+

WO2004026993A1 - Hydro-extraction supercritique de kerogene et extraction aqueuse d'alumine et de cendre de soude avec un residu pour la production de ciment portland - Google Patents

Hydro-extraction supercritique de kerogene et extraction aqueuse d'alumine et de cendre de soude avec un residu pour la production de ciment portland Download PDF

Info

Publication number
WO2004026993A1
WO2004026993A1 PCT/US2003/013165 US0313165W WO2004026993A1 WO 2004026993 A1 WO2004026993 A1 WO 2004026993A1 US 0313165 W US0313165 W US 0313165W WO 2004026993 A1 WO2004026993 A1 WO 2004026993A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil
solvent
alumina
shale
kerogen
Prior art date
Application number
PCT/US2003/013165
Other languages
English (en)
Inventor
John S. Rendall
Original Assignee
Rendall John S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rendall John S filed Critical Rendall John S
Priority to EP03721906A priority Critical patent/EP1556460A1/fr
Priority to AU2003225192A priority patent/AU2003225192A1/en
Publication of WO2004026993A1 publication Critical patent/WO2004026993A1/fr
Priority to AU2010224338A priority patent/AU2010224338B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
    • C10G1/042—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction by the use of hydrogen-donor solvents

Definitions

  • Kerogen in oil shale is relatively insoluble in most organic solvents at or below their normal boiling points. But if the environmental pressure is increased to raise the boiling point to higher than 600°K, solvents like toluene will dissolve the kerogen. Solvent extraction separates shale oil from spent shale without vaporization. The converted hydrocarbon products result from dissolution under reaction conditions, e.g., heating the oil shale and a solvent to 380°C-540°C . Sometimes hydrogenation is also needed for good conversion. In general, solvent processes have better yields than retorting processes . Although there are a number of solvent process variations, none efficiently separate spent-shale particles from the solvent and bitumen. And apparently no prior art processes have thought to use supercritical pressures to keep the solvents in their liquid phases at temperatures that would otherwise cause them to boil away.
  • the preferred requirement of the aqueous leach circuit leaving the pressure leach section of the residue is that is contains a saturated solution of the alumina and soda ash values, adjusted by water dilution of the recycle spent liquor. E.g., after primary removal of soda ash and alumina values) .
  • the recovery of soda ash values by crystallization as a mono hydrate is preferable at about 150°C as is practices industrially today, (ref. Isonex, June 11, 1997)
  • the alumina values are then recovered with an alumina to sodium carbonate ratio of about 0.7 and an alumina , concentration around 165 grams-per-liter as is practices in the Bayer process today (in notes of Don Donaldson 3/11/97) .
  • the alumina (as aluminum trihydrate) is precipitated by sparging with C0 2 .
  • a liquor 234 at around 70°C is then transferred to a precipitator-filter-washer 236.
  • the feed preferably has concentration of about 30 grams-per-liter alumina, e.g., as aluminum trihydrate fines with 50% less than 44-microns.
  • concentration of alumina increases from 165-grams-per- liter to 195-grams-per-liter of the aluminum for precipitation at 70 °C. This leaves a aluminum hydroxide residue with a concentration of about 80-grams-per-liter.
  • C0 2 is introduced under pressure at temperatures above 100 °C after the sodium carbonate monohydrate Na 2 C0 3 H 2 0 is removed at around 100°C to 200°C. Such precipitates aluminum hydroxide.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

La présente invention a trait à un procédé et un appareil pour l'extraction de produits hydrocarbonés, d'alumine et de cendre de soude à partir de schistes bitumineux comprenant diverses quantités de tels produits chimiques, tous basés sur l'extraction par solvant de la majeure partie d'hydrocarbures à des températures d'environ 400 °C. L'invention permet la lixiviation de valeurs d'alumine et de cendre de soude par lixiviation aqueuse au carbonate de sodium à des températures réduites d'environ 150 °C avec une pression réduite correspondante. Les valeurs de cendre de soude monohydraté sont précipitées du liqueur de lixiviation à environ 100 °C avec les valeurs d'alumine précipitées au moyen de CO2. En variante, le trihydrate d'aluminium fin recyclé à 65° est utilisé pour produire de l'alumine. L'hydroxyde d'aluminium est converti en alumine acide par un flux de recyclage acide qui dissout l'alumine de manière à éliminer par filtration tout contaminant de silice. Du sulfate d'aluminium de base est ensuite précipité à environ 100 °C et 250 psi pour une calcination ultérieure à environ 900 °C. Cela produit de l'alumine et des gaz d'oxyde de sulfate sont recyclés via une installation d'acide sulfurique.
PCT/US2003/013165 2000-01-24 2003-04-30 Hydro-extraction supercritique de kerogene et extraction aqueuse d'alumine et de cendre de soude avec un residu pour la production de ciment portland WO2004026993A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP03721906A EP1556460A1 (fr) 2002-09-19 2003-04-30 Hydro-extraction supercritique de kerogene et extraction aqueuse d'alumine et de cendre de soude avec un residu pour la production de ciment portland
AU2003225192A AU2003225192A1 (en) 2002-09-19 2003-04-30 Supercritical hydro extraction of kerogen and aqueous extraction of alumina and soda ash with a residue for portland cement production
AU2010224338A AU2010224338B2 (en) 2002-09-19 2010-09-20 Supercritical hydro extraction of kerogen and aqueous extraction of alumina and soda ash with a residue for portland cement production

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US49025400A 2000-01-24 2000-01-24
US10/247,868 2002-09-19
US10/247,868 US20030098262A1 (en) 2000-01-24 2002-09-19 Supercritical hydro extraction of kerogen and aqueous extraction of alumina and soda ASH with a residue for portland cement production

Publications (1)

Publication Number Publication Date
WO2004026993A1 true WO2004026993A1 (fr) 2004-04-01

Family

ID=34272174

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/013165 WO2004026993A1 (fr) 2000-01-24 2003-04-30 Hydro-extraction supercritique de kerogene et extraction aqueuse d'alumine et de cendre de soude avec un residu pour la production de ciment portland

Country Status (6)

Country Link
US (2) US20030098262A1 (fr)
EP (1) EP1556460A1 (fr)
CN (1) CN1688672A (fr)
AU (3) AU779333B2 (fr)
RU (1) RU2312126C2 (fr)
WO (1) WO2004026993A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008036514A2 (fr) * 2006-09-20 2008-03-27 Rp International Pty Limited Hydroextraction supercritique de kerogene a partir de minerais de schistes bitumineux
CN111954708A (zh) * 2018-04-11 2020-11-17 沙特阿拉伯石油公司 与减粘裂化炉一体化的超临界水方法

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7662275B2 (en) * 2006-05-19 2010-02-16 Colorado School Of Mines Methods of managing water in oil shale development
US8205674B2 (en) 2006-07-25 2012-06-26 Mountain West Energy Inc. Apparatus, system, and method for in-situ extraction of hydrocarbons
WO2008061304A1 (fr) * 2006-11-21 2008-05-29 Technological Resources Pty. Limited Extraction d'hydrocarbures à partir de schiste bitumineux
US7674369B2 (en) * 2006-12-29 2010-03-09 Chevron U.S.A. Inc. Process for recovering ultrafine solids from a hydrocarbon liquid
US20090221417A1 (en) * 2007-06-05 2009-09-03 Alex Magdics Catalyst slurry recycle
US8002972B2 (en) * 2007-10-12 2011-08-23 Enshale, Inc. Petroleum products from oil shale
US8221710B2 (en) * 2007-11-28 2012-07-17 Sherritt International Corporation Recovering metals from complex metal sulfides
EA201100292A1 (ru) * 2008-07-28 2011-12-30 Форбс Ойл Энд Гэс Пти Лтд. Способ сжижения углеродсодержащего материала с получением жидкого углеводорода
CA2756556A1 (fr) * 2009-03-25 2010-09-30 Chevron U.S.A. Inc. Procede de recuperation de metaux de catalyseurs epuises contenant des residus de liquefaction du charbon
CN101871339B (zh) * 2010-06-28 2013-03-27 吉林大学 一种地下原位提取油页岩中烃类化合物的方法
US8894846B2 (en) * 2010-12-23 2014-11-25 Stephen Lee Yarbro Using supercritical fluids to refine hydrocarbons
WO2014200167A1 (fr) * 2013-06-12 2014-12-18 주식회사 시알아이 Appareil et procédé d'alimentation en chaleur/mise sous pression en continu permettant d'acheminer et d'évacuer en continu des boues de schistes bitumineux chauffées/sous pression en direction/hors d'un réacteur d'extraction de kérogène
KR20140144850A (ko) * 2013-06-12 2014-12-22 주식회사 시알아이 오일셰일 추출 잔류물의 재활용을 위한 휘발물질의 증발 시스템 및 이를 사용한 오일셰일 추출 잔류물의 재활용 방법
CN110940790B (zh) * 2018-09-21 2022-08-12 中国石油化工股份有限公司 一种判识高效烃源岩的方法及装置
CN111174210B (zh) * 2020-01-17 2024-08-06 北京云水浩瑞环境科技有限公司 处理固体废弃物的系统和方法
CN112391190B (zh) * 2020-11-17 2022-02-25 西南石油大学 Co2/n2开关型双循环萃取工艺及其应用
CN115093875B (zh) * 2022-07-14 2022-11-04 太原理工大学 通过连续催化热解提高油页岩热解油品质的方法及设备
CN114989854B (zh) * 2022-07-14 2022-11-01 太原理工大学 提高油页岩热解轻质油产率的方法
CN114989852B (zh) * 2022-07-14 2022-10-28 太原理工大学 提高油页岩热解油产率的方法及设备

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3516787A (en) * 1966-08-10 1970-06-23 Sinclair Research Inc Recovery of oil and aluminum from oil shale
DE1949778A1 (de) * 1969-10-02 1971-04-22 Vaw Ver Aluminium Werke Ag Verfahren zur Entfernung von schwerloeslichen Krusten aus Bauxit-Aufschlussanlagen,mit Ausnahme von Rohraufschlussanlagen
US3821353A (en) * 1968-05-06 1974-06-28 Superior Oil Co Shale oil and mineral recovery process
US4238315A (en) * 1978-10-31 1980-12-09 Gulf Research & Development Company Recovery of oil from oil shale
US4325803A (en) * 1980-08-07 1982-04-20 Chem Systems Inc. Process for hydrogenation/extraction of organics contained in rock
US4390411A (en) * 1981-04-02 1983-06-28 Phillips Petroleum Company Recovery of hydrocarbon values from low organic carbon content carbonaceous materials via hydrogenation and supercritical extraction
US4541913A (en) * 1981-10-16 1985-09-17 Coal Industry (Patents) Limited Process for hydrocracking supercritical gas extracts of carbonaceous material
US4737267A (en) * 1986-11-12 1988-04-12 Duo-Ex Coproration Oil shale processing apparatus and method

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3516878A (en) * 1967-01-13 1970-06-23 Atomic Energy Commission Ultra-high-strength pressure vessel
US3607716A (en) * 1970-01-09 1971-09-21 Kerr Mc Gee Chem Corp Fractionation of coal liquefaction products in a mixture of heavy and light organic solvents
US4521293A (en) * 1983-01-11 1985-06-04 James Scinta Oil recovery
US4551224A (en) * 1983-12-16 1985-11-05 Texaco Inc. Coal liquefaction process
JPH0753965A (ja) * 1993-08-09 1995-02-28 Nkk Corp 石炭の液化方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3516787A (en) * 1966-08-10 1970-06-23 Sinclair Research Inc Recovery of oil and aluminum from oil shale
US3821353A (en) * 1968-05-06 1974-06-28 Superior Oil Co Shale oil and mineral recovery process
DE1949778A1 (de) * 1969-10-02 1971-04-22 Vaw Ver Aluminium Werke Ag Verfahren zur Entfernung von schwerloeslichen Krusten aus Bauxit-Aufschlussanlagen,mit Ausnahme von Rohraufschlussanlagen
US4238315A (en) * 1978-10-31 1980-12-09 Gulf Research & Development Company Recovery of oil from oil shale
US4325803A (en) * 1980-08-07 1982-04-20 Chem Systems Inc. Process for hydrogenation/extraction of organics contained in rock
US4390411A (en) * 1981-04-02 1983-06-28 Phillips Petroleum Company Recovery of hydrocarbon values from low organic carbon content carbonaceous materials via hydrogenation and supercritical extraction
US4541913A (en) * 1981-10-16 1985-09-17 Coal Industry (Patents) Limited Process for hydrocracking supercritical gas extracts of carbonaceous material
US4737267A (en) * 1986-11-12 1988-04-12 Duo-Ex Coproration Oil shale processing apparatus and method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008036514A2 (fr) * 2006-09-20 2008-03-27 Rp International Pty Limited Hydroextraction supercritique de kerogene a partir de minerais de schistes bitumineux
WO2008036514A3 (fr) * 2006-09-20 2009-03-12 Rp Internat Pty Ltd Hydroextraction supercritique de kerogene a partir de minerais de schistes bitumineux
AU2007200890B2 (en) * 2006-09-20 2011-12-01 Rp International Pty Ltd Supercritical Hydroextraction of Kerogen From Oil Shale Ores
CN111954708A (zh) * 2018-04-11 2020-11-17 沙特阿拉伯石油公司 与减粘裂化炉一体化的超临界水方法

Also Published As

Publication number Publication date
US20030098262A1 (en) 2003-05-29
EP1556460A1 (fr) 2005-07-27
AU779333B2 (en) 2005-01-20
AU2003225192A1 (en) 2004-04-08
AU2010224338B2 (en) 2011-07-14
US20060180503A1 (en) 2006-08-17
AU2010224338A1 (en) 2010-10-14
CN1688672A (zh) 2005-10-26
RU2005109907A (ru) 2006-01-20
RU2312126C2 (ru) 2007-12-10
AU1486100A (en) 2001-07-26

Similar Documents

Publication Publication Date Title
AU2010224338B2 (en) Supercritical hydro extraction of kerogen and aqueous extraction of alumina and soda ash with a residue for portland cement production
AU2007200890B2 (en) Supercritical Hydroextraction of Kerogen From Oil Shale Ores
US4737267A (en) Oil shale processing apparatus and method
KR101629753B1 (ko) 탄화수소 함유 재료로부터 탄화수소를 추출 및/또는 탄화수소 함유 재료를 가공하는 방법
CA2833353C (fr) Procedes integres pour la recuperation des hydrocarbures dans les sable bitumineux
CA2913617C (fr) Procedes integres pour la recuperation des hydrocarbures dans les sables bitumineux
UA110316C2 (en) Hydrocarbons extraction of hydrocarbons containing materials
KR20100107459A (ko) 고온의 가압된 물 및 회수 유체에 의하여 전체 원유를 개량하기 위한 공정
WO2008061304A1 (fr) Extraction d'hydrocarbures à partir de schiste bitumineux
US20140366432A1 (en) Process Flow Sheet for Pre-Treatment of High Ash Coal to Produce Clean Coal
US6936159B1 (en) Process for recovering hydrocarbons from a carbon containing material
EP1361262A1 (fr) Installation et procédé pour l' hydroextraction sous conditions supercritiques de schiste bitumineux
US9441175B2 (en) Process for production of low ash clean coal from high ash coal with total solvent recovery
CN102203216A (zh) 液化可燃性矿物的方法
US9505989B2 (en) Processing a hydrocarbon stream using supercritical water
AU2020202042A1 (en) Method and apparatus for preparing additive for coke
AU1505001A (en) A process for recovering hydrocarbons from a carbon containing material
JPS6247918B2 (fr)

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2003225192

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 20038236621

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2003721906

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 2005109907

Country of ref document: RU

Kind code of ref document: A

WWP Wipo information: published in national office

Ref document number: 2003721906

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: JP

WWW Wipo information: withdrawn in national office

Country of ref document: JP

点击 这是indexloc提供的php浏览器服务，不要输入任何密码和下载