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WO2003003861A1 - Methods of freezing and thawing food, method of freezing, thawing, and cooking food, devices for freezing and thawing food, device of freezing, thawing, and cooking food, and frozen food - Google Patents

Methods of freezing and thawing food, method of freezing, thawing, and cooking food, devices for freezing and thawing food, device of freezing, thawing, and cooking food, and frozen food Download PDF

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Publication number
WO2003003861A1
WO2003003861A1 PCT/JP2002/005717 JP0205717W WO03003861A1 WO 2003003861 A1 WO2003003861 A1 WO 2003003861A1 JP 0205717 W JP0205717 W JP 0205717W WO 03003861 A1 WO03003861 A1 WO 03003861A1
Authority
WO
WIPO (PCT)
Prior art keywords
food
freezing
thawing
enzyme
browning
Prior art date
Application number
PCT/JP2002/005717
Other languages
French (fr)
Japanese (ja)
Inventor
Tomoko Tani
Hajime Oyabu
Toshiko Yasunobu
Mai Hashino
Masatoshi Inatani
Original Assignee
Matsushita Electric Industrial Co., Ltd.
Matsushita Refrigeration Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co., Ltd., Matsushita Refrigeration Company filed Critical Matsushita Electric Industrial Co., Ltd.
Priority to KR10-2003-7003154A priority Critical patent/KR20030032004A/en
Priority to US10/362,842 priority patent/US20040028786A1/en
Publication of WO2003003861A1 publication Critical patent/WO2003003861A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B2/00Preservation of foods or foodstuffs, in general
    • A23B2/80Freezing; Subsequent thawing; Cooling
    • A23B2/82Thawing subsequent to freezing
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B2/00Preservation of foods or foodstuffs, in general
    • A23B2/80Freezing; Subsequent thawing; Cooling
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B2/00Preservation of foods or foodstuffs, in general
    • A23B2/80Freezing; Subsequent thawing; Cooling
    • A23B2/805Materials not being transported through or in the apparatus with or without shaping, e.g. in the form of powders, granules or flakes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B7/00Preservation of fruit or vegetables; Chemical ripening of fruit or vegetables
    • A23B7/04Freezing; Subsequent thawing; Cooling
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B7/00Preservation of fruit or vegetables; Chemical ripening of fruit or vegetables
    • A23B7/04Freezing; Subsequent thawing; Cooling
    • A23B7/0441Treatment other than blanching preparatory to freezing
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B7/00Preservation of fruit or vegetables; Chemical ripening of fruit or vegetables
    • A23B7/06Blanching
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/04Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
    • F25D17/06Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection by forced circulation
    • F25D17/062Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection by forced circulation in household refrigerators
    • F25D17/065Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection by forced circulation in household refrigerators with compartments at different temperatures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/12Arrangements of compartments additional to cooling compartments; Combinations of refrigerators with other equipment, e.g. stove
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2317/00Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass
    • F25D2317/06Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass with forced air circulation
    • F25D2317/061Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass with forced air circulation through special compartments
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2317/00Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass
    • F25D2317/06Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass with forced air circulation
    • F25D2317/065Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass with forced air circulation characterised by the air return
    • F25D2317/0653Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass with forced air circulation characterised by the air return through the mullion

Definitions

  • the present invention relates to a food thawing method for preventing discoloration of food when the food is thawed, or further, is frozen and thawed for cooking, and an apparatus thereof.
  • JP-A-4-73583 As a conventional technique which uses a refrigerator as a cooking apparatus instead of preparing the preparation, there is JP-A-4-73583. After the food is frozen for a certain period of time, it is immersed in a seasoning liquid to raise the temperature of the food, to promote the penetration of the seasoning liquid, and to make pickles. The configuration of this cooking device will be described with reference to FIG.
  • reference numeral 15 denotes a low-temperature cooking device for a freezer-refrigerator configured by partitioning a freezer compartment 16 and a refrigerator compartment 17 by partition walls. 1 8 on the outer circumference This is a low-temperature control room having a heat insulating material 19 and a door 20 which can be opened and closed at a front opening.
  • Reference numeral 6 denotes a cooling means comprising a cooler 24 which pressurizes the refrigerant by the compressor 21 and vaporizes the refrigerant liquefied by the condenser 22 at a stretch by the expansion valve 23.
  • the cool air cooled by the cooling means 6 is forcibly ventilated, and the cool air is sent to the low-temperature cooking chamber 18 via the air passage 7.
  • Reference numeral 8 denotes a temperature control means such as a damper thermostat, which is provided in the air passage 7 so as to maintain the low-temperature cooking chamber 18 at an appropriate temperature.
  • the cooking chamber 18 is provided with a heating means 2 including an upper heater 26 and a lower heater 27.
  • Reference numeral 27 denotes a control panel for setting the temperature and time in the low-temperature control room 28 in accordance with the foodstuffs 29 in the low-temperature cooking room 28. Appropriate temperature management is performed according to the conditions.
  • the user puts the foodstuff 29 into the low-temperature cooking chamber 18 and makes settings according to the foodstuff 29 using the control panel 27, so that the cool air cooled by the cooling means 6 is blown by the blowing means.
  • the food 29 is circulated into the low-temperature cooking chamber 18 to freeze the food 29 for a certain period of time according to the setting, and then the food 29 is heated by the heating means 2 of the upper and lower heaters 26, 27.
  • the heating means 2 of the upper and lower heaters 26, 27 Without the addition of salt, sedimentation of the cytoplasm occurs in the cell tissue of the food, and the seasoning material penetrates, reducing the saltiness of the pickles and shortening the pickling time.
  • the conventional cooking apparatus is as described above.
  • the food having a cell wall such as a vegetable
  • the food having a cell wall is broken due to an increase in the volume of water in the tissue during freezing.
  • water is drained from the destroyed cell wall to the same state as pickles. For example, if potatoes are used as food, the potato surface will turn brown significantly if it is frozen and then thawed.
  • the present invention solves the above-mentioned conventional problems, and provides a food freezing method, a food thawing method, a food freezing device, a food thawing device, and the like, which can prevent the browning of frozen food and thaw it.
  • a further object of the present invention is to provide a freeze-thaw cooking method using the above-described food freezing method, food thaw method and the like, and an apparatus therefor.
  • a first invention (corresponding to claim 1) is a food freezing method for freezing food
  • a food freezing method in which an enzyme for browning the food is deactivated in the food before the freezing and during or during the freezing.
  • the state in which the enzyme is inactivated is realized by raising the temperature of the food to an enzyme inactivation temperature at which the enzyme that browns the food is inactivated.
  • the first c also a food freezing method of the present invention for a third of the present invention (corresponding to claim 3)
  • the enzyme is Chiroshina Ze, poly phenol O carboxymethyl synthetase, or all of Fueno one / Reokishitaze Is the first or second method of freezing a food according to the present invention, including a part thereof.
  • a fourth invention is the food freezing method according to the second invention, wherein the enzyme inactivation temperature is 80 ° C. or higher.
  • a fifth invention is the food freezing method according to any one of the first to fourth inventions, wherein the food is infiltrated into a seasoning before freezing.
  • a sixth invention is a food thawing method for thawing frozen food, wherein:
  • the predetermined amount is a food thawing method in which an enzyme for browning the food using the oxygen as a catalyst is a minimum amount required for browning the food.
  • a seventh invention is the food thawing method according to the sixth invention, wherein the atmosphere is realized by the presence of an inert gas.
  • An eighth invention (corresponding to claim 8) is a freeze-thaw cooking method comprising a step of thawing food frozen by at least the food freezing method of any of the first to fifth inventions. is there.
  • the ninth invention (corresponding to claim 9) is a freeze-thaw cooking method comprising a step of thawing frozen food at least by the food thawing method of the sixth or seventh invention.
  • a tenth invention (corresponding to claim 10) is the freeze-thaw-thaw cooking method according to the eighth or ninth invention, wherein the freezing and the thawing are repeated at least once or more. .
  • the eleventh invention (corresponding to claim 11) includes a freezing means for freezing a food,
  • a twelfth invention (corresponding to claim 12) includes a freezing means for freezing a food
  • -A food freezing apparatus provided with an enzyme inactivating means for inactivating the enzyme for browning the food in the food before and / or during the freezing operation of the freezing means.
  • the enzyme inactivating means reduces the temperature of the food and the enzyme for browning the food before the freezing means performs the freezing operation.
  • a twelfth aspect of the present invention is a food freezing apparatus for raising the temperature of an active enzyme to a deactivation temperature.
  • the enzyme is preferably one of the eleventh to thirteenth containing all or a part of tyrosinase, polypheno / reoxidase, and phenenolexoxidase. It is any one of the food freezing apparatuses of the present invention.
  • a fifteenth invention is the food freezing apparatus according to the thirteenth invention, wherein the enzyme inactivation temperature is 80 ° C. or higher.
  • a sixteenth invention (corresponding to claim 16) is a storage chamber for storing frozen food, a degassing means for degassing the storage chamber, and a thaw for thawing the frozen food.
  • a food thawing apparatus comprising:
  • the deaeration means maintains an atmosphere around the food at least during a time when the thawing is performed, such that oxygen is less than a predetermined amount.
  • An enzyme for browning is a food thawing apparatus which is a minimum amount required for browning the food.
  • a seventeenth invention (corresponding to claim 17) comprises an inert gas introduction means for introducing an inert gas into the storage chamber, A food defrosting apparatus according to a sixteenth aspect of the present invention, wherein the atmosphere is realized by the presence of the inert gas.
  • the eighteenth invention is a food freezing apparatus according to any one of the first to fifteenth inventions, wherein the food before the freezing is performed is a seasoning.
  • a freeze-thaw cooking device comprising a wetting means for infiltrating.
  • a nineteenth invention is a food thawing apparatus according to the sixteenth or seventeenth invention,
  • a freeze-thaw cooking device comprising: a wetting means for infiltrating the foodstuff into the seasoning before the freezing is performed.
  • a twenty-first invention (corresponding to claim 20) is a frozen food obtained by freezing a food
  • the food is a frozen food in an enzyme inactivated state in which an enzyme for browning the food is inactivated.
  • the enzyme-inactivated state is that an enzyme that browns the food in the food before and / or during the freezing.
  • a twenty-fourth frozen food according to the present invention which is realized by being heated to an inactivating enzyme inactivating temperature.
  • a twenty-second invention is the food freezing method according to the first invention, wherein the temperature of the food is changed to a state in which an enzyme for browning the food is inactivated.
  • This is a program for causing a computer to execute all or a part of the process of performing the above.
  • the atmosphere around the food is reduced by oxygen It is a program that causes a computer to execute all or part of the process of keeping the state lower than the fixed amount.
  • the temperature of the food is changed to a state in which an enzyme that browns the food is inactivated. This is a medium carrying a program for causing a computer to execute all or a part of the step of performing the above, and is a medium that can be processed by the computer.
  • a twenty-fifth aspect of the present invention is the food thawing method of the sixth aspect, wherein the atmosphere around the food is changed at least during the thawing.
  • the present invention as described above comprises, as one example, a cooking chamber capable of storing food, cooling means for freezing the food, heating means for thawing, and temperature control means for controlling the temperature in the cooking chamber,
  • a freeze-thaw cooker provided with a container for sealing food in the cooking chamber, a degassing unit connected to the container for sucking gas around the food, and a gas suction unit for replacing gas with an inert gas.
  • Another example of the present invention is a freeze-thaw cooker having a configuration using microwaves as heating means.
  • another example of the present invention is a freeze-thaw cooking method in which two steps of a freezing step of freezing the food and a thawing step of thawing the food after the freezing step are repeated at least once or more, And a step of heating to the inactivation temperature of an enzyme involved in discoloration of food.
  • Another example of the present invention is a method for freezing and thawing cooking, comprising a step of heating the food to an edible temperature after the freezing step.
  • Another example of the present invention is a freeze-thaw cooking method in which the microwave output is switched during the heating process of the freeze-thaw cooking.
  • a food surrounding is provided during or before the freezing step.
  • This is a freeze-thaw cooking method to which a degassing step for removing gas is added.
  • Another example of the present invention is a method for freezing and thawing cooking, in which a gas replacement step for replacing gas around food with an inert gas is added during or before the freezing step.
  • FIG. 1 is a configuration diagram of a freeze-thaw cooker according to Embodiment 1 of the present invention.
  • FIG. 2 is a flow sheet diagram of a cooking step of the freeze-thaw cooker according to Embodiment 1 of the present invention.
  • FIG. 3 is a flow sheet diagram of a cooking process of the freeze-thaw cooker according to Embodiment 1 of the present invention.
  • FIG. 4 is a flow sheet diagram of a second example of the cooking process of the freeze-thaw cooking device according to Embodiment 1 of the present invention.
  • FIG. 5 is a configuration diagram of a storage container with a deaeration function of a freeze-thaw cooker according to Embodiment 2 of the present invention.
  • FIG. 6 is a flow sheet diagram of a cooking process of the freeze-thaw cooker according to Embodiment 2 of the present invention.
  • FIG. 7 is a configuration diagram of a storage container with a gas injection function of a freeze-thaw cooker according to Embodiment 3 of the present invention.
  • FIG. 8 is a flow sheet diagram of a cooking step of the freeze-thaw cooker according to Embodiment 3 of the present invention.
  • FIG. 9 is a configuration diagram of a conventional low-temperature cooking device. (Explanation of code) 2 Heating means
  • cooling air in a refrigerator can be used as a means for cooling food.
  • heater heating or microwave heating can be used as the heating means. All of these means are conventionally used means, and a technical description thereof will be omitted in this specification.
  • FIG. 1 is a configuration diagram of a freeze-thaw cooker according to Embodiment 1 of the present invention.
  • FIG. 2 is a flow sheet diagram of the cooking process of the freeze-thaw cooker.
  • a cooking room 1 is composed of a compartment in which the inside of a refrigerator is partitioned by a heat insulating material, and includes a heating means 2 and a storage container 3.
  • the heating means 2 is a means for heating the food material in the storage container 3, and is composed of, for example, a magnetron heater that outputs microwaves.
  • the heating time is calculated and operated by the microcomputer 5 based on the detection signal of the weight sensor 4 installed at the lower part of the container 3.
  • Numeral 6 is a cooling means for sending cool air to each section in the refrigerator, and includes a compressor for pressurizing the refrigerant, a condenser for liquefying the refrigerant, an expansion valve for vaporizing the liquefied refrigerant at a stretch, and a cooler for cooling by vaporization.
  • the cool air from the cooling means 6 is sent to the preparation room 1 via the air passage 7.
  • a temperature control means 8 is provided at the entrance from the ventilation path 7 to the cooking chamber 1.
  • the temperature control means 8 is realized by, for example, a damper thermostat or the like, and operates so as to maintain a proper temperature in the cooking chamber based on a signal from a temperature sensor 9 provided in the cooking chamber 1.
  • the weight sensor 4 detects the weight of the storage container 3 and the potato, and a signal is sent to the microcomputer 5 (S201). According to the weight of the food stored in the cooking chamber 1, a time for the temperature of the food to reach the enzyme inactivation temperature described later is preset and input to the microcomputer 5. The microcomputer 5 calculates the heating time based on the transmitted signal (S203), and the heating means 2 is activated (S204). On the other hand, while the heating means is operating, the temperature control means 8 operates so as to shut off the cooking chamber and the ventilation path so that the cool air generated by the cooling means 6 does not enter the cooking chamber 1 (S 2 0 2).
  • the weight sensor 4 detects the weight of the storage container 3 and the heated potato, and sends a signal to the microcomputer 5 (S208).
  • the microcomputer 5 calculates the freezing time based on the transmitted signal (S 209), and the temperature control means 8 performs the cooking so that the cool air generated by the cooling means 6 is introduced into the cooking chamber 1. An operation is performed so as to connect the chamber 1 with the air passage 7 (S206). Thereby, the cooking chamber 1 is cooled.
  • the temperature sensor 9 detects the temperature in the cooking chamber 1 (S207), and based on this, the temperature control means 8 sends the cooling air from the air passage 7 to the cooling means 6 until the temperature in the cooking chamber reaches -5 ° C. Is introduced. After the temperature reaches 5 ° C, leave it for a certain period of time, then store it in a 0 ° C atmosphere until cooking.
  • the cooking chamber 1 is controlled to maintain a temperature of 5 ° C. for a time set according to the type and weight of the food.
  • the operation of S208 may be omitted, and the microcomputer 5 may use the weight data detected in S201 as it is.
  • the weight sensor 4 detects the weight of the storage container 3 and the frozen potato, and sends a signal to the microcomputer 5 (S211).
  • the time required for heating the food is set in advance in the microcomputer 5 according to the weight of the food stored in the cooking chamber 1.
  • the microcomputer 5 calculates the heating time based on the transmitted signal (S212), and the heating means 2 is activated (S214).
  • the temperature control means 8 shuts off the space between the cooking chamber 1 and the air passage 7 so that the cool air generated by the cooling means 6 does not enter the cooking chamber 1. (S210).
  • the heating means 2 stops operating and the thawing is completed.
  • the operation of S211 may be omitted, and the microcomputer 5 may use the weight data detected in S201 as it is.
  • the potato when the potato is frozen in the freezing step, water in the cell tissue becomes ice, and the cell wall is deformed or cracked due to volume expansion. Furthermore, in the thawing process, the ice inside the cells then turns into water and flows out of cracks in the cell walls. The seasoning permeates into the cells of the potato so as to replace the effluent.
  • enzymes such as tyrosinase are deactivated in the heating step.
  • the air can be shut off by completely immersing the potato in the seasoning solution; otherwise, before the freezing process of freeze-thaw cooking Heat to deactivate the enzyme.
  • heat so that the product temperature is at least 80 ° C.
  • Pickles that are eaten without heating and show browning include pickled mustard, pickled cabbage, and pickled cucumber.
  • salt is added to drain the water in the food, but in freeze-thaw cooking, the water in the food is frozen by using the cell rupture due to the volume expansion of the ice when the water is frozen. Because the outflow, salt can be added without salting can be made.
  • freezing and thawing cooking makes it easier for components inside the cells to flow out. Oxidative degradation of chlorophyll by active enzymes, which occurs due to the presence of oxygen and light, promotes browning.
  • the enzymes include tyrosinase, polyphenol oxidase, and phenol oxidase.
  • the food contains all or a part of these. In this case, it can be understood that browning of food can be prevented by setting the enzyme deactivation temperature to 80 ° C or more.
  • the container is made of a material that transmits microwaves and has resistance to temperature.
  • a material that transmits microwaves and has resistance to temperature For example, polypropylene having a temperature resistance of 120 ° C. to 110 ° C. can be used.
  • a heater is used for heating means 2, use a material with good thermal conductivity, such as aluminum, to speed up the transfer of heat to food.
  • the freezing step and the thawing step are performed once each.
  • the freezing step and the thawing step may be performed one or more times.
  • the temperature of the atmosphere of the potato may be changed each time the freezing step and the thawing step are repeated.
  • the present invention also provides a method of preliminarily preserving food that is thawed by other methods using a microwave oven, an oven, or other external means, regardless of the freeze-thaw cooker of the first embodiment.
  • the above-described heating step may be implemented as a food freezing method or a food freezing apparatus, in which the enzyme contained therein is inactivated and then frozen.
  • the A seasoning may not be used.
  • the present invention relates to a frozen food obtained by freezing a food, wherein, for example, the enzyme contained therein is in an inactivated state in which an enzyme for browning the food is inactivated by the heating step. It may be realized as frozen food.
  • the enzyme inactivated state for the food is realized by heating the food, but the present invention realizes the enzyme inactivated state for the food by another method. It may be.
  • FIG. 3 is a flow chart of a cooking process, which is a further operation of the freeze-thaw cooking device according to the first embodiment of the present invention.
  • the heating process is performed after the thawing process of the operation of the freeze-thaw cooking device according to the first embodiment of the present invention. Is what you do. Hereinafter, this point will be described with reference to the drawings.
  • the frozen and thawed food may be eaten raw or cooked normally. In the latter case, it may be boiled or grilled.
  • a heating step using a heating means is added after the thawing step as shown in the flow sheet in Fig. 3.
  • the time required for the temperature of the food to reach 0 ° C by the heating means 2 is set according to the type and amount of the food. Then, when the thawing process set time has elapsed, the temperature control means 8 is closed, the heating means is operated, and the heating process proceeds.
  • the heating time is calculated based on the detection data of the weight sensor 4, and the heating end time is determined.
  • the temperature is maintained at 5 ° C. by the temperature control means 8 until the food is taken out, and can be stored in a normal refrigerator.
  • the menus used in such a cooking process include meat and chicken, boiled chikuzen, boiled beans, and boiled fish. In these menus, microwaves are applied to heating means 2 If used, heating can be done in a short time in a small amount. In addition, even if the cooking time is short and there is only a small amount of broth, the seasoning liquid penetrates inside the food by freezing and thawing, so that a simmered dish with good taste can be made. In addition, by incorporating a heating step, it is possible to eliminate the cumbersome operation of transferring cooked food to a pan and performing cooking.
  • FIG. 4 is a flow sheet of a second example of the cooking process, which is another example of the further operation of the freeze-thaw cooker according to the first embodiment of the present invention.
  • Microwave heating is used for the thawing step and the heating step of the operation of the freeze-thaw cooking device according to the first embodiment of the present invention, and a method of controlling the microwave will be described.
  • the microwave input power to the food during the thawing process should be around 200 W.
  • the food in the thawing process is in a frozen state and easily penetrates even when irradiated with microwaves, and the food itself is hard to warm.
  • microwave absorption in that part improves, causing uneven heating. This phenomenon becomes more conspicuous as the power of the irradiated microwave increases. Therefore, a microwave of about 200 W is irradiated until the food is melted.
  • the process proceeds to the heating step, in which the microwave power is switched to around 500 W to heat.
  • the switching of microwave power is based on the ability to pre-set the thawing time into the microcomputer based on the type and weight of the food, and the change in shape from the time the food is frozen to the time it is thawed. For example, liquids containing broth form liquid as they are thawed from the frozen state. Vibration when liquid is generated is detected by the weight sensor, and microwave power is switched. If there is no broth, the vibration of the water flowing out of the vegetables at the time of thawing is also detected by a weight sensor, and microwave power is controlled.
  • microwaves can be used to freeze and thaw food. By switching the output and performing heating, the freeze-thaw cooking can be performed well, while suppressing the uneven heating of the microphone mouth wave.
  • the freeze-thaw cooker according to the second embodiment of the present invention is basically the same as the first embodiment, except that it has a function of degassing the air in storage container 3.
  • FIG. 5 is a configuration diagram of a storage container with a deaeration function in a freeze-thaw cooker according to Embodiment 2 of the present invention
  • FIG. 6 is a flow sheet diagram of a cooking process of the freeze-thaw cooker.
  • the storage container 50 with a degassing function is a means having deaeration means 10 provided in contact with the storage container 3, and the deaeration means 10 is provided with a suction pump 11 It is built in and has an exhaust port 13.
  • the tube 12 of the suction pump 11 is made of, for example, a rubber tube and is connected to the storage container 3 so that the suction pump 11 communicates with the inside of the storage container 3.
  • the operation of the freeze-thaw cooking device according to the second embodiment of the present invention having such a configuration will be described, and thereby, one embodiment of the food freezing method and the freeze-thaw cooking method of the present invention will be described. I do. However, parts that are the same as those in Embodiment 1 are omitted, and differences are mainly described.
  • the operation of the freeze-thaw cooking device according to the present embodiment is as follows. Perform the degassing process using the container 50 c The degassing process starts with the operation of the suction pump 11, whereby the air in the storage container 3 is sucked and discharged into the cooking chamber from the exhaust port 13. . The operation of the suction pump 11 stops when the displacement becomes equal to or less than a certain displacement. The displacement is detected by connecting a flow meter to tube 12.
  • the freezing and thawing processes after the degassing process are the same as in the first embodiment described above.
  • browning of food is caused by enzymes and oxygen contained in air around food.
  • air around food is degassed. This ensures that less oxygen remains than is needed for browning food. Therefore, since the amount of oxygen in the storage container 3 is smaller than the amount of oxygen required for browning, even when the thawing process starts, the browning reaction of the food does not occur, and the browning of foods such as potatoes and vegetables is prevented. can do.
  • the degassing process is carried out in an atmosphere in which the amount of enzymes contained in the food is less than the minimum amount required for browning at least until the time when the thawed food starts browning. Therefore, a part of the deaeration step may be performed in parallel with the freezing step.
  • the operation has been described as being performed from the three steps of the degassing step, the freezing step, and the thawing step, but the heating of the first embodiment is performed between the degassing step and the freezing step.
  • a step may be added.
  • the food material in the storage container 3 is heated to the enzyme inactivation temperature in a degassed state, and the effect of preventing browning can be further improved.
  • a change in the atmospheric pressure in the storage container 3 may be detected using a pressure gauge or the like, in addition to the detection of the displacement.
  • the residual oxygen amount may be directly detected using a sensor.
  • FIG. 7 is a configuration diagram of a storage container with a gas injection function in the freeze-thaw cooker according to Embodiment 3 of the present invention
  • FIG. 8 is a flow sheet diagram of a cooking process of the freeze-thaw cooker.
  • the gas injection means 14 injects an inert gas into the storage container 3
  • the gas injection means 14 is configured to set a cartridge type can that is detachable from the deaeration means 10 main body.
  • Examples of the inert gas include nitrogen.
  • the operation of the freeze-thaw cooker according to the present embodiment having such a configuration includes, as shown in FIG. 8, a deaeration step, a freezing step, and a defrosting step in the operation of the second embodiment.
  • a gas injection step using a storage container 70 having a gas injection function is further added. Therefore, the same points as in the second embodiment are omitted, and the differences will be mainly described.
  • an inert gas is supplied from the gas injection means 14 as a gas injection step.
  • the gas is injected into the storage container 3, and the inside of the storage container 3 is filled with an inert gas.
  • the freezing step and the thawing step after the gas injection step are the same as in the first embodiment described above.
  • the amount of oxygen in the storage container 3 becomes smaller than that required for browning. No browning reaction occurs, and furthermore, it is difficult to put chemical changes in food components. Along with this, not only browning of foods but also deterioration due to oxidation of ingredients are prevented, and the finish of freeze-thaw cooking of foods such as potatoes and vegetables is improved.
  • Embodiment 1 may be added before or in parallel with the degassing step or the gas injection step. At this time, the ingredients in the storage container 3 are heated to the enzyme inactivation temperature in a state in which the inert gas is injected, thereby further improving the effect of preventing browning. Can be.
  • Each of the embodiments of the present invention as described above can prevent browning of food by providing a means for sucking or replacing gas around the food with an inert gas and using a cooking device for freezing and thawing the food. Freeze-thaw cooking, which has advantages such as good taste penetration, is performed well.
  • microwaves as the heating means for freezing and thawing cooking, it is possible to cook for a short time in a small amount.
  • the step of heating to the edible temperature of the food after the freezing step can eliminate the cumbersome operation of transferring the cooked food to the pot and performing the heating and cooking.
  • the microcomputer 5 and the heating means 2 are examples of the freezing means of the present invention
  • the storage container 3 is an example of the humidifying means of the present invention.
  • the microcomputer 5 and the degassing means 10 are examples of the degassing means of the present invention
  • the microcomputer 5 and the gas injection means 14 are examples of the inert gas introducing means of the present invention. It is.
  • the present invention is not limited to the above embodiment, and the storage room of the present invention does not need to double as a wetting means for performing freezing and thawing cooking. It may store frozen foods. Therefore, the present invention provides not only freezing and thawing cooking, but also thawing frozen food by external means, and maintaining the atmosphere around the food in such a state that oxygen becomes less than a predetermined amount.
  • the quantification is realized as a food thawing apparatus or a food thawing method in which the enzyme for browning the food using the oxygen as a catalyst is the minimum amount required for browning the food.
  • some means (or devices, elements, circuits, units, and the like) of the present invention and some steps (or steps, operations, functions, and the like) of the present invention refer to a plurality of these means or steps. Means some means or steps, or means one function or part of one means or step. To taste.
  • some devices (or elements, circuits, units, and the like) of the present invention mean some of the plurality of devices, or one of the devices. part of the means (or devices, circuits, parts etc.) the meaning taste, or of the single unit, is intended to mean a part of the function c also records a program of the present invention, the computer The present invention also includes a recording medium that can be read.
  • One use form of the program of the present invention may be a form in which the program is recorded on a computer-readable recording medium and operates in cooperation with the computer.
  • the recording medium includes ROM and the like
  • the transmission medium includes transmission mechanisms such as the Internet and optical fibers, light, radio waves, sound waves, and the like. Not only pure hardware such as, but also firmware, OS, and peripherals may be included. ⁇
  • the configuration of the present invention may be realized by software or hardware. Industrial applicability

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Abstract

A method of freezing food capable of preventing frozen food from being discolored into brown at the time of thawing, comprising the steps (S206 to S210) of freezing the food and the steps (S201 to S205) of raising, before the freezing step, the temperature of the food to an enzyme deactivation temperature where the enzyme discoloring the food into brown is deactivated.

Description

明 細 書 食品凍結方法、 食品解凍方法、 凍結解凍調理方法、 食品凍結装置、 食 品解凍装置、 凍結解凍調理装置、 冷凍食品 技術分野  Description Food freezing method, food thawing method, freezing and thawing cooking method, food freezing device, food thawing device, freezing and thawing cooking device, frozen food

本発明は、 食品を解凍したり、 さらには凍結解凍して調理する際に、 食品の変色を防止する食品解凍方法とその装置等に関するものである。 背景技術  The present invention relates to a food thawing method for preventing discoloration of food when the food is thawed, or further, is frozen and thawed for cooking, and an apparatus thereof. Background art

冷凍冷蔵庫の機能としては、 食品の保存機能の追究がなされてきた。 近年、 その保存機能の中でも冷凍で高品位の保存をおこなうため、 食品 凍結時の最大氷結晶生成帯となる一 1〜一 5 °Cの温度帯をすばやく通過 させる急速冷凍における技術開発が多くなされ、 長期間かつ肉、 魚の解 凍時のドリップが少ない高品位の保存が可能となってきた。 その後、 冷 凍冷蔵庫の新しい機能として、 加熱後の熱い状態からすばやく冷却した り、 常温の飲料を短時間で冷やすなどの開発がされてきた。 これらの機 能は、 冷凍冷蔵庫においては、 下ごしらえ的な調理機能の一つである。  As for the function of refrigerators, the function of preserving food has been pursued. In recent years, among the preservation functions, in order to perform high-quality preservation by freezing, many technologies have been developed for rapid refrigeration that quickly passes through the temperature range of 11 to 15 ° C, which is the maximum ice crystal formation zone when food is frozen. However, it has become possible to store high-quality meat for a long time with little dripping when meat and fish are thawed. Since then, new functions of refrigerators have been developed, such as quick cooling from the hot state after heating and cooling of room temperature beverages in a short time. These functions are one of the prepared cooking functions in a refrigerator.

さらに、 下ごしらえではなく、 冷蔵庫を調理装置として使用する従来 の技術としては、 特開平 4— 7 3 5 8 3号公報がある。 食材を一定時間 、 凍結状態にした後、 調味液に浸漬して食材の温度を上昇させて、 調味 液の浸透を促し、 漬け物をつくるというものである。 この調理装置の構 成について、 図 9に従い説明する。  Further, as a conventional technique which uses a refrigerator as a cooking apparatus instead of preparing the preparation, there is JP-A-4-73583. After the food is frozen for a certain period of time, it is immersed in a seasoning liquid to raise the temperature of the food, to promote the penetration of the seasoning liquid, and to make pickles. The configuration of this cooking device will be described with reference to FIG.

図 9において、 1 5は冷凍室 1 6と冷蔵室 1 7とを、 区画壁によって 区画されて構成される冷凍冷蔵庫の低温調理装置である。 1 8は外周に 断熱材 1 9を有し、 前面開口部に開閉自在の扉 2 0を備えている低温調 理室である。 6は圧縮機 2 1で冷媒を加圧し、 凝縮機 2 2で液化した冷 媒を膨張弁 2 3で一気に気化することにより冷却される冷却器 2 4から 成る冷却手段で、 送風手段 2 5により、 冷却手段 6で冷却された冷気を 強制通風させ、 送風路 7を介して低温調理室 1 8へ冷気を送るようにし ている。 8はダンパーサーモ等の温度制御手段で、 送風路 7に設けられ 、 低温調理室 1 8を適温に維持するようにしている。 さらにこの調理室 1 8には上部ヒータ 2 6と下部ヒータ 2 7とからなる加熱手段 2が設置 されている。 2 7は低温調理室 2 8内の食材 2 9に応じて、 前記低温調 理室 2 8内の温度と時間とを設定するコントロールパネルであり、 これ らのキーを設定することにより、 各材料等に応じた適切な温度管理が行 なわれる。 In FIG. 9, reference numeral 15 denotes a low-temperature cooking device for a freezer-refrigerator configured by partitioning a freezer compartment 16 and a refrigerator compartment 17 by partition walls. 1 8 on the outer circumference This is a low-temperature control room having a heat insulating material 19 and a door 20 which can be opened and closed at a front opening. Reference numeral 6 denotes a cooling means comprising a cooler 24 which pressurizes the refrigerant by the compressor 21 and vaporizes the refrigerant liquefied by the condenser 22 at a stretch by the expansion valve 23. Meanwhile, the cool air cooled by the cooling means 6 is forcibly ventilated, and the cool air is sent to the low-temperature cooking chamber 18 via the air passage 7. Reference numeral 8 denotes a temperature control means such as a damper thermostat, which is provided in the air passage 7 so as to maintain the low-temperature cooking chamber 18 at an appropriate temperature. Further, the cooking chamber 18 is provided with a heating means 2 including an upper heater 26 and a lower heater 27. Reference numeral 27 denotes a control panel for setting the temperature and time in the low-temperature control room 28 in accordance with the foodstuffs 29 in the low-temperature cooking room 28. Appropriate temperature management is performed according to the conditions.

よって、 使用者が食材 2 9を低温調理室 1 8に入れ、 コントロールパ ネル 2 7を用いて前記食材 2 9に応じた設定をすることにより、 冷却手 段 6で冷却された冷気が送風手段 2 5で前記低温調理室 1 8内へ循環し 、 設定に応じて一定時間食材 2 9を凍結し、 その後、 上下ヒータ 2 6、 2 7の加熱手段 2により、 食材 2 9を昇温させる。 食塩を加えずに、 食 材の細胞組織に原形質分離が起こり、 調味材料が浸透し、 漬け物の減塩 化と漬け込み時間の短縮が図れる。  Therefore, the user puts the foodstuff 29 into the low-temperature cooking chamber 18 and makes settings according to the foodstuff 29 using the control panel 27, so that the cool air cooled by the cooling means 6 is blown by the blowing means. At 25, the food 29 is circulated into the low-temperature cooking chamber 18 to freeze the food 29 for a certain period of time according to the setting, and then the food 29 is heated by the heating means 2 of the upper and lower heaters 26, 27. Without the addition of salt, sedimentation of the cytoplasm occurs in the cell tissue of the food, and the seasoning material penetrates, reducing the saltiness of the pickles and shortening the pickling time.

従来の調理装置は、 以上のようなものであるが、 食材を一旦凍結させ た後解凍させるという工程において、 野菜などの細胞壁を有する食材は 、 凍結時の組織の水分の体積増加により細胞壁が破壌され、 解凍時に水 分が破壊された細胞壁から外部へ流出して漬け物と同様の状態になる。 例えば、 食材としてじやがいもを用いた場合、 凍結させた後に解凍さ せるとすると、 ジャガイモの表面は著しく褐変する。 これは、 ジャガイ モの成分であるアミノ酸の一種であるチロシンが空気にさらされ、 酵素 であるチロシナーゼを触媒として酸化してしてしまうことにより生ずる c この褐変は、 ジャガイモの皮を普通に剥いて、 表面を露出させるだけで も生ずる現象であるが、 ー且凍結させた後に解凍させる場合は、 細胞内 部の組織が外部へ流出しているため、 空気にさらされるチロシンおょぴ チロシナーゼの量は、 単に外皮を剥いた場合よりも多くなるため、 褐変 化の進行度合いが大きくなってしまう。 The conventional cooking apparatus is as described above. In the process of once freezing and then thawing the food, the food having a cell wall, such as a vegetable, is broken due to an increase in the volume of water in the tissue during freezing. When thawed, water is drained from the destroyed cell wall to the same state as pickles. For example, if potatoes are used as food, the potato surface will turn brown significantly if it is frozen and then thawed. This is because tyrosine, a kind of amino acid that is a component of potato, is exposed to the air, Tyrosinase c The browning caused by the resulting in oxidized as a catalyst is the Peel the potatoes normally, but is a phenomenon occurring alone exposing the surface to thawed after being over且frozen In this case, the amount of tyrosine and tyrosinase exposed to the air is greater than in the case of simply peeling the skin, and the degree of browning is greater because the tissue inside the cells is flowing out. Would.

したがって、 ー且凍結した食品を解凍すると、 褐変のために食材のダ メージが大きくなるという課題があった。 発明の開示  Therefore, when the frozen food is thawed, there is a problem that the damage of the foodstuff becomes large due to browning. Disclosure of the invention

本発明は上記従来の課題を解決するもので、 凍結した食材の褐変を防 止して解凍することができる食品凍結方法、 食品解凍方法、 食品凍結装 置、 食品解凍装置等を提供することを目的とする。 さらに本発明は、 上 記の食品凍結方法、 食品解凍方法等を用いた凍結解凍調理方法とその装 置を提供することを目的とする。  The present invention solves the above-mentioned conventional problems, and provides a food freezing method, a food thawing method, a food freezing device, a food thawing device, and the like, which can prevent the browning of frozen food and thaw it. Aim. A further object of the present invention is to provide a freeze-thaw cooking method using the above-described food freezing method, food thaw method and the like, and an apparatus therefor.

上記の目的を達成するために、 第 1の本発明 (請求項 1に対応) は、 食品を凍結する食品凍結方法であって、  In order to achieve the above object, a first invention (corresponding to claim 1) is a food freezing method for freezing food,

前記凍結を行う前および Zまたは前記凍結中に、 前記食品内の、 前記 食品を褐変させる酵素が失活する状態にする食品凍結方法である。  A food freezing method in which an enzyme for browning the food is deactivated in the food before the freezing and during or during the freezing.

また、 第 2の本発明 (請求項 2に対応) は、 前記酵素が失活する状態 は、 前記食品の温度を、 前記食品を褐変させる酵素が失活する酵素失活 温度まで上げることにより実現する第 1の本発明の食品凍結方法である c また、 第 3の本発明 (請求項 3に対応) は、 前記酵素は、 チロシナー ゼ、 ポリフエノールォキシターゼ、 フエノ一/レオキシターゼの全部また は一部を含む第 1または第 2の本発明の食品凍結方法である。 また、 第 4の本発明 (請求項 4に対応) は、 前記酵素失活温度は、 8 0 °C以上である第 2の本発明の食品凍結方法である。 In the second invention (corresponding to claim 2), the state in which the enzyme is inactivated is realized by raising the temperature of the food to an enzyme inactivation temperature at which the enzyme that browns the food is inactivated. the first c also a food freezing method of the present invention for a third of the present invention (corresponding to claim 3), the enzyme is Chiroshina Ze, poly phenol O carboxymethyl synthetase, or all of Fueno one / Reokishitaze Is the first or second method of freezing a food according to the present invention, including a part thereof. A fourth invention (corresponding to claim 4) is the food freezing method according to the second invention, wherein the enzyme inactivation temperature is 80 ° C. or higher.

また、 第 5の本発明 (請求項 5に対応) は、 前記食品を、 凍結前に調 味料に浸潤させる第 1から第 4のいずれかの本発明の食品凍結方法であ る。  A fifth invention (corresponding to claim 5) is the food freezing method according to any one of the first to fourth inventions, wherein the food is infiltrated into a seasoning before freezing.

また、 第 6の本発明 (請求項 6に対応) は、 凍結した食品を解凍する 食品解凍方法であって、 /:  Further, a sixth invention (corresponding to claim 6) is a food thawing method for thawing frozen food, wherein:

少なくとも前記解凍が行われている間、 前記食品の周囲の雰囲気を、 酸素が所定量より少なくなるような状態に保つ工程を備え、  At least while the thawing is being performed, a step of maintaining an atmosphere around the food in a state where oxygen is less than a predetermined amount,

前記所定量は、 前記酸素を触媒として前記食品を褐変させる酵素が、 前記食品を褐変させるのに最低限必要な量である食品解凍方法である。  The predetermined amount is a food thawing method in which an enzyme for browning the food using the oxygen as a catalyst is a minimum amount required for browning the food.

また、 第 7の本発明 (請求項 7に対応) は、 前記雰囲気を、 不活性ガ スを存在させることにより実現している第 6の本発明の食品解凍方法で ある。  A seventh invention (corresponding to claim 7) is the food thawing method according to the sixth invention, wherein the atmosphere is realized by the presence of an inert gas.

また、 第 8の本発明 (請求項 8に対応) は、 少なくとも第 1から第 5 のいずれかの本発明の食品凍結方法により凍結した食品を、 解凍するェ 程を備えた凍結解凍調理方法である。  An eighth invention (corresponding to claim 8) is a freeze-thaw cooking method comprising a step of thawing food frozen by at least the food freezing method of any of the first to fifth inventions. is there.

また、 第 9の本発明 (請求項 9に対応) は、 凍結した食品を、 少なく とも第 6または第 7の本発明の食品解凍方法により解凍する工程を備え た凍結解凍調理方法である。  The ninth invention (corresponding to claim 9) is a freeze-thaw cooking method comprising a step of thawing frozen food at least by the food thawing method of the sixth or seventh invention.

また、 第 1 0の本発明 (請求項 1 0に対応) は、 前記凍結と、 前記解 凍とを少なくとも 1回以上繰り返して行う第 8または第 9の本発明の凍 結解凍調理方法である。  A tenth invention (corresponding to claim 10) is the freeze-thaw-thaw cooking method according to the eighth or ninth invention, wherein the freezing and the thawing are repeated at least once or more. .

また、 第 1 1の本発明 (請求項 1 1に対応) は、 食品を凍結する凍結 手段を備え、  The eleventh invention (corresponding to claim 11) includes a freezing means for freezing a food,

前記凍結手段が凍結動作を行う前および zまたは凍結動作中に、 前記 食品内の、 前記食品を褐変させる酵素が失活する状態にする食品凍結装 ft 5ある。 Before the freezing means performs the freezing operation and during or during the freezing operation, In food, enzymes for browning the food is food freezing instrumentation ft 5 to the state being deactivated.

また、 第 1 2の本発明 (請求項 1 2に対応) は、 食品を凍結する凍結 手段と、  Further, a twelfth invention (corresponding to claim 12) includes a freezing means for freezing a food,

-前記凍結手段が凍結動作を行う前および/または凍結動作中に、 前記 食品内の、 前記食品を褐変させる酵素が失活する状態にする酵素失活手 段を備えた食品凍結装置である。  -A food freezing apparatus provided with an enzyme inactivating means for inactivating the enzyme for browning the food in the food before and / or during the freezing operation of the freezing means.

また、 第 1 3の本発明 (請求項 1 3に対応) は、 前記酵素失活手段は 、 前記凍結手段が凍結動作を行う前に、 前記食品の温度を、 前記食品を 褐変させる酵素が失活する酵素失活温度まで上げる第 1 2の本発明の食 品凍結装置 ある。  According to a thirteenth aspect of the present invention (corresponding to claim 13), the enzyme inactivating means reduces the temperature of the food and the enzyme for browning the food before the freezing means performs the freezing operation. A twelfth aspect of the present invention is a food freezing apparatus for raising the temperature of an active enzyme to a deactivation temperature.

また、 第 1 4の本発明 (請求項 1 4に対応) は、 前記酵素は、 チロシ ナーゼ、 ポリフエノー/レオキシターゼ、 フエノーノレォキシターゼの全部 または一部を含む第 1 1から第 1 3のいずれかの本発明の食品凍結装置 である。  Further, in a fifteenth aspect of the present invention (corresponding to claim 14), the enzyme is preferably one of the eleventh to thirteenth containing all or a part of tyrosinase, polypheno / reoxidase, and phenenolexoxidase. It is any one of the food freezing apparatuses of the present invention.

また、 第 1 5の本発明 (請求項 1 5に対応) は、 前記酵素失活温度は 、 8 0 °C以上である第 1 3の本発明の食品凍結装置である。  A fifteenth invention (corresponding to claim 15) is the food freezing apparatus according to the thirteenth invention, wherein the enzyme inactivation temperature is 80 ° C. or higher.

また、 第 1 6の本発明 (請求項 1 6に対応) は、 凍結した食品が収納 される収納室と、 前記収納室内の脱気を行う脱気手段と、 前記凍結した 食品を解凍する解凍手段とを備えた食品解凍装置であって、  Also, a sixteenth invention (corresponding to claim 16) is a storage chamber for storing frozen food, a degassing means for degassing the storage chamber, and a thaw for thawing the frozen food. A food thawing apparatus comprising:

前記脱気手段は、 少なくとも前記解凍が行われている間、 前記食品の 周囲の雰囲気を、 酸素が所定量より少なくなるような状態に保ち、 前記所定量は、 前記酸素を触媒として前記食品を褐変させる酵素が、 前記食品を褐変させるのに最低限必要な量である食品解凍装置である。  The deaeration means maintains an atmosphere around the food at least during a time when the thawing is performed, such that oxygen is less than a predetermined amount. An enzyme for browning is a food thawing apparatus which is a minimum amount required for browning the food.

また、 第 1 7の本発明 (請求項 1 7に対応) は、 前記収納室内に不活 性ガスを導入する不活性ガス導入手段を備え、 前記雰囲気を、 前記不活性ガスを存在させることにより実現している 第 1 6の本発明の食品解凍装置である。 Further, a seventeenth invention (corresponding to claim 17) comprises an inert gas introduction means for introducing an inert gas into the storage chamber, A food defrosting apparatus according to a sixteenth aspect of the present invention, wherein the atmosphere is realized by the presence of the inert gas.

また、 第 1 8の本発明 (請求項 1 8に対応) は、 第 1 1から第 1 5の いずれかの本発明の食品凍結装置と、 前記凍結が行われる前の前記食品 を調味料に浸潤させる湿潤手段とを備えた凍結解凍調理装置である。 また、 第 1 9の本発明 (請求項 1 9に対応) は、 第 1 6または第 1 7 の本発明の食品解凍装置と、  The eighteenth invention (corresponding to claim 18) is a food freezing apparatus according to any one of the first to fifteenth inventions, wherein the food before the freezing is performed is a seasoning. A freeze-thaw cooking device comprising a wetting means for infiltrating. Also, a nineteenth invention (corresponding to claim 19) is a food thawing apparatus according to the sixteenth or seventeenth invention,

前記食品を凍結させる凍結手段と、  Freezing means for freezing the food,

前記凍結が行われる前の前記食品を調味料に浸潤させる湿潤手段とを 備えた凍結解凍調理装置である。  A freeze-thaw cooking device comprising: a wetting means for infiltrating the foodstuff into the seasoning before the freezing is performed.

また、 第 2 0の本発明 (請求項 2 0に対応) は、 食品を凍結して得ら れた冷凍食品であって、  A twenty-first invention (corresponding to claim 20) is a frozen food obtained by freezing a food,

前記食品は、 前記'食品を褐変させる酵素が失活した酵素失活状態にあ る冷凍食品である。  The food is a frozen food in an enzyme inactivated state in which an enzyme for browning the food is inactivated.

また、 第 2 1の本発明 (請求項 2 1に対応) は、 前記酵素失活状態は 、 前記凍結を行う前および/または前記凍結中に、 前記食品内の、 前記 食品を褐変させる酵素が失活する酵素失活温度まで加熱されることによ り実現されている第 2 0の本発明の冷凍食品である。  In the twenty-first aspect of the present invention (corresponding to claim 21), the enzyme-inactivated state is that an enzyme that browns the food in the food before and / or during the freezing. A twenty-fourth frozen food according to the present invention, which is realized by being heated to an inactivating enzyme inactivating temperature.

また、 第 2 2の本発明 (請求項 2 2に対応) は、 第 1の本発明の食品 凍結方法の、 前記食品の温度を、 前記食品を褐変させる酵素が失活する 酵素失活する状態にする工程の全部または一部をコンピュータに実行さ せるためのプログラムである。  Further, a twenty-second invention (corresponding to claim 22) is the food freezing method according to the first invention, wherein the temperature of the food is changed to a state in which an enzyme for browning the food is inactivated. This is a program for causing a computer to execute all or a part of the process of performing the above.

また、 第 2 3の本発明 (請求項 2 3に対応) は、 第 6の本発明の食品 解凍方法の、 少なくとも前記解凍が行われている間、 前記食品の周囲の 雰囲気を、 酸素が所定量より少なくなるような状態に保つ工程の全部ま たは一部をコンピュータに実行させるためのプログラムである。 また、 第 2 4の本発明 (請求項 2 4に対応) は、 第 1の本発明の食品 凍結方法の、 前記食品の温度を、 前記食品を褐変させる酵素が失活する 酵素失活する状態にする工程の全部または一部をコンピュータに実行さ せるためのプログラムを担持した媒体であって、 コンピュータにより処 理可能な媒体である。 According to a twenty-third aspect of the present invention (corresponding to claim 23), in the food defrosting method of the sixth aspect of the present invention, at least during the defrosting, the atmosphere around the food is reduced by oxygen It is a program that causes a computer to execute all or part of the process of keeping the state lower than the fixed amount. In a twenty-fourth aspect of the present invention (corresponding to claim 24), in the food freezing method of the first aspect of the present invention, the temperature of the food is changed to a state in which an enzyme that browns the food is inactivated. This is a medium carrying a program for causing a computer to execute all or a part of the step of performing the above, and is a medium that can be processed by the computer.

また、 第 2 5の本発明 (請求項 2 5に対応) は、 第 6の本発明の食品 解凍方法の、 少なくとも前記解凍が行われている間、 前記食品の周囲の 雰囲気を、 酸素が所定量より少なくなるような状態に保つ工程の全部ま たは一部をコンピュータに実行させるためのプログラムを担持した媒体 であって、 コンピュータにより処理可能な媒体である。  A twenty-fifth aspect of the present invention (corresponding to claim 25) is the food thawing method of the sixth aspect, wherein the atmosphere around the food is changed at least during the thawing. A medium that carries a program for causing a computer to execute all or a part of the process of maintaining a state where the amount is less than the fixed amount, and is a medium that can be processed by a computer.

以上のような本発明は、 その一例として、 食品を収納できる調理室と 、 前記食品を凍結する冷却手段と、 解凍する加熱手段と、 調理室内の温 度を制御する温度制御手段から構成し、 前記調理室内に食品を密封する 容器と、 前記容器に接続して食品周囲の気体を吸引する脱気手段および 不活性ガスに置換するガス吸入手段を設けた凍結解凍調理器である。 また、 本発明の他の一例は、 加熱手段でマイクロ波を用いる構成と b た凍結解凍調理器である。  The present invention as described above comprises, as one example, a cooking chamber capable of storing food, cooling means for freezing the food, heating means for thawing, and temperature control means for controlling the temperature in the cooking chamber, A freeze-thaw cooker provided with a container for sealing food in the cooking chamber, a degassing unit connected to the container for sucking gas around the food, and a gas suction unit for replacing gas with an inert gas. Another example of the present invention is a freeze-thaw cooker having a configuration using microwaves as heating means.

また、 本発明の他の一例は、 食品を凍結する凍結工程と、 前記凍結ェ 程を経た食品を解凍する解凍工程の 2工程を少なくとも 1回以上繰り返 す凍結解凍調理において、 前記凍結工程前に食品の変色に関与する酵素 失活温度まで加熱を行う工程からなる方法とする。  Further, another example of the present invention is a freeze-thaw cooking method in which two steps of a freezing step of freezing the food and a thawing step of thawing the food after the freezing step are repeated at least once or more, And a step of heating to the inactivation temperature of an enzyme involved in discoloration of food.

また、 本発明の他の一例は、 前記凍結工程後に食品の可食温度に加熱 を行う工程からなる凍結解凍調理の方法である。  Another example of the present invention is a method for freezing and thawing cooking, comprising a step of heating the food to an edible temperature after the freezing step.

また、 本発明の他の一例は、 前記凍結解凍調理の加熱工程において、 途中でマイクロ波の出力を切り替える凍結解凍調理の方法である。  Another example of the present invention is a freeze-thaw cooking method in which the microwave output is switched during the heating process of the freeze-thaw cooking.

また、 本発明の他の一例は、 前記凍結工程中あるいは前に、 食品周囲 の気体を除去する脱気工程を加えた凍結解凍調理の方法である。 Further, another example of the present invention is that a food surrounding is provided during or before the freezing step. This is a freeze-thaw cooking method to which a degassing step for removing gas is added.

また、 本発明の他の一例は、 前記凍結工程中あるいは前に、 食品周囲 の気体を不活性ガスに換えるガス置換工程を加えた凍結解凍調理の方法 である。 図面の簡単な説明  Another example of the present invention is a method for freezing and thawing cooking, in which a gas replacement step for replacing gas around food with an inert gas is added during or before the freezing step. BRIEF DESCRIPTION OF THE FIGURES

図 1は、 本発明の実施の形態 1における凍結解凍調理器の構成図であ る。  FIG. 1 is a configuration diagram of a freeze-thaw cooker according to Embodiment 1 of the present invention.

図 2は、 本発明の実施の形態 1における凍結解凍調理器の調理工程の フローシート図である。  FIG. 2 is a flow sheet diagram of a cooking step of the freeze-thaw cooker according to Embodiment 1 of the present invention.

図 3は、 本発明の実施の形態 1における凍結解凍調理器の調理工程の フローシート図である。  FIG. 3 is a flow sheet diagram of a cooking process of the freeze-thaw cooker according to Embodiment 1 of the present invention.

図 4は、 本発明の実施の形態 1における凍結解凍調理器の調理工程の 第 2例のフローシート図である。  FIG. 4 is a flow sheet diagram of a second example of the cooking process of the freeze-thaw cooking device according to Embodiment 1 of the present invention.

図 5は、 本発明の実施の形態 2における凍結解凍調理器の脱気機能付 き収納容器の構成図である。  FIG. 5 is a configuration diagram of a storage container with a deaeration function of a freeze-thaw cooker according to Embodiment 2 of the present invention.

図 6は、 本発明の実施の形態 2における凍結解凍調理器の調理工程の フローシート図である。  FIG. 6 is a flow sheet diagram of a cooking process of the freeze-thaw cooker according to Embodiment 2 of the present invention.

図 7は、 本発明の実施の形態 3における凍結解凍調理器のガス注入機 能付き収納容器の構成図である。  FIG. 7 is a configuration diagram of a storage container with a gas injection function of a freeze-thaw cooker according to Embodiment 3 of the present invention.

図 8は、 本発明の実施の形態 3における凍結解凍調理器の調理工程の フローシート図である。  FIG. 8 is a flow sheet diagram of a cooking step of the freeze-thaw cooker according to Embodiment 3 of the present invention.

図 9は、 従来の低温調理装置の構成図である。 (符号の説明) 2 加熱手段 FIG. 9 is a configuration diagram of a conventional low-temperature cooking device. (Explanation of code) 2 Heating means

3 収納容器  3 Storage container

4 重量センサ  4 Weight sensor

5 マイコン  5 Microcomputer

6 冷却手段  6 Cooling means

7 送風路  7 Ventilation path

8 温度制御手段  8 Temperature control means

9 温度センサ  9 Temperature sensor

1 0 脱気手段  1 0 Deaeration means

1 1 吸引ポンプ  1 1 Suction pump

1 2 チューブ  1 2 tube

1 3 排気口  1 3 Exhaust port

1 4 ガス注入手段  1 4 Gas injection means

5 0 脱気機能付き収納容器  5 0 Storage container with degassing function

7 0 ガス注入機能付き収納容器 発明を実施するための最良の形態  70 Storage container with gas injection function BEST MODE FOR CARRYING OUT THE INVENTION

以下、 本発明の実施の形態を、 図 1から図 8に基づいて説明する。 本 発明の実施には、 食品を冷却するための手段として冷蔵庫内の冷却空気 が利用できる。 また、 加熱手段としてヒータ加熱あるいはマイクロ波加 熱が用いることができる。 これらの手段はいずれも、 従来より用いられ ている手段で、 本明細書ではこれらについての技術的説明は省略する。  Hereinafter, embodiments of the present invention will be described with reference to FIGS. 1 to 8. In practicing the present invention, cooling air in a refrigerator can be used as a means for cooling food. In addition, heater heating or microwave heating can be used as the heating means. All of these means are conventionally used means, and a technical description thereof will be omitted in this specification.

(実施の形態 1 )  (Embodiment 1)

図 1は本発明の実施の形態 1における凍結解凍調理器の構成図であり 、 図 2は、 凍結解凍調理器の調理工程のフローシート図である。 FIG. 1 is a configuration diagram of a freeze-thaw cooker according to Embodiment 1 of the present invention. FIG. 2 is a flow sheet diagram of the cooking process of the freeze-thaw cooker.

図 1において、 調理室 1は冷蔵庫内部を断熱材で仕切った一区画から なり、 加熱手段 2と収納容器 3を備える。 加熱手段 2は収納容器 3内の 食材を加熱する手段で、 例えばマイクロ波を出力するマグネトロンゃヒ ータからなる。 そして、 容器 3の下部に設置した重量センサ 4の検知信 号をもとにマイコン 5で加熱時間が演算され動作する。 6は冷蔵庫内部 の各区画に冷気を送り出す冷却手段で、 冷媒を加圧する圧縮機、 冷媒を 液化する凝縮機、 液化した冷媒を一気に気化する膨張弁、 気化により冷 却される冷却器から成る。 冷却手段 6からの冷気は送風路 7を介して調 理室 1に送るようにしている。 送風路 7から調理室 1への入り口に温度 制御手段 8が設けられている。 温度制御手段 8は、 例えばダンパーサー モ等により実現され、 調理室 1内に設けられた温度センサ 9の信号をも とに調理室内を適温に維持するように作動する。  In FIG. 1, a cooking room 1 is composed of a compartment in which the inside of a refrigerator is partitioned by a heat insulating material, and includes a heating means 2 and a storage container 3. The heating means 2 is a means for heating the food material in the storage container 3, and is composed of, for example, a magnetron heater that outputs microwaves. The heating time is calculated and operated by the microcomputer 5 based on the detection signal of the weight sensor 4 installed at the lower part of the container 3. Numeral 6 is a cooling means for sending cool air to each section in the refrigerator, and includes a compressor for pressurizing the refrigerant, a condenser for liquefying the refrigerant, an expansion valve for vaporizing the liquefied refrigerant at a stretch, and a cooler for cooling by vaporization. The cool air from the cooling means 6 is sent to the preparation room 1 via the air passage 7. A temperature control means 8 is provided at the entrance from the ventilation path 7 to the cooking chamber 1. The temperature control means 8 is realized by, for example, a damper thermostat or the like, and operates so as to maintain a proper temperature in the cooking chamber based on a signal from a temperature sensor 9 provided in the cooking chamber 1.

上記の様な構成の、 本発明の実施の形態による凍結解凍調理器の動作 を、 図 2のフローを参照して説明するとともに、 これによ'り、 本発明の 食品凍結方法、 凍結解凍調理方法の一実施の形態について説明を行う。 食品の一例として、 ジャガイモ調理を行う場合を説明する。 まず、 4 つ切りにしたジャガイモと合わせ調味料とを収納容器 3に入れる。  The operation of the freeze-thaw cooking device according to the embodiment of the present invention having the above-described configuration will be described with reference to the flow chart of FIG. 2, and according to this, the food freezing method and the freeze-thaw cooking of the present invention will be described. An embodiment of the method will be described. A case where potato cooking is performed will be described as an example of food. First, put the potatoes cut into quarters and the seasonings into storage container 3.

重量センサ 4が、 収納容器 3およぴジャガイモの重量を検知し、 マイ コン 5に信号が送られる (S 2 0 1 ) 。 マイコン 5には、 調理室 1に格 納された食品重量に応じて、 食品の温度が後述する酵素失活温度に到達 する時間があらかじめ設定入力されている。 マイコン 5は、 送られた信 号をもとに、 加熱時間を算出する (S 2 0 3 ) と、 加熱手段 2が作動す る (S 2 0 4 ) 。 一方、 加熱手段が作動している間は、 温度制御手段 8 は、 冷却手段 6が生成する冷気が調理室 1内に入らないように調理室と 送風路を遮断するように動作する ( S 2 0 2 ) 。 加熱工程終了後、 重量センサ 4は、 収納容器 3および加熱後のジャガ ィモの重量を検知し、 マイコン 5に信号が送られる (S 208) 。 マイ コン 5は、 送られた信号をもとに、 凍結時間を算出する (S 209) と 、 温度制御手段 8は、 冷却手段 6が生成する冷気が調理室 1内に導入さ れるように調理室 1と送風路 7とを連通するように動作する (S 206 ) 。 これにより、 調理室 1内は冷却される。 The weight sensor 4 detects the weight of the storage container 3 and the potato, and a signal is sent to the microcomputer 5 (S201). According to the weight of the food stored in the cooking chamber 1, a time for the temperature of the food to reach the enzyme inactivation temperature described later is preset and input to the microcomputer 5. The microcomputer 5 calculates the heating time based on the transmitted signal (S203), and the heating means 2 is activated (S204). On the other hand, while the heating means is operating, the temperature control means 8 operates so as to shut off the cooking chamber and the ventilation path so that the cool air generated by the cooling means 6 does not enter the cooking chamber 1 (S 2 0 2). After the heating step, the weight sensor 4 detects the weight of the storage container 3 and the heated potato, and sends a signal to the microcomputer 5 (S208). The microcomputer 5 calculates the freezing time based on the transmitted signal (S 209), and the temperature control means 8 performs the cooking so that the cool air generated by the cooling means 6 is introduced into the cooking chamber 1. An operation is performed so as to connect the chamber 1 with the air passage 7 (S206). Thereby, the cooking chamber 1 is cooled.

温度センサ 9は調理室 1内の温度を検出し (S 207) 、 これに基づ き、 調理室内が _ 5 °Cに達するまで、 温度制御手段 8は、 送風路 7から 冷却手段 6の冷気を導入させる。 一 5°C到達後は、 一定時間放置したの ち、 加熱調理を行うまで 0°C雰囲気にて保存する。  The temperature sensor 9 detects the temperature in the cooking chamber 1 (S207), and based on this, the temperature control means 8 sends the cooling air from the air passage 7 to the cooling means 6 until the temperature in the cooking chamber reaches -5 ° C. Is introduced. After the temperature reaches 5 ° C, leave it for a certain period of time, then store it in a 0 ° C atmosphere until cooking.

このように、 食品の種類と重量に応じて設定された時間だけ、 調理室 1内は一5°Cを保持するように制御される。 なお、 上記の S 206〜2 09の動作において、 S 208の動作は省略し、 マイコン 5は、 S 20 1で検知した重量データをそのまま用いてもよい。  In this way, the cooking chamber 1 is controlled to maintain a temperature of 5 ° C. for a time set according to the type and weight of the food. In the above operations of S206 to S209, the operation of S208 may be omitted, and the microcomputer 5 may use the weight data detected in S201 as it is.

次に、 解凍工程においては、 重量センサ 4が、 収納容器 3および凍結 されたジャガイモの重量を検知し、 マイコン 5に信号が送られる (S 2 1 1) 。 マイコン 5には、 調理室 1に格納された食品重量に応じて、 食 品を加熱するのに要する時間があらかじめ設定入力されている。 マイコ ン 5は、 送られた信号をもとに、 加熱時間を算出する (S 212) と、 加熱手段 2が作動する (S 214) 。 一方、 加熱手段 2が作動している 間は、 温度制御手段 8は、 冷却手段 6が生成する冷気が調理室 1内に入 らないように調理室 1と送風路 7との間を遮断するように動作する (S 210) 。 加熱時間が到達すると、 加熱手段 2は動作を停止し、 解凍が 完了する。 なお、 上記の S 210〜214の動作において、 S 21 1の 動作は省略し、 マイコン 5は、 S 201で検知した重量データをそのま ま用いてもよい。 上記の動作において、 凍結工程にてジャガイモを凍結すると、 細胞組 織内の水分が氷となり、 体積膨張によつて細胞壁に変形または亀裂が生 ずる。 さらに解凍工程では、 そのとき、 細胞内部の氷は水となって、 細 胞壁に生じた亀裂から流出する。 流出した水分と入れ替わるように、 あ わせ調味料がジャガイモの細胞内へ浸透する。 Next, in the thawing process, the weight sensor 4 detects the weight of the storage container 3 and the frozen potato, and sends a signal to the microcomputer 5 (S211). The time required for heating the food is set in advance in the microcomputer 5 according to the weight of the food stored in the cooking chamber 1. The microcomputer 5 calculates the heating time based on the transmitted signal (S212), and the heating means 2 is activated (S214). On the other hand, while the heating means 2 is operating, the temperature control means 8 shuts off the space between the cooking chamber 1 and the air passage 7 so that the cool air generated by the cooling means 6 does not enter the cooking chamber 1. (S210). When the heating time has elapsed, the heating means 2 stops operating and the thawing is completed. In the above operations of S210 to S214, the operation of S211 may be omitted, and the microcomputer 5 may use the weight data detected in S201 as it is. In the above operation, when the potato is frozen in the freezing step, water in the cell tissue becomes ice, and the cell wall is deformed or cracked due to volume expansion. Furthermore, in the thawing process, the ice inside the cells then turns into water and flows out of cracks in the cell walls. The seasoning permeates into the cells of the potato so as to replace the effluent.

このような凍結解凍調理を施したものを加熱すると、 ジャガイモの細 胞組織が脆弱になっているため、 柔らかくなりやすく、 普通の加熱調理 時間に較べて調理時間が短縮される。 また、 解凍時に細胞内にあわせ調 味料液が浸透しているため、 加熱時間が短くても、 味の良くしみこんだ 煮物となる。  When such a freeze-thaw-cooked dish is heated, the potato's cellular tissue becomes fragile and tends to become softer, reducing the cooking time compared to normal cooking time. In addition, the seasoning liquid permeates into the cells when thawing, so that even if the heating time is short, it becomes a well-boiled boiled dish.

しかし、 凍結後、 解凍直後からジャガイモの表面は褐変する。 これは 、 従来例の場合でも述べたように、 ジャガイモの成分であるアミノ酸の 一種であるチロシンが空気にさらされ、 酵素であるチロシナーゼを触媒 として酸化してしてしまうことにより生ずる。 この褐変は、 ジャガイモ の皮を普通に剥いて、 表面を露出させるだけでも生ずる現象であるが、 一旦凍結させた後に解凍させる場合は、 細胞内部の成分が外部へ流出し ているため、 空気にさらされるチロシンおよぴチロシナーゼの量は、 単 に外皮を剥いた場合よりも多くなるため、 褐変化の進行度合いが大きく なってしまう。  However, after freezing, the surface of the potato turns brown immediately after thawing. This is caused by the fact that tyrosine, a kind of amino acid, which is a component of potato, is exposed to the air and oxidized using tyrosinase, which is an enzyme, as a catalyst, as described in the conventional example. This browning is a phenomenon that occurs only by peeling the potato skin normally and exposing the surface.However, when the potato is frozen and then thawed, the components inside the cells flow out to the outside, so the air is exposed to the air. The amount of tyrosine and tyrosinase exposed is greater than if the hulls were simply stripped, thus increasing the degree of browning.

本実施の形態においては、 このような褐変を防止するため、 上記の加 熱工程において、 チロシナーゼなどの酵素を失活させている。 あわせ調 味液の量を、 ある程度まで多くしてもよい料理では、 調味液にジャガイ モを完全に浸漬することで空気の遮断が可能だが、 そうでない場合は、 凍結解凍調理の凍結工程の前に加熱を行って、 酵素を失活させる。 ジャ ガイモの場合、 品温が 8 0 °C以上になるように加熱を行う。  In the present embodiment, in order to prevent such browning, enzymes such as tyrosinase are deactivated in the heating step. For dishes in which the amount of seasoning solution can be increased to a certain extent, the air can be shut off by completely immersing the potato in the seasoning solution; otherwise, before the freezing process of freeze-thaw cooking Heat to deactivate the enzyme. In the case of potatoes, heat so that the product temperature is at least 80 ° C.

この加熱工程により、 凍結解凍調理後から加熱調理を行うまでに生ず る食材の褐変を防止できる。 Due to this heating process, there is no birth between freeze-thaw cooking and heating cooking. Browning of foodstuffs can be prevented.

また、 ジャガイモの他に褐変する食品としては、 ごぼうやレンコンな どがあり、 これらについても、 酵素を失活するために品温が 8 0 °C以上 になるような加熱工程を行うことにより、 凍結解凍調理における褐変を 防止できる。  In addition to potatoes, other foods that turn brown include burdock and lotus root, and these are also subjected to a heating step in which the product temperature is raised to 80 ° C or higher in order to deactivate enzymes. Browning during freeze-thaw cooking can be prevented.

また、 加熱しない状態で食する漬け物において、 褐変が見られるもの としては、 からし菜の漬け物、 白菜の漬け物、 キユウリのピクルス等が ある。 通常の漬け物では、 塩を添加して、 食品中の水分を流出させるが 、 凍結解凍調理では、 食品中の水分を凍結させたときの氷の体積膨張に よる細胞破壌を利用して、 水分を流出させるので、 塩を添加せずにでき 、 無塩漬け物をつくることができる。 しかし、 通常の漬け物の調理方法 と較べると、 凍結解凍調理では、 細胞内部の成分が流出しやすくなり、 白菜ではポリフエノール物質のポリフエノールォキシダーゼ作用による 酸化がおこりやすく、 キユウリやからし菜では酸素と光の存在により生 ずる、 活性酵素によるクロロフィルの酸化分解が生じ、 褐変が促進され る。  Pickles that are eaten without heating and show browning include pickled mustard, pickled cabbage, and pickled cucumber. In normal pickles, salt is added to drain the water in the food, but in freeze-thaw cooking, the water in the food is frozen by using the cell rupture due to the volume expansion of the ice when the water is frozen. Because the outflow, salt can be added without salting can be made. However, compared to the usual method of cooking pickles, freezing and thawing cooking makes it easier for components inside the cells to flow out. Oxidative degradation of chlorophyll by active enzymes, which occurs due to the presence of oxygen and light, promotes browning.

そこで、 凍結解凍調理で、 生の状態で食べる漬け物風の野菜を作る場 合にも、 加熱工程を入れることで、 白菜などで見られる褐変が防止でき る。 また、 キユウリのピクルスやからし菜の漬け物風を作る場合も、 凍 結解凍工程の前に品温が 7 0 °Cになるような加熱工程を行うと、 クロ口 フィラーゼという酵素が作用し、 緑色の色素ク口口フィルがクロロフィ リンに変化して鮮緑色となり、 凍結解凍調理での褐変が防止できる。 ここで表 1に、 褐変する食品の一例と、 褐変の原因となる食品中の成 分、 および食品を褐変させる原因の一つである酵素の種類、 および酵素 失活温度を示す ( 「食材を生かす調理学」 弘学出版 田辺尚子編著、 に 基づく) 。 (表 1 ) Therefore, when making pickled vegetables that are eaten raw by freeze-thaw cooking, adding a heating step can prevent browning seen in Chinese cabbage. Also, in the case of pickled pickled cucumber or mustard vegetables, if a heating step is performed to bring the product temperature to 70 ° C before the freezing and thawing step, an enzyme called black mouth fillase will act, The green-colored orifice fill turns into chlorophyllin and becomes bright green, preventing browning during freeze-thaw cooking. Table 1 shows examples of browning foods, the components in foods that cause browning, the types of enzymes that cause browning of foods, and the enzyme inactivation temperatures. Cooking Studies ”based on Kogaku Shuppan, edited by Naoko Tanabe). (table 1 )

Figure imgf000015_0001
表 1に示すように、 酵素としては、 チロシナーゼ、 ポリフエノールォ キシターゼ、 フエノールォキシターゼがあるが、 本実施の形態の凍結解 凍調理においては、 食品がこれらの全部または一部を含んでいる場合、 酵素失活温度として 8 0 °C以上を設定するようにすれば、 食品の褐変を 防止することができることがわかる。
Figure imgf000015_0001
As shown in Table 1, the enzymes include tyrosinase, polyphenol oxidase, and phenol oxidase. In the freeze-thawing cooking of the present embodiment, the food contains all or a part of these. In this case, it can be understood that browning of food can be prevented by setting the enzyme deactivation temperature to 80 ° C or more.

なお、 加熱手段 2にマイクロ波を使う場合、 容器はマイクロ波が透過 し、 かつ温度に対する耐性を有する素材を用いる。 たとえば、 温度に対 する耐性が一 2 0 °C〜1 1 0 °Cのポリプロピレンなどがあげられる。 加 熱手段 2にヒータを使う場合は、 食品への熱伝達を速やかにするために アルミなど熱伝導性のよいものを使用する。  When microwaves are used for the heating means 2, the container is made of a material that transmits microwaves and has resistance to temperature. For example, polypropylene having a temperature resistance of 120 ° C. to 110 ° C. can be used. If a heater is used for heating means 2, use a material with good thermal conductivity, such as aluminum, to speed up the transfer of heat to food.

また、 上記の動作において、 凍結工程と解凍工程はそれぞれ一度ずつ 行うものとしたが、 凍結工程と解凍工程とは、 一度以上繰り返して行う ようにしてもよい。 また、 凍結工程と解凍工程 繰り返す毎に、 ジャガ ィモの雰囲気の温度を変動させるようにしてもよい。  In the above operation, the freezing step and the thawing step are performed once each. However, the freezing step and the thawing step may be performed one or more times. Further, the temperature of the atmosphere of the potato may be changed each time the freezing step and the thawing step are repeated.

' また、 本発明は、 上記実施の形態 1の凍結解凍調理器によらず、 電子 レンジ、 オーブン他の外部手段を用いた他の方法によって解凍される食 品に対しても、 その食品をあらかじめ上記加熱工程によって、 その内部 に含まれる酵素が失活した後に凍結させる処理を行う、 食品冷凍方法ま たは食品冷凍装置として実現してもよい。 さらに、 食品に湿潤させるた めの調味料は用いなくてもよい。 'The present invention also provides a method of preliminarily preserving food that is thawed by other methods using a microwave oven, an oven, or other external means, regardless of the freeze-thaw cooker of the first embodiment. The above-described heating step may be implemented as a food freezing method or a food freezing apparatus, in which the enzyme contained therein is inactivated and then frozen. In addition, the A seasoning may not be used.

また、 本発明は、 食品を凍結して得られる冷凍食品であって、 例えば 上記加熱工程によって、 その内部に含まれる酵素が、 食品を褐変させる 酵素が失活した酵素失活状態にあるような冷凍食品として実現してもよ レ、。  Further, the present invention relates to a frozen food obtained by freezing a food, wherein, for example, the enzyme contained therein is in an inactivated state in which an enzyme for browning the food is inactivated by the heating step. It may be realized as frozen food.

また、 上記の実施の形態においては、 食品に対する酵素失活状態は、 食品の加熱によって実現するものとしたが、 本発明は、 他の方法によつ て食品に対する酵素失活状態を実現するものであってもよい。  Further, in the above embodiment, the enzyme inactivated state for the food is realized by heating the food, but the present invention realizes the enzyme inactivated state for the food by another method. It may be.

さらに、 以下の動作を行う。  Further, the following operation is performed.

図 3は本発明の実施の形態 1の凍結解凍調理器のさらなる動作である 調理工程のフローシートであり、 本発明の実施の形態 1の凍結解凍調理 器の動作の解凍工程の後に加熱工程を行うものである。 以下、 図を参照 して、 その点について説明を行う。  FIG. 3 is a flow chart of a cooking process, which is a further operation of the freeze-thaw cooking device according to the first embodiment of the present invention. The heating process is performed after the thawing process of the operation of the freeze-thaw cooking device according to the first embodiment of the present invention. Is what you do. Hereinafter, this point will be described with reference to the drawings.

凍結工程、 解凍工程を経た凍結解凍調理物はその後、 生のまま食する もの、 あるいは、 通常の調理を行うものがある。 後者の場合は、 煮物で あったり、 焼き物であったりする。 このうち煮物のように凍結解凍後の 調理物を鍋に移し変えて加熱調理を行うものについて、 図 3のフローシ ートに示すように、 解凍工程後に加熱手段による加熱工程を加える。 解凍工程は、 加熱手段 2により食品の温度が 0 °Cに到達するまでの時 間を食品の種類、 量に応じて設定しておく。 そして、 解凍工程設定時間 が経過した時点で、 温度制御手段 8が閉じ、 加熱手段が作動して加熱ェ 程がすすむ。 加熱時間は、 重量センサ 4の検知データをもとに演算され 、 加熱終了時間がきまる。 加熱終了後、 食品が取り出されるまでは、 温 度制御手段 8によって 5°Cに保持され、通常の冷蔵室保存ができる。 この ような調理工程で行うメニューは、 肉じやが、 筑前煮、 煮豆、魚の煮つけ などがある。 これらのメニューにおいては、 加熱手段 2にマイクロ波を 用いると、 少量の場合、 短時間で加熱がすむ。 また、 煮ている時間が短 く、 煮汁が少量しかなくても、 凍結解凍によって食品内部に調味液が浸 透しているので、 味のよくしみこんだ煮物を作ることができる。 また、 加熱工程を組み入れることにより、調理物を鍋に移し変えて加熱調理を行 うという煩わしい操作をなくすことができる。 After the freezing and thawing processes, the frozen and thawed food may be eaten raw or cooked normally. In the latter case, it may be boiled or grilled. Among them, for the cooked foods such as boiled foods, which have been frozen and thawed, transferred to a pan and cooked, a heating step using a heating means is added after the thawing step as shown in the flow sheet in Fig. 3. In the thawing step, the time required for the temperature of the food to reach 0 ° C by the heating means 2 is set according to the type and amount of the food. Then, when the thawing process set time has elapsed, the temperature control means 8 is closed, the heating means is operated, and the heating process proceeds. The heating time is calculated based on the detection data of the weight sensor 4, and the heating end time is determined. After the heating is completed, the temperature is maintained at 5 ° C. by the temperature control means 8 until the food is taken out, and can be stored in a normal refrigerator. The menus used in such a cooking process include meat and chicken, boiled chikuzen, boiled beans, and boiled fish. In these menus, microwaves are applied to heating means 2 If used, heating can be done in a short time in a small amount. In addition, even if the cooking time is short and there is only a small amount of broth, the seasoning liquid penetrates inside the food by freezing and thawing, so that a simmered dish with good taste can be made. In addition, by incorporating a heating step, it is possible to eliminate the cumbersome operation of transferring cooked food to a pan and performing cooking.

さらに、 以下の動作を行うようにしてもよい。  Further, the following operation may be performed.

図 4は本発明の実施の形態 1の凍結解凍調理器のさらなる動作の他の 例である調理工程の第 2例のフローシートである。 本発明の実施の形態 1の凍結解凍調理器の動作の解凍工程と加熱工程にマイクロ波加熱を用 い、 そのマイクロ波の制御方法についての説明をおこなう。  FIG. 4 is a flow sheet of a second example of the cooking process, which is another example of the further operation of the freeze-thaw cooker according to the first embodiment of the present invention. Microwave heating is used for the thawing step and the heating step of the operation of the freeze-thaw cooking device according to the first embodiment of the present invention, and a method of controlling the microwave will be described.

解凍工程でのマイクロ波の食品への入力電力は、 2 0 0 W前後でおこな う。 解凍工程での食品は凍った状態であり、 マイクロ波を照射しても、 透過しやすく、 食品自体は温まりにくい。 そして、 食品の一部分が解け 始めると、 その部分におけるマイクロ波の吸収がよくなり、 加熱むらの 原因となる。 この現象は照射するマイクロ波の電力が大きいほど顕著に 現れる。 よって、 食品が解けるまでは 2 0 0 W前後のマイクロ波を照射す る。  The microwave input power to the food during the thawing process should be around 200 W. The food in the thawing process is in a frozen state and easily penetrates even when irradiated with microwaves, and the food itself is hard to warm. When a part of the food begins to melt, microwave absorption in that part improves, causing uneven heating. This phenomenon becomes more conspicuous as the power of the irradiated microwave increases. Therefore, a microwave of about 200 W is irradiated until the food is melted.

そして、 完全に食品が解凍されたら加熱工程へ移り、 マイクロ波の電 力を 5 0 0 W前後に切り替えて加熱をおこなう。 マイクロ波の電力の切替 は、 あらかじめ食品の種類と重量から解凍時間をマイコンに設定入力し ておく力、、 食品の凍結時から解凍時の形状変化をとらえておこなう。 例 えば、 煮汁を含むものでは、 凍結状態から解凍していくにしたがって液 体が生じる。 液体が生じるときの振動を重量センサでとらえ、 マイクロ 波の電力切替を行う。 また、 煮汁がないものでは、 解凍時に野菜から流 出する水分の振動を同様に重量センサでとらえて、 マイクロ波の電力制 御をおこなう。 このように、 食品の凍結状態と解凍状態でマイクロ波の 出力を切り替えて加熱を行うことにより、 マイク口波の加熱ムラを抑え つつ、 凍結解凍調理の出来栄えが良好なものとなる。 Then, when the food is completely thawed, the process proceeds to the heating step, in which the microwave power is switched to around 500 W to heat. The switching of microwave power is based on the ability to pre-set the thawing time into the microcomputer based on the type and weight of the food, and the change in shape from the time the food is frozen to the time it is thawed. For example, liquids containing broth form liquid as they are thawed from the frozen state. Vibration when liquid is generated is detected by the weight sensor, and microwave power is switched. If there is no broth, the vibration of the water flowing out of the vegetables at the time of thawing is also detected by a weight sensor, and microwave power is controlled. Thus, microwaves can be used to freeze and thaw food. By switching the output and performing heating, the freeze-thaw cooking can be performed well, while suppressing the uneven heating of the microphone mouth wave.

(実施の形態 2 )  (Embodiment 2)

本発明の実施の形態 2における凍結解凍調理器は、 基本的には実施の 形態 1と同一であるが、 収納容器 3内の空気を脱気する機能を有する点 が異なる。  The freeze-thaw cooker according to the second embodiment of the present invention is basically the same as the first embodiment, except that it has a function of degassing the air in storage container 3.

図 5は本発明の実施の形態 2における凍結解凍調理器における、 脱気 機能付き収納容器の構成図であり、 図 6は、 この凍結解凍調理器の調理 工程のフローシート図である。  FIG. 5 is a configuration diagram of a storage container with a deaeration function in a freeze-thaw cooker according to Embodiment 2 of the present invention, and FIG. 6 is a flow sheet diagram of a cooking process of the freeze-thaw cooker.

図 5に示すように、 脱気機能付き収納容器 5 0は、 収納容器 3に瞵接 して設けられた脱気手段 1 0を有する手段であり、 脱気手段 1 0は吸引 ポンプ 1 1を内蔵し、 排気口 1 3を有している。 吸引ポンプ 1 1のチュ ーブ 1 2は、 例えばゴム管などからなり、 収納容器 3と接続され、 吸引 ポンプ 1 1と収納容器 3の内部とを連通するようにしている。  As shown in FIG. 5, the storage container 50 with a degassing function is a means having deaeration means 10 provided in contact with the storage container 3, and the deaeration means 10 is provided with a suction pump 11 It is built in and has an exhaust port 13. The tube 12 of the suction pump 11 is made of, for example, a rubber tube and is connected to the storage container 3 so that the suction pump 11 communicates with the inside of the storage container 3.

このような構成を有する、 本発明の実施の形態 2による凍結解凍調理 器の動作について、 説明を行うとともに、 これにより、 本発明の食品凍 結方法および凍結解凍調理方法の一実施の形態について説明を行う。 た だし、 実施の形態 1と重複する部分は省略し、 相違点を中心に述べる。 本実施の形態による凍結解凍調理器の動作は、 図 6に示すように、 実 施の形態 1の動作における加熱工程、 凍結工程、 解凍工程において、 加 熱工程の代わりに、 脱気機能付き収納容器 5 0を用いた脱気工程を行う c 脱気工程は、 吸引ポンプ 1 1の作動からはじまり、 こ により収納容 器 3内の空気が吸引され、 排気口 1 3から調理室内に排出される。 一定 の排気量以下になった時点で、 吸引ポンプ 1 1の動作は停止する。 排気 量の検知はチューブ 1 2に流量計などを接続して行う。  The operation of the freeze-thaw cooking device according to the second embodiment of the present invention having such a configuration will be described, and thereby, one embodiment of the food freezing method and the freeze-thaw cooking method of the present invention will be described. I do. However, parts that are the same as those in Embodiment 1 are omitted, and differences are mainly described. As shown in FIG. 6, the operation of the freeze-thaw cooking device according to the present embodiment is as follows. Perform the degassing process using the container 50 c The degassing process starts with the operation of the suction pump 11, whereby the air in the storage container 3 is sucked and discharged into the cooking chamber from the exhaust port 13. . The operation of the suction pump 11 stops when the displacement becomes equal to or less than a certain displacement. The displacement is detected by connecting a flow meter to tube 12.

脱気工程終了後の凍結工程、 解凍工程は前述した実施の形態 1に準ず る。 実施の形態 1にて説明したように、 食品の褐変は、 酵素と、 食品周 囲の空気に含まれる酸素によって引き起こされるが、 本実施の形態にお いては、 食品周囲の空気を脱気することにより、 食品の褐変に必要な量 より少ない量の酸素しか残留してしないようにする。 したがって、 収納 容器 3内においては、 褐変に必要な酸素の量よりも少ないため、 解凍ェ 程が始まっても、 食品の褐変反応は生じず、 ジャガイモゃ、 野菜等の食 品の褐色化を防止することができる。 このとき、 脱気工程は、 少なくと も解凍された食品が褐変を開始するタイミングまで、 食品の周辺の酸素 力 食品に含まれる酵素が褐変に必要とする最低限の量よりも少ないよ うな雰囲気を実現できればよく、 したがって、 脱気工程の一部は凍結ェ 程と平行して行われてもよい。 The freezing and thawing processes after the degassing process are the same as in the first embodiment described above. You. As described in the first embodiment, browning of food is caused by enzymes and oxygen contained in air around food. In this embodiment, air around food is degassed. This ensures that less oxygen remains than is needed for browning food. Therefore, since the amount of oxygen in the storage container 3 is smaller than the amount of oxygen required for browning, even when the thawing process starts, the browning reaction of the food does not occur, and the browning of foods such as potatoes and vegetables is prevented. can do. At this time, the degassing process is carried out in an atmosphere in which the amount of enzymes contained in the food is less than the minimum amount required for browning at least until the time when the thawed food starts browning. Therefore, a part of the deaeration step may be performed in parallel with the freezing step.

なお、 上記の説明においては、 脱気工程、 凍結工程、 解凍工程の 3ェ 程から動作を行うものとして説明を行ったが、 脱気工程と凍結工程との 間に、 実施の形態 1の加熱工程を加えてもよい。 このとき、 収納容器 3 内の食材は、 脱気された状態で、 酵素失活温度まで加熱されることとな り、 褐変防止の効果をさらに向上させることができる。  In the above description, the operation has been described as being performed from the three steps of the degassing step, the freezing step, and the thawing step, but the heating of the first embodiment is performed between the degassing step and the freezing step. A step may be added. At this time, the food material in the storage container 3 is heated to the enzyme inactivation temperature in a degassed state, and the effect of preventing browning can be further improved.

また、 収納容器 3内の酸素の残流量を検知する方法としては、 排気量 の検知によるほか、 圧力計などを用いて収納容器 3内の気圧の変化を検 知するようにしてもよい。 また、 センサを用いて残留酸素量を直接検出 するようにしてもよい。  As a method of detecting the remaining flow rate of oxygen in the storage container 3, a change in the atmospheric pressure in the storage container 3 may be detected using a pressure gauge or the like, in addition to the detection of the displacement. Alternatively, the residual oxygen amount may be directly detected using a sensor.

(実施の形態 3 )  (Embodiment 3)

図 7は本発明の実施の形態 3における凍結解凍調理器における、 ガス 注入機能付き収納容器の構成図であり、 図 8は、 この凍結解凍調理器の 調理工程のフローシート図である。  FIG. 7 is a configuration diagram of a storage container with a gas injection function in the freeze-thaw cooker according to Embodiment 3 of the present invention, and FIG. 8 is a flow sheet diagram of a cooking process of the freeze-thaw cooker.

図 7において、 図 5と同一部または相当部には同一符号を付し、 詳細 な説明は省略する。 また、 1 4は収納容器 3内に不活性ガスを注入する 、 ガス注入手段である。 ガス注入手段 1 4としては、 脱気手段 1 0本体 から脱着可能な、 カートリッジ型の缶の状態のものをセットするような 構成となっている。 不活性ガスの例として、 窒素などがあげられる。 In FIG. 7, the same or corresponding parts as those in FIG. 5 are denoted by the same reference numerals, and detailed description will be omitted. In addition, 14 injects an inert gas into the storage container 3 The gas injection means. The gas injection means 14 is configured to set a cartridge type can that is detachable from the deaeration means 10 main body. Examples of the inert gas include nitrogen.

このような構成を有する、 本実施の形態による凍結解凍調理器の動作 は、 図 8に示すように、 実施の形態 2の動作における脱気工程、 凍結ェ 程、 解凍工程において、 脱気工程と凍結工程との間に、 ガス注入機能付 き機能付き収納容器 7 0を用いたガス注入工程をさらに加えたものであ る。 したがって、 実施の形態 2と同様の点は省略し、 相違点を中心に述 ベる。  The operation of the freeze-thaw cooker according to the present embodiment having such a configuration includes, as shown in FIG. 8, a deaeration step, a freezing step, and a defrosting step in the operation of the second embodiment. In addition to the freezing step, a gas injection step using a storage container 70 having a gas injection function is further added. Therefore, the same points as in the second embodiment are omitted, and the differences will be mainly described.

脱気工程において、 食品の褐変に必要な酸素量より少ない酸素量にな るまで、 収納容器 3内の空気が排出されると、 ガス注入工程として、 ガ ス注入手段 1 4から不活性ガスが収納容器 3に注入され、 収納容器 3内 は、 不活性ガスが充填される。  In the deaeration step, when the air in the storage container 3 is exhausted until the amount of oxygen becomes smaller than the amount of oxygen necessary for browning the food, an inert gas is supplied from the gas injection means 14 as a gas injection step. The gas is injected into the storage container 3, and the inside of the storage container 3 is filled with an inert gas.

ガス注入工程終了後の凍結工程、 解凍工程は前述してきた実施の形態 1に準ずる。 収納容器 3内において、 食品周辺の空気を不活性ガスにお きかえることにより、 収納容器 3内の酸素の量が、 褐変に必要な量より 少なくなるため、 解凍工程が始まっても、 食品の褐変反応は生じず、 さ らに、 食品成分の化学変化が置きにくい状態となる。 それにともない、 食品の褐変だけではなく、 成分酸化による劣化も防止され、 ジャガイモ や、 野菜等の食品の凍結解凍調理の仕上がりが良好となる。  The freezing step and the thawing step after the gas injection step are the same as in the first embodiment described above. By switching the air around the food into an inert gas in the storage container 3, the amount of oxygen in the storage container 3 becomes smaller than that required for browning. No browning reaction occurs, and furthermore, it is difficult to put chemical changes in food components. Along with this, not only browning of foods but also deterioration due to oxidation of ingredients are prevented, and the finish of freeze-thaw cooking of foods such as potatoes and vegetables is improved.

なお、 上記の説明においては、 脱気工程、 ガス注入工程、 凍結工程、 解凍工程の 4工程から動作を行うものとして説明を行ったが、 ガス注入 工程と凍結工程との間、 脱気工程の前、 もしくは脱気工程またはガス注 入工程と平行して、 実施の形態 1の加熱工程を加えてもよい。 このとき 、 収納容器 3内の食材は、 不活性ガスが注入された状態で、 酵素失活温 度まで加熱されることとなり、 褐変防止の効果をさらに向上させること ができる。 In the above description, the description has been made assuming that the operation is performed from the four steps of the deaeration step, the gas injection step, the freezing step, and the thawing step, but the operation of the deaeration step is performed between the gas injection step and the freezing step. The heating step of Embodiment 1 may be added before or in parallel with the degassing step or the gas injection step. At this time, the ingredients in the storage container 3 are heated to the enzyme inactivation temperature in a state in which the inert gas is injected, thereby further improving the effect of preventing browning. Can be.

以上のような本発明の各実施の形態は、 食品周囲の気体を吸引あるい は不活性ガスに置換する手段を設け、 食品を凍結解凍する調理器にする ことによって、 食品の褐変を防止でき、 味の染み込みがよいなど利点の ある凍結解凍調理の出来栄えが良好となる。  Each of the embodiments of the present invention as described above can prevent browning of food by providing a means for sucking or replacing gas around the food with an inert gas and using a cooking device for freezing and thawing the food. Freeze-thaw cooking, which has advantages such as good taste penetration, is performed well.

さらに、 凍結解凍調理の加熱手段にマイクロ波を用いることによって 、 少量の場合、 短時間調理が可能となる。  Furthermore, by using microwaves as the heating means for freezing and thawing cooking, it is possible to cook for a short time in a small amount.

さらに、 凍結と解凍工程の前に加熱工程を行うことにより、 食品の酵 素作用による褐色化をおさえることができ、 凍結解凍調理の出来栄えが 良好なものとなる。  Furthermore, by performing the heating step before the freezing and thawing steps, it is possible to suppress the browning due to the enzymatic action of the food, and the quality of the freeze-thaw cooking is improved.

さらに、 凍結工程後に食品の可食温度まで加熱を行う工程にすること により、 調理物を鍋に移し変えて加熱調理を行うという煩わしい操作を なくすことができる。  Furthermore, the step of heating to the edible temperature of the food after the freezing step can eliminate the cumbersome operation of transferring the cooked food to the pot and performing the heating and cooking.

さらに、 凍結解凍調理の解凍工程と加熱調理工程でマイクロ波の出力 を切り替えて加熱を行うことにより、 マイクロ波の加熱ムラを抑えつつ 、 凍結解凍調理の出来栄えが良好なものにすることができる。  Further, by switching the microwave output between the thawing step and the heating and cooking step of the freeze-thaw cooking and performing the heating, it is possible to improve the quality of the freeze-thaw cooking while suppressing the heating unevenness of the microwave.

また、 前記凍結工程中あるいは前に、 食品周囲の気体を除去する脱気 工程を加えることによって、 食品周辺の空気を取り除かれ、 カットした 野菜での褐色化を防止して凍結解凍調理の出来栄えをよくすることがで さる。  In addition, during or before the freezing step, by adding a degassing step for removing gas around the food, air around the food is removed, browning of the cut vegetables is prevented, and the quality of freeze-thaw cooking is improved. You can do better.

また、 前記凍結工程中あるいは前に、 食品周囲の気体を不活性ガスに 置き換えることにより、 酸素が除去されるとともに、 食品成分の化学変 化が置きにくい状態となり、 食品の褐変だけではなく、 成分酸化による 劣化も防止され、 カツトした野菜での凍結解凍調理の仕上がりが良好と なる。  In addition, by replacing the gas around the food with an inert gas during or before the freezing step, oxygen is removed, and chemical changes of the food components become difficult to place. Deterioration due to oxidation is also prevented, and the finish of freeze-thaw cooking with cut vegetables is improved.

なお、 上記の各実施の形態において、 マイコン 5および加熱手段 2は 、 本発明の酵素失活手段および解凍手段の一例であり、 マイコン 5およ ぴ冷却手段 6は、 本発明の凍結手段の一例であり、 収納容器 3は、 本発 明の湿潤手段おょぴ収納室の一例であり、 マイコン 5およぴ脱気手段 1 0は、 本発明の脱気手段の一例であり、 マイコン 5およびガス注入手段 1 4は、 本発明の不活性ガス導入手段の一例である。 In each of the above embodiments, the microcomputer 5 and the heating means 2 The microcomputer 5 and the cooling means 6 are examples of the freezing means of the present invention, and the storage container 3 is an example of the humidifying means of the present invention. The microcomputer 5 and the degassing means 10 are examples of the degassing means of the present invention, and the microcomputer 5 and the gas injection means 14 are examples of the inert gas introducing means of the present invention. It is.

なお、 本発明は上記の実施の形態に限定されるものではなく、 本発明 の収納室は、 凍結解凍調理を行うための湿潤手段と兼用する必要はなく 、 外部の冷凍装置等、 他の手段により凍結した食品を収納するものであ つてもよい。 したがって、 本発明は、 凍結解凍調理ばかりでなく、 外部 手段により凍結された食品を解凍し、 その際に該食品の周囲の雰囲気を 、 酸素が所定量より少なくなるような状態に保ち、 前記所定量は、 前記 酸素を触媒として前記食品を褐変させる酵素が、 前記食品を褐変させる のに最低限必要な量である食品解凍装置または食品解凍方法として実現 また、 本発明は、 上述した本発明の食品解凍方法または食品凍結方法 の全部又は一部の工程の動作をコンピュータにより実行させるためのプ ログラムであって、 コンピュータと協働して動作するプログラムである c また、 本発明は、 上述した本発明の食品解凍方法または食品凍結方法 の全部または一部の工程の全部または一部の動作をコンピュータにより 実行させるためのプログラムを担持した媒体であり、 コンピュータによ り読み取り可能且つ、 読み取られた前記プログラムが前記コンピュータ と協動して前記機能を実行する媒体である。 It should be noted that the present invention is not limited to the above embodiment, and the storage room of the present invention does not need to double as a wetting means for performing freezing and thawing cooking. It may store frozen foods. Therefore, the present invention provides not only freezing and thawing cooking, but also thawing frozen food by external means, and maintaining the atmosphere around the food in such a state that oxygen becomes less than a predetermined amount. The quantification is realized as a food thawing apparatus or a food thawing method in which the enzyme for browning the food using the oxygen as a catalyst is the minimum amount required for browning the food. this whole food thawing method or food freezing process or the operation of some of the steps a program for causing a computer to execute, c also a computer in cooperation with program operating, the present invention is described above A program for causing a computer to execute all or a part of all or part of the steps of the food thawing method or the food freezing method of the invention A carrying medium, readable Ri by the computer and a medium in which the program read performs the functions in cooperation with the computer.

なお、 本発明の一部の手段 (又は、 装置、 素子、 回路、 部等) 、 本発 明の一部のステップ (又は、 工程、 動作、 作用等) とは、 それらの複数 の手段又はステップの内の、 幾つかの手段又はステップを意味し、 ある いは、 一つの手段又はステップの内の、 一部の機能又は一部の動作を意 味するものである。 また、 本発明の一部の装置 (又は、 素子、 回路、 部等) とは、 それらの複数の装置の内の、 幾つかの装置を意味し、 ある いは、 一つの装置の内の、 一部の手段 (又は、 素子、 回路、 部等) を意 味し、 あるいは、 一つの手段の内の、 一部の機能を意味するものである c また、 本発明のプログラムを記録した、 コンピュータに読みとり可能 な記録媒体も本発明に含まれる。 Note that some means (or devices, elements, circuits, units, and the like) of the present invention and some steps (or steps, operations, functions, and the like) of the present invention refer to a plurality of these means or steps. Means some means or steps, or means one function or part of one means or step. To taste. In addition, some devices (or elements, circuits, units, and the like) of the present invention mean some of the plurality of devices, or one of the devices. part of the means (or devices, circuits, parts etc.) the meaning taste, or of the single unit, is intended to mean a part of the function c also records a program of the present invention, the computer The present invention also includes a recording medium that can be read.

また、 本発明のプログラムの一利用形態は、 コンピュータにより読み 取り可能な記録媒体に記録され、 コンピュータと協働して動作する態様 であっても良い。  One use form of the program of the present invention may be a form in which the program is recorded on a computer-readable recording medium and operates in cooperation with the computer.

また、 本発明のプログラムの一利用形態は、 伝送媒体中を伝送し、 コ ンピュータにより読みとられ、 コンピュータと協働して動作する態様で めって5 b民い。 Moreover, one utilizing form of the program of the present invention, transmitted through a transmission medium, read by computers, Mette 5 b people physician in a manner which operates in cooperation with the computer.

また、 記録媒体としては、 R OM等が含まれ、 伝送媒体としては、 ィ ンターネット、 光ファイバ等の伝送機構、 光 ·電波 ·音波等が含まれる また、 上述した本発明のコンピュータは、 C P U等の純然たるハード ウェアに限らず、 ファームウェアや、 O S、 更に周辺機器を含むもので あっても良い。 ·  Further, the recording medium includes ROM and the like, and the transmission medium includes transmission mechanisms such as the Internet and optical fibers, light, radio waves, sound waves, and the like. Not only pure hardware such as, but also firmware, OS, and peripherals may be included. ·

なお、 以上説明した様に、 本発明の構成は、 ソフトウェア的に実現して も良いし、 ハードウェア的に実現しても良い。 産業上の利用可能性 As described above, the configuration of the present invention may be realized by software or hardware. Industrial applicability

以上のように本発明によれば、 凍結した食品を解凍する際に、 食品の 褐変を防止することができる。  As described above, according to the present invention, when thawing frozen food, browning of the food can be prevented.

Claims

求 の 囲 Request box 1 . 食品を凍結する食品凍結方法であって、 1. A food freezing method for freezing food, 前記凍結を行う前および/または前記凍結中に、 前記食品内の、 前記 食品を褐変させる酵素が失活する状態にする食品凍結方法。  A food freezing method in which an enzyme for browning the food is deactivated in the food before and / or during the freezing. 2 . 前記酵素が失活する状態は、 前記食品の温度を、 前記食品を褐 変させる酵素が失活する酵.素失活温度まで上げることにより実現する請 求項 1に記載の食品凍結方法。  2. The food freezing method according to claim 1, wherein the enzyme is inactivated by raising the temperature of the food to an enzyme at which an enzyme that inactivates the food browns is inactivated. . 3 . 前記酵素は、 チロシナーゼ、 ポリフエノールォキシターゼ、 フ ェノールォキシターゼの全部または一部を含む請求項 1または 2に記載 の食品凍結方法。  3. The method for freezing food according to claim 1, wherein the enzyme comprises all or a part of tyrosinase, polyphenol oxidase, or phenol oxidase. 4 . 前記酵素失活温度は、 8 0 °C以上である請求項 2に記載の食品 凍結方法。  4. The food freezing method according to claim 2, wherein the enzyme deactivation temperature is 80 ° C or higher. 5 . 前記食品を、 凍結前に調味料に浸潤させる請求項 1から 4のい ずれかに記載の食品凍結方法。  5. The food freezing method according to any one of claims 1 to 4, wherein the food is infiltrated into a seasoning before freezing. 6 . 凍結した食品を解凍する食品解凍方法であって、  6. A food thawing method for thawing frozen food, 少なくとも前記解凍が行われている間、 前記食品の周囲の雰囲気を、 酸素が所定量より少なくなるような状態に保つ工程を備え、  At least while the thawing is being performed, a step of maintaining an atmosphere around the food in a state where oxygen is less than a predetermined amount, 前記所定量は、 前記酸素を触媒として前記食品を褐変させる酵素が、 前記食品を褐変させるのに最低限必要な量である食品解凍方法。  The food thawing method, wherein the predetermined amount is a minimum amount required for the enzyme for browning the food using the oxygen as a catalyst to brown the food. 7 . 前記雰囲気を、 不活性ガスを存在させることにより実現してい る請求項 6に記載の食品解凍方法。  7. The food thawing method according to claim 6, wherein the atmosphere is realized by the presence of an inert gas. 8 . 少なくとも請求項 1から 5のいずれかの食品凍結方法により凍 結した食品を、 解凍する工程を備えた凍結解凍調理方法。  8. A freeze-thaw cooking method comprising the step of thawing food frozen by at least the food freezing method according to any one of claims 1 to 5. 9 . 凍結した食品を、 少なくとも請求項 6または 7に記載の食品解 凍方法により解凍する工程を備えた凍結解凍調理方法。 9. Frozen food must be disintegrated at least according to claim 6 or 7. A freeze-thaw cooking method comprising a step of thawing by a freezing method. 1 0 . 前記凍結と、 前記解凍とを少なくとも 1回以上繰り返して行う 請求項 8または 9に記載の凍結解凍調理方法。  10. The freeze-thaw cooking method according to claim 8 or 9, wherein the freezing and the thawing are repeated at least once or more. 1 1 . 食品を凍結する凍結手段を備え、  1 1. Equipped with freezing means for freezing food, 前記凍結手段が凍結動作を行う前および/または凍結動作中に、 前記 食品内の、 前記食品を褐変させる酵素が失活する状態にする食品凍結装  Before and / or during the freezing operation of the freezing means, a food freezing device for setting an enzyme in the food for browning the food to be inactivated. 1 2 . 食品を凍結する凍結手段と、 1 2. Freezing means for freezing the food; 前記凍結手段が凍結動作を行う前および/または凍結動作中に、 前記 食品内の、 前記食品を褐変させる酵素が失活する状態にする酵素失活手 段とを備えた食品凍結装置。  An enzyme inactivating means for inactivating the enzyme for browning the food in the food before the freezing means performs the freezing operation and / or during the freezing operation. 1 3 . 前記酵素失活手段は、 前記凍結手段が凍結動作を行う前に、 前 記食品の温度を、 前記食品を褐変させる酵素が失活する酵素失活温度ま で上げる請求項 1 2に記載の食品凍結装置。  13. The enzyme inactivating means according to claim 12, wherein the enzyme inactivating means raises the temperature of the food to an enzyme inactivating temperature at which an enzyme for browning the food is inactivated before the freezing means performs a freezing operation. A food freezing device as described. 1 4 . 前記酵素は、 チロシナーゼ、 ポリフエノールォキシターゼ、 フ ェノールォキシターゼの全部または一部を含む請求項 1 1から 1 3のい ずれかに記載の食品凍結装置。  14. The food freezing apparatus according to any one of claims 11 to 13, wherein the enzyme comprises all or a part of tyrosinase, polyphenol oxidase, or phenol oxidase. 1 5 . 前記酵素失活温度は、 8 0 °C以上である請求項 1 3に記載の食  15. The food according to claim 13, wherein the enzyme inactivation temperature is 80 ° C or higher. 1 6 . 凍結した食品が収納される収納室と、 前記収納室内の脱気を行 う脱気手段と、 前記凍結した食品を解凍する解凍手段とを備えた食品解 凍装置であって、 16. A food decompression device comprising: a storage chamber for storing frozen food; deaeration means for deaeration of the storage chamber; and thawing means for thawing the frozen food. 前記脱気手段は、 少なくとも前記解凍が行われている間、 前記食品の 周囲の雰囲気を、 酸素が所定量より少なくなるような状態に保ち、 前記所定量は、 前記酸素を触媒として前記食品を褐変させる酵素が、 前記食品を褐変させるのに最低限必要な量である食品解凍装置。 The deaeration means maintains an atmosphere around the food at least during a time when the thawing is performed, such that oxygen is less than a predetermined amount. A food thawing device, wherein the amount of the browning enzyme is a minimum necessary for browning the food. 1 7 . 前記収納室内に不活性ガスを導入する不活性ガス導入手段を備 え、 17. An inert gas introducing means for introducing an inert gas into the storage chamber is provided. 前記雰囲気を、 前記不活性ガスを存在させることにより実現している 請求項 1 6に記載の食品解凍装置。  The food thawing apparatus according to claim 16, wherein the atmosphere is realized by the presence of the inert gas. 1 8 . 請求項 1 1から 1 5のいずれかに記載の食品凍結装置と、 前記 凍結が行われる前の前記食品を調味料に浸潤させる湿潤手段とを備えた  18. The food freezing device according to any one of claims 11 to 15, and a wetting means for infiltrating the food into a seasoning before the freezing is performed. 1 9 . 請求項 1 6または 1 7に記載の食品解凍装置と、 1 9. The food defrosting device according to claim 16 or 17, 前記食品を凍結させる凍結手段と、  Freezing means for freezing the food, 前記凍結が行われる前の前記食品を調味料に浸潤させる湿潤手段とを 備えた凍結解凍調理装置。  A freeze-thaw cooking device comprising: a wetting means for infiltrating the food into the seasoning before the freezing is performed. 2 0 . 食品を凍結して得られた冷凍食品であって、  20. Frozen food obtained by freezing food, 前記食品は、 前記食品を褐変させる酵素が失活した酵素失活状態にあ る冷凍食品。  The food is a frozen food in an enzyme inactivated state in which an enzyme for browning the food is inactivated. 2 1 . 前記酵素失活状態は、 前記凍結を行う前および/または前記凍 結中に、 前記食品内の、 前記食品を褐変させる酵素が失活する酵素失活 温度まで加熱されることにより実現ざれている請求項 2 0に記載の冷凍  21. The enzyme inactivated state is realized by heating to an enzyme inactivating temperature at which the enzyme for browning the food in the food is inactivated before and / or during the freezing. Claim 20: Refrigeration according to claim 20 2 2 . 請求項 1に記載の食品凍結方法の、 前記食品の温度を、 前記食 品を褐変させる酵素が失活する酵素失活する状態にする工程の全部また は一部をコンピュータに実行させるためのプログラム。 22. The computer according to claim 1, wherein the computer performs all or part of the step of bringing the temperature of the food into an enzyme-inactive state in which an enzyme that causes browning of the food is inactivated. Program for. 2 3 . 請求項 6に記載の食品解凍方法の、 少なくとも前記解凍が行わ れている間、 前記食品の周囲の雰囲気を、 酸素が所定量より少なくなる ような状態に保つ工程の全部または一部をコンピュータに実行させるた めのプログラム。  23. The food thawing method according to claim 6, wherein at least during the thawing is performed, the atmosphere around the food is kept in a state in which the amount of oxygen is less than a predetermined amount. Is a program that causes a computer to execute. 2 4 . 請求項 1に記載の食品凍結方法の、 前記食品の温度を、 前記食 品を褐変させる酵素が失活する酵素失活する状態にする工程の全部また は一部をコンピュータに実行させるためのプログラムを担持した媒体で あって、 コンピュータにより処理可能な媒体。 24. The method for freezing a food according to claim 1, wherein the temperature of the food is A medium carrying a program for causing a computer to execute all or a part of a step of deactivating an enzyme which causes browning of an article to deactivate the enzyme, the medium being processable by a computer. 2 5 . 請求項 6に記載の食品解凍方法の、 請求項 6に記載の食品解凍 方法の、 少なくとも前記解凍が行われている間、 前記食品の周囲の雰囲 気を、 酸素が所定量より少なくなるような状態に保つ工程の全部または 一部をコンピュータに実行させるためのプログラムを担持した媒体であ つて、 コンピュータにより処理可能な媒体。  25. The method for thawing food according to claim 6 and the method for thawing food according to claim 6, wherein at least during the thawing is performed, the atmosphere around the food is reduced to a predetermined amount of oxygen. A medium that carries a program for causing a computer to execute all or a part of the process of keeping the number of steps to be reduced, and is a medium that can be processed by a computer.
PCT/JP2002/005717 2001-07-03 2002-06-10 Methods of freezing and thawing food, method of freezing, thawing, and cooking food, devices for freezing and thawing food, device of freezing, thawing, and cooking food, and frozen food WO2003003861A1 (en)

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