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WO2003011063A1 - Bonnet constitue d'une structure en fibre composite et procede de production associe - Google Patents

Bonnet constitue d'une structure en fibre composite et procede de production associe Download PDF

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Publication number
WO2003011063A1
WO2003011063A1 PCT/JP2002/006841 JP0206841W WO03011063A1 WO 2003011063 A1 WO2003011063 A1 WO 2003011063A1 JP 0206841 W JP0206841 W JP 0206841W WO 03011063 A1 WO03011063 A1 WO 03011063A1
Authority
WO
WIPO (PCT)
Prior art keywords
polyester
fiber
elastic
fiber structure
fibers
Prior art date
Application number
PCT/JP2002/006841
Other languages
English (en)
Japanese (ja)
Inventor
Kenji Baba
Yasuyuki Yamazaki
Original Assignee
Teijin Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teijin Limited filed Critical Teijin Limited
Priority to KR1020037004683A priority Critical patent/KR100842197B1/ko
Priority to JP2003516307A priority patent/JPWO2003011063A1/ja
Publication of WO2003011063A1 publication Critical patent/WO2003011063A1/fr
Priority to HK04104056A priority patent/HK1060962A1/xx

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Classifications

    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41C—CORSETS; BRASSIERES
    • A41C5/00—Machines, appliances, or methods for manufacturing corsets or brassieres
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41C—CORSETS; BRASSIERES
    • A41C3/00—Brassieres
    • A41C3/12—Component parts
    • A41C3/14—Stiffening or bust-forming inserts

Definitions

  • Patent Document I Cup comprising composite fiber structure and method for producing the same
  • the present invention relates to a cup made of a composite fiber structure and a method for producing the same.
  • the present invention relates to a mold-formed breast forcep having a high shaping function for adjusting the shape of the breast, having an excellent wearing feeling, and having high washing durability, and a method for producing the same.
  • breasts such as bras, long line bras, bodysuits, three-in-ones, underwear such as bladders, bra camisole, bra slips, bustiers, and leopard wears such as leopards, swimwear, evening dresses, bustiers, etc.
  • Women's clothing with a cup to cover the breast is widely used as clothing for women.
  • the following three types of these cups have been manufactured and marketed.
  • Another breast cup is made of fiber, and is a thin sheet of non-woven fabric prepared by punching out a number of sheets of different sizes in a mold of a predetermined size. 4 to 8 layers are laminated to form a curved shape, and they are bonded to each other with an adhesive and thermoformed at the same time, or a so-called binder-fiber is mixed and a force web is laminated. A method is known in which the binder fibers are melted and bonded during thermoforming to obtain a cup.
  • Japanese Patent Application Laid-Open No. 5-195397 discloses a method of manufacturing a pad material by thermoforming a single cushion structure. In this method, since the pad is molded from a single structure, the mold retention is improved. However, when manufacturing padding with a single structure with front and back lining, padding that achieves both a softer texture and mold retention without changing the texture And its production method was not known. Disclosure of the invention
  • An object of the present invention is to solve the above-mentioned problems of the prior art, to provide a high-strength, high-hand, excellent breathability, and excellent washing durability and shape retention, to be recyclable, and to be moldable.
  • Another object of the present invention is to provide a breast cup with a front and back lining and a method for producing the same.
  • a polyester woven / knitted fabric is formed on both sides of a polyester-based elastic fiber structure having the structure shown in the following (1) to (5).
  • thermoplastic elastomer comprising an inelastic polyester-based crimped short fiber aggregate as a matrix and having a melting point of at least 40 ° C. lower than the melting point of the polyester polymer constituting the short fibers, and an inelastic polyester.
  • Elastic composite fibers with the elastomer exposed at least on the fiber surface are dispersed and mixed,
  • the mixing ratio of the non-thermophilic polyester-based crimped staple fiber to the non-thermophilic polyester fiber is 10:90 to 50:50
  • the polyester elastic fiber structure in which the fineness of the inelastic polyester crimped short fiber is 2 to 15 dtex.
  • a polyester woven or knitted fabric with a polyester-based adhesive which is a hot-melt type resin binder, is laminated on both sides of a sheet-like polyester-based elastic fiber structure having the structure shown in the following (1) to (5). Then, after forming the composite fiber structure, the composite fiber structure is thermoformed into a curved shape by a die forming process to produce a cup comprising the composite fiber structure.
  • An inelastic polyester crimped short fiber aggregate is made into a matrix, and is composed of a thermoplastic elastomer having a melting point of at least 40 ° C lower than the melting point of the polyester polymer constituting the short fiber and a non-conductive polyester. Elastic composite fibers with the thermoplastic elastomer exposed at least on the fiber surface are dispersed and mixed,
  • polyester-based elastic fiber structure used in the present invention
  • thermoplastic elastomer comprising an inelastic polyester-based crimped short fiber aggregate as a matrix, a thermoplastic elastomer having a melting point of at least 40 ° C lower than the melting point of the polyester polymer constituting the short fibers, and an inelastic polyester. At least one elastic composite fiber exposed on the fiber surface is dispersed and mixed,
  • the fusible conjugate fibers have thermal fixation points in a crossed state, and (3) are formed by heat fusion in a state where the fusible conjugate fibers and the non-vulcanized polyester crimped short fibers are crossed. Heat fixation point,
  • the mixing ratio of the conjugated conjugate fiber and the non-condensable polyester-based crimped staple fiber is 10:90 to 50:50, and
  • the fineness of the inelastic polyester crimped short fibers is 2 to 15 dtex.
  • thermoplastic elastomer is used as a component of the elastic conjugate fiber which plays a role of a heat-adhesive fiber in order to fix a cross point between the matrix and the elastic conjugate fiber or a cross point between the elastic conjugate fibers.
  • a thermoplastic elastomer By using a thermoplastic elastomer, a fiber structure composed of 100% of fibers is formed.
  • the elastic composite fibers are uniformly dispersed in the fibrous structure and intersect with the matrix fibers and / or the elastic composite fibers to form entanglement points. Then, when the entanglement point is heated, the thermoplastic elastomer, which is one component in the elastic conjugate fiber, covers the entanglement point so as to wrap around the entanglement point, and fixes the entanglement point.
  • the confounding point is Occasionally, an amoeba-like omnidirectional flexible fixation point is formed. Since these attachment points are formed by the thermoplastic elastomer, they are extremely strong and highly elastic.
  • the fibrous structure is thermally shaped into a predetermined shape, but the elastically fixed points still remain.
  • the present invention enables the formation of a cup consisting of only high-strength fibers.
  • the present inventors have made various studies and found that in order to maintain the so-called shape retention, the entanglement between fibers was maintained from inside to outside of the fibrous structure. It has been found that it is effective to bond the dough and the backing cloth with an adhesive component, and then integrally mold them into a force-up mold.
  • the inner layer has an unbonded structure, which is not preferable from the viewpoint of long-term shape retention.
  • the fiber structure used in the present invention is firstly moderately mechanically entangled to increase the three-dimensional entanglement of the fibers in the fiber structure and, at the same time, to leave voids in the fiber structure as much as possible. To form an eye structure.
  • the mechanically entangled fiber structure is pre-fused with a heat treatment machine to fix a number of three-dimensional entangled points formed by mechanical entanglement with a thermoplastic elastomer component. It is preferable that the mesh structure is almost completed.
  • the fiber structure is thermoformed and final shaping is performed. If the mesh structure of the fibrous structure has already been formed by fusion, the purpose of thermoforming is limited to simply providing shapeability. For this reason, the surface is not unnecessarily hardened because unnecessary heating is not required in the final shaping.
  • the fibrous structure is formed by the above steps and compositions, not only the feel is soft as a whole, but also the elastic repulsion between the central portion and the outer peripheral portion of the fibrous structure greatly differs. In addition, it is possible to manufacture a cup having stable fiber structure retention.
  • thermoplastic elastomers are important for the formation of firm bonding points between fibers that stabilize the softness of hand, the formation of soft feeling, and the shape retention. Plays a role.
  • the fibers of the non-conductive polyester-based crimped short fiber aggregate constituting the matrix include ordinary polyethylene terephthalate, polybutyrene terephthalate, polyhexamethylene terephthalate, polytetramethylene terephthalate, and polytetramethylene terephthalate. 1,4-dimethylcyclohexaneterephthalate, polypivalolactone, short fibers composed of copolymerized esters of these, mixed cotton of these fibers, or composite fibers composed of two or more of the above polymer components, etc. Is suitable.
  • the cross-sectional shape of the short fiber may be any of circular, flat, irregular, hollow, and the like.
  • the crimped short fibers of the inelastic polyester-based crimped short fiber aggregate according to the present invention are not particularly limited, but short fibers in which crimps have already become apparent are preferable.
  • This manifested crimped fiber may be mechanically crimped by crimper or the like at the time of production, spiral crimped by anisotropic cooling, etc., by side-by-side type or eccentric sheath / core type composite fiber. It can be obtained by heating or the like.
  • the single-fiber fineness is preferably 2 to 15 dte X, more preferably 2 to 13 dte X, and still more preferably 3 to 7 dte X. If the fineness is smaller than 2 dtex, the structure becomes too dense to obtain a moderate sensation of strength, and if the fineness is larger than 15 dtex, the texture becomes coarse and a good feel is obtained. You will not be able to get a cup.
  • the elastic conjugate fiber used in the present invention is formed from a thermoplastic elastomer and an inelastic polyester.
  • the surface of the elastic conjugate fiber is preferably one in which the thermoplastic elastomer occupies at least 1/2 of the surface area.
  • the weight ratio is suitably such that the thermoplastic elastomer and the non-conductive polyester are in a composite ratio in the range of 370 to 70Z30.
  • the form of the elastic conjugate fiber is not particularly limited, but the thermoplastic elastomer and the non-aqueous polyester are preferably of a side-by-side or sheath-core type, and more preferably a sheath. ⁇ Core type.
  • the inelastic polyester forms the core and the thermoplastic elastomer forms the sheath.
  • the core may be concentric or eccentric.
  • eccentric elastic composite fibers are preferable to concentric ones because coiled elastic crimps appear.
  • thermoplastic elastomer is not particularly limited, but is preferably a polyurethane-based elastomer or a polyester-based elastomer.
  • the polyurethane elastomer has a low melting point polyol having a molecular weight of about 500 to 600, such as dihydroxy polyether, dihydroxy polyester, dihydroxy polycarbonate, dihydroxy polyesteramide, and the like.
  • Organic diisocyanates for example, P, p'diphenylmethane diisocyanate, tolylene diisocyanate, isophorone diisocyanate, hydrogenated diphenyl methane diisocyanate, xylylene diisocyanate, 2,6 Diisocyanate methyl propylate, hexamethylene diisocyanate, etc., and a chain extender having a molecular weight of 500 or less, for example, glycol, amino alcohol or triacetate It is a polymer obtained by reaction with all.
  • polyurethanes using polytetramethylene glycol, or polyproprolactone or polybutylene adipate as the polyol.
  • p p'diphenylmethane diisocyanate is preferred as the organic diisocyanate.
  • chain extender P, p'bishydroxyethoxybenzene or 1,4-butanediol is preferable.
  • polyester elastomer examples include a polyetherester block copolymer obtained by copolymerizing thermoplastic polyester as a hard segment and poly (alkylene oxide) glycol as a soft segment, more specifically, terephthalic acid.
  • Aromatic dicarboxylic acids such as sodium, alicyclic dicarboxylic acids such as 1,4-cyclohexanedicarboxylic acid, aliphatic dicarboxylic acids such as succinic acid, oxalic acid, adipic acid, sebacic acid, dodecandioic acid, and dimer acid; Or at least one dicarboxylic acid selected from these ester-forming
  • the polyester-based elastomer has a hard segment of polybutylene-based terephthalate and a soft segment of polyoxybutylene blendy recall. Polymerized polyether polyesters are preferred.
  • the polyester portion constituting the hard segment of the polyester-based elastomer is preferably polybutylene terephthalate in which the main acid component is terephthalic acid and the main diol component is a butylene glycol component.
  • a part (usually 30 mol% or less) of this acid component may be substituted with another dicarboxylic acid component or oxycarboxylic acid component, and similarly, a part of the diol component (usually 30 mol% or less). May be substituted with a dioxy component other than the butylene glycol component.
  • the polyether portion constituting the soft segment of the polyester-based elastomer may be a polyether substituted with a dioxy component other than butylene glycol.
  • the weight ratio of the elastic conjugate fibers in the polyester-based elastic fiber structure of the present invention is preferably from 10 to 50%, more preferably from 25 to 35%. If the weight ratio is less than 10%, a sufficient number of heat fixation points cannot be obtained, resulting in insufficient durability. Conversely, if the weight ratio exceeds 50%, the number of heat-bonded points becomes too large, resulting in a coarse cup. Further, the density of ⁇ fibrous structure of the present invention (the cup member), the fiber density of the maximum thickness portion of the curved structure, 0. 0 1 ⁇ 0. 0 3 5 g Z is preferred cm is 3 New
  • the surface of the constituent fibers of the polyester-based elastic fiber structure is subjected to a surface treatment mainly comprising a polyether / ester-based block copolymer. It is preferred that the agent be applied in an amount of 0.02 to 5.0% by weight based on the total weight of the polyester-based elastic fiber structure.
  • the surface treatment agent mainly composed of a polyether / ester block copolymer is most preferably attached to the entire constituent fibers of the polyester elastic fiber structure.
  • the effect of the present invention can be sufficiently obtained even if the adhesion between them is improved.
  • a surface treatment agent mainly composed of a ter-ester-based block copolymer includes terephthalic acid, isophthalic acid, methasdium sulfoisophthalic acid, or a lower alkyl ester thereof, and a lower alkylenedali.
  • Polyether ester block copolymer consisting of coal, polyalkylene glycol, and polyalkylene glycol monoether.
  • Polyethylene alkyl phenyl ether phosphate metal salt, polyoxyethylene alkyl phenyl ether Examples thereof include those in which an alkali metal or sulfate of sulfur is dispersed using a surfactant such as an ammonium salt or an alkanolamine salt thereof.
  • the resin binder used in the present invention is required to be a hot melt type resin binder which is melted and bonded for the first time by heat in the form of powder, sheet, net or the like.
  • resin binders that are liquid at room temperature are widely used for laminating, but they are not only poor in handling and working environment in the manufacturing process, but also because the adhesive penetrates into the inside of the fiber structure. As a result, the elasticity of the texture is impaired by the precious software.
  • the composition of the resin binder is the same polyester resin as that of the polyester elastic fiber structure, the outer material and the lining.
  • the cloth used as the surface material and lining of the lip of the present invention is not particularly limited as long as it is a cloth made of polyester fibers having a higher melting point than the hot melt type resin binder used in the present invention. Further, it is preferable that the composition of the fabric to be the front and back linings is made of only polyester. Further, the fabric of the front and back lining is preferably a woven or knitted fabric, but may be a nonwoven fabric or the like.
  • An elastic conjugate fiber containing a thermoplastic elastomer as one component and inelastic polyester crimped staple fiber are mixed at a predetermined ratio, and after a normal carding process, the required weight per unit is obtained by a cross layer. After laminating and forming a sheet, the sheet is mechanically entangled by a method such as needle punching and Z or warping, and the fiber structure density is 0.009 to 0.040 g Z cm 3 non-woven fabric sheet.
  • a non-woven fabric sheet is pre-fused with a heat treatment machine at a temperature within a range of not less than Em (the melting point of the thermoplastic elastomer) and not more than [T m (the melting point of the inelastic polyester) 130]. Fix the confounding point between them and wind up with a winder.
  • a hot melt type resin binder is sandwiched between the nonwoven fabric sheet and the front and back linings in order to adhere the polyester fiber top and bottom linings to both sides of the nonwoven fabric sheet. Then, the resin sandwiched between the resin binders is heated to dissolve the binder, and the nonwoven fabric sheet and the front and back linings are laminated and bonded to obtain a composite fiber structure.
  • the composite fiber structure has a polyester fiber front and back lining bonded to both sides of a nonwoven fabric sheet with a polyester adhesive.
  • the composite fiber structure is set in a cup mold for thermoforming, and the outer material and lining and the fiber structure are thermoformed integrally to obtain a predetermined curved cup.
  • the cup of the present invention and the method of manufacturing the same are not limited to cups due to mold changes and the like.
  • the inside has a fiber structure such as a pad such as a bust pad, a shoulder pad, or a hip pad, and the surface has a surface. It can also be used for those covered with cloth and its manufacturing method.
  • thermoplastic elastomer has an intrinsic viscosity of 1.0 (dissolved in orthochlorophenol and measured by a conventional method at 3), a melting point of 1551 :, and a breaking elongation of the film of 1500%.
  • the 300% elongation stress was 0.3 kgZmm 2 and the 300% elongation recovery rate was 75%.
  • thermoplastic elastomer as a sheath
  • polybutylene terephthalate as a core
  • an elastic composite fiber was spun by a conventional method so that the weight ratio of the core Z sheath was 550.
  • This elastic composite fiber is an eccentric sheath-core type composite fiber. This fiber was drawn about twice, cut into 64 mm, and then heat-treated with hot water of 95 to exhibit low shrinkage and crimp. After drying, a surface treatment agent (oil) was applied. The obtained elastic conjugate fiber was 6.6 dtex.
  • the composite fiber structure was put into a thermoforming cup mold, and subjected to thermoforming at 200 ° C. for 30 seconds to produce a curved breast cup material.
  • Table 1 shows the physical properties of the obtained breast patch.
  • the mold retention after 100 cycles of 0 cycle washing was visually evaluated.
  • the repulsion (g) at the center of the cup material (at the position where the thickness is maximum) is 10
  • the feeling is also correlated with the repulsion force.
  • the touch feeling was judged, and a soft and repulsive material was rated as ⁇ , and a hard tactile sensation or one with low repulsion force was rated as ⁇ .
  • the single yarn fineness of the inelastic polyester short fiber was set to 13.0 dte X in Example 2, 0.6 dte X in Comparative Example 1, and 20.0 dtex in Comparative Example 2.
  • Table 1 shows the physical properties of the obtained breast patch.
  • Example 1 6. 6 0. 023 3 5 ⁇ ⁇ Example 2 1 3.0 0. 022 40 ⁇ ⁇ Comparative example 1 0.6. 0. 022 43 ⁇ (hard) ⁇ Comparative example 2 20. 0 0. 022 22 ⁇ (coarse) mu (fluff)
  • the single-fiber fineness of the non-woven polyester fiber is 6.6 dtex in Example 1 and 1 3. O dtex in Example 2, and it has excellent elasticity, good texture, and good mold retention. The material was obtained.
  • Polyester crimped short fibers (single yarn fineness: 6.6 dte X, fiber length: 51 mm, number of crimps: 14 pieces / inch (5.5 cm)) obtained by a conventional method, and viscous conjugate fibers ( Eccentric sheath core type) 6. dtex, 51 mm length (sheath: melting point: 155, block copolymer polyether polyester elastomer, core: polybutylene terephthalate) and polyether ester About 16% by weight of a surface treating agent mainly composed of a block copolymer is attached to the total fiber weight.
  • the mixing ratio of the hydrophilic composite fiber in the polyester-based elastic fiber structure was 1%. 0%, 20% in Example 4, 50% in Example 5, 60% in Comparative Example 3, and 5% in Comparative Example 4 were mixed with a card to prepare a web.
  • the composite fiber structure was put into a thermoforming machine and heat-treated at 190 ° C. for 10 seconds to obtain a curved cup material.
  • Table 2 shows the physical properties of the obtained breast patch.
  • Example 3 10 0. 03 1 ⁇ ⁇ ⁇ Example 4 20 0.02 ⁇ ⁇ ⁇ Example 5 50 0.028 ⁇ ⁇ ⁇ Comparative Example 3 60 0.030 0 ⁇ - ⁇ ⁇ Comparative Example 4 5 0.030 ⁇ ⁇ ⁇ — X
  • the cup material made with the blending ratio of the elastic conjugate fiber in the range of 10 to 50% is excellent in feeling, elasticity, and washing resistance.
  • the feeling becomes coarse and hard.
  • Comparative Example 4 of 5%, it was found that there was a problem in elasticity and washing durability, and it was not suitable for practical use.
  • the forcep made of the composite fiber structure of the present invention has a high elasticity because the polyester-based elastic fiber structure, the outer and lining materials, and the molten sheet of the resin binder are integrally molded by die molding. It not only has excellent air permeability, but also has outstanding washing durability and shape retention.
  • the polyester-based elastic fiber structure, the outer material and the lining, and the molten sheet are integrally molded, the outer material or the lining hardly peels off from the polyester-based fibrous structure, and the inner polyester-based fiber structure is hardly separated. Since the elastic fiber structure is supported by the outer material or the lining, it is less likely to lose its shape.
  • the cup made of the composite fiber structure of the present invention is entirely made of polyester, it can be easily handled during manufacturing and after washing, has quick drying properties, is inexpensive, and can be recycled. .

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Corsets Or Brassieres (AREA)
  • Multicomponent Fibers (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

L'invention concerne un tricot en polyester, laminé collé par un adhésif polyester utilisé comme charge liante de type thermofusible sur les deux surfaces d'une structure en fibre élastique polyester en forme de feuille dans laquelle sont dispersés puis mélangés des fibres composites élastiques qui utilisent, en tant que matrice, un ensemble à fibres courtes de frisure polyester non-élastique; lesquelles fibres composites sont constituées d'un élastomère thermoplastique présentant un point de fusion inférieur d'au moins 40 °C à celui d'un polymère polyester constituant les fibres courtes et le polyester non-élastique. Dans ces fibres composites, l'élastomère thermoplastique est exposé sur les surfaces des fibres de manière à former une structure en fibre composite, laquelle est ensuite thermoformée en une forme courbe par formation par moulage afin d'obtenir un bonnet.
PCT/JP2002/006841 2001-08-01 2002-07-05 Bonnet constitue d'une structure en fibre composite et procede de production associe WO2003011063A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR1020037004683A KR100842197B1 (ko) 2001-08-01 2002-07-05 복합섬유 구조체로 이루어진 컵 및 그 제조방법
JP2003516307A JPWO2003011063A1 (ja) 2001-08-01 2002-07-05 複合繊維構造体からなるカップ及びその製造方法
HK04104056A HK1060962A1 (en) 2001-08-01 2004-06-07 Cup consisting of composite fiber structure and production method therefor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001233334 2001-08-01
JP2001-233334 2001-08-01

Publications (1)

Publication Number Publication Date
WO2003011063A1 true WO2003011063A1 (fr) 2003-02-13

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PCT/JP2002/006841 WO2003011063A1 (fr) 2001-08-01 2002-07-05 Bonnet constitue d'une structure en fibre composite et procede de production associe

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JP (1) JPWO2003011063A1 (fr)
KR (1) KR100842197B1 (fr)
CN (1) CN1289014C (fr)
HK (1) HK1060962A1 (fr)
TW (1) TW567046B (fr)
WO (1) WO2003011063A1 (fr)

Cited By (3)

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WO2005102683A1 (fr) * 2004-04-26 2005-11-03 Teijin Fibers Limited Structure de fibre mélangée et son procedé de production
JP2005307408A (ja) * 2004-04-26 2005-11-04 Teijin Fibers Ltd 多層繊維構造体からなるカップ材およびその製造方法および乳房用カップ
KR20160132429A (ko) * 2014-03-13 2016-11-18 칼 프로이덴베르크 카게 광 조정용 소자

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JP5144416B2 (ja) * 2008-07-28 2013-02-13 株式会社ワコール 湾曲型テープ、及び、これを備えたカップ付き女性用衣類
TWI405886B (zh) * 2009-12-31 2013-08-21 San Fang Chemical Industry Co 含彈性體之複合纖維及其製造方法，及包含該複合纖維之基材及其製造方法
CN105795537A (zh) * 2016-05-04 2016-07-27 蔡荣鹏 一种内衣
CN107183801A (zh) * 2017-07-26 2017-09-22 上海嫒妤服装有限公司 一种丝绸棉本体、丝绸棉模杯及其制造方法

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JPH01174659A (ja) * 1987-12-29 1989-07-11 Kanai Hiroyuki 成型ブラジャーカップ用基材
JPH01239105A (ja) * 1988-03-15 1989-09-25 Datsuchiesu:Kk 装身用パッド及びその製造法
JPH05195397A (ja) * 1992-01-16 1993-08-03 Teijin Ltd パッド材及びその製造方法
JP2001234402A (ja) * 2000-02-24 2001-08-31 Wacoal Corp 衣類用パッドの成型方法および衣類用パッド

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005102683A1 (fr) * 2004-04-26 2005-11-03 Teijin Fibers Limited Structure de fibre mélangée et son procedé de production
JP2005307408A (ja) * 2004-04-26 2005-11-04 Teijin Fibers Ltd 多層繊維構造体からなるカップ材およびその製造方法および乳房用カップ
US7387976B2 (en) 2004-04-26 2008-06-17 Teijin Fibers Limited Composite fiber structure and method for producing the same
JP4496002B2 (ja) * 2004-04-26 2010-07-07 帝人ファイバー株式会社 多層繊維構造体からなるカップ材の製造方法および乳房用カップ
KR20160132429A (ko) * 2014-03-13 2016-11-18 칼 프로이덴베르크 카게 광 조정용 소자
KR101922192B1 (ko) 2014-03-13 2018-11-26 칼 프로이덴베르크 카게 광 조정용 소자
US10472770B2 (en) 2014-03-13 2019-11-12 Carl Freudenberg Kg Element for manipulating light

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HK1060962A1 (en) 2004-09-03
JPWO2003011063A1 (ja) 2004-11-18
KR20040028642A (ko) 2004-04-03
KR100842197B1 (ko) 2008-06-30
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TW567046B (en) 2003-12-21

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