaped close to production (net-shaped).
- high-strength structural components with high-specific rigidity or with a high specific modulus of elasticity, which are shaped close to production (net-shaped).
- a prepreg which consists of a layer composite of alternating layers of fiber layers and sheets (foils);
- 3 shows a prepreg consisting of a sequence of fiber composites coated with metallic matrix material; 4 shows a globolithic structure of an Al-Si alloy;
- FIG. 5 shows a cross section through an Al-Si composite material infiltrated with a metal matrix with embedded C fibers after a Thixo separation process
- Fig. 6 is a. Schematic representation of a winding system for thermal ' spray coating of fiber fabrics on an industrial scale.
- FIG. 1 shows a phase diagram of the preferred eutectic system Al-Si (with magnesium additives).
- the fixed part in the dark hatched area is ⁇ (AI).
- the wrought alloy AlMgSil and the cast alloy AlSi7Mg are entered as alloys suitable for thixotropic forming.
- a thixotropic forming a narrow temperature range is required, which for the wrought alloy AlMgSil lies between the solid line and the liquid line and is characterized in Fig. 1 by the rectangular temperature range, which lies between 635 and 645 ° C. In this area there is a liquid share (L) of 15 to 35%.
- the thixoforming of such light metal materials was developed in particular for the production of molded components which have a shape close to the production line.
- the semi-finished product in question is still of sufficient strength, which enables the semi-finished product to be handled (also called “bolts” in thixo forging).
- the alloys in question ideally have a globolithic structure which Forms solid phase skeleton and thus ensures the easy handling of the heated semi-finished product when inserting it into the tool (the press mold) (see Fig. 4).
- This solid phase skeleton breaks open under shear stress and thus reduces the yield stress, so that long flow distances in the tool and a near-net-shape forming can be guaranteed.
- MMCs are now produced with a metallic matrix material which is reinforced by embedded fibers or particles by preparing a semi-finished product in which the fibers or particles are contained under a metallic matrix tool and the semi-finished product by thixoforming in a tool at a temperature above the solidus temperature and below the liquidus temperature of the metallic matrix tool is formed.
- a loose combination of fibers on the one hand and metallic matrix material on the other is sufficient to to produce a high-quality, practically non-porous composite material in the thixoforming process with only a short forming time.
- a fiber composite 12 consists, for example, of carbon fibers which are arranged in the form of a fabric.
- fiber composite layers 12 are alternately laminated with thin sheets 14 made of the matrix material, for example AlSi7Mg.
- the thicknesses d x of the fiber composites 12 and d 2 of the sheets 14 are adjusted.
- the semifinished product 10 is expediently enclosed by an outer layer 18 made of matrix material, in order to ensure that during the subsequent thixoforming, if possible, no fibers reach the surface of the component.
- an outer layer 18 made of matrix material, in order to ensure that during the subsequent thixoforming, if possible, no fibers reach the surface of the component.
- Such a semifinished product or prepreg is placed in a suitable die mold and shaped therein by thixo forging in the suitable temperature range using a ram.
- precompacting can first take place inside the tool while it is still cold, and then the semifinished product 10 can be preheated outside the die shape to the temperature necessary for thixoforming.
- This can be done by quickly heating the pre-compressed semi-finished product inductively or alternatively in a forced-air oven with a protective gas atmosphere or with high-performance infrared radiators or using a laser.
- a quick transfer takes place into the suitably preheated die mold (100 to 400 ° C).
- This process can be done manually, semi or fully automatically.
- the Thixo forging process is then carried out.
- the plunger hits the surface of the semi-finished product with a plunger speed of up to 800 mm / s, which is adapted to the process.
- the speed of impact of the ram on the semi-finished product is preferably set between 10 mm / s and 300 mm / s depending on the fiber-matrix ratio, the component complexity and the component volume.
- the plunger is also appropriately preheated.
- the semi-finished product can also be heated within the die.
- the layered semi-finished product can be brought into contact with the tool wall by a low pressure, which improves the heat transfer and reduces the heating-up time.
- the thixotropic forming is carried out by thixo forging.
- cold-rolled sheets are preferably used, since the high dislocation density during subsequent reheating in the course of thixoforming results in fine-grained recrystallization with a globular structure.
- a second process variant for the production of a semi-finished product consists in the coating of individual fiber composites, which are then laminated to form a prepreg by superimposing them and are expediently in turn surrounded by an outer sheet metal layer or film layer made of matrix material. This method variant is explained in more detail below with reference to FIGS. 3 and 6.
- a third alternative to the production of the semi-finished product consists in the production of a mixture of short fibers or powdery reinforcement particles with metallic matrix powders. This is followed by shaping by dry pressing or further processing, in turn by application to a fiber composite using a coating process.
- An electrically conductive or electrically conductive fiber structure is switched as an electrode by means of EPD, and the charge-carrying metal powder particles are deposited on the fiber or fabric surface as a uniform layer, driven by an electric field.
- the metal particles have a grain size with diameters between 10 nm and 100 ⁇ m, preferably with sizes between 100 nm and 10 ⁇ m.
- the use of surface-active liquid or dissolved auxiliaries enables a targeted charge distribution of the solid particles in the suspension to be set, which permits concentration and field strength-dependent material transport for layer deposition.
- a particularly preferred coating method is coating by thermal spraying.
- special electric arc wire spraying and powder plasma spraying preferably atmospheric plasma spraying (APS) in the foreground.
- APS atmospheric plasma spraying
- cooling can be carried out locally using coolant injectors and other suitable devices, preferably using compressed air and possibly liquid carbon dioxide (C0 2 ).
- the fiber composite material can be unwound continuously or intermittently from a roll 34, which contains fiber composite layers to be coated, in a coating plane (left curved surface in FIG. 6) and then again after the coating on a roll 32 wind up.
- a coating can first be carried out on a first upper side and then a coating on the opposite surface.
- a particular advantage lies in the targeted prestressing of the fabrics in the coating plane, which can also be designed to be adjustable in order to ensure an equal, permanent prestressing. Thereby, thermally and convectively generated tensions in the fiber structure are mechanically compensated.
- a 5-axis robot-based movement system can be used for coating, which moves an arc or plasma torch in such a way that NC-controlled movement sequences with the aim of uniform coating can be called up from previously saved programs and can be reproduced and realized in a process-stable manner ,
- Spray distances of 50 to 200 mm between the nozzle outlet and the fiber surface are preferably used between 100 and 140 mm for APS and between 120 and 160 mm for electric arc spraying.
- such layers 22 of fiber composites which are coated on both sides with matrix metal 24, are laminated together to form a prepreg and are preferably enclosed in turn by a sheet or foil 18 made of matrix metal in order to produce a semi-finished product 20.
- the coating thickness d 3 can be controlled in a suitable manner in the previous coating process. For this purpose, single or multiple layers can be applied and the layer thickness can, of course, be influenced by the speed at which the vehicle is driven over or the length of stay and the other spray parameters. If larger layers of matrix metal are desired, individual metal sheets or foils can also be interposed.
- mixtures of matrix metal powders and short fibers or reinforcing particle powders are produced.
- This granu- Gelled or pelleted mixtures can then be compacted into a green body by cold pressing, which is then used as a semi-finished product. If the matrix metal has sufficient ductility, cold pressing can be carried out without pressing aids. If the ductility of the metal matrix material is lower, suitable binder additives (e.g. paraffin) that easily volatilize during later heating are added ...
- a further process variant consists in applying the mixtures produced by granulating or pelleting to a fiber composite by means of a suitable coating process, which in turn can be carried out, for example, by thermal spraying.
- graded layers can be used to produce special component properties that are adapted to specific local thermal or mechanical stresses, for which purpose the entire spectrum can be used in the processing of fiber composites.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
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- Organic Chemistry (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003282089A AU2003282089A1 (en) | 2003-11-05 | 2003-11-05 | Method for producing a component provided with a metal matrix and a fibre or particle reinforcement |
PCT/EP2003/012352 WO2005052199A1 (fr) | 2003-11-05 | 2003-11-05 | Procede de production d'un composant a matrice metallique et a renforcement par des fibres ou des particules |
EP03773705A EP1685263B1 (fr) | 2003-11-05 | 2003-11-05 | Procede de production d'un composant a matrice metallique et a renforcement par des fibres ou des particules |
DE50310214T DE50310214D1 (de) | 2003-11-05 | 2003-11-05 | Verfahren zur herstellung eines bauteils mit metallischer matrix und verstärkung durch fasern oder partikel |
AT03773705T ATE402271T1 (de) | 2003-11-05 | 2003-11-05 | Verfahren zur herstellung eines bauteils mit metallischer matrix und verstärkung durch fasern oder partikel |
US11/186,006 US20060021728A1 (en) | 2003-11-05 | 2005-07-20 | Method and device for producing a reinforced component by thixoforming |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2003/012352 WO2005052199A1 (fr) | 2003-11-05 | 2003-11-05 | Procede de production d'un composant a matrice metallique et a renforcement par des fibres ou des particules |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/186,006 Continuation US20060021728A1 (en) | 2003-11-05 | 2005-07-20 | Method and device for producing a reinforced component by thixoforming |
Publications (1)
Publication Number | Publication Date |
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WO2005052199A1 true WO2005052199A1 (fr) | 2005-06-09 |
Family
ID=34626348
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/012352 WO2005052199A1 (fr) | 2003-11-05 | 2003-11-05 | Procede de production d'un composant a matrice metallique et a renforcement par des fibres ou des particules |
Country Status (6)
Country | Link |
---|---|
US (1) | US20060021728A1 (fr) |
EP (1) | EP1685263B1 (fr) |
AT (1) | ATE402271T1 (fr) |
AU (1) | AU2003282089A1 (fr) |
DE (1) | DE50310214D1 (fr) |
WO (1) | WO2005052199A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE202006004118U1 (de) * | 2006-03-14 | 2007-08-02 | Institut für Umformtechnik Universität Stuttgart | Bauteil auf der Basis eines Hybridwerkstoffes |
DE102007042494A1 (de) * | 2007-09-03 | 2009-03-05 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Bauteil sowie seine Verwendung |
DE102009015418A1 (de) * | 2009-03-27 | 2010-09-30 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zur Herstellung eines Bauteils |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004001644A1 (de) * | 2004-01-12 | 2005-08-04 | Mtu Aero Engines Gmbh | Halbzeug aus Verbundwerkstoff und Verfahren zur Herstellung eines Halbzeugs aus Verbundwerkstoff |
JP4685357B2 (ja) * | 2004-01-20 | 2011-05-18 | 本田技研工業株式会社 | 金属基複合材製成形品の成形方法 |
SE0701358L (sv) * | 2007-06-01 | 2008-10-07 | Skf Ab | En lagerkomponent för ett rullningslager eller ett glidlager |
DE102011008646A1 (de) * | 2011-01-14 | 2012-07-19 | Recan Gmbh | Gießverfahren |
DE102011003415A1 (de) * | 2011-02-01 | 2012-08-02 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zum Herstellen eines metallischen Bauteils |
DE102014118747A1 (de) | 2014-12-16 | 2016-06-16 | Universität Stuttgart | Verfahren und Vorrichtung zur Verbindung von Faserwerkstoffen mit Metallwerkstoffen |
Citations (2)
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US6135195A (en) * | 1998-02-04 | 2000-10-24 | Korea Institute Of Science And Technology | Thixoformable SiC/2xxx Al composites |
US6151198A (en) * | 1998-11-18 | 2000-11-21 | International Business Machines Corporation | Overmolding of actuator E-block by thixotropic or semisolid forging |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
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DE3000171C2 (de) * | 1980-01-04 | 1982-04-29 | Vereinigte Aluminium-Werke Ag, 5300 Bonn | Faserverstärkter Verbundwerkstoff und Verfahren zu seiner Herstellung |
US4469757A (en) * | 1982-05-20 | 1984-09-04 | Rockwell International Corporation | Structural metal matrix composite and method for making same |
US4894088A (en) * | 1986-12-16 | 1990-01-16 | Kabushiki Kaisha Kobe Seiko Sho | Pellet for fabricating metal matrix composite and method of preparing the pellet |
US5211776A (en) * | 1989-07-17 | 1993-05-18 | General Dynamics Corp., Air Defense Systems Division | Fabrication of metal and ceramic matrix composites |
US5468358A (en) * | 1993-07-06 | 1995-11-21 | General Atomics | Fabrication of fiber-reinforced composites |
US6250364B1 (en) * | 1998-12-29 | 2001-06-26 | International Business Machines Corporation | Semi-solid processing to form disk drive components |
-
2003
- 2003-11-05 EP EP03773705A patent/EP1685263B1/fr not_active Expired - Lifetime
- 2003-11-05 WO PCT/EP2003/012352 patent/WO2005052199A1/fr active IP Right Grant
- 2003-11-05 AT AT03773705T patent/ATE402271T1/de active
- 2003-11-05 DE DE50310214T patent/DE50310214D1/de not_active Expired - Lifetime
- 2003-11-05 AU AU2003282089A patent/AU2003282089A1/en not_active Abandoned
-
2005
- 2005-07-20 US US11/186,006 patent/US20060021728A1/en not_active Abandoned
Patent Citations (2)
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US6135195A (en) * | 1998-02-04 | 2000-10-24 | Korea Institute Of Science And Technology | Thixoformable SiC/2xxx Al composites |
US6151198A (en) * | 1998-11-18 | 2000-11-21 | International Business Machines Corporation | Overmolding of actuator E-block by thixotropic or semisolid forging |
Non-Patent Citations (1)
Title |
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S.W. YOUN, C.G. KANG, P.K. SEO: "Mechanical characteristics evaluation of hollow shape part with metal matrix composites fabricated by thixoforging process", JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, vol. 130, 2002, pages 574 - 580, XP002277297 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE202006004118U1 (de) * | 2006-03-14 | 2007-08-02 | Institut für Umformtechnik Universität Stuttgart | Bauteil auf der Basis eines Hybridwerkstoffes |
DE102007042494A1 (de) * | 2007-09-03 | 2009-03-05 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Bauteil sowie seine Verwendung |
DE102007042494B4 (de) * | 2007-09-03 | 2009-09-24 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Bauteil sowie seine Verwendung |
DE102009015418A1 (de) * | 2009-03-27 | 2010-09-30 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zur Herstellung eines Bauteils |
DE102009015418B4 (de) * | 2009-03-27 | 2017-07-13 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zur Herstellung eines Bauteils |
Also Published As
Publication number | Publication date |
---|---|
EP1685263A1 (fr) | 2006-08-02 |
EP1685263B1 (fr) | 2008-07-23 |
DE50310214D1 (de) | 2008-09-04 |
US20060021728A1 (en) | 2006-02-02 |
ATE402271T1 (de) | 2008-08-15 |
AU2003282089A1 (en) | 2005-06-17 |
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