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WO2003087261A1 - Afficheur a cristaux liquides - Google Patents

Afficheur a cristaux liquides Download PDF

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Publication number
WO2003087261A1
WO2003087261A1 PCT/JP2003/004791 JP0304791W WO03087261A1 WO 2003087261 A1 WO2003087261 A1 WO 2003087261A1 JP 0304791 W JP0304791 W JP 0304791W WO 03087261 A1 WO03087261 A1 WO 03087261A1
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WO
WIPO (PCT)
Prior art keywords
liquid crystal
crystal display
display device
monomer
substrates
Prior art date
Application number
PCT/JP2003/004791
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English (en)
Japanese (ja)
Inventor
Yohei Nakanishi
Masakazu Shibasaki
Kazutaka Hanaoka
Yuichi Inoue
Kazuaki Tarumi
Matthias Bremer
Melanie Klasen-Memmer
Simon Greenfield
Richard Harding
Original Assignee
Fujitsu Display Technologies Corporation
Merck Patent Gesellschaft Mit Beschrankter Haftung
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=29243372&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2003087261(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Fujitsu Display Technologies Corporation, Merck Patent Gesellschaft Mit Beschrankter Haftung filed Critical Fujitsu Display Technologies Corporation
Priority to EP03746491A priority Critical patent/EP1498468B1/fr
Priority to CN03808533XA priority patent/CN1646662B/zh
Priority to AU2003235166A priority patent/AU2003235166A1/en
Priority to DE60324541T priority patent/DE60324541D1/de
Priority to KR1020047016527A priority patent/KR100677804B1/ko
Publication of WO2003087261A1 publication Critical patent/WO2003087261A1/fr
Priority to US10/966,692 priority patent/US7169449B2/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/12—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings at least two benzene rings directly linked, e.g. biphenyls
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
    • C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/32—Non-steroidal liquid crystal compounds containing condensed ring systems, i.e. fused, bridged or spiro ring systems
    • C09K19/322—Compounds containing a naphthalene ring or a completely or partially hydrogenated naphthalene ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/38—Polymers
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/133365—Cells in which the active layer comprises a liquid crystalline polymer
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • G02F1/13378—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation
    • G02F1/133788—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation by light irradiation, e.g. linearly polarised light photo-polymerisation
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/137—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
    • G02F1/139—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering based on orientation effects in which the liquid crystal remains transparent
    • G02F1/1393—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering based on orientation effects in which the liquid crystal remains transparent the birefringence of the liquid crystal being electrically controlled, e.g. ECB-, DAP-, HAN-, PI-LC cells
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
    • C09K2019/0448—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
    • C09K19/54—Additives having no specific mesophase characterised by their chemical composition
    • C09K19/542—Macromolecular compounds
    • C09K2019/548—Macromolecular compounds stabilizing the alignment; Polymer stabilized alignment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C09K2323/03—Viewing layer characterised by chemical composition
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/133397—Constructional arrangements; Manufacturing methods for suppressing after-image or image-sticking
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • G02F1/133707—Structures for producing distorted electric fields, e.g. bumps, protrusions, recesses, slits in pixel electrodes
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/137—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
    • G02F1/13775—Polymer-stabilized liquid crystal layers

Definitions

  • a liquid crystal material containing a monomer or oligomer polymerized by light or heat is sealed between the substrates, and the polymerizable component is polymerized while adjusting the voltage applied to the liquid crystal layer to change the alignment direction.
  • the present invention relates to a liquid crystal display device and a liquid crystal material using the determined liquid crystal.
  • the voltage includes 0 volts, and the voltage adjustment hereinafter includes 0 volts.
  • a pair of flat comb electrodes facing each other is provided in a horizontal plane parallel to the display surface direction, and liquid crystal molecules between the facing electrodes are switched in a horizontal plane.
  • a flat comb-shaped electrode significantly reduces the aperture ratio of a liquid crystal display device, so a strong pack light is required for an IPS mode liquid crystal display device.
  • the liquid crystal In the MVA mode, the liquid crystal is oriented perpendicular to the substrate, and the orientation of the liquid crystal molecules is defined by a slit provided on the transparent electrode (ITO film) and a projection provided on the opposing substrate.
  • ITO film transparent electrode
  • MVA mode LCD Although the reduction in the effective aperture ratio due to the slit projection is not as large as in the IPS mode LCD using a comb-shaped electrode, the light transmission of the MVA mode LCD is lower than that of the TN mode LCD. The rate is low. For this reason, MVA mode liquid crystal display devices have not been adopted for notebook computers that require low power consumption.
  • the banks (projections) and ITO slits are arranged in a complicated manner so that the liquid crystal molecules fall in four directions when a voltage is applied to widen the viewing angle. Rates are even lower. Simplifying these arrangements and widening the bank spacing or ITO slit gap can increase the light transmittance. However, if the gap between the banks or the ITO slit is very wide, it takes time for the tilt of the liquid crystal molecules to propagate, and the response of the device when a voltage is applied to the device for display is extremely large. become slow.
  • a liquid material containing a polymerizable monomer is injected between the substrates, and the monomer is polymerized while voltage is applied.
  • a technique was introduced to memorize the direction in which the liquid crystal molecules fall.
  • An object of the present invention is to provide a liquid crystal display device in which image sticking is effectively reduced, in particular,
  • An object of the present invention is to provide an MVA mode liquid crystal display device.
  • the liquid crystal display device provided by the present invention has two substrates provided with a transparent electrode and an alignment control film for aligning liquid crystal molecules, and a liquid crystal display comprising a liquid crystal composition between these substrates.
  • a liquid crystal composition containing a polymerizable monomer is injected between two substrates, and while applying a voltage between the transparent electrodes facing each other on the substrates, the monomer is formed.
  • a liquid crystal display device manufactured through a polymerizing step, wherein the polymerizable monomer contained in the liquid crystal composition includes one or more ring structures or condensed ring structures, and the ring structure or condensed ring structures. This is a liquid crystal display device having two directly bonded functional groups.
  • FIG. 1 is a schematic plan view illustrating the liquid crystal display devices manufactured in the comparative example and the example.
  • FIG. 2 is a cross-sectional view taken along the line II-II of FIG. BEST MODE FOR CARRYING OUT THE INVENTION
  • the so-called image sticking phenomenon in a liquid crystal display device in which the response delay at the time of voltage application is improved by memorizing the direction in which the liquid crystal molecules enclosed between the substrates fall can be reduced. This is greatly reduced by using special compounds as monomer compounds to be used in the liquid crystal display device manufacturing stage to regulate.
  • the present invention provides the following knowledge obtained as a result of various studies conducted by the inventors on various monomer compounds and liquid crystal compositions used in order to solve the problem of seizure of a liquid crystal display device. Is based on The smaller the molecular weight of the monomer contained in the liquid crystal composition, the more Is less.
  • the monomer contained in the liquid crystal composition has a ring structure or a condensed ring structure and a functional group, and the ring structure and the functional group are directly bonded, seizure is reduced.
  • a monomer having two condensed ring structures it is better to use a monomer having two condensed ring structures than a monomer having one ring structure, and to use a monomer having two non-condensed ring structures rather than a monomer having two condensed ring structures. Use reduces the seizure.
  • the use of a monomer compound having a ring structure or a condensed ring structure is necessary because the direction of ordinary liquid crystal molecules having no functional group is aligned with the molecular direction of the monomer.
  • a monomer having two ring structures is more condensed than a monomer having one ring, and a monomer having two non-condensed ring structures is more preferable than a monomer having two ring structures.
  • the ability to align ordinary liquid crystal molecules is higher, and the ratio of the functional group in the molecule is relatively reduced, and the molecule itself becomes rigid.
  • the monomer contains a bendable portion such as an alkylene group or a polymethylene group between the ring structure and the functional group, when a voltage is applied to the liquid crystal display after the polymerization, the liquid crystal molecule and the It also deforms and causes seizure.
  • the monomer compound used in the present invention is preferably selected from those represented by the following general formula (1).
  • P 1 -A 1- (Z 1 -A 2 ) n — P 2 (1)
  • P 1 and P 2 are functional groups, each of which is independently atalylate or metalacrylate , Vinyl, vinyloxy or epoxy group, A 1 and A 2 each have a ring structure and each independently represents 1,4-phenylene or naphthalene-1,2,6-diyl group; One or one OCO— group or single bond, and n is 0, 1 or 2.
  • P 1 and P 2 are preferably an acrylate group, Z 1 is preferably a single bond, and n is preferably 0 or 1.
  • Particularly preferred monomers in the present invention are compounds represented by the following formula:
  • liquid crystal display devices in the following examples a vertical alignment film was used.
  • a liquid crystal having a negative dielectric anisotropy was used, and the director of the liquid crystal molecules when no voltage was applied was set to be substantially perpendicular to the substrate.
  • the polarizing plate was normally black because it was stuck to both sides of the liquid crystal display device on the mouth snicole, and the polarizing axis of the polarizing plate was parallel to the pass line.
  • the panel size was 15 inches and the resolution was XGA.
  • FIG. 1 is a schematic plan view illustrating the manufactured liquid crystal display device
  • FIG. 2 is a cross-sectional view taken along line II-II of FIG.
  • a black matrix 34 for shading and a color separation filter are provided on one glass substrate 16.
  • a common electrode 12 of ITO is formed on one surface of the color separation filter 39.
  • the glass substrate 16 is further formed with zigzag projections 20 and auxiliary projections 20 ′.
  • the other glass substrate 17 has a plurality of parallel gate pass lines 31, a plurality of data pass lines 32 formed in parallel with the gate pass lines 31, a gate pass line 31, and a data path.
  • a thin-film transistor (TFT) 33 formed in a matrix shape corresponding to the intersection with the line 32 and a display pixel electrode 13 of ITO are provided.
  • the gate path line 31 is separated from the data path line 32 by the insulating film 51, and the source / drain electrode of the TFT 33 is formed in the same layer as the data path line 32.
  • An insulating film 52 is formed on the layer of the data bus line 32, and a pixel electrode 13 is formed thereon.
  • the pixel electrode 13 is provided with a slit 21 force S at a position parallel to the protrusion 20 in the plan view of FIG. 1 and at an intermediate position between the adjacent protrusions 20.
  • An s-electrode 35 is provided in parallel with the gate pass line 31 and at an intermediate position between the adjacent gate bus lines 31 as an auxiliary capacitor for stabilizing the potential of each pixel electrode 13. .
  • two glass substrates 16 and 17 are combined so that the common electrode 12 and the pixel electrode 13 face each other, and a liquid crystal composition (not shown) is interposed therebetween. Is held.
  • alignment control films are formed on the surfaces of the common electrode 12 and the pixel electrode 13, these are not shown in FIG. 2 for simplicity.
  • the polarizing plate attached to the outer surface of each of the glass substrates 16 and 17 is not shown in FIG. 2 for simplicity.
  • the seizure rate was determined as follows.
  • the black and white checker pattern was displayed in the display area for 48 hours. After that, a predetermined halftone (gray) is displayed over the entire display area, and white display is performed. The difference between the brightness [3 of the connected area] 3 and the brightness ⁇ of the black display area ( ⁇ ) was divided by the brightness ⁇ of the black display area to determine the image sticking rate.
  • the ratio ⁇ was calculated by the following equation.
  • Diatalylate represented by the following formula which has a trimethylene chain between the ring structure and the functional group and has a relatively large molecular weight was added between the opposing substrates of the liquid crystal display device, and then irradiated with 4 J / cm 2 of ultraviolet light at room temperature while applying a voltage of 10, V.
  • This liquid crystal display device has an image sticking rate of 25% for 48 hours, and is 7 times.
  • Diatalylate having a hexamethylene chain between the ring structure and the functional group represented by the following formula

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nonlinear Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Mathematical Physics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Liquid Crystal (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Liquid Crystal Substances (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

La présente invention concerne un afficheur à cristaux liquides produit selon les étapes suivantes: une composition de cristaux liquides contenant un monomère polymérisable est injectée dans l'espace laissé entre deux substrats, ce monomère est polymérisé tandis qu'on applique une tension entre des électrodes transparentes opposées destinées à ces substrats, le monomère polymérisable contenu dans la composition de cristaux liquides possède une ou plusieurs structures de cycle ou de cycles fusionnés et un groupe fonctionnel directement lié à chaque structure de cycle ou de cycles fusionnés. Le monomère est de préférence représenté par la formule générale suivante: P1-A1-(Z1-A2)n-P2. Dans cette formule P1 et P2 sont chacun acrylate, etc., A1 et A2 sont chacun 1,4-phénylène, etc., Z1 est COO-, etc. et n est compris entre 0 et 2.
PCT/JP2003/004791 2002-04-16 2003-04-15 Afficheur a cristaux liquides WO2003087261A1 (fr)

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EP03746491A EP1498468B1 (fr) 2002-04-16 2003-04-15 Afficheur a cristaux liquides
CN03808533XA CN1646662B (zh) 2002-04-16 2003-04-15 液晶显示装置
AU2003235166A AU2003235166A1 (en) 2002-04-16 2003-04-15 Liquid-crystal display
DE60324541T DE60324541D1 (de) 2002-04-16 2003-04-15 Flüssigkristallanzeige
KR1020047016527A KR100677804B1 (ko) 2002-04-16 2003-04-15 액정 표시 장치
US10/966,692 US7169449B2 (en) 2002-04-16 2004-10-15 Liquid crystal display device

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JP2002113972A JP4175826B2 (ja) 2002-04-16 2002-04-16 液晶表示装置
JP2002-113972 2002-04-16

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KR (1) KR100677804B1 (fr)
CN (1) CN1646662B (fr)
AU (1) AU2003235166A1 (fr)
DE (1) DE60324541D1 (fr)
TW (1) TWI321666B (fr)
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JP2024009784A (ja) 2022-07-11 2024-01-23 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング 液晶媒体
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KR20050009294A (ko) 2005-01-24
DE60324541D1 (de) 2008-12-18
US20050116200A1 (en) 2005-06-02
JP2003307720A (ja) 2003-10-31
EP1498468B1 (fr) 2008-11-05
AU2003235166A1 (en) 2003-10-27
TWI321666B (en) 2010-03-11
CN1646662A (zh) 2005-07-27
CN1646662B (zh) 2011-07-27
AU2003235166A8 (en) 2003-10-27
TW200307828A (en) 2003-12-16
KR100677804B1 (ko) 2007-02-02
EP1498468A1 (fr) 2005-01-19
EP1498468A4 (fr) 2007-03-28
US7169449B2 (en) 2007-01-30
JP4175826B2 (ja) 2008-11-05

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