+

WO2004079840A3 - Three-dimensional flow-through electrode and electrochemical cell - Google Patents

Three-dimensional flow-through electrode and electrochemical cell Download PDF

Info

Publication number
WO2004079840A3
WO2004079840A3 PCT/US2004/005902 US2004005902W WO2004079840A3 WO 2004079840 A3 WO2004079840 A3 WO 2004079840A3 US 2004005902 W US2004005902 W US 2004005902W WO 2004079840 A3 WO2004079840 A3 WO 2004079840A3
Authority
WO
WIPO (PCT)
Prior art keywords
electrode
flow
dimensional flow
chemical
graphite
Prior art date
Application number
PCT/US2004/005902
Other languages
French (fr)
Other versions
WO2004079840A2 (en
Inventor
Arden L Larson
Original Assignee
Evat Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evat Inc filed Critical Evat Inc
Publication of WO2004079840A2 publication Critical patent/WO2004079840A2/en
Publication of WO2004079840A3 publication Critical patent/WO2004079840A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/46109—Electrodes
    • C02F1/46114—Electrodes in particulate form or with conductive and/or non conductive particles between them
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/02—Apparatus therefor
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/045—Leaching using electrochemical processes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60—Constructional parts of cells
    • C25B9/65—Means for supplying current; Electrode connections; Electric inter-cell connections
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02—Electrodes; Connections thereof
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • C02F1/4674—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/46109—Electrodes
    • C02F2001/46152—Electrodes characterised by the shape or form
    • C02F2001/46157—Perforated or foraminous electrodes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/4619—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/18—Removal of treatment agents after treatment
    • C02F2303/185—The treatment agent being halogen or a halogenated compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/30—Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Abstract

A three-dimensional flow-through electrode includes an efficient current feeding mechanism including current feeders (2) comprising rods of conductive material, such as graphite, which are inserted at predetermined spacing into a flow-through electrode (1), such as a block of graphite felt. The current feeders are appropriately spaced throughout the electrode to allow for efficient current distribution. The large surface area provided by the flow-through electrode makes it possible to expose solutions or gases to relatively large areas of electrical charges, intituting electrical chemical reactions. A number of electrolytic chemical processes using the electrolytic cells include water treatment, chemical processing and production, hydro-metallurgical applications, and environmental clean-up. A method to replace the use of cyanide in gold and silver processing operations is also provided.
PCT/US2004/005902 2003-02-28 2004-02-27 Three-dimensional flow-through electrode and electrochemical cell WO2004079840A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US45089103P 2003-02-28 2003-02-28
US60/450,891 2003-02-28

Publications (2)

Publication Number Publication Date
WO2004079840A2 WO2004079840A2 (en) 2004-09-16
WO2004079840A3 true WO2004079840A3 (en) 2004-10-28

Family

ID=32962543

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/005902 WO2004079840A2 (en) 2003-02-28 2004-02-27 Three-dimensional flow-through electrode and electrochemical cell

Country Status (2)

Country Link
US (1) US20040168909A1 (en)
WO (1) WO2004079840A2 (en)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5140218B2 (en) 2001-09-14 2013-02-06 有限会社コヒーレントテクノロジー Electrolyzer for producing charged anode water suitable for surface cleaning and surface treatment, method for producing the same, and method of use
MXPA03007923A (en) 2001-12-05 2005-02-17 Micromed Lab Inc Method and apparatus for producing negative and positive oxidative reductive potential (orp) water.
US7378011B2 (en) 2003-07-28 2008-05-27 Phelps Dodge Corporation Method and apparatus for electrowinning copper using the ferrous/ferric anode reaction
US7494580B2 (en) * 2003-07-28 2009-02-24 Phelps Dodge Corporation System and method for producing copper powder by electrowinning using the ferrous/ferric anode reaction
US9168318B2 (en) 2003-12-30 2015-10-27 Oculus Innovative Sciences, Inc. Oxidative reductive potential water solution and methods of using the same
US7378010B2 (en) * 2004-07-22 2008-05-27 Phelps Dodge Corporation System and method for producing copper powder by electrowinning in a flow-through electrowinning cell
US7393438B2 (en) * 2004-07-22 2008-07-01 Phelps Dodge Corporation Apparatus for producing metal powder by electrowinning
US7452455B2 (en) * 2004-07-22 2008-11-18 Phelps Dodge Corporation System and method for producing metal powder by electrowinning
US7351331B2 (en) * 2004-09-08 2008-04-01 Pioneer H20 Technologies, Inc. Recreational spa including a bromine generator
ES2701153T3 (en) 2005-03-23 2019-02-21 Sonoma Pharmaceuticals Inc Method to treat skin ulcers using a solution with water of oxidative reductive potential
JP5907645B2 (en) 2005-05-02 2016-04-26 オキュラス イノヴェイティヴ サイエンシズ、インコーポレイテッド Usage of redox potential aqueous solution in dental applications
JP4907950B2 (en) * 2005-10-31 2012-04-04 住友大阪セメント株式会社 Method and apparatus for removing metal from waste water
WO2007085018A2 (en) 2006-01-20 2007-07-26 Oculus Innovative Sciences, Inc. Methods of treating or preventing inflammation and hypersensitivity with oxidative reductive potential water solution
US20100089763A1 (en) * 2006-09-26 2010-04-15 Brackenbury Darron Devices and methods of copper recovery
US20080116146A1 (en) * 2006-11-17 2008-05-22 Miox Corproation Water purification system
US20110042202A1 (en) * 2007-04-22 2011-02-24 Woody America Llc Apparatus and Methods for Dispensing Solutions
JP4785800B2 (en) * 2007-07-17 2011-10-05 三洋電機株式会社 Water treatment equipment
US8273237B2 (en) 2008-01-17 2012-09-25 Freeport-Mcmoran Corporation Method and apparatus for electrowinning copper using an atmospheric leach with ferrous/ferric anode reaction electrowinning
MX2008008671A (en) 2008-07-02 2010-01-04 Univ Autonoma Metropolitana Electrochemical reactor of the press filter-type for the recovery of gold (au) and silver (ag) in powder.
JP6033082B2 (en) 2009-06-15 2016-11-30 オキュラス イノヴェイティヴ サイエンシズ、インコーポレイテッド Solution containing hypochlorous acid and method of using the same
EP2649014B1 (en) 2010-12-06 2017-10-25 Council of Scientific & Industrial Research Carbon bed electrolyser for treatment of liquid effluents and a process thereof
KR101333686B1 (en) * 2011-11-25 2013-11-27 한국지질자원연구원 System for treating acid mine drainage
US11046596B2 (en) 2012-10-25 2021-06-29 Hydrus Technology Pty. Ltd. Electrochemical liquid treatment apparatus
US9617646B2 (en) 2012-11-14 2017-04-11 Elwha Llc Comminution water contaminant removal system
MX2016014770A (en) 2014-05-12 2017-05-25 Summit Mining Int Inc SALMUERA LEADING PROCESS FOR THE RECOVERY OF VALUABLE METALS OF OXIDE MATERIALS.
US10850994B2 (en) 2014-05-23 2020-12-01 Hydrus Technology Pty. Ltd. Electrochemical liquid treatment apparatus
US11046595B2 (en) 2014-05-23 2021-06-29 Hydrus Technology Pty. Ltd. Electrochemical treatment methods
WO2016040244A2 (en) * 2014-09-09 2016-03-17 JALBOUT, Abraham, Fouad A system, apparatus, and process for leaching metal and storing thermal energy during metal extraction
US10844494B2 (en) * 2015-09-18 2020-11-24 The Trustees Of Columbia University In The City Of New York Membraneless electrochemical flow-through reactor
CN105923713B (en) * 2016-05-25 2019-04-12 广东工业大学 A kind of three-diemsnional electrode water treatment system
US10323331B2 (en) * 2016-12-29 2019-06-18 Industrial Technology Research Institute Valuable metal selectively adsorbing electrode and method for selectively recovering valuable metals
CN106746054A (en) * 2017-01-16 2017-05-31 北京化工大学 A kind of method that three-dimensional electrolysis process galvanograph waste water
US11827952B2 (en) * 2019-03-13 2023-11-28 Bromine Compounds Ltd. Process for recovering gold from ores

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3840365A (en) * 1970-04-24 1974-10-08 P Kayser Metal recovery process
US3994789A (en) * 1974-10-02 1976-11-30 Progressive Scientific Associates, Inc. Galvanic cementation process
US4263118A (en) * 1979-07-18 1981-04-21 August K. Reis Disinfection device
US4278521A (en) * 1978-05-30 1981-07-14 Dechema Electrochemical cell
US5770037A (en) * 1996-11-21 1998-06-23 Konica Corporation Water processing method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3764490A (en) * 1972-04-20 1973-10-09 W Chambers Method of recovering metals
US5882502A (en) * 1992-04-01 1999-03-16 Rmg Services Pty Ltd. Electrochemical system and method
US5569370A (en) * 1992-04-01 1996-10-29 Rmg Services Pty. Ltd. Electrochemical system for recovery of metals from their compounds

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3840365A (en) * 1970-04-24 1974-10-08 P Kayser Metal recovery process
US3994789A (en) * 1974-10-02 1976-11-30 Progressive Scientific Associates, Inc. Galvanic cementation process
US4278521A (en) * 1978-05-30 1981-07-14 Dechema Electrochemical cell
US4263118A (en) * 1979-07-18 1981-04-21 August K. Reis Disinfection device
US5770037A (en) * 1996-11-21 1998-06-23 Konica Corporation Water processing method

Also Published As

Publication number Publication date
US20040168909A1 (en) 2004-09-02
WO2004079840A2 (en) 2004-09-16

Similar Documents

Publication Publication Date Title
WO2004079840A3 (en) Three-dimensional flow-through electrode and electrochemical cell
Wang et al. Recovery of high-purity silver from spent silver oxide batteries by sulfuric acid leaching and electrowinning
EP0071443A1 (en) Device for waste water treatment
Wang et al. Recovery of silver from dilute effluents via electrodeposition and redox replacement
JP5502983B2 (en) Method for obtaining copper powder and copper nanopowder from industrial electrolytes including waste industrial electrolytes
CA2204858A1 (en) Process for making copper metal powder, copper oxides and copper foil
ATE215134T1 (en) INTENSIVE BUT ENERGY EFFICIENT PROCESS FOR THE ELECTRICAL EXTRACTION OF ZINC IN MOBILE PARTICLE BEDS
IL95832A0 (en) Fibril aggregates,their production and electro-chemical cells containing them
Lim et al. Recovery of silver metal and electric power generation using a microbial fuel cell
Simonsson A flow-by packed-bed electrode for removal of metal ions from waste waters
JP2010532818A5 (en)
Diaz et al. Optimization of the electrochemical extraction and recovery of metals from electronic waste using response surface methodology
ATE283384T1 (en) PRODUCTION PROCESS FOR ELECTRICAL CONDUCTORS AND THEIR USE FOR SOLAR COLLECTORS AND ELECTROCHEMICAL CELLS
EP0013572A3 (en) Electrocatalyst, electrode comprising the electrocatalyst, use of the electrode and electrolysis process
CA1132089A (en) Electrochemical cell
KR101365694B1 (en) Recovery of silver from wastewater coupled with power generation using a microbial fuel cell
GB2368349A (en) Electrolytic extraction of metals; recycling
DE69602907D1 (en) Process for the electrolysis of silver in Moebius cells
Rudnik et al. Study on copper recovery from smelted low-grade e-scrap using hydrometallurgical methods
DE59107541D1 (en) Method and device for the electrolytic discharge of metals from a solution containing metal ions and electrode for carrying out the method
RU2258768C1 (en) Method of extraction of gold and silver from polymetallic raw material
Lu et al. Anodic behaviour of alkaline solutions containing copper cyanide and sulfite on the graphite anode
CN110983048A (en) A method of recovering metallic tin and lead from waste circuit boards
CN204570062U (en) Reclaim the electrolyzer of valuable metal
JP2010271236A (en) Method and apparatus for electrochemical measurement of arsenic

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
点击 这是indexloc提供的php浏览器服务，不要输入任何密码和下载