WO2003035704A1 - Process for polymerization of olefins - Google Patents
Process for polymerization of olefins Download PDFInfo
- Publication number
- WO2003035704A1 WO2003035704A1 PCT/JP2002/010677 JP0210677W WO03035704A1 WO 2003035704 A1 WO2003035704 A1 WO 2003035704A1 JP 0210677 W JP0210677 W JP 0210677W WO 03035704 A1 WO03035704 A1 WO 03035704A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- compound
- group
- reacting
- periodic table
- olefins
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 4
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 150000002901 organomagnesium compounds Chemical class 0.000 abstract 2
- 230000000737 periodic effect Effects 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- -1 siloxane compounds Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/61—Pretreating the metal or compound covered by group C08F4/60 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/612—Pretreating with metals or metal-containing compounds
- C08F4/618—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, provided for in at least two of the groups C08F4/613 - C08F4/617
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02802014.7A EP1449853B1 (en) | 2001-10-19 | 2002-10-15 | Process for polymerization of olefins |
KR1020047005674A KR100594336B1 (ko) | 2001-10-19 | 2002-10-15 | 올레핀 중합 방법 |
US10/492,907 US6956002B2 (en) | 2001-10-19 | 2002-10-15 | Process for polymerization of olefins |
JP2003538217A JP3865314B2 (ja) | 2001-10-19 | 2002-10-15 | オレフィンの重合方法 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001322620 | 2001-10-19 | ||
JP2001-322620 | 2001-10-19 | ||
JP2001375541 | 2001-12-10 | ||
JP2001-375541 | 2001-12-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003035704A1 true WO2003035704A1 (en) | 2003-05-01 |
Family
ID=26624005
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2002/010677 WO2003035704A1 (en) | 2001-10-19 | 2002-10-15 | Process for polymerization of olefins |
Country Status (8)
Country | Link |
---|---|
US (1) | US6956002B2 (ja) |
EP (1) | EP1449853B1 (ja) |
JP (1) | JP3865314B2 (ja) |
KR (1) | KR100594336B1 (ja) |
CN (1) | CN100434444C (ja) |
MY (1) | MY134308A (ja) |
TW (1) | TWI229087B (ja) |
WO (1) | WO2003035704A1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006273977A (ja) * | 2005-03-29 | 2006-10-12 | Asahi Kasei Chemicals Corp | オレフィン重合用触媒およびオレフィンの重合方法 |
JP2006321990A (ja) * | 2005-04-22 | 2006-11-30 | Asahi Kasei Chemicals Corp | 容器包装用エチレン系樹脂 |
JP2007162014A (ja) * | 2005-11-17 | 2007-06-28 | Asahi Kasei Chemicals Corp | オレフィン重合用触媒およびオレフィンの重合方法 |
JP2007169611A (ja) * | 2005-11-22 | 2007-07-05 | Asahi Kasei Chemicals Corp | オレフィン重合体の製造方法 |
JP2015124285A (ja) * | 2013-12-26 | 2015-07-06 | 旭化成ケミカルズ株式会社 | ポリエチレンの製造方法 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0501100D0 (en) * | 2005-01-19 | 2005-02-23 | Bp Chem Int Ltd | Process |
WO2007076398A2 (en) * | 2005-12-21 | 2007-07-05 | Albemarle Corporation | Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins |
WO2020101372A1 (ko) * | 2018-11-14 | 2020-05-22 | 롯데케미칼 주식회사 | 올레핀 중합용 담지 촉매 및 이를 이용하는 폴리올레핀의 제조방법 |
BR112022001387A2 (pt) * | 2019-07-31 | 2022-03-22 | Dow Global Technologies Llc | Sistema de catalisador, e, processo de polimerização |
FR3104585B1 (fr) * | 2019-12-17 | 2021-12-03 | Michelin & Cie | Système catalytique à base d’un métallocène et d’un diorganomagnésien |
FR3104584B1 (fr) * | 2019-12-17 | 2021-12-03 | Michelin & Cie | Composé diorganomagnésien asymétrique |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1991014713A1 (en) * | 1990-03-20 | 1991-10-03 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
JPH10298222A (ja) * | 1997-04-25 | 1998-11-10 | Nippon Polyolefin Kk | ポリオレフィン製造用触媒成分およびポリオレフィン製造用触媒 |
JPH11199618A (ja) * | 1998-01-08 | 1999-07-27 | Asahi Chem Ind Co Ltd | 新規重合用触媒及び該触媒を用いた共重合体の製造方法 |
WO1999067302A1 (de) * | 1998-06-25 | 1999-12-29 | Elenac Gmbh | Verfahren zur herstellung eines geträgerten katalysatorsystems |
WO2000050469A1 (fr) * | 1999-02-26 | 2000-08-31 | Idemitsu Petrochemical Co., Ltd. | Catalyseur pour copolymerisation d'olefine/styrene et procede de production de copolymere d'olefine/styrene |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5241025A (en) * | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
ATE137770T1 (de) | 1989-10-10 | 1996-05-15 | Fina Technology | Metallocenkatalysator mit lewissäure und alkylaluminium |
EP0426638B2 (en) | 1989-10-30 | 2005-03-02 | Fina Technology, Inc. | Addition of aluminium alkyl for improved metallocene catalyst |
JP3414769B2 (ja) | 1991-05-01 | 2003-06-09 | 日本ポリケム株式会社 | オレフィン重合用触媒およびこれを用いたオレフィン重合体の製造方法 |
US6143845A (en) * | 1992-05-28 | 2000-11-07 | Idemitsu Petrochemical Co., Ltd. | Process for producing polyolefin |
JP3299318B2 (ja) | 1992-10-29 | 2002-07-08 | 三菱化学株式会社 | オレフィン重合用触媒及びオレフィン重合体の製造方法 |
JP3572328B2 (ja) | 1995-06-16 | 2004-09-29 | 東ソー株式会社 | エチレン系重合体の製造方法 |
AU1567297A (en) * | 1995-12-28 | 1997-07-28 | Lyondell Petrochemical Company | High efficiency catalyst systems |
KR20000068220A (ko) * | 1996-08-21 | 2000-11-25 | 우에다 마사히로 | 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 폴리올레핀의 제조방법 |
KR20010032116A (ko) * | 1997-12-01 | 2001-04-16 | 보 구스타프쏜 | 수분 흡수 장치 |
JPH11269222A (ja) | 1998-03-20 | 1999-10-05 | Idemitsu Petrochem Co Ltd | オレフィン重合体製造触媒およびオレフィン重合体の 製造方法 |
US6211311B1 (en) * | 1999-05-25 | 2001-04-03 | Equistar Chemicals, L.P. | Supported olefin polymerization catalysts |
-
2002
- 2002-10-15 EP EP02802014.7A patent/EP1449853B1/en not_active Expired - Lifetime
- 2002-10-15 CN CNB028205359A patent/CN100434444C/zh not_active Expired - Lifetime
- 2002-10-15 US US10/492,907 patent/US6956002B2/en not_active Expired - Lifetime
- 2002-10-15 WO PCT/JP2002/010677 patent/WO2003035704A1/ja active Application Filing
- 2002-10-15 JP JP2003538217A patent/JP3865314B2/ja not_active Expired - Lifetime
- 2002-10-15 KR KR1020047005674A patent/KR100594336B1/ko not_active Expired - Lifetime
- 2002-10-16 TW TW091123851A patent/TWI229087B/zh not_active IP Right Cessation
- 2002-10-17 MY MYPI20023874A patent/MY134308A/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1991014713A1 (en) * | 1990-03-20 | 1991-10-03 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
JPH10298222A (ja) * | 1997-04-25 | 1998-11-10 | Nippon Polyolefin Kk | ポリオレフィン製造用触媒成分およびポリオレフィン製造用触媒 |
JPH11199618A (ja) * | 1998-01-08 | 1999-07-27 | Asahi Chem Ind Co Ltd | 新規重合用触媒及び該触媒を用いた共重合体の製造方法 |
WO1999067302A1 (de) * | 1998-06-25 | 1999-12-29 | Elenac Gmbh | Verfahren zur herstellung eines geträgerten katalysatorsystems |
WO2000050469A1 (fr) * | 1999-02-26 | 2000-08-31 | Idemitsu Petrochemical Co., Ltd. | Catalyseur pour copolymerisation d'olefine/styrene et procede de production de copolymere d'olefine/styrene |
Non-Patent Citations (1)
Title |
---|
See also references of EP1449853A4 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006273977A (ja) * | 2005-03-29 | 2006-10-12 | Asahi Kasei Chemicals Corp | オレフィン重合用触媒およびオレフィンの重合方法 |
JP4596951B2 (ja) * | 2005-03-29 | 2010-12-15 | 旭化成ケミカルズ株式会社 | オレフィン重合用触媒およびオレフィンの重合方法 |
JP2006321990A (ja) * | 2005-04-22 | 2006-11-30 | Asahi Kasei Chemicals Corp | 容器包装用エチレン系樹脂 |
JP2007162014A (ja) * | 2005-11-17 | 2007-06-28 | Asahi Kasei Chemicals Corp | オレフィン重合用触媒およびオレフィンの重合方法 |
JP2007169611A (ja) * | 2005-11-22 | 2007-07-05 | Asahi Kasei Chemicals Corp | オレフィン重合体の製造方法 |
JP2015124285A (ja) * | 2013-12-26 | 2015-07-06 | 旭化成ケミカルズ株式会社 | ポリエチレンの製造方法 |
Also Published As
Publication number | Publication date |
---|---|
EP1449853B1 (en) | 2015-06-03 |
US6956002B2 (en) | 2005-10-18 |
EP1449853A1 (en) | 2004-08-25 |
KR100594336B1 (ko) | 2006-06-30 |
KR20040045855A (ko) | 2004-06-02 |
TWI229087B (en) | 2005-03-11 |
EP1449853A4 (en) | 2010-03-24 |
CN100434444C (zh) | 2008-11-19 |
US20040254314A1 (en) | 2004-12-16 |
CN1571800A (zh) | 2005-01-26 |
JPWO2003035704A1 (ja) | 2005-02-10 |
JP3865314B2 (ja) | 2007-01-10 |
MY134308A (en) | 2007-12-31 |
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