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WO2003017958A1 - Colorant capillaire - Google Patents

Colorant capillaire Download PDF

Info

Publication number
WO2003017958A1
WO2003017958A1 PCT/JP2002/008609 JP0208609W WO03017958A1 WO 2003017958 A1 WO2003017958 A1 WO 2003017958A1 JP 0208609 W JP0208609 W JP 0208609W WO 03017958 A1 WO03017958 A1 WO 03017958A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
agent
dye
component
weight
Prior art date
Application number
PCT/JP2002/008609
Other languages
English (en)
Japanese (ja)
Inventor
Atsushi Murakami
Heiichiro Matsumoto
Mitsuo Sano
Yoshio Tsujino
Original Assignee
Mandom Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mandom Corporation filed Critical Mandom Corporation
Priority to JP2003522479A priority Critical patent/JP3578276B2/ja
Priority to KR1020037014178A priority patent/KR100576596B1/ko
Publication of WO2003017958A1 publication Critical patent/WO2003017958A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67—Vitamins
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67—Vitamins
    • A61K8/676—Ascorbic acid, i.e. vitamin C
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the present invention relates to a hair dye, and more specifically, has excellent dye stability in a preparation, does not have an irritating odor due to an alkali agent when used, and has a good texture after hair dyeing.
  • the present invention relates to a hair dye having excellent fastness properties.
  • Oxidative hair dyes are widely used because hair dyes are durable and have a bleaching effect, so they can be dyed lighter than the original hair.
  • Oxidative hair dyes can be mixed with water at the time of use, either as a single-drug type or as a multi-drug type.However, a two-drug type consisting of a first agent containing an oxidizing dye and an alkaline agent and a second agent containing an oxidizing agent Is the mainstream.
  • the alkaline agent in the first agent decomposes the oxidizing agent in the second agent to generate oxygen, thereby decomposing the melanin in the hair to decolorize the hair and oxidizing the first agent.
  • the dye is oxidatively polymerized in the hair by an oxidizing agent and is formulated to dye the hair.
  • ammonia is widely used because it has volatility and does not remain on hair. However, ammonia has a peculiar pungent odor and has drawbacks such as irritation to mucous membranes such as eyes.
  • the alkaline agent also has the effect of swelling the cuticle on the surface of the hair and of penetrating the dye into the interior of the hair to improve the hair dyeing effect.
  • the hair is damaged and the texture of the hair after dyeing is adversely affected.
  • the oxidation dye in the first part is obtained by converting the oxidation dye in the first part into the oxidant in the second part.
  • the hair is dyed by undergoing an oxidative polymerization reaction. Therefore, before mixing the first and second components, a reducing agent is generally added to prevent the oxidation dye in the first component from reacting.
  • a reducing agent is generally added to prevent the oxidation dye in the first component from reacting.
  • it is not sufficient to suppress the oxidation of the oxidation dye and there is a problem that the dye polymerizes during storage of the preparation and the base material is colored before use.
  • An object of the present invention is to provide a hair dye which has excellent dye stability in a formulation, has no irritating odor due to an alkali agent when used, and has a good texture after hair dyeing, and is also excellent in fastness. Is to provide. Disclosure of the invention
  • an oxidative hair dye comprising a first agent containing an oxidation dye and a second agent containing an oxidizing agent, wherein the first agent comprises: (A) monoethanolamine and / or Monoisopropanolamine, (B) cysteine, homocystin, N-acetyl cysteine, and at least one selected from the group consisting of salts thereof, and (C) ascorbic acid and / or a salt thereof.
  • a hair dye characterized by containing it is provided.
  • the hair dye of the present invention is an oxidative hair dye comprising a first agent containing an oxidizing dye and a second agent containing an oxidizing agent.
  • the first agent at least one selected from the group consisting of (A) monoethanolamine and Z or monoisopropanolamine, (B) cysteine, homocystine, N-acetylcystine, and salts thereof. At least one species, and (C) ascorbic acid and / or a salt thereof are contained as essential components.
  • the combination of the alkali agent and the two or more reducing agents has excellent dye stability in the preparation, and has a good texture and fastness after hair dyeing.
  • Hair dye The essential components of the first agent blended in the present invention are the above-mentioned component (A), monoethanolamine and Z or monoisopropanolamine.
  • Monoethanolamine and monoisopropanolamine when formulated as an aqueous solution in the first agent, make the system more viscous, swell the hair, and promote the penetration of the dye into the hair. Also, when mixed with a second agent containing hydrogen peroxide, it has many advantages such as accelerating the decomposition of hydrogen peroxide and improving the bleaching of hair. It is preferably used because it has no pungent odor. Of these, monoisopropanolamine is preferred.
  • the content of the component (A) in the first agent is preferably from 0.1 to 10% by weight, and more preferably from 0.3 to 6% by weight. The reason is that if the content is less than 0.1% by weight, the function as an alkaline agent tends to be insufficient, and if it exceeds 10% by weight, skin irritation and hair damage tend to occur. Because there is.
  • the first agent of the hair dye of the present invention contains, in addition to the above-mentioned alkaline agent, two types of reducing agents of component (B) and component (C).
  • component (B) as the first reducing agent at least one selected from the group consisting of cysteine, homocystin, N-acetyl cysteine, and salts thereof is used.
  • the component (C) as the second reducing agent is ascorbic acid and / or a salt thereof.
  • the color development of the oxidation dye in the first agent is effectively suppressed, the color development time of the oxidation dye during hair dyeing is adjusted, and the dye precursor remaining in the hair The function of preventing re-oxidation of the metal is exhibited.
  • the content of the component (B) in the first agent is preferably from 0.05 to 0.9% by weight, more preferably from 0.3 to 0.5% by weight.
  • the reason is that when the content is less than 0.05% by weight, the antioxidant effect tends to be insufficient, and exceeds 0.9% by weight. This is because, in this case, it takes a long time to develop color during hair dyeing.
  • the content of the component (C) in the first agent is preferably from 0.05 to 0.9% by weight, more preferably from 0.3 to 0.5% by weight. The reason is that if the content is less than 0.05% by weight, the antioxidant effect tends to be insufficient, and if it exceeds 0.9% by weight, it takes time to develop color during hair dyeing. This is because there is a tendency.
  • the total content of the component (B) and the component (C) in the first agent is preferably 0.1 to 1% by weight. The reason is that if the total content is less than 0.1% by weight, the antioxidant effect tends to be insufficient, and if it exceeds 1% by weight, the color development time during hair dyeing becomes longer. This is because it tends to be too much.
  • the alkaline agent of the component (A) and the two reducing agents of the components (B) and (C) are specified. It is preferable to mix them at the following ratio.
  • the ratio of the content of the component (A) to the total content of the components (B) and (C) is (A): [(B) + (C)] is 0.5: 1. ⁇ 30: 1 is preferable, and 1: 1 ⁇ 10: 1 is more preferable.
  • the reason is that if the amount of the component (A) is less than 0.5 part by weight with respect to 1 part by weight of ((B) + (C)), the hair dyeing power tends to be insufficient, If the amount exceeds 30 parts by weight, skin irritation and damage to hair tend to occur.
  • the oxidation dye to be blended in the first agent of the present invention means a dye used for an oxidation hair dye such as an oxidation dye precursor or Ryppura.
  • the oxidation dye that can be used in the present invention is not particularly limited.
  • the oxidation dye precursor include phenylenediamines, tolylenediamines, N-phenylphenylenediamines, aminophenols, and the like. Aminonitrophenols, diphenylamines, diaminophenylamines, diaminopyridines, and the like.
  • power couplers include resorcin, m-aminophenol, m-phenylenediamine, catechol, and pyrogallol.
  • the oxidation dye in the first part Is preferably about 0.01 to about 10% by weight.
  • Examples of the oxidizing agent blended in the second agent of the present invention include hydrogen peroxide, urea peroxide, peroxides, alkali metal bromates, and oxide reductases such as two-electron oxidoreductase.
  • the hair dye of the present invention may contain the following components in addition to the above components as long as the effects of the present invention are not impaired.
  • the first agent includes a surfactant (for example, polyoxyethylene alkyl ether such as polyoxyethylene cetyl ether and polyoxyethylene stearyl ether), an oily component (for example, cetyl alcohol, stearyl alcohol, oleyl alcohol, etc.). Higher alcohols; silicones such as dimethylpolysiloxane; hydrocarbon oils such as liquid paraffin); thickeners (eg, water-soluble polymer compounds such as carboxyvinyl polymer, hydroxyshethyl cellulose, guar gum, xanthan gum). , Moisturizers (eg, polyhydric alcohols such as glycerin, 1,3-butylene glycol, and polyethylene glycol), animal and plant extracts, and fragrances can be appropriately added as necessary.
  • a surfactant for example, polyoxyethylene alkyl ether such as polyoxyethylene cetyl ether and polyoxyethylene stearyl ether
  • an oily component for example, cetyl alcohol, stearyl alcohol,
  • the first agent may contain water.
  • water examples include purified water, ion-exchanged water, tap water, and the like.
  • the content of water in the first agent can be appropriately adjusted so as to obtain a desired viscosity.
  • a stabilizer such as hydrogen peroxide, a surfactant, an oily component, an acid, a pH adjuster, a fragrance, and the like can be appropriately added to the second agent as necessary.
  • the hair dye of the present invention can be used in various dosage forms such as lotions, creams, pastes, gels, aerosols, and foam forms.
  • the first agent and the second agent may be appropriately mixed and applied to hair immediately before the hair dyeing treatment.
  • the present invention will be described in detail with reference to Examples, but the present invention is not limited to these Examples. It is not limited at all. Examples 1-3 and Comparative Examples 1-3
  • Each component was mixed by a conventional method so that the composition shown in Table 1 was obtained to prepare a first hair dye.
  • a second hair dye was prepared by a conventional method according to the following formulation.
  • the first part of the hair dye and the second part of the hair dye were mixed in equal amounts, applied evenly to the hair bundle of gray hair, and then left at 30 ° C. for 20 minutes to thoroughly wash. At this time, the irritating odor of the hair dye and the texture of the hair bundle after the hair dyeing were evaluated according to the following evaluation criteria. ⁇ Evaluation criteria for pungent odor>
  • ⁇ Slightly inferior to the hair bundle before dyeing.
  • Equal amounts of hair dye 1st agent and hair dye 2nd agent are mixed in equal amounts, applied evenly to goat hair bundles, and then washed thoroughly with 10% sodium lauryl sulfate. It was immersed in an aqueous solution, sonicated at 40 ° C. for 10 minutes, and evaluated according to the following evaluation criteria. As a control, a goat hair bundle before ultrasonic treatment was used.
  • the hair dyes of Examples 1 to 3 according to the present invention in which the components (A) to (C) are blended have no irritating odor, and all of the dye stability, texture and fastness are smelled. It can be seen that the effect is excellent.
  • Example 4 According to the following formulation, the first preparation of an oxidized hair dye in the form of an emulsion was obtained by a conventional method.
  • Example 5 Purified water Remainder The obtained first agent and a second agent having the same composition as that used in Example 1 were mixed in equal amounts and uniformly applied to the bleached hair bundle, and then at 30 eC . Left for 20 minutes, washed thoroughly, dried and stained with color.
  • Example 5 Purified water Remainder The obtained first agent and a second agent having the same composition as that used in Example 1 were mixed in equal amounts and uniformly applied to the bleached hair bundle, and then at 30 eC . Left for 20 minutes, washed thoroughly, dried and stained with color.
  • Example 5 Purified water Remainder The obtained first agent and a second agent having the same composition as that used in Example 1 were mixed in equal amounts and uniformly applied to the bleached hair bundle, and then at 30 eC . Left for 20 minutes, washed thoroughly, dried and stained with color.
  • the first preparation of an oxidized hair dye in the form of an emulsion was obtained by a conventional method.
  • Purified water Remainder The obtained first agent and the second agent are mixed in equal amounts and uniformly applied to the bleached hair bundle, then left at 30 for 20 minutes and washed thoroughly When dried, it was dyed orange. Industrial applicability
  • the hair dye of the present invention has excellent dye stability in a preparation, does not have an irritating odor due to an alkaline agent when used, has a good texture after hair dyeing, and has excellent fastness. It is a thing. Therefore, the hair dye of the present invention can be suitably used when dyeing hair.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un colorant capillaire oxydatif comprenant un premier ingrédient contenant un colorant d'oxydation et un second ingrédient contenant un agent oxydant, se caractérisant en ce que le premier ingrédient comprend (A) une monoéthanolamine et/ou un monoisopropanolamine, (B) au moins un élément choisi dans le groupe comprenant cystéine, homocystéine, N-acétylcystéine et des sels de ceux-ci, et (C) un acide ascorbique et/ou un sel de celui-ci. Le colorant capillaire présente une excellente stabilité en matière de colorant. En outre, en emploi, il ne dégage pas d'odeur irritante des alcalis et, après coloration des cheveux, il procure un sentiment de satisfaction et sa solidité est excellente.
PCT/JP2002/008609 2001-08-27 2002-08-27 Colorant capillaire WO2003017958A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2003522479A JP3578276B2 (ja) 2001-08-27 2002-08-27 染毛剤
KR1020037014178A KR100576596B1 (ko) 2001-08-27 2002-08-27 염모제

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001-256053 2001-08-27
JP2001256053 2001-08-27

Publications (1)

Publication Number Publication Date
WO2003017958A1 true WO2003017958A1 (fr) 2003-03-06

Family

ID=19083926

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/008609 WO2003017958A1 (fr) 2001-08-27 2002-08-27 Colorant capillaire

Country Status (4)

Country Link
JP (1) JP3578276B2 (fr)
KR (1) KR100576596B1 (fr)
CN (1) CN1505500A (fr)
WO (1) WO2003017958A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004045567A1 (fr) * 2002-11-19 2004-06-03 Dsm Ip Assets B.V. Utilisation de derives d'acide ascorbique dans des produits de soin capillaire
JP2005232075A (ja) * 2004-02-19 2005-09-02 Takara Belmont Co Ltd 毛髪処理用緩衝組成物、毛髪脱色剤、及び、染毛剤
JP2006342124A (ja) * 2005-06-10 2006-12-21 Mandom Corp 毛髪脱色剤並びに酸化染毛剤
JP2007169165A (ja) * 2005-12-19 2007-07-05 Kao Corp 染毛剤組成物
JP2009149647A (ja) * 2007-12-21 2009-07-09 L'oreal Sa 特定の有機アミンの存在下における明色化直接染色または酸化染色の方法、そのためのデバイスおよび無水組成物
JP2009286713A (ja) * 2008-05-28 2009-12-10 Henkel Japan Ltd 酸化染毛剤
JP2016132776A (ja) * 2015-01-22 2016-07-25 ホーユー株式会社 芳香族化合物の安定性向上剤及び芳香族化合物の安定性向上方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102307559B (zh) * 2009-01-26 2014-02-26 朋友株式会社 头发染料组合物、氧化头发染料组合物以及防止头发染色的色调变化的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001041722A1 (fr) * 1999-12-08 2001-06-14 L'oreal Composition pour la decoloration ou la deformation permanente de s fibres keratiniques comprenant un polymere epaissis a squelette aminoplaste-ether
WO2001043708A1 (fr) * 1999-12-13 2001-06-21 L'oreal Composition de deux polyethers polyurethanes
WO2002038118A1 (fr) * 2000-11-08 2002-05-16 L'oreal Composition pour la decoloration ou la deformation permanente des fibres keratiniques comprenant un polyurethane associatif cationique
WO2002043675A2 (fr) * 2000-12-01 2002-06-06 Henkel Kommanditgesellschaft Auf Aktien Immobilisation d'agents actifs sur des fibres

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001041722A1 (fr) * 1999-12-08 2001-06-14 L'oreal Composition pour la decoloration ou la deformation permanente de s fibres keratiniques comprenant un polymere epaissis a squelette aminoplaste-ether
WO2001043708A1 (fr) * 1999-12-13 2001-06-21 L'oreal Composition de deux polyethers polyurethanes
WO2002038118A1 (fr) * 2000-11-08 2002-05-16 L'oreal Composition pour la decoloration ou la deformation permanente des fibres keratiniques comprenant un polyurethane associatif cationique
WO2002043675A2 (fr) * 2000-12-01 2002-06-06 Henkel Kommanditgesellschaft Auf Aktien Immobilisation d'agents actifs sur des fibres

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004045567A1 (fr) * 2002-11-19 2004-06-03 Dsm Ip Assets B.V. Utilisation de derives d'acide ascorbique dans des produits de soin capillaire
JP2005232075A (ja) * 2004-02-19 2005-09-02 Takara Belmont Co Ltd 毛髪処理用緩衝組成物、毛髪脱色剤、及び、染毛剤
JP2006342124A (ja) * 2005-06-10 2006-12-21 Mandom Corp 毛髪脱色剤並びに酸化染毛剤
JP2007169165A (ja) * 2005-12-19 2007-07-05 Kao Corp 染毛剤組成物
JP2009149647A (ja) * 2007-12-21 2009-07-09 L'oreal Sa 特定の有機アミンの存在下における明色化直接染色または酸化染色の方法、そのためのデバイスおよび無水組成物
JP2009286713A (ja) * 2008-05-28 2009-12-10 Henkel Japan Ltd 酸化染毛剤
JP2016132776A (ja) * 2015-01-22 2016-07-25 ホーユー株式会社 芳香族化合物の安定性向上剤及び芳香族化合物の安定性向上方法

Also Published As

Publication number Publication date
KR20040019290A (ko) 2004-03-05
JP3578276B2 (ja) 2004-10-20
JPWO2003017958A1 (ja) 2004-12-09
KR100576596B1 (ko) 2006-05-04
CN1505500A (zh) 2004-06-16

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