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WO2004058864A3 - Hydrophilic ester polyurethane foams - Google Patents

Hydrophilic ester polyurethane foams Download PDF

Info

Publication number
WO2004058864A3
WO2004058864A3 PCT/US2003/041032 US0341032W WO2004058864A3 WO 2004058864 A3 WO2004058864 A3 WO 2004058864A3 US 0341032 W US0341032 W US 0341032W WO 2004058864 A3 WO2004058864 A3 WO 2004058864A3
Authority
WO
WIPO (PCT)
Prior art keywords
ester polyurethane
water
foam
polyurethane foams
hydrophilic ester
Prior art date
Application number
PCT/US2003/041032
Other languages
French (fr)
Other versions
WO2004058864A2 (en
Inventor
Sharon A Free
Charles V Rose
Original Assignee
Foamex Lp
Sharon A Free
Charles V Rose
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foamex Lp, Sharon A Free, Charles V Rose filed Critical Foamex Lp
Priority to EP03814339A priority Critical patent/EP1597307A2/en
Priority to JP2004563979A priority patent/JP4589730B2/en
Priority to AU2003300298A priority patent/AU2003300298A1/en
Publication of WO2004058864A2 publication Critical patent/WO2004058864A2/en
Publication of WO2004058864A3 publication Critical patent/WO2004058864A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36After-treatment
    • C08J9/38Destruction of cell membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/56After-treatment of articles, e.g. for altering the shape
    • B29C44/5627After-treatment of articles, e.g. for altering the shape by mechanical deformation, e.g. crushing, embossing, stretching
    • B29C44/5636After-treatment of articles, e.g. for altering the shape by mechanical deformation, e.g. crushing, embossing, stretching with the addition of heat
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0008Foam properties flexible
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0041Foam properties having specified density
    • C08G2110/005< 50kg/m3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0083Foam properties prepared using water as the sole blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Cell Biology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

An ester polyurethane foam is prepared by reacting a mixture of one or more polyester polyols with one or more isocyanates and one or more silicone surfactants in the presence of a blowing agent, such as water, and other additives, such as catalysts. The cured foam is chemically treated in a caustic solution and is then felted (compressed under heat and pressure) to form a hydrophilic ester polyurethane foam having a water absorption rate of at least 30 pounds of water per square foot per minute (1.44 kPa/min). The foam also has greater water holding capacity and wet strength than cellulose.
PCT/US2003/041032 2002-12-23 2003-12-23 Hydrophilic ester polyurethane foams WO2004058864A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP03814339A EP1597307A2 (en) 2002-12-23 2003-12-23 Hydrophilic ester polyurethane foams
JP2004563979A JP4589730B2 (en) 2002-12-23 2003-12-23 Hydrophilic ester polyurethane foam
AU2003300298A AU2003300298A1 (en) 2002-12-23 2003-12-23 Hydrophilic ester polyurethane foams

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US43527702P 2002-12-23 2002-12-23
US60/435,277 2002-12-23

Publications (2)

Publication Number Publication Date
WO2004058864A2 WO2004058864A2 (en) 2004-07-15
WO2004058864A3 true WO2004058864A3 (en) 2004-09-30

Family

ID=32682210

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/041032 WO2004058864A2 (en) 2002-12-23 2003-12-23 Hydrophilic ester polyurethane foams

Country Status (4)

Country Link
EP (1) EP1597307A2 (en)
JP (1) JP4589730B2 (en)
AU (1) AU2003300298A1 (en)
WO (1) WO2004058864A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015537098A (en) * 2012-12-07 2015-12-24 イノアック ユーエスエー インク Hydro-retarded polyurethane foam with hydrophilic properties that can be used to produce molten metal filters

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB789481A (en) * 1954-12-08 1958-01-22 Johann Bauer Process for the production of foam materials
GB858127A (en) * 1956-06-15 1961-01-04 Scott Paper Co Polymer foam modification
US6020390A (en) * 1996-11-08 2000-02-01 Imperial Chemical Industries Plc Process for making flexible polyurethane foams
US6045741A (en) * 1996-07-10 2000-04-04 Bridgestone Corporation Preparation of flexible polyurethane foam

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2702772B2 (en) * 1989-04-28 1998-01-26 花王株式会社 Method for producing molded article of water-absorbing polyurethane foam
JPH03239736A (en) * 1990-02-19 1991-10-25 Kao Corp Production of water-absorptive polyurethane foam
JP2841011B2 (en) * 1993-06-15 1998-12-24 三洋化成工業株式会社 Thermoforming material and thermoforming method
DE4341973A1 (en) * 1993-12-09 1995-06-14 Basf Ag Process for the production of compact or cellular polyurethanes, polyisocyanate compositions containing urethane groups that can be used for this purpose and their use
JP3733991B2 (en) * 1996-07-10 2006-01-11 株式会社ブリヂストン Method for producing flexible polyurethane foam
JP4053635B2 (en) * 1997-11-17 2008-02-27 株式会社イノアックコーポレーション Antibacterial polyurethane resin and method for producing the same
JP2002012646A (en) * 2000-06-29 2002-01-15 Bridgestone Corp Sheet material for food
US6756416B2 (en) * 2002-02-12 2004-06-29 Foamex L.P. Hydrophilic ester polyurethane foams

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB789481A (en) * 1954-12-08 1958-01-22 Johann Bauer Process for the production of foam materials
GB858127A (en) * 1956-06-15 1961-01-04 Scott Paper Co Polymer foam modification
US6045741A (en) * 1996-07-10 2000-04-04 Bridgestone Corporation Preparation of flexible polyurethane foam
US6020390A (en) * 1996-11-08 2000-02-01 Imperial Chemical Industries Plc Process for making flexible polyurethane foams

Also Published As

Publication number Publication date
WO2004058864A2 (en) 2004-07-15
AU2003300298A1 (en) 2004-07-22
EP1597307A2 (en) 2005-11-23
AU2003300298A8 (en) 2004-07-22
JP2006511654A (en) 2006-04-06
JP4589730B2 (en) 2010-12-01

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