WO2003035704A1 - Process for polymerization of olefins - Google Patents

Process for polymerization of olefins Download PDF

Info

Publication number: WO2003035704A1
Authority: WO; WIPO (PCT)
Prior art keywords: compound; group; reacting; periodic table; olefins
Prior art date: 2001-10-19

Application number

PCT/JP2002/010677

Other languages

English (en)

French (fr)

Inventor

Takashi Nozaki

Akio Fujiwara

Original Assignee

Asahi Kasei Kabushiki Kaisha

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-10-19

Filing date

2002-10-15

Publication date

2003-05-01

2002-10-15 Application filed by Asahi Kasei Kabushiki Kaisha filed Critical Asahi Kasei Kabushiki Kaisha

2002-10-15 Priority to EP02802014.7A priority Critical patent/EP1449853B1/en

2002-10-15 Priority to KR1020047005674A priority patent/KR100594336B1/ko

2002-10-15 Priority to US10/492,907 priority patent/US6956002B2/en

2002-10-15 Priority to JP2003538217A priority patent/JP3865314B2/ja

2003-05-01 Publication of WO2003035704A1 publication Critical patent/WO2003035704A1/ja

Links

150000001336 alkenes Chemical class 0.000 title abstract 2
238000006116 polymerization reaction Methods 0.000 title abstract 2
238000000034 method Methods 0.000 title 1
150000001875 compounds Chemical class 0.000 abstract 4
230000003197 catalytic effect Effects 0.000 abstract 2
150000002430 hydrocarbons Chemical class 0.000 abstract 2
150000002901 organomagnesium compounds Chemical class 0.000 abstract 2
230000000737 periodic effect Effects 0.000 abstract 2
239000007787 solid Substances 0.000 abstract 2
239000004215 Carbon black (E152) Substances 0.000 abstract 1
239000012190 activator Substances 0.000 abstract 1
150000001298 alcohols Chemical class 0.000 abstract 1
150000001412 amines Chemical class 0.000 abstract 1
125000004432 carbon atom Chemical group C* 0.000 abstract 1
239000003054 catalyst Substances 0.000 abstract 1
150000004696 coordination complex Chemical class 0.000 abstract 1
229930195733 hydrocarbon Natural products 0.000 abstract 1
125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
229910052751 metal Inorganic materials 0.000 abstract 1
239000002184 metal Substances 0.000 abstract 1
150000002739 metals Chemical class 0.000 abstract 1
239000000203 mixture Substances 0.000 abstract 1
-1 siloxane compounds Chemical class 0.000 abstract 1
239000002904 solvent Substances 0.000 abstract 1
229910052723 transition metal Inorganic materials 0.000 abstract 1
150000003624 transition metals Chemical class 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/61—Pretreating the metal or compound covered by group C08F4/60 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/612—Pretreating with metals or metal-containing compounds
- C08F4/618—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, provided for in at least two of the groups C08F4/613 - C08F4/617
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

PCT/JP2002/010677 2001-10-19 2002-10-15 Process for polymerization of olefins WO2003035704A1 (en)

Priority Applications (4)

Application Number	Priority Date	Filing Date	Title
EP02802014.7A EP1449853B1 (en)	2001-10-19	2002-10-15	Process for polymerization of olefins
KR1020047005674A KR100594336B1 (ko)	2001-10-19	2002-10-15	올레핀 중합 방법
US10/492,907 US6956002B2 (en)	2001-10-19	2002-10-15	Process for polymerization of olefins
JP2003538217A JP3865314B2 (ja)	2001-10-19	2002-10-15	オレフィンの重合方法

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
JP2001322620		2001-10-19
JP2001-322620		2001-10-19
JP2001375541		2001-12-10
JP2001-375541		2001-12-10

Publications (1)

Publication Number	Publication Date
WO2003035704A1 true WO2003035704A1 (en)	2003-05-01

Family

ID=26624005

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PCT/JP2002/010677 WO2003035704A1 (en)	2001-10-19	2002-10-15	Process for polymerization of olefins

Country Status (8)

Country	Link
US (1)	US6956002B2 (ja)
EP (1)	EP1449853B1 (ja)
JP (1)	JP3865314B2 (ja)
KR (1)	KR100594336B1 (ja)
CN (1)	CN100434444C (ja)
MY (1)	MY134308A (ja)
TW (1)	TWI229087B (ja)
WO (1)	WO2003035704A1 (ja)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2006273977A (ja) *	2005-03-29	2006-10-12	Asahi Kasei Chemicals Corp	オレフィン重合用触媒およびオレフィンの重合方法
JP2006321990A (ja) *	2005-04-22	2006-11-30	Asahi Kasei Chemicals Corp	容器包装用エチレン系樹脂
JP2007162014A (ja) *	2005-11-17	2007-06-28	Asahi Kasei Chemicals Corp	オレフィン重合用触媒およびオレフィンの重合方法
JP2007169611A (ja) *	2005-11-22	2007-07-05	Asahi Kasei Chemicals Corp	オレフィン重合体の製造方法
JP2015124285A (ja) *	2013-12-26	2015-07-06	旭化成ケミカルズ株式会社	ポリエチレンの製造方法

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB0501100D0 (en) *	2005-01-19	2005-02-23	Bp Chem Int Ltd	Process
WO2007076398A2 (en) *	2005-12-21	2007-07-05	Albemarle Corporation	Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
WO2020101372A1 (ko) *	2018-11-14	2020-05-22	롯데케미칼 주식회사	올레핀 중합용 담지 촉매 및 이를 이용하는 폴리올레핀의 제조방법
BR112022001387A2 (pt) *	2019-07-31	2022-03-22	Dow Global Technologies Llc	Sistema de catalisador, e, processo de polimerização
FR3104585B1 (fr) *	2019-12-17	2021-12-03	Michelin & Cie	Système catalytique à base d’un métallocène et d’un diorganomagnésien
FR3104584B1 (fr) *	2019-12-17	2021-12-03	Michelin & Cie	Composé diorganomagnésien asymétrique

Citations (5)

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WO1991014713A1 (en) *	1990-03-20	1991-10-03	Exxon Chemical Patents Inc.	Catalyst system of enhanced productivity
JPH10298222A (ja) *	1997-04-25	1998-11-10	Nippon Polyolefin Kk	ポリオレフィン製造用触媒成分およびポリオレフィン製造用触媒
JPH11199618A (ja) *	1998-01-08	1999-07-27	Asahi Chem Ind Co Ltd	新規重合用触媒及び該触媒を用いた共重合体の製造方法
WO1999067302A1 (de) *	1998-06-25	1999-12-29	Elenac Gmbh	Verfahren zur herstellung eines geträgerten katalysatorsystems
WO2000050469A1 (fr) *	1999-02-26	2000-08-31	Idemitsu Petrochemical Co., Ltd.	Catalyseur pour copolymerisation d'olefine/styrene et procede de production de copolymere d'olefine/styrene

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PL276385A1 (en)	1987-01-30	1989-07-24	Exxon Chemical Patents Inc	Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IL85097A (en)	1987-01-30	1992-02-16	Exxon Chemical Patents Inc	Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
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EP0426638B2 (en)	1989-10-30	2005-03-02	Fina Technology, Inc.	Addition of aluminium alkyl for improved metallocene catalyst
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2002
- 2002-10-15 EP EP02802014.7A patent/EP1449853B1/en not_active Expired - Lifetime
- 2002-10-15 CN CNB028205359A patent/CN100434444C/zh not_active Expired - Lifetime
- 2002-10-15 US US10/492,907 patent/US6956002B2/en not_active Expired - Lifetime
- 2002-10-15 WO PCT/JP2002/010677 patent/WO2003035704A1/ja active Application Filing
- 2002-10-15 JP JP2003538217A patent/JP3865314B2/ja not_active Expired - Lifetime
- 2002-10-15 KR KR1020047005674A patent/KR100594336B1/ko not_active Expired - Lifetime
- 2002-10-16 TW TW091123851A patent/TWI229087B/zh not_active IP Right Cessation
- 2002-10-17 MY MYPI20023874A patent/MY134308A/en unknown

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WO1991014713A1 (en) *	1990-03-20	1991-10-03	Exxon Chemical Patents Inc.	Catalyst system of enhanced productivity
JPH10298222A (ja) *	1997-04-25	1998-11-10	Nippon Polyolefin Kk	ポリオレフィン製造用触媒成分およびポリオレフィン製造用触媒
JPH11199618A (ja) *	1998-01-08	1999-07-27	Asahi Chem Ind Co Ltd	新規重合用触媒及び該触媒を用いた共重合体の製造方法
WO1999067302A1 (de) *	1998-06-25	1999-12-29	Elenac Gmbh	Verfahren zur herstellung eines geträgerten katalysatorsystems
WO2000050469A1 (fr) *	1999-02-26	2000-08-31	Idemitsu Petrochemical Co., Ltd.	Catalyseur pour copolymerisation d'olefine/styrene et procede de production de copolymere d'olefine/styrene

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See also references of EP1449853A4 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2006273977A (ja) *	2005-03-29	2006-10-12	Asahi Kasei Chemicals Corp	オレフィン重合用触媒およびオレフィンの重合方法
JP4596951B2 (ja) *	2005-03-29	2010-12-15	旭化成ケミカルズ株式会社	オレフィン重合用触媒およびオレフィンの重合方法
JP2006321990A (ja) *	2005-04-22	2006-11-30	Asahi Kasei Chemicals Corp	容器包装用エチレン系樹脂
JP2007162014A (ja) *	2005-11-17	2007-06-28	Asahi Kasei Chemicals Corp	オレフィン重合用触媒およびオレフィンの重合方法
JP2007169611A (ja) *	2005-11-22	2007-07-05	Asahi Kasei Chemicals Corp	オレフィン重合体の製造方法
JP2015124285A (ja) *	2013-12-26	2015-07-06	旭化成ケミカルズ株式会社	ポリエチレンの製造方法

Also Published As

Publication number	Publication date
EP1449853B1 (en)	2015-06-03
US6956002B2 (en)	2005-10-18
EP1449853A1 (en)	2004-08-25
KR100594336B1 (ko)	2006-06-30
KR20040045855A (ko)	2004-06-02
TWI229087B (en)	2005-03-11
EP1449853A4 (en)	2010-03-24
CN100434444C (zh)	2008-11-19
US20040254314A1 (en)	2004-12-16
CN1571800A (zh)	2005-01-26
JPWO2003035704A1 (ja)	2005-02-10
JP3865314B2 (ja)	2007-01-10
MY134308A (en)	2007-12-31

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Publication	Publication Date	Title
WO2003035704A1 (en)	2003-05-01	Process for polymerization of olefins
EP2050769A3 (en)	2011-08-03	Olefin polymerization catalyst and process for olefin polymerization
EP1270603A3 (en)	2003-05-14	Olefin polymerization catalyst, process for polymerizing olefins, ethylene polymer obtained by said process and use thereof
WO2003010207A1 (fr)	2003-02-06	Catalyseurs de polymerisation ou de copolymerisation d'olefines, leur procede de preparation et leur utilisation
MY121053A (en)	2005-12-30	Olefin polymerization catalyst component, its preparation and use
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