WO2003010259A1 - Procede de fabrication de carburants distilles - Google Patents
Procede de fabrication de carburants distilles Download PDFInfo
- Publication number
- WO2003010259A1 WO2003010259A1 PCT/RU2001/000283 RU0100283W WO03010259A1 WO 2003010259 A1 WO2003010259 A1 WO 2003010259A1 RU 0100283 W RU0100283 W RU 0100283W WO 03010259 A1 WO03010259 A1 WO 03010259A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oil
- shale
- raw materials
- κiπ
- mass
- Prior art date
Links
- 239000000446 fuel Substances 0.000 title abstract description 30
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 124
- 239000000203 mixture Substances 0.000 claims abstract description 54
- 239000003079 shale oil Substances 0.000 claims abstract description 38
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 36
- 239000011707 mineral Substances 0.000 claims abstract description 36
- 238000002156 mixing Methods 0.000 claims abstract description 23
- 239000004058 oil shale Substances 0.000 claims description 63
- 239000007788 liquid Substances 0.000 claims description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 11
- 238000000265 homogenisation Methods 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 235000015076 Shorea robusta Nutrition 0.000 claims description 3
- 244000166071 Shorea robusta Species 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 239000003245 coal Substances 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 37
- 239000000295 fuel oil Substances 0.000 abstract description 10
- 238000004517 catalytic hydrocracking Methods 0.000 abstract description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 4
- 238000009835 boiling Methods 0.000 abstract description 4
- 239000002283 diesel fuel Substances 0.000 abstract description 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 2
- 239000003208 petroleum Substances 0.000 abstract 1
- 230000008569 process Effects 0.000 description 106
- 239000002994 raw material Substances 0.000 description 77
- 239000000047 product Substances 0.000 description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 37
- 239000007789 gas Substances 0.000 description 26
- 239000000654 additive Substances 0.000 description 15
- 239000010454 slate Substances 0.000 description 15
- 230000036571 hydration Effects 0.000 description 14
- 238000006703 hydration reaction Methods 0.000 description 14
- 230000000996 additive effect Effects 0.000 description 10
- 238000004821 distillation Methods 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 230000007423 decrease Effects 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 238000012546 transfer Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000003502 gasoline Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 231100001261 hazardous Toxicity 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000012263 liquid product Substances 0.000 description 3
- 239000013589 supplement Substances 0.000 description 3
- -1 3-15 Chemical compound 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000010763 heavy fuel oil Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000002169 hydrotherapy Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000004137 mechanical activation Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 1
- 229960005382 phenolphthalein Drugs 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000003609 sapropelite Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/22—Non-catalytic cracking in the presence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
Definitions
- the yield of fuel distillates is 55-60m. % on raw materials ⁇ and thermoinvestment and up to 90m. % ⁇ and hydropacking.
- the hydraulic process distillation and hydraulic distillation process it can be converted to light motor fuel, including automobile gasoline and diesel.
- Methaline is obtained by hydration of technical products that contain condensed aromatic hydrocarbons, mainly, phthalin and its products.
- the process of obtaining tetralin and its alkaline derivatives is very advantageous.
- a positive product is also obtained and the final product.
- the well-known method in the form of liquid activating additive, is the use of hydrated fraction with ⁇ . ⁇ i ⁇ . 300 - 400 ° ⁇ in the amount of 1 - 5 wt. %
- the yield of fuel distillates is 55-60 wt. % ⁇ and thermal expansion and up to 90 wt. % ⁇ and hydropacking.
- a well-known solution has a drawback, which is used in the quality of the added component of the hydrated fraction with ⁇ . ⁇ i ⁇ . 300-400 ° C also increases the cost of the end products in view of the fact that for its production an additional stage is necessary for highlighting the distillation and further cooling for the operation.
- ⁇ i ⁇ . 300-400 ° C WITH HIGHER WATER PRODUCTS. Sufficiently high cost of hydrated fractions with ⁇ . ⁇ i ⁇ . 300-400 ° C supports the process of use in an inactive processing industry of a known method.
- the objective of the present invention is to increase the efficiency of the process in order to process heavy inactive products, including the reduction of the output of the invention.
- a non-technical result of the invention is the exclusion of the use of a hydrated fraction with ⁇ . ⁇ i ⁇ . 300 - 400 ° C when stored, the product is safe.
- I use hot oil shales containing g / ⁇ : molybdenum 3-15, nickel 20-35, caliber 3-10, ⁇ m 30-40, copper 15-40 and lead 5-20.
- the homogenization is carried out in a mixing device with a temperature of 80 - 10 ° ⁇ .
- hot oil shale and mechanical activation are additionally crushed for sizes of 30-100 microns.
- the chemical exposure is known to the type ⁇ -14 type equipment, as well as to the known disperse mixture (homogenizing mixture), the mixture is dispersed.
- An optional embodiment of the invention is also available, while the mixture is also dual-homogenized.
- the resulting mixture promotes mixing and intensive homogenization in order to equally distribute the added actives to the entire raw material volume.
- P ⁇ nya ⁇ ie " ⁇ e ⁇ m ⁇ nve ⁇ siya" or gid ⁇ e ⁇ ing, is ⁇ lzuem ⁇ e in resort ⁇ m iz ⁇ b ⁇ e ⁇ enii, imee ⁇ ⁇ aditsi ⁇ nn ⁇ e value and v ⁇ lyuchae ⁇ ⁇ ivedenie in ⁇ n ⁇ a ⁇ ⁇ e ⁇ i ⁇ uem ⁇ g ⁇ sy ⁇ ya with v ⁇ d ⁇ d ⁇ m - 500-2000 ⁇ bem ⁇ v v ⁇ d ⁇ da or v ⁇ d ⁇ d ⁇ s ⁇ de ⁇ zhascheg ⁇ gas ⁇ i n ⁇ malny ⁇ usl ⁇ viya ⁇ ( ⁇ 0 ° C, ⁇ -0,1013 ⁇ Pa) for one volume of liquid raw materials at a pressure of 4.0-15.0 PSa, a volumetric speed of 1-3 hours "1 (an adjustable contact time of 20-90 min) and a temperature of 390-440 ° ⁇ .
- ⁇ imalnymi usl ⁇ viyami ( ⁇ em ⁇ e ⁇ a ⁇ u ⁇ a, pressure, ⁇ bemnaya s ⁇ s ⁇ ) yavlyayu ⁇ sya Te, ⁇ i ⁇ y ⁇ ⁇ b ⁇ azue ⁇ sya ma ⁇ simaln ⁇ e ⁇ liches ⁇ v ⁇ tselev ⁇ g ⁇ ⁇ du ⁇ a not nablyudae ⁇ sya nezhela ⁇ eln ⁇ g ⁇ susches ⁇ venn ⁇ g ⁇ ⁇ s ⁇ l ⁇ zheniya, ⁇ s ⁇ benn ⁇ in ⁇ ubcha ⁇ y ⁇ echi and ⁇ ea ⁇ e.
- Water-based products are also available in liquid form.
- the direct catalytic effect on the reduction of compounds of raw materials and the products of its decay indicates a significant increase in the mineral content, which increases
- oil shale which contains (wt.%): 45-60 mineral part and 40-55 mineral part.
- shales containing g / ⁇ are used: molybdenum , 3-15, nickel 20-53, temperature 3-10, ⁇ m 30-40, copper 15-40 and lead 5-20.
- the mineral part of the oil shale contains (wt.%):
- any raw materials of a heavy type can be used - vacuum gas oil, heavy fuel oil, heavy oil, heavy oil, heavy oil, heavy oil, heavy oil, and heavy oil.
- shale oil which consists of a fraction with a boiling range of 200–400 ° ⁇ and which contains at least
- This oil is well-known - thermal oil shale with a solid transfer agent.
- the well-known fine-grained oil shale is dried, it is heated to a furnace with a separate heating medium with a vapor-gas mixture.
- the last, after its dry calculation, is spoiled with a mixture of solvents with the output of a heavy oil mist. Further, the vapor-gas mixture is cooled in the condensate with the output of the direct condensate of the heavy oil fraction in the product kachestvo.
- the condensed part of the vapor-gas mixture is separated in the refined section with the release of the light oil fraction, which is discharged from the by-product.
- the method ensures the production of valuable fractions from the oil shale with a low content of mechanical impurities and the optimization of the economic situation (“Waste and industrial waste”.
- Distinctive feature obtained from the t.kip. 200-400 ° C is a shale oil, which, in its composition, contains a high amount of water (not less than 10 wt.%) Due to the fact that it is significantly These compounds are supplied with a 2-4-group of large hydrocarbon hydrocarbons (di-, tetra- and hexane-derivatives of phenylanthene, benzene, benzene, and benzene). Indicated function with ⁇ . ⁇ i ⁇ . 200-400 ° C of oil is a sufficiently efficient product of hydrogen and heat treatment and hydraulic processing of non-essential raw materials (non-productive).
- the optimal water content in shale oil is supplied with oil.
- 200-400 ° C should be no less than Yumas. % With a decrease in the amount of water in shale oil below Yumas. % noticeably decreases the yield of fuel distillations in the process of heat treatment and hydraulics.
- the increase in the amount of water in shale oil is higher than 12 wt. % Practically do not affect the output of fuel distillates, but they do not end up.
- the fraction of shale oil with a range of 200-400 ° ⁇ and containing at least 10.0 wt.% Of the water is included in the amount of 1.0 - 6.0 wt.% Of non-raw materials.
- a good and good result is that it is possible to obtain and use oil or hydraulic products in the Czech Republic or in Finland However, in this and other cases, the output of light products will be significantly lower due to the result of that, in 9 The reactive system will not have the necessary quantity of hydraulic compounds that are equipped with non-aquatic properties.
- the target fuel distillates for the separation of food products and hydraulics in conjunction with the invention are the usual widespread fuel activities:
- the resulting fuel distillates may be processed into components of commercial fuels or into conventional fuels by conventional methods of processing.
- a gasoline fraction can be doubled up for special catalytic converters with a petrol processing unit 82-93.
- Diesel fraction after hydraulics can be used as a diesel fuel with a chain number of 48-50.
- Conventional fuel products are the basic products of the process in accordance with the invention. They can be easily converted to consumer fuels, i.e.
- the invention results in a result that does not result from obvious evidence from the prior art.
- the installation diagram for the implementation of the required method is provided in the figure.
- An open (combustible) oil shale with a size of 25–250 mm or a shale fines with a size of 0–25 mm from an iron wagon is empty for storage.
- Warehouse for oil shale is available in the bunker for the purchase of oil shale 1.
- hot oil shale for the storage of the oil in the bunker for oil oil shale 1
- hot oil shale is fed to a crusher with a manual filter (2), where it is crushed to a size 10 particles 8mm.
- the shale shredded up to 8 mm in size is fed into the “Nez-14” disembratement (3), where further shale is shredded up to a 1 mm particle size.
- the “K ⁇ -14” demis- Disintegrator “Ez ⁇ -14” is equipped with a cyclone, air filter, manual filter, and a sockets.
- the shredded slate is released to the vibrator with a working distance of 140 mb.
- the entire shale grinding unit is equipped with protective equipment and protective equipment. It is intended for separating shale particles with sizes above 140 mk.
- Raw materials are prepared by the following process. ⁇ Brass ⁇ A heated mixer, where a temperature of 80-100 C is maintained, or another stirring device (9), is used (if it is not emitted), First, the shale oil is supplied to the mixing apparatus (9), then the oil from the reservoir (8) and the slate are supplied through the dispenser (6). Processors for the supply of components of the raw material mixture carry out the operations of the stirring device in order to avoid sitting on the bottom of the oil shale.
- the mixing device does not provide an efficient mixing of the 3 large-sized mixture, then it is more suitable for the large-scale mixing (hermetic). At this temperature, in the unit for the production of raw materials, it is necessary to maintain raw materials in the range of 80 -10 ° C to ensure the pumping is good.
- the raw material heating furnace (14) has two sections ⁇ and B. In the section, they are maintained in the range of 380-400 ° ⁇ , and at the outlet from the furnace, 460-490 ° ⁇ is dependent on it. Partially converted raw materials are delivered to the lower part of the furnace from the furnace.
- P ⁇ dacha v ⁇ d ⁇ d ⁇ s ⁇ de ⁇ lsascheg ⁇ gas (s ⁇ de ⁇ zhanie 80% water) is 1000–1500 nm 3 per m 3 of raw material.
- on top of the hot unit go to the main fractions, growing up to 360-380 ° C, from below the hot unit ⁇ a ⁇ a ⁇ tsii, vy ⁇ i ⁇ ayuschie above 360-380 ° C in admixture with ⁇ vo ⁇ dymi ⁇ du ⁇ ami.
- ⁇ e ⁇ ny ⁇ g ⁇ yacheg ⁇ se ⁇ a ⁇ a ⁇ a vmes ⁇ e with v ⁇ d ⁇ d ⁇ s ⁇ de ⁇ z haschim gaz ⁇ m ( ⁇ SG) ⁇ ydya sis ⁇ emu ⁇ lazhdeniya (17) in na ⁇ a ⁇ livae ⁇ sya se ⁇ a ⁇ a ⁇ e vys ⁇ g ⁇ pressure (18), wherein ⁇ is ⁇ di ⁇ ⁇ delenie ⁇ SG ⁇ gid ⁇ geniza ⁇ a. ⁇ SG is ideal for mixing with fresh water, and then on a circulating chamber (25).
- the bottom product of the hot unit (such as sludge) is cooled by a coolant valve 20 and is cooled to an intermediate temperature (21)
- Liquid (such as a liquid) is mixed with hydrogenation (a hot heater) and the mixture is used after heating in a furnace (24), which leads to a decrease in gas (water) radiation (26).
- ⁇ i ⁇ . up to 180 C diesel fraction with ⁇ . ⁇ i ⁇ . 180-360 ° C, gas oil with ⁇ . ⁇ i ⁇ . 360-500 ° ⁇ and a residue that grows above 500 ° ⁇ (figure).
- ⁇ ⁇ aches ⁇ ve ⁇ s ⁇ a ⁇ chn ⁇ g ⁇ ne ⁇ yan ⁇ g ⁇ sy ⁇ ya in ⁇ ivedenny ⁇ ⁇ ime ⁇ a ⁇ is ⁇ lzuyu ⁇ : gud ⁇ n mixture za ⁇ adn ⁇ sibi ⁇ s ⁇ i ⁇ ne ⁇ ey, ⁇ y imee ⁇ ⁇ a ⁇ a ⁇ e ⁇ is ⁇ i ⁇ u following: ⁇ l ⁇ n ⁇ s ⁇ - 984 ⁇ g / m 3, elemen ⁇ ny s ⁇ s ⁇ av, wt%: C, 86.8;.
- ⁇ ⁇ aches ⁇ ve sa ⁇ eli ⁇ a is ⁇ lzuyu ⁇ : ⁇ yad ⁇ v ⁇ y ⁇ ibal ⁇ iys ⁇ y shale having the following ⁇ a ⁇ a ⁇ e ⁇ is ⁇ i ⁇ u wt%: ⁇ ⁇ - 46,70; C ⁇ 01 2 min -8.32; C ⁇ a ⁇ - 81.3; ⁇ ( ⁇ -9.25; ⁇ s - 0.28; 8 ", - 0.90; ⁇ ⁇ a - 3.0.
- ⁇ ⁇ aches ⁇ ve zhid ⁇ y a ⁇ ivi ⁇ uyuschey d ⁇ bav ⁇ i is ⁇ lzuyu ⁇ slantsev ⁇ e masl ⁇ , s ⁇ s ⁇ yaschee of ⁇ a ⁇ tsii with ⁇ edelami vy ⁇ i ⁇ aniya 200-400 ° C, having the following ⁇ a ⁇ a ⁇ e ⁇ is ⁇ i ⁇ u: 995 ⁇ l ⁇ n ⁇ s ⁇ ⁇ g / m ⁇ aza ⁇ el ⁇ el ⁇ mleniya 1.5696, m ⁇ le ⁇ ulya ⁇ naya weight 290 s ⁇ de ⁇ zhanie as ⁇ al ⁇ en ⁇ v 3,8mas. %, elemental composition, wt. %: C-82.95, ⁇ -10.0; ⁇ - 0.56; 8-0.6; Stagnation temperature - minus 20 ° ⁇ , viscosity - 14.9 cSt and 50 ° ⁇ .
- the process of temperature control or hydraulics of the appliance is either on or on installation with a volume of 6 liters or on a manual installation of 10.
- the quantitatively edible and aromatic additives make up 0.5–6.0%, the quantitative gain is 0.5–5.0% of the total weight of the pulp.
- Liquid products of the process are distilled at a fraction of ⁇ . ⁇ i ⁇ . up to 180 ° ⁇ , 180-360 ° ⁇ , 360-500 ° ⁇ and remains above 500 ° ⁇ .
- Shale-free mixture for processes of thermal treatment or hydroprocessing is prepared by means of the subsequent mixing of non-volatile raw materials, especially in case of heavy oil. ⁇ i ⁇ . 200-400 ° C and ryadovo 13 oil shale. Mixing is carried out in a heated stirrer at a temperature of at least 85 ° ⁇ for 2.5 hours, and then the resulting mixture is homogenized in a dispersing device or on a device. By doing this, a mixture is not stratified over a long period of time.
- EXAMPLE 1 The initial mixture is prepared by mixing a pot of 10 ⁇ , hot shale 0.2 ⁇ (mineral composition of the mineral part is 40 wt.%) And a fraction of the shale oil with ⁇ . ⁇ i ⁇ . 200-400 C with a water content of 10 wt. %, 0.3 ⁇ . Mixing is carried out in a heated mixer at a temperature of at least 85 ° C for 2.5 hours. Then the mixture promotes activation and homogenization. ⁇ e ⁇ m ⁇ nve ⁇ siyu vedu ⁇ ⁇ d pressure ⁇ Pa 3-5, ⁇ em ⁇ e ⁇ a ⁇ u ⁇ e 425-450 ° C ⁇ bemn ⁇ y s ⁇ s ⁇ i 1-2 hour "1.
- EXAMPLE 2 The raw materials and conditions of the process are similar to those of Example 1, with the exception of the fact that the slate contained 45 wt. % of the mineral part.
- the indicators of the process of heat transfer are given in the table ⁇ ° 1.
- Example 3 The raw materials and conditions of the process of heat transfer are similar to the method
- EXAMPLE 4 The raw materials and conditions of the thermoinvestment are similar to Example 1, with the exception of the fact that the slate contained 60 wt. % of the mineral part. The performance indicators of the process are listed in Table 1.
- EXAMPLE 5 The raw materials and conditions of the process are similar to those of Example 1, with the exception of the fact that the slate contained 65 wt. % of the mineral part.
- the performance indicators of the process are listed in Table 1.
- Example 6 The starting raw material is prepared by mixing a 10 ton oil tank, 0.2 ton hot oil shale, and oil shale oil fraction with ⁇ . boiling 200 - 400 ° C and a water content of 10 wt. % 0.3 ⁇ . Mixing is carried out in a heated mixer at a temperature of at least 85 ° C for 2.5 hours. Then the mixture promotes activation and homogenization. At this time, the shale content is 0.5 mass. % 14 ⁇
- the products obtained have the following characteristics: gasoline fraction with ⁇ . ⁇ i ⁇ . up to 180 ° C: index of application 1, 4216, elemental composition, wt.%: C 84, 53; ⁇ 13.75; 8 0.46; ⁇ 0.06; diesel ⁇ with ⁇ . ⁇ i ⁇ . 180-360 ° C: index of application 1, 4786; elemental composition, wt.%: C 85.89, ⁇ 12.26, 8 0.69, ⁇ 0.06 gas oil fraction with ⁇ . ⁇ i ⁇ . 360-500 ° C: index of application 1, 5211, elemental composition, wt.%: C 86.60, ⁇ 11.24, 8 1.29, ⁇ 0.21; left with t.kip.
- EXAMPLE 8 The raw materials and conditions of the thermoinvestment are similar to Example 6, except for the shale content in the amount of 2.0 mass. % Thermostatic indicators are shown in Table 2.
- EXAMPLE 9 The raw materials and conditions of the process are similar to those of Example 6, except for the addition of oil shale in the amount of 3.0 mass. % Indicators of the thermal process are given in Table 2.
- EXAMPLE 10 The raw materials and conditions of the process are similar to those of Example 6, except for the addition of oil shale in the amount of 5.0 wt. % Thermostatic indicators are shown in Table 2.
- EXAMPLE 11 The raw materials and conditions of the process are similar to those of Example 6, with the exception of the amount of oil shale with ⁇ . ⁇ i ⁇ . 200-400 ° C - 0.5 wt.%.
- the indicators of the process are given in Table 2.
- Example 12 The raw materials and conditions of the process are similar to the example.
- Example 14 The raw materials and conditions of the process are similar to those for the process.
- EXAMPLE 15 The raw materials and conditions of the process are similar to those of Example 6, with the exception of the amount of shale oil fractions with ⁇ . ⁇ i ⁇ . 200-400 ° C shale oil - 6.0 wt. % Indicators of the thermal process are given in Table 2.
- EXAMPLE 16 The raw materials and conditions of the thermal process are similar to those of Example 6, with the exception of the quantity of hot oil shale - 2.0 wt. % Indicators of the thermal process are given in Table 2.
- Example 17 The raw materials and conditions of the process are similar to those of Example 6, with the exception of the quantity of fractions with ⁇ . ⁇ i ⁇ . 200-400 With shale oil - 3.0m. % Indicators of the thermal process are given in Table 2.
- EXAMPLE 18 The starting raw material is prepared by mixing a 7-, 5, t, risel with ⁇ . ⁇ i ⁇ . above 500 ° C - 2.5 ⁇ , hot oil shale - 0.2 ⁇ and oil shale - 0.3 ⁇ .
- Mixing is carried out in a heated mixer at a temperature of at least 85 ° ⁇ , for
- the mixture is activated or homogenized.
- the content of the mineral part in the shale was - 40mass. %
- EXAMPLE 19 The raw materials and conditions of the hydroprocessing process are similar to Example 18, with the exception of the fact that the slate was 45 months old. % of the mineral part. The performance of the hydraulic process is shown in Table 3. EXAMPLE 20. The raw materials and conditions of the hydraulic process are similar.
- Example 21 The raw materials and conditions of the hydroprocessing process are similar to Example 18, with the exception of the fact that the slate contained a mass of 60%. % of the mineral part. Hydraulic process indicators are shown in Table 3.
- EXAMPLE 22 The raw materials and conditions of the hydroprocessing process are similar to Example 18, with the exception of the fact that the slate contained 65 wt. % of the mineral part. Hydraulic process indicators are shown in Table 3.
- EXAMPLE 23 The raw materials and conditions of the hydroprocessing process are similar to Example 18, except for the shale content in the amount of 0.5 mass. % Hydration indicators are shown in Table 4.
- EXAMPLE 24 The raw materials and conditions of the hydroprocessing process are similar to Example 18, with the exception of shale formation in the amount of 1.0 mass. % The performance of the hydraulic process is shown in table 4.
- Example 25 The raw materials and conditions of the hydraulic process are similar.
- EXAMPLE 26 The raw materials and conditions of the hydroprocessing process are similar to Example 18, except for the shale content in the amount of 3.0 mass. % Hydration indicators are shown in Table 4.
- EXAMPLE 27 The raw materials and conditions of the hydroprocessing process are similar to Example 18, with the exception of shale formation in the amount of 5.0 mass. % Hydration indicators are shown in Table 4. 17 EXAMPLE 28. The raw materials and conditions of the hydroprocessing process are similar to Example 18, with the exception of the contraction of the oil shale of the fraction with ⁇ .kip. 200-400 ° C shale oil 0.5 wt. % The performance of the hydraulic process is shown in table 4. EXAMPLE 29. The raw materials and conditions of the hydraulic process are similar.
- EXAMPLE 30 The raw materials and conditions of the hydration process are similar to Example 18, with the exception of the fraction with ⁇ . ⁇ i ⁇ . 200-400 ° C shale oil 2.0mass. % Hydration indicators are shown in Table 4.
- EXAMPLE 31 The raw materials and conditions of the hydration process are similar to Example 18, with the exception of the fraction with ⁇ . ⁇ i ⁇ . 200-400 ° C shale oil 3.0mass. % Hydration indicators are shown in Table 4.
- EXAMPLE 32 The raw materials and conditions of the hydraulic process are similar to Example 18, with the exception of the fraction with ⁇ . ⁇ i ⁇ . 200-400 ° ⁇ shale oil 6.0mass. % Hydration indicators are shown in Table 4.
- EXAMPLE 33 The raw materials and conditions of the hydroprocessing process are similar to Example 18, with the exception of a bulk oil shale of 2.0 months. % The performance of the hydraulic process is shown in Table 4.
- EXAMPLE 34 The raw materials and conditions of the hydraulic process are similar.
- EXAMPLE 35 The raw materials and conditions of the process are similar to those of Example 6, with the exception of the water content of oil shale from ⁇ . ⁇ i ⁇ . 200 - 400 C 8.0 mt. % Indicators of the process of heat transfer are given in Table 5.
- EXAMPLE 36 The raw materials and conditions of the process are similar to those of Example 6, with the exception of the presence of water in the oil shale with ⁇ . ⁇ i ⁇ . 200-400 ° C Yumas. % Indicators of the process of heat transfer are given in Table 5.
- EXAMPLE 37 The raw materials and conditions of the process are similar to those of Example 6, with the exception of the water content of oil shale from ⁇ . ⁇ i ⁇ . 200 - 400 C 12mas. % Indicators of the process of heat transfer are given in Table 5.
- Example 38 The raw materials and conditions of hydroprocessing of the process are similar to those of Example 18, with the exception of the combination of water and oil shale oil with ⁇ . ⁇ i ⁇ . 200-400 ° C 8.0m. % Hydration indicators are shown in Table 5.
- EXAMPLE 39 The raw materials and conditions of the hydroprocessing process are similar to those of Example 18, with the exception of the presence of water containing oil shale from ⁇ . ⁇ i ⁇ . 200-400 ° C 10.0m. % Hydration indicators are shown in Table 5.
- EXAMPLE 40 The raw materials and conditions of the hydroprocessing process are similar to those of Example 18, with the exception of the water content of shale oil fractions with ⁇ . ⁇ i ⁇ . 200-400 ° C 12.0m. %
- the indicators of the hydroprocessing process are given in table 5.
- Example 41 According to the method, the closest analogue to the patent
- Example 42 In accordance with method - the closest analogue to the patent ⁇ 2128207, mix (wt.%): Good - 100.0; Baltic shale -2.0, in t.h. the mineral part is 1.3; shale tar-3.0; Waste water -2.5. Hydrocracking is carried out under the following conditions: temperature - 425 ° ⁇ , pressure - JuPa, volumetric speed 1.0 hour "1. Receive the following gas output - 0.5%; with a temperature of up to 180 ° ⁇ - 19.0; a fraction with a temperature of 180-360 ° ⁇ -63.0; a function with a temperature of 360-520 ° ⁇ - 11.0; it remains with ⁇ . kipip. above 520 C -1.5; koks on the mineral part of the sapropelite is 6.5.
- Examples 11–15 illustrate the present invention, in other words, as a liquid liquid additive, an active fraction is used with ⁇ . ⁇ i ⁇ . 200-400 With oil shale.
- Composition of the indicated additive in the range of 11–15 is 0.5; 1.0; 2.0; 3.0 and 6.0 wt. % based on good.
- the total yield of fractions with ⁇ . ⁇ i ⁇ . up to 180 ° ⁇ , 180-360 ° ⁇ and 360-500 ° ⁇ have a maximum in the amount of 68.5-70.7 (under conditions of 13 and 14).
- the yield of the target products is slightly higher (74.5% by weight under conditions of Example 15).
- introduce a fraction of shale oil with ⁇ . ⁇ i ⁇ . 200-400 ° C and containing at least 10.0 wt. % of residual non-raw materials is in the range of 1.0 - b, 0mass. % on raw materials.
- EXAMPLE 16 illustrates the use of the present invention in the process of thermoanalysis of good in case of only oil shale in the vicinity of 2.0. % on good.
- the temperature range (up to 180 ° C, 180-360 ° C, 360-500 ° C) under conditions of 16 is 57.8 mass. % based on good.
- EXAMPLE 17 demon- strates the indicators of the process of the sale of the good when used in the form of bulk additives - active - fractions with ⁇ . ⁇ i ⁇ . 200 - 400 ° C shale oil with a water content of 10.0 wt. %
- the yield of targeted products under conditions of Example 17 is 47.9 mass. % based on good.
- Table 3 shows the following. With an increase in the mineral content in the shale from 40 to 50 wt. % of production and hydroprocessing of the house, the output of the target products increases from 84.5m. % (under condition 18) to 93.7 (under conditions 20), and the increase in the share of the mineral part in the shale is up to mass.
- s ⁇ avnenie ⁇ gid ⁇ e ⁇ ingu ⁇ ⁇ ime ⁇ am 18, 20 and 21 ⁇ azyvayu ⁇ d ⁇ s ⁇ izhenie ⁇ e ⁇ niches ⁇ g ⁇ ⁇ ezul ⁇ a ⁇ a nas ⁇ yascheg ⁇ iz ⁇ b ⁇ e ⁇ eniya on account ⁇ imeneniya g ⁇ yucheg ⁇ shale s ⁇ de ⁇ lsaniem mine ⁇ aln ⁇ y chas ⁇ i in g ⁇ yuchem shale in ⁇ liches ⁇ ve 45-60 wt.
- composition 40 and 65mas. % of the mineral part in oil shale in the process of hydroprocessing of the reservoir does not ensure the achievement of the technical result.
- Examples 23-27 illustrate the present invention, as a result of a third-party additive-activation, and when the appliance is hydraulically used, it is fire-proof.
- the content of the specified slate in paragraphs 23-27 is 0.5; 1.0; 2.0; 3.0; 5.0.
- the total yield of the fractions with ⁇ . ⁇ i ⁇ . up to 180 ° C, 180-360 ° C and 360-500 ° C have a maximum of 93.7 wt. % of the good for grades 25 and 26.
- the oil shale is kept in the amount of 5.0 months. %, the yield of fuel distillation in nils than at 2.0 and 3.0 mass. % on good.
- Examples 28-32 demon- strate the present invention, in fact, as a liquid supplement, the oil is activated and the oil is hydrated using a slurry.
- Composition of the indicated supplement in examples 28-32 is equal to 0.5; 1.0; 2.0; 3.0 and 6.0 mass. % in terms of raw materials.
- the total yield of fractions with ⁇ . ⁇ i ⁇ . up to 180 ° ⁇ , 180-360 ° ⁇ and 360-500 ° ⁇ have a maximum in the amount of 92.3-93, 7mass. % (under conditions of ⁇ primes 30 and 31).
- the yield of the target products is slightly higher (95.7% by weight, given the condition of 32), but the increase of 3 percent results in the separation of the fraction from ⁇ . ⁇ i ⁇ . 200-400 ° C of shale oil is produced due to insignificant increase in the yield of the target products due to the significant loss of oil due to oil shale.
- introduce a fraction of shale oil with ⁇ . ⁇ i ⁇ . 200-400 ° C with a water content of at least 10.0 wt. % of the rest of the non-ferrous raw materials follows in the amount of 1.0-6.0 wt. % on raw materials.
- EXAMPLE 33 illustrates the use of the present invention in the process of hydrotherapy only for oil shale in the amount of 2.0 months. % on good.
- the output of the reaction (up to 180 ° ⁇ , 180-360 ° ⁇ , 360-500 ° ⁇ ) under conditions of 33 is 63.6 mass. % based on good.
- EXAMPLE 34 demon- strates the indicators of the hydraulic process of the hood when used in the form of a liquid additive-fraction - with ⁇ . ⁇ i ⁇ . 200 - 400 ° C shale oil in the amount of 3.0 wt. % on good.
- the yield of targeted products under conditions of 34 is 57.7m. % based on good.
- EXAMPLES 35, 36, 37 illustrate the present invention with a thermocouple, in addition to a liquid additive, it is used in the process.
- ⁇ i ⁇ . 200 - 400 ° ⁇ of shale oil which is contained in its composition 8.0; 10.0 and 12 wt. % WATER.
- the content of water in shale oil is in oil. 35 of them is 8.0 months. %, in ⁇ prime 36-1 ⁇ mass. %, in ⁇ imer 37-12 wt. %% Of 3 fractions (up to 180 ° ⁇ , 180-360 ° ⁇ , 360-500 ° ⁇ ) under conditions of 36 is 77.5 wt. % ⁇ good.
- Reduction of water content of oil shale oil up to 8.0 mass. % in the case of an example of 35 leads to a decrease in the yield of target fractions up to 61.3 mass. % ⁇ good.
- EXAMPLES 38, 39, 40 illustrate the present invention by hydroprocessing the good, in addition to the quality of the liquid additive, use the fraction with ⁇ . ⁇ i ⁇ . 200 - 400 ° ⁇ of shale oil, which is contained in its composition 8.0; 10.0; 12.0 wt. % WATER.
- the yield of 3 fractions (up to 180 ° ⁇ , 180-360 ° ⁇ , 360-500 ° ⁇ ) under conditions of Example 39 is 92.2 wt. % ⁇ good. With this, the yield of gas from the gas phase was 1.0 wt. % ⁇ raw materials.
- the present invention ensures that there is no loss of technical results, which does not result in an obvious result. 29 Intended use
- the most successful invention can be used in the process of processing fuel distillates, which are a raw material for motor vehicles.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0402417A GB2393731B (en) | 2001-07-12 | 2001-07-12 | Method for producing fuel distillates |
PCT/RU2001/000283 WO2003010259A1 (fr) | 2001-07-12 | 2001-07-12 | Procede de fabrication de carburants distilles |
CNB018236286A CN1238471C (zh) | 2001-07-12 | 2001-07-12 | 生产燃料馏出物的方法 |
US10/486,028 US20040238406A1 (en) | 2001-07-12 | 2001-07-12 | Method for producing fuel distillates |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/RU2001/000283 WO2003010259A1 (fr) | 2001-07-12 | 2001-07-12 | Procede de fabrication de carburants distilles |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003010259A1 true WO2003010259A1 (fr) | 2003-02-06 |
Family
ID=20129635
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/RU2001/000283 WO2003010259A1 (fr) | 2001-07-12 | 2001-07-12 | Procede de fabrication de carburants distilles |
Country Status (4)
Country | Link |
---|---|
US (1) | US20040238406A1 (fr) |
CN (1) | CN1238471C (fr) |
GB (1) | GB2393731B (fr) |
WO (1) | WO2003010259A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7984566B2 (en) * | 2003-10-27 | 2011-07-26 | Staples Wesley A | System and method employing turbofan jet engine for drying bulk materials |
US8647398B2 (en) * | 2010-10-22 | 2014-02-11 | Kior, Inc. | Production of renewable biofuels |
US8936714B2 (en) * | 2012-11-28 | 2015-01-20 | Uop Llc | Process for producing diesel |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4035281A (en) * | 1976-03-05 | 1977-07-12 | Mobil Oil Corporation | Production of fuel oil |
GB2071133A (en) * | 1980-03-04 | 1981-09-16 | Coal Industry Patents Ltd | Cracking process |
RU2009166C1 (ru) * | 1992-04-30 | 1994-03-15 | Международный бизнес-центр "Альфа" | Способ получения топливных дистиллятов |
RU2128207C1 (ru) * | 1998-05-22 | 1999-03-27 | Региональная общественная организация инвалидов - Патриотическое объединение инвалидов войны в Афганистане и воинов-интернационалистов "Панджшер" | Способ получения топливных дистиллятов |
RU2132354C1 (ru) * | 1998-09-25 | 1999-06-27 | Андриенко Владимир Георгиевич | Способ получения жидких продуктов из тяжелых нефтяных остатков |
-
2001
- 2001-07-12 US US10/486,028 patent/US20040238406A1/en not_active Abandoned
- 2001-07-12 WO PCT/RU2001/000283 patent/WO2003010259A1/fr active Application Filing
- 2001-07-12 GB GB0402417A patent/GB2393731B/en not_active Expired - Fee Related
- 2001-07-12 CN CNB018236286A patent/CN1238471C/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4035281A (en) * | 1976-03-05 | 1977-07-12 | Mobil Oil Corporation | Production of fuel oil |
GB2071133A (en) * | 1980-03-04 | 1981-09-16 | Coal Industry Patents Ltd | Cracking process |
RU2009166C1 (ru) * | 1992-04-30 | 1994-03-15 | Международный бизнес-центр "Альфа" | Способ получения топливных дистиллятов |
RU2128207C1 (ru) * | 1998-05-22 | 1999-03-27 | Региональная общественная организация инвалидов - Патриотическое объединение инвалидов войны в Афганистане и воинов-интернационалистов "Панджшер" | Способ получения топливных дистиллятов |
RU2132354C1 (ru) * | 1998-09-25 | 1999-06-27 | Андриенко Владимир Георгиевич | Способ получения жидких продуктов из тяжелых нефтяных остатков |
Also Published As
Publication number | Publication date |
---|---|
GB2393731A8 (en) | 2004-08-26 |
CN1238471C (zh) | 2006-01-25 |
CN1545547A (zh) | 2004-11-10 |
GB2393731B (en) | 2005-02-16 |
US20040238406A1 (en) | 2004-12-02 |
GB2393731A (en) | 2004-04-07 |
GB0402417D0 (en) | 2004-03-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
RU2547826C2 (ru) | Способ гидропереработки тяжелой и сверхтяжелой нефти и нефтяных остатков | |
US6660157B2 (en) | Heavy oil hydrocracking process with multimetallic liquid catalyst in slurry bed | |
AU2005266712B2 (en) | A process for direct liquefaction of coal | |
RU2385346C2 (ru) | Способ обработки с использованием водорода и система для обогащения тяжелой нефти с использованием коллоидного или молекулярного катализатора | |
RU2541324C2 (ru) | Добавка для процесса гидропереработки и способ ее получения и применения | |
US5064523A (en) | Process for the hydrogenative conversion of heavy oils and residual oils, used oils and waste oils, mixed with sewage sludge | |
CN102471054A (zh) | 从炼厂气高剪切生产增值产品 | |
EP4408956A1 (fr) | Procédé de valorisation d'huiles hautement oléfiniques issues de la pyrolyse de déchets plastiques | |
CA1134304A (fr) | Decendrage de la houille par agglomeration au petrole | |
WO1999061560A1 (fr) | Procede de production de distillats de carburants | |
WO2004094562A1 (fr) | Procede de recyclage de dechets caoutchouteux | |
CN108745026B (zh) | 一种适应于焦化法处理清罐污泥的均质预处理系统和方法 | |
WO2003010259A1 (fr) | Procede de fabrication de carburants distilles | |
US20140209513A1 (en) | System and process for coal liquefaction | |
CN105038853B (zh) | 一种利用fcc油浆和煤共炼制油的方法 | |
CA1322746C (fr) | Hydrocraquage de petrole lourd en presence de coke de petrole sous-produit de la cokefaction de petrole lourd | |
RU2288940C1 (ru) | Способ термохимической переработки тяжелых нефтяных остатков | |
CN108456550B (zh) | 一种外循环式反应装置和煤油共炼方法 | |
EP0020656A1 (fr) | Procede de liquefaction du charbon utilisant des mineraux etrangers | |
CA1155411A (fr) | Methode d'hydrogenation de la houille | |
US4764270A (en) | Simultaneous upgrading of tar sand bitumen and coal by corefining | |
EP0020663A1 (fr) | Procede de liquefaction du charbon avec un systeme ameliore de recyclage de la boue | |
US4421632A (en) | Process for hydrogenation of coal | |
US4098583A (en) | Method of removing ash components from high-ash coals | |
CN116328663A (zh) | 一种浆态床反应器、劣质油浆态床加氢裂化系统及方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BY CA CH CN CR CU CZ DE DK DM EE ES FI GB GD GE GH GM HR HU ID IN IS JP KE KG KP KR KZ LC LK LR LT LU LV MA MD MG MK MN MW NO NZ PL PT RO RU SD SE SG SI SK TJ TM TR TT TZ UA UG US UZ VN YU Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ UG ZW AM AZ BY KG KZ MD TJ TM AT BE CH CY DE DK ES FI GB GR IE IT LU MC NL PT SE BF CF CG CI CM GA GN GW ML MR NE TD TG |
|
ENP | Entry into the national phase |
Ref document number: 0402417 Country of ref document: GB Kind code of ref document: A Free format text: PCT FILING DATE = 20010712 |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: 223/DELNP/2004 Country of ref document: IN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 0402417.0 Country of ref document: GB |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2004/01109 Country of ref document: ZA Ref document number: 200401109 Country of ref document: ZA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 20018236286 Country of ref document: CN |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 10486028 Country of ref document: US |
|
122 | Ep: pct application non-entry in european phase | ||
NENP | Non-entry into the national phase |
Ref country code: JP |