WO2003030289A3 - Polymer membrane for fuel cells and method for the production thereof - Google Patents
Polymer membrane for fuel cells and method for the production thereof Download PDFInfo
- Publication number
- WO2003030289A3 WO2003030289A3 PCT/DE2002/003736 DE0203736W WO03030289A3 WO 2003030289 A3 WO2003030289 A3 WO 2003030289A3 DE 0203736 W DE0203736 W DE 0203736W WO 03030289 A3 WO03030289 A3 WO 03030289A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- conducting
- segment
- electrons
- protons
- fuel cells
- Prior art date
Links
- 239000000446 fuel Substances 0.000 title abstract 3
- 229920005597 polymer membrane Polymers 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- 239000012528 membrane Substances 0.000 abstract 2
- 229920000359 diblock copolymer Polymers 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 229920006030 multiblock copolymer Polymers 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
- B01D71/80—Block polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1041—Polymer electrolyte composites, mixtures or blends
- H01M8/1044—Mixtures of polymers, of which at least one is ionically conductive
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1041—Polymer electrolyte composites, mixtures or blends
- H01M8/1046—Mixtures of at least one polymer and at least one additive
- H01M8/1051—Non-ion-conducting additives, e.g. stabilisers, SiO2 or ZrO2
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1086—After-treatment of the membrane other than by polymerisation
- H01M8/1088—Chemical modification, e.g. sulfonation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2365/00—Characterised by the use of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Derivatives of such polymers
- C08J2365/02—Polyphenylenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
- C08J2371/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08J2371/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08J2371/12—Polyphenylene oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Fuel Cell (AREA)
Abstract
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2002339343A AU2002339343A1 (en) | 2001-09-28 | 2002-09-27 | Polymer membrane for fuel cells and method for the production thereof |
EP02776768A EP1430560A2 (en) | 2001-09-28 | 2002-09-27 | Polymer membrane for fuel cells and method for the production thereof |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10149716.4 | 2001-09-28 | ||
DE10149716A DE10149716A1 (en) | 2001-09-28 | 2001-09-28 | Polymer fuel cell membrane and process for its manufacture |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2003030289A2 WO2003030289A2 (en) | 2003-04-10 |
WO2003030289A3 true WO2003030289A3 (en) | 2003-11-13 |
Family
ID=7701871
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE2002/003736 WO2003030289A2 (en) | 2001-09-28 | 2002-09-27 | Polymer membrane for fuel cells and method for the production thereof |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1430560A2 (en) |
AU (1) | AU2002339343A1 (en) |
DE (1) | DE10149716A1 (en) |
WO (1) | WO2003030289A2 (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7572535B2 (en) | 2002-05-13 | 2009-08-11 | Polyfuel, Inc. | Ion conductive copolymers containing one or more hydrophobic oligomers |
DE10316323A1 (en) * | 2003-04-10 | 2004-10-28 | Daimlerchrysler Ag | Functionalizing polyarylethersulfones with basic groups, for use in electrolytes, ion exchangers, catalysts, polymer electrolyte membranes or blends, involves a Grignard reaction and reaction with an anchoring compound |
JP2007517923A (en) | 2003-11-13 | 2007-07-05 | ポリフューエル・インコーポレイテッド | Ion conductive copolymers containing one or more hydrophobic oligomers |
CA2559556A1 (en) | 2004-03-12 | 2005-09-29 | Polyfuel, Inc. | Ion-conductive copolymers containing one or more ion-conducting oligomers |
DE102004055129A1 (en) * | 2004-11-16 | 2006-05-18 | Volkswagen Ag | Production of polymer electrolyte membrane for fuel cells based on liquid electrolyte containing polymer |
US7459505B2 (en) | 2005-05-03 | 2008-12-02 | General Motors Corporation | Block copolymers with acidic groups |
US7977394B2 (en) | 2005-05-03 | 2011-07-12 | GM Global Technology Operations LLC | Triblock copolymers with acidic groups |
US7993792B2 (en) * | 2006-07-26 | 2011-08-09 | GM Global Technology Operations LLC | Polymer blocks for PEM applications |
US8492460B2 (en) | 2006-07-28 | 2013-07-23 | GM Global Technology Operations LLC | Fluorinated polymer blocks for PEM applications |
DE102006036496A1 (en) | 2006-07-28 | 2008-02-07 | Leibniz-Institut Für Polymerforschung Dresden E.V. | Sulfonated polyaryl compounds, membrane material therefrom, process for their preparation and use |
US8216740B2 (en) | 2006-12-12 | 2012-07-10 | Bose Corporation | Fuel cell |
US8557473B2 (en) * | 2007-12-11 | 2013-10-15 | Bose Corporation | Fuel cell polymer electrolyte membrane |
CN102643546B (en) * | 2012-05-03 | 2013-12-04 | 长春工业大学 | 1, 3, 4-oxadiazole ring containing poly (aromatic ether sulfone) medium-high temperature proton exchange membrane and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0424041A2 (en) * | 1989-10-16 | 1991-04-24 | Exxon Research And Engineering Company | Membranes obtained from copolymers of polyimides and aliphatic polyesters. |
US5028685A (en) * | 1989-10-16 | 1991-07-02 | Exxon Research & Engineering Company | Halogenated polyurethanes |
EP0574791A2 (en) * | 1992-06-13 | 1993-12-22 | Hoechst Aktiengesellschaft | Polymer electrolyte membrane and process for its manufacture |
-
2001
- 2001-09-28 DE DE10149716A patent/DE10149716A1/en not_active Withdrawn
-
2002
- 2002-09-27 WO PCT/DE2002/003736 patent/WO2003030289A2/en not_active Application Discontinuation
- 2002-09-27 AU AU2002339343A patent/AU2002339343A1/en not_active Abandoned
- 2002-09-27 EP EP02776768A patent/EP1430560A2/en not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0424041A2 (en) * | 1989-10-16 | 1991-04-24 | Exxon Research And Engineering Company | Membranes obtained from copolymers of polyimides and aliphatic polyesters. |
US5028685A (en) * | 1989-10-16 | 1991-07-02 | Exxon Research & Engineering Company | Halogenated polyurethanes |
EP0574791A2 (en) * | 1992-06-13 | 1993-12-22 | Hoechst Aktiengesellschaft | Polymer electrolyte membrane and process for its manufacture |
Non-Patent Citations (10)
Title |
---|
ARNOLD C ET AL: "DEVELOPMENT OF SULFONATED POLYSULFONE MEMBRANES FOR REDOX FLOW BATTERIES", JOURNAL OF MEMBRANE SCIENCE, ELSEVIER SCIENTIFIC PUBL.COMPANY. AMSTERDAM, NL, vol. 38, 1988, pages 71 - 83, XP009014843, ISSN: 0376-7388 * |
DANG T D ET AL: "Polybenzobisthiazoles with crosslinking sites for improved fibre axial compressive strength", POLYMER, ELSEVIER SCIENCE PUBLISHERS B.V, GB, vol. 38, no. 3, 1 February 1997 (1997-02-01), pages 621 - 629, XP004015335, ISSN: 0032-3861 * |
FAURE S ET AL: "SULFONATED POLYIMIDES AS NOVEL PROTON EXCHANGE MEMBRANES FOR H2/O2 FUEL CELLS", PROCEEDINGS OF THE SYMPOSIUM ON NEW MATERIALS FOR FUEL-CELL AND MODERN BATTERY SYSTEMS, XX, XX, 1997, pages 818 - 827, XP008003162 * |
GENIES C ET AL: "Soluble sulfonated naphthalenic polyimides as materials for proton exchange membranes", POLYMER, ELSEVIER SCIENCE PUBLISHERS B.V, GB, vol. 42, no. 2, January 2001 (2001-01-01), pages 359 - 373, XP004216918, ISSN: 0032-3861 * |
HEINZEL,A. ET AL.: "A review of the state-of-the-art of the methanol crossover in direct methnol fuel cells", JOURNAL OF POWER SOURCES, vol. 84, 1999, AMSTERDAM, pages 70 - 74, XP001153867 * |
KERRES J ET AL: "PREPARATION, CHARACTERIZATION AND FUEL CELL APPLICATION OF NEW ACID-BASE BLEND MEMBRANES", JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS, ECOLE POLYTECHNIQUE DE MONTREAL, MONTREAL, CA, vol. 3, 2000, pages 229 - 239, XP009014845, ISSN: 1480-2422 * |
KUMUDINIE C ET AL: "Toughening of some high-temperature poly(arylene ether)s and a hydroxypoly(benzoxazole) by sol-gel generated rubbery particles", POLYMER, ELSEVIER SCIENCE PUBLISHERS B.V, GB, vol. 42, no. 12, June 2001 (2001-06-01), pages 5275 - 5283, XP004230993, ISSN: 0032-3861 * |
SAVODOGO,O.: "Emerging membranes for electrochemical systems: (I) solid polymer electrolyte membranes for fuel cell systems", J.NEW MAT.ELECTROCHEM.SYSTEMS, vol. 1, 1998, pages 47-66, XP009014846 * |
STAITI,P. ET AL.: "Membranes based on phosphotungstic acid and polybenzimidazole for fuel cell application", JOURNAL OF POWER SOURCES, vol. 90, 2000, AMSTERDAM, pages 231 - 235, XP002251389 * |
WAINRIGHT J S ET AL: "ACID-DOPED POLYBENZIMIDAZOLES: A NEW POLYMER ELECTROLYTE", JOURNAL OF THE ELECTROCHEMICAL SOCIETY, ELECTROCHEMICAL SOCIETY. MANCHESTER, NEW HAMPSHIRE, US, vol. 142, no. 7, July 1995 (1995-07-01), pages L121 - L123, XP009014336, ISSN: 0013-4651 * |
Also Published As
Publication number | Publication date |
---|---|
DE10149716A1 (en) | 2003-04-30 |
EP1430560A2 (en) | 2004-06-23 |
AU2002339343A1 (en) | 2003-04-14 |
WO2003030289A2 (en) | 2003-04-10 |
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