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WO2003066017A1 - Preparations de lavage contenant des huiles vegetales - Google Patents

Preparations de lavage contenant des huiles vegetales Download PDF

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Publication number
WO2003066017A1
WO2003066017A1 PCT/EP2003/000908 EP0300908W WO03066017A1 WO 2003066017 A1 WO2003066017 A1 WO 2003066017A1 EP 0300908 W EP0300908 W EP 0300908W WO 03066017 A1 WO03066017 A1 WO 03066017A1
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Prior art keywords
oil
weight
acid
washing preparations
alkyl
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PCT/EP2003/000908
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German (de)
English (en)
Inventor
Werner Seipel
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Cognis Deutschland Gmbh & Co. Kg
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Publication of WO2003066017A1 publication Critical patent/WO2003066017A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic

Definitions

  • the invention relates to cosmetic preparations containing vegetable oils from the field of washing products which contain selected surfactant mixtures, and to the use of the special surfactant mixtures for producing stable washing products containing vegetable oils.
  • European patent EP 0 744 936 B1 discloses skin and hair treatment compositions with alkylpolyglycosides, a polymer and a vegetable oil, which, particularly in the form of hair aftertreatment compositions, are intended to enable a combined use of various active ingredients which improve wet and dry combability and are effective against split ends and for a better one Color distribution of hair dyes lead. Up to 5% by weight of vegetable oils are processed in these formulations.
  • Wax-containing shampoos with small amounts of vegetable oils are also described in EP 0 505 616 AI.
  • the object of the present invention was to provide washing preparations with large amounts of vegetable oils which have good physical and chemical stability.
  • the preparations should be well tolerated, have a good washing effect, protect the skin and scalp from drying out and leave a pleasant feeling on the skin after use.
  • the invention relates to detergent-containing washing preparations containing at least 25% by weight of vegetable oils.
  • Another object of the invention is the use of surfactant mixtures containing alkyl and / or alkenyl oligoglycosides, amphoteric surfactants and optionally
  • the stable incorporation of large quantities of vegetable oil effectively reduces the drying out of the skin and scalp even with frequent washing and retains the moisture in the skin.
  • the washing preparations are characterized by good lipid-replenishing and moisturizing properties. Surprisingly, it was found that the preparations according to the invention have an excellent washing performance despite the high oil content, leave a pleasant feeling on the skin without a noticeable lubricating film and have good physical and chemical stability.
  • the combination of non-ionic and amphoteric surfactants enables physico-chemically stable incorporation of large quantities of vegetable oils. If cationic polymers are added to washing products for hair cosmetics, the conditioning effect, combability and manageability of the hair are improved even more sustainably.
  • Non-ionic, anionic, cationic and / or amphoteric or zwitterionic surfactants can be present as surface-active substances, the proportion of which in the detergents is usually about 10 to 90% by weight, preferably 20 to 70 and preferably 30 is up to 50% by weight.
  • anionic surfactants are soaps, alkyl benzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates,
  • Glycerol ether ⁇ -methyl ester sulfonates, sulfofatty acids, alkyl sulfates, fatty alcohol ether sulfates, Glycerol ether, Fettklareethersulfate, Hydroxymischethersul- sulfates, monoglyceride (ether) sulfates, fatty acid amide (ether) sulfates, mono- and dialkyl sulfosuccinates, mono- and dialkyl sulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts, fatty acid isethionates, fatty acid sarcosinates, fatty acid retaurides, N-acylamino acids, such as, for example, acyl lactylates, acyl tartrates, acyl glutamates and acyl aspartates, alkyl oligoglucoside sulfates
  • anionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • Typical examples of nonionic surfactants are fatty alcohol polyglycol ethers, alkyl phenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, mixed ethers or mixed formals, optionally partially oxidized alk (en) yl oligoglycosides or alkyl glucoramide acid derivatives, in particular glucoronic acid protein derivatives, and glucoronic acid protein derivatives Wheat base), polyol fatty acid esters, sugar esters, sorbitan esters, polysorbates and amine oxides.
  • nonionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • Typical examples of cationic surfactants are quaternary ammonium compounds and ester quats, in particular quaternized fatty acid trialkanolamine ester salts.
  • the vegetable oils used are - in contrast to volatile essential oils - fatty oils with a high proportion of di- and triglycerides.
  • Almond oil walnut oil, peach seed oil, avocado oil, soybean oil, sesame oil, sunflower seed oil,
  • Tsubaki oil evening primrose oil, rice bran oil, palm kernel oil, mangokem oil, cuckoo flower oil,
  • Safflower oil macadamia nut oil, grape seed oil, apricot kernel oil, babassu oil, olive oil,
  • Sasanqua oil, calendula oil, passion flower oil, Shorea Stenoptera butter and Shea butter are considered as vegetable oils.
  • Soybean oil almond oil, jojoba oil, olive oil, sunflower seed oil, sesame oil, evening primrose oil,
  • Thistle oil and wheat germ oil are preferred among them.
  • Soybean oil is particularly preferred.
  • At least 25% by weight, preferably at least 35% by weight and particularly preferably even at least 45% by weight of vegetable oils, based on the washing preparations, are used in the surfactant-containing washing preparations according to the invention.
  • Alkyl and alkenyl oligoglycosides are known nonionic surfactants which follow the formula (I)
  • R 1 is an alkyl and / or alkenyl radical having 4 to 22 carbon atoms
  • G is a sugar radical having 5 or 6 carbon atoms
  • p is a number from 1 to 10.
  • the alkyl and / or alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably glucose.
  • the preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides.
  • the index number p in the general formula (I) indicates the degree of oligomerization (DP), ie the distribution of mono- and oligoglycosides, and stands for a number between 1 and 10.
  • Alkyl and / or alkenyl oligoglycosides with an average degree of oligomerization p of 1.1 to 3.0 are preferably used. From an application point of view, preference is given to those alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.4.
  • the alkyl or alkenyl radical R 1 can be derived from primary alcohols having 4 to 11, preferably 8 to 10, carbon atoms. Typical examples are butanol, capronic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and their technical mixtures, such as are obtained, for example, in the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelen's oxosynthesis.
  • the alkyl or alkenyl radical R 1 can also be derived from primary alcohols having 12 to 22, preferably 12 to 14, carbon atoms.
  • Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol and the technical mixtures described above, which can be obtained as well as their technical mixtures.
  • Alkyl oligoglucosides based on hardened C 2 -C 4 coco alcohol with a DP of 1 to 3 are preferred.
  • the alkyl oligoglucosides are used in amounts of 0.5 to 20% by weight, preferably 2.5 to 15 and particularly preferably 5 to 10% by weight, based on the washing preparation.
  • amphoteric - also listed under “zwitterionic surfactants” - are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines.
  • the surfactants mentioned are exclusively known compounds .Falbe (ed.), "Surfactants in Consumer Products", Springer Verlag, Berlin, 1987, pp. 54-124 or J.Falbe (ed.), "Catalysts, surfactants and mineral oil additives", Thieme Verlag, Stuttgart, 1978, Pp. 123-217.
  • Betaines are known surfactants which are predominantly produced by carboxyalkylation, preferably carboxymethylation, of aminic compounds.
  • the starting materials are preferably condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, one mol of salt being formed per mole of betaine.
  • unsaturated carboxylic acids such as acrylic acid, is also possible.
  • betaines and "real" amphoteric surfactants reference is made to U.PIoog's contribution in Seifen- ⁇ le-Fette-Wwachs, 108, 373 (1982). Further overviews on this topic can be found for example by A. O'Lennick et al. in HAPPI, Nov.
  • betaines are the carboxyalkylation products of secondary and in particular tertiary amines which follow the formula (II) R 3
  • R 2 for alkyl and / or alkenyl radicals with 6 to 22 carbon atoms
  • R 3 for hydrogen or alkyl radicals with 1 to 4 carbon atoms
  • R 4 for alkyl radicals with 1 to 4 carbon atoms
  • n for numbers from 1 to 6
  • X for a Alkali and / or alkaline earth metal or ammonium.
  • Typical examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, De-cyldimethylamin, dodecylmethylamine, dodecyldimethylamine, Dodecylethylmethylamin, C i2 / ⁇ kyldimethylamin 4 -Kokosal-, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, Stearylethylmethyl-amine, oleyl dimethyl amine, C ⁇ 6 / i 8 - Tallow alkyl dimethylamine and their technical mixtures.
  • R 5 CO represents an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds
  • m represents numbers from 1 to 3 and R 3 , R 4 , n and X have the meanings given above.
  • Typical examples are reaction products of fatty acids with 6 to 22 carbon atoms, namely caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, araachearic acid , Gadoleic acid, behenic acid and erucic acid as well as their technical mixtures with N, N-dimethylaminoethylamine, N, N-dimethylaminopropylamine, N, N-diethylaminoethylamine and N, N-diethy
  • suitable starting materials for the betaines to be used in accordance with the invention are also imidazolines which follow the formula (IV) (IV)
  • R 6 is an alkyl radical having 5 to 21 carbon atoms
  • R 7 is a hydroxyl group
  • an OCOR 6 or NHCOR 7 radical and m is 2 or 3.
  • These substances are also known substances which can be obtained, for example, by the condensing condensation of 1 or 2 moles of fatty acid with polyhydric amines, such as, for example, aminoethylethanolamine (AEEA) or diethylenetriamine.
  • AEEA aminoethylethanolamine
  • diethylenetriamine diethylenetriamine
  • Typical examples are condensation products of the above-mentioned fatty acids with AEEA, preferably imidazolines based on lauric acid or again C 2 -C 4 coconut fatty acid, which are subsequently betainized with sodium chloroacetate.
  • the preferred amphoteric surfactants for the purposes of the present invention are betaines of the cocamidopropyl betaine type and sodium cocoamphoacetate.
  • the amphoteric surfactants are used in amounts of 0.5 to 30% by weight, preferably 2.5 to 20% by weight and particularly preferably 9 to 19% by weight, based on the washing preparations.
  • Suitable cationic polymers are, for example, cationic cellulose derivatives, such as, for example, a quaternized hydroxyethyl cellulose, which is available under the name Polymer JR 400® from Amerchol, cationic starch, copolymers of diallylammonium salts and acrylamides, quaternized vinyl-pyrrolidone / vinyl-imidazole polymers, such as, for example, luviquat ® (BASF), condensation products of polyglycols and amines, quaternized collagen polypeptides, such as, for example, lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat®L / Grünau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers, such as, for example, amidomethicones, copolymers of adipodinoxypropylene acid and dimethylaminohydroxyethylenediaminetroxyne diaminohydroxyethylene
  • copolymers of acrylic acid with dimethyldiallyl ammonium chloride (Merquat® 550 / Chemviron), polyaminopolyamides, as described for example in FR-A 2252840, and their crosslinked water-soluble polymers, cationic chitin derivatives, such as quaternized chit osan, optionally microcrystalline, condensation products from dihaloalkylene, such as dibromobutane with bisdialkylamines, such as bis-dimethylamino-1,3- propane, cationic guar gum, such as Jaguar® CBS, Jaguar® C-17, Jaguar® C-16 from Celanese, quaternized ammonium salt polymers, such as Mirapol® A-15, Mirapol® AD-1, Mirapol® AZ -1 from Miranol.
  • dihaloalkylene such as dibromobutane
  • bisdialkylamines such as bis-dimethylamino-1,3- propane
  • Cation polymers are used in the agents according to the invention in amounts of 0.02 to 5% by weight, preferably 0.05 to 3% by weight and particularly preferably in amounts of 0.1 to 2% by weight.
  • the average molecular weights of the cationic polymers should be between 5,000 and 1,000,000, preferably between 8,000 and 500,000 and particularly preferably between 10,000 and 400,000.
  • Cationic guar gum and / or quaternized ammonium salt polymers are particularly preferred as cation polymers.
  • Cation polymers are used in the washing preparations according to the invention in amounts of 0.1 to 5% by weight, preferably 0.5 to 4% by weight and particularly preferably 1 to 3% by weight, based on the washing preparations.
  • Predispersed wax dispersions can be used in the washing preparations in amounts of 0 to 5% by weight, preferably 0.005 to 3.5% by weight and particularly preferably in amounts of 0.01 to 3.1% by weight.
  • the proportion of the wax bodies contained in the wax dispersions is 10 to 40% by weight, preferably 15 to 35% by weight and particularly preferably 20 to 30% by weight, based on the predispersed wax dispersion.
  • Possible wax bodies in the wax dispersions are: alkylene glycol esters, fatty acid alkanolamides, partial glycerides, esters of polyvalent, optionally hydroxy-substituted carboxylic acids, fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers, fatty carbonates, ring-opening products of olefin epoxides and mixtures thereof.
  • alkylene glycol esters which form the preferred wax bodies are usually mono- and / or diesters of alkylene glycols which follow the formula (V)
  • R 8 CO is a linear or branched, saturated or unsaturated acyl radical having 6 to 22 carbon atoms
  • R 9 is hydrogen or R 8 CO
  • A is a linear or branched alkylene radical having 2 to 4 carbon atoms and n is a number from 1 to 5 stands.
  • Typical examples are mono- and / or diesters of ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, triethylene glycol or tetraethylene glycol with fatty acids with 6 to 22, preferably 12 to 18 carbon atoms as there are: caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, linolenic acid Elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures.
  • the use of ethylene glycol mono- and / or distearate is particularly preferred.
  • the water content of the formulations must be relatively low. Good physico-chemical stability of the washing preparations was achieved when the pure water content was at most 55% by weight, preferably at most 45% by weight and particularly preferably at most 35% by weight, based on the washing preparation.
  • the vegetable oil-containing washing preparations according to the invention are predominantly, but not exclusively, used in the field of cosmetic products.
  • washing preparations according to the invention preferably contain
  • the preparations according to the invention can serve as cosmetic and / or pharmaceutical preparations, such as, for example, hair shampoos, solid bars of soap, washing lotions, bubble baths, shower baths and preferably oil baths.
  • auxiliaries and additives they can also contain emulsifiers, further oil bodies, pearlescent waxes, consistency agents, superfatting agents, stabilizers, further polymers, silicone compounds, lecithins, phospholipids, biogenic active substances, antioxidants, antidandruff agents, film formers, hydrotropes, solubilizers, preservatives, perfume oils, dyes and dyes the like included.
  • suitable emulsifiers are, for example, nonionic substances from at least one of the following groups:
  • Partial esters of polyglycerin (average degree of self-condensation 2 to 8), polyethylene glycol (molecular weight 400 to 5000), trimethylolpropane, pentaerythritol, sugar alcohols (e.g. sorbitol), alkyl glucosides (e.g. methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides saturated (e.g. cellulose) unsaturated, linear or branched fatty acids with 12 to 22 carbon atoms and / or hydroxycarboxylic acids with 3 to 18 carbon atoms and their adducts with 1 to 30 moles of ethylene oxide;
  • Block copolymers e.g. Polyethylene glycol 30 dipolyhydroxystearate;
  • the adducts of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols or with castor oil are known, commercially available products. These are mixtures of homologs whose average degree of alkoxylation is the ratio of the amounts of ethylene oxide and / or propylene oxide and Substrate with which the addition reaction is carried out corresponds.
  • C 12 ⁇ 8 - fatty acid monoesters and diesters of adducts of ethylene oxide with glycerol are known from DE 2024051 PS as refatting agents for cosmetic preparations.
  • Suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride,
  • Addition products of 1 to 30, preferably 5 to 10, mol of ethylene oxide onto the partial glycerides mentioned are also suitable.
  • sorbitan sorbitan As sorbitan sorbitan, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan dioleate, trioleate, Sorbitanmonoerucat, Sorbitansesquierucat, Sorbitandierucat, Sorbitantrierucat, Sorbitanmonoricinoleat, Sorbitansesquiricinoleat, Sorbitandiricinoleat, Sorbitantriricinoleat, Sorbitanmonohydroxystearat, sorbitan come sesquihydroxystearat, Sorbitandihydroxystearat, Sorbitantrihydroxystearat,
  • Addition products of 1 to 30, preferably 5 to 10, mol of ethylene oxide onto the sorbitan esters mentioned are also suitable. > Polyglycerol esters
  • polyglycerol esters are polyglyceryl-2 dipolyhydroxystearate (Dehymuls® PGPH), polyglycerol-3-diisostearate (Lameform® TGI), polyglyceryl-4 isostearate (Isolan® GI 34), polyglyceryl-3 oleate, diisostearoyl polyglyearyl-3 diisostearate ® PDI), Polyglyceryl-3 Methylglucose Distearate (Tego Care® 450), Polyglyceryl-3 Beeswax (Cera Bellina®), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010 / 90), Polyglyceryl-3 Cetyl Ether (Chimexane® NL), Polyglyceryl -3 Distearate (Cremophor® GS 32) and Polyglyceryl Polyricinoleate (Admul® WOL 1403) Polyglyceryl Dimerate Is
  • polystyrene resin examples include the mono-, di- and triesters of trimethylolpropane or pentaerythritol with lauric acid, coconut fatty acid, taig fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like which are optionally reacted with 1 to 30 mol of ethylene oxide.
  • Typical anionic emulsifiers are aliphatic fatty acids with 12 to 22 carbon atoms, such as, for example, palmitic acid, stearic acid or behenic acid, and dicarboxylic acids with 12 to 22 carbon atoms, such as, for example, azelaic acid or sebacic acid.
  • Washing preparations also use smaller amounts of other oil bodies, such as Guerbet alcohols based on fatty alcohols having 6 to 18, preferably 8 to 10 carbon atoms, esters of linear C 6 -C 22 fatty acids with linear or branched C 6 -C 22 fatty alcohols or Esters of branched C 6 -C 3 carboxylic acids with linear or branched C 6 -C 22 fatty alcohols, such as myristyl myristate, myristyl palmitate,
  • other oil bodies such as Guerbet alcohols based on fatty alcohols having 6 to 18, preferably 8 to 10 carbon atoms, esters of linear C 6 -C 22 fatty acids with linear or branched C 6 -C 22 fatty alcohols or Esters of branched C 6 -C 3 carboxylic acids with linear or branched C 6 -C 22 fatty alcohols, such as myristyl myristate, myristyl palmitate,
  • esters of linear C 6 -C 22 fatty acids with branched alcohols in particular 2-ethylhexanol
  • esters of C 8 -C 38 alkylhydroxycarboxylic acids with linear or branched C 6 -C 22 fatty alcohols cf.
  • dioctyl malates esters of linear and / or branched fatty acids with polyhydric alcohols (such as propylene glycol, dimer diol or trimer triol) and / or Guerbet alcohols, triglycerides based on C 6 -C0 0 fatty acids, liquid mono7 di / triglyceride mixtures based on C 6 -C 8 fatty acids, esters of C 6 -C 22 fatty alcohols and / or Guerbet alcohols with aromatic carboxylic acids, in particular benzoic acid, esters of C 2 -C 2 dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms or polyols 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, branched primary alcohols, substituted cyclohexanes, linear and branched C 6 -C 22 fatty alcohol carbonates, such as, for example, dicaprylyl car bonate (C
  • Finsolv® TN linear or branched , symmetrical or asymmetrical dialkyl ethers with 6 to 22 carbon atoms per alkyl group, such as dicaprylyl ether (Cetiol® OE), ring opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclomethicones, silicon methicone types etc.) and / or aliphatic or naphthenic hydrocarbons, such as squalane , Squalene or dialkylcyclohexanes.
  • dicaprylyl ether such as dicaprylyl ether (Cetiol® OE)
  • silicone oils cyclomethicones, silicon methicone types etc.
  • aliphatic or naphthenic hydrocarbons such as squalane , Squalene or dialkylcyclohexanes.
  • Pearlescent waxes that can be used are, for example: alkylene glycol esters, especially ethylene glycol distearate; Fatty acid alkanolamides, especially coconut fatty acid diethanolamide; Partial glycerides, especially stearic acid monoglyceride; Esters of polyvalent, optionally hydroxy-substituted carboxylic acids with fatty alcohols having 6 to 22 carbon atoms, especially long-chain esters of tartaric acid; Fatty substances, such as, for example, fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, which have a total of at least 24 carbon atoms, especially lauron and distearyl ether; Fatty acids such as stearic acid, hydroxystearic acid or behenic acid, ring opening products of olefin epoxides with 12 to 22 carbon atoms with fatty alcohols. Consistency agents and thickeners
  • Suitable consistency agents are primarily fatty alcohols or hydroxy fatty alcohols with 12 to 22 and preferably 16 to 18 carbon atoms and, in addition, partial glycerides, fatty acids or hydroxy fatty acids.
  • a combination of these substances with alkyl oligoglucosides and / or fatty acid N-methylglucamides of the same chain length and / or polyglycerol poly-12-hydroxystearates is preferred.
  • Suitable thickeners are, for example, Aerosil types (hydrophilic silicas), polysaccharides, in particular xanthan gum, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl and hydroxypropyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates (e.g. Carbopole® and Pemulen types from Goodrich; Synthalene® from Sigma; Keltrol types from Kelco; Sepigel types from Seppic; Salcare types from Allied Colloids), polyacrylamides, polymers, polyvinyl alcohol and polyvinylpyrrolidone. Bentonites, such as e.g.
  • Bentone® Gel VS-5PC which is a mixture of cyclopentasiloxane, disteardimonium hectorite and propylene carbonate.
  • Surfactants such as ethoxylated fatty acid glycerides, esters of fatty acids with polyols such as pentaerythritol or trimethylolpropane, fatty alcohol ethoxylates with a narrow homolog distribution or alkyl oligoglucosides as well as electrolytes such as table salt and ammonium chloride are also suitable.
  • Substances such as, for example, lanolin and lecithin and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides can be used as superfatting agents, the latter simultaneously serving as foam stabilizers.
  • Metal salts of fatty acids such as magnesium, aluminum and / or zinc stearate or ricinoleate can be used as stabilizers.
  • the preferred polymers are the cation polymers already described. However, other polymers can also be used.
  • Anionic, zwitterionic, amphoteric and nonionic polymers are, for example, vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate copolymers,
  • Hydroxypropyl methacrylate copolymers polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / dimethylaminoethyl methacrylate / vinylcaprolactam terpolymers and, if appropriate, derivatized cellulose ethers and silicones.
  • Other suitable polymers and thickeners are in Cosm.Toil. 108, 95 (1993).
  • Suitable silicone compounds are, for example, dimethylpolysiloxanes, methylphenylpolysiloxanes, cyclic silicones and amino, fatty acid, alcohol, polyether, epoxy, fluorine, glycoside and / or alkyl-modified silicone compounds, which can be both liquid and resinous at room temperature.
  • Simethicones which are mixtures of dimethicones with an average chain length of 200 to 300 dimethylsiloxane units and hydrogenated silicates, are also suitable.
  • a detailed overview of suitable volatile silicones can also be found by Todd et al. in Cosm.Toil. 91, 27 (1976).
  • biogenic active substances include tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, (deoxy) ribonucleic acid and its fragmentation products, ß-glucans, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudocleamides, extracts of essential oils, essential extracts such as Prunus extract, Bambaranus extract and vitamin complexes. film formers
  • Common film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid or its salts and similar compounds.
  • Piroctone olamine (1-hydroxy-4-methyl-6- (2,4,4-trimythylpentyl) -2- (1H) -pyridinone monoethanolamine salt
  • Baypival® (climbazole), Ketoconazol®, (4-acetyl-l - ⁇ - 4- [2- (2.4-dichlorophenyl) r-2- (lH-imidazol-l-ylmethyl) -l, 3-dioxylan-c-4-ylmethoxyphenyl ⁇ piperazine, ketoconazole, elubiol, selenium disulfide, sulfur colloidal, Schwefelpolyehtylenglykolsorbitanmonooleat, Schwefelrizinolpolyehtoxylat, Schwfel tar distillate, salicylic acid (or in combination with hexachlorophene), Undexy- lensäure monoethanolamide sulfosuccinate Na salt, Lamepon® UD (protein unde
  • Hydrotropes such as ethanol, isopropyl alcohol or polyols can also be used to improve the flow behavior.
  • Polyols that come into consideration here preferably have 2 to 15 carbon atoms and at least two hydroxyl groups.
  • the polyols can also contain further functional groups, in particular amino groups, or be modified with nitrogen. Typical examples are
  • Alkylene glycols such as ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1,000 daltons;
  • Methyl compounds such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;
  • Dialcohol amines such as diethanolamine or 2-amino-l, 3-propanediol.
  • Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid, as well as the silver complexes known under the name Surfacine® and the other classes of substances listed in Appendix 6, Parts A and B of the Cosmetics Ordinance.
  • Perfume oils include mixtures of natural and synthetic fragrances. Natural fragrances are extracts of flowers (lily, lavender, roses, jasmine, neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, caraway, juniper), fruit peel (bergamot, lemon, Oranges), roots (mace, angelica, celery, cardamom, costus, iris, calmus), wood (pine, sandal, guaiac, cedar, rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme), Needles and twigs (spruce, fir, pine, mountain pine), resins and balms (galbanum, elemi, benzoin, myrrh, olibanum, opoponax).
  • Typical synthetic fragrance compounds are products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type. Fragrance compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate, phenylethyl acetate, linalyl benzoate, benzyl formate, ethyl methylphenyl glycinate, allyl cyclohexyl benzylatepylpropionate, stally.
  • the ethers include, for example, benzyl ethyl ether, the aldehydes, for example, the linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, lilial and bourgeonal, the ketones, for example, the jonones, ⁇ -isomethylionone and methylcedryl ketone, the alcohols Anethol, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol, the hydrocarbons mainly include the terpenes and balsams.
  • the aldehydes for example, the linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamenalde
  • fragrance oils which together produce an appealing fragrance.
  • essential oils of lower volatility most of the time are used as aroma components, are suitable as perfume oils, for example sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil, vetiver oil, oliban oil, galbanum oil, labolanum oil and lavandin oil.
  • Suitable flavors are, for example, peppermint oil, spearmint oil, anise oil, star anise oil, caraway oil, eucalyptus oil, fennel oil, lemon oil, wintergreen oil, clove oil, menthol and the like.
  • the dyes which can be used are those substances which are suitable and approved for cosmetic purposes, as compiled, for example, in the publication "Cosmetic Dyes” by the Dye Commission of the German Research Foundation, Verlag Chemie, Weinheim, 1984, pp. 81-106. Examples are culinary red A (CI 16255), patent blue V (CI42051), indigotine (CI73015), chlorophyllin (CI75810), quinoline yellow (CI47005), titanium dioxide (CI77891), indanthrene blue RS (CI 69800) and madder varnish (CI58000). Luminol may also be present as the luminescent dye. These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
  • the production takes place at room temperature. All substances are mixed together homogeneously.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
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Abstract

L'invention concerne des préparations de lavage contenant des tensioactifs et au moins 25 % en poids d'une huile végétale, ainsi que l'utilisation de mélanges contenant des oligoglucosides alkyle et/ou alcényle, des tensioactifs amphotères et éventuellement des polymères cationiques pour réaliser des préparations de lavage contenant au moins 25 % en poids d'huiles végétales. Ces préparations de lavage se caractérisent par leur aptitude à enrichir et humidifier la peau, par une grande stabilité physico-chimique et par le fait qu'elles confèrent à la peau une sensation de bien-être après utilisation.
PCT/EP2003/000908 2002-02-08 2003-01-30 Preparations de lavage contenant des huiles vegetales WO2003066017A1 (fr)

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DE2002105296 DE10205296A1 (de) 2002-02-08 2002-02-08 Waschzubereitungen mit Pflanzenölen

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009071945A2 (fr) * 2007-12-03 2009-06-11 Neal's Yard (Natural Remedies) Ltd Préparation de savon pour la peau et les cheveux
FR2956975A1 (fr) * 2010-03-03 2011-09-09 Rhodia Operations Nouvel agent pour ameliorer le depot d'huile sur les cheveux
WO2017194339A1 (fr) 2016-05-10 2017-11-16 Basf Se Microémulsions concentrées comprenant des tensioactifs amphotères

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EP0502616A1 (fr) * 1991-02-14 1992-09-09 Unilever Plc Compositions cosmétique
EP0507047A2 (fr) * 1991-03-30 1992-10-07 Hüls Aktiengesellschaft Emulsifiants pour la préparation d'emulsions d'huiles étherées du type huile dans l'eau d'utilisables en cosmétique ou en médicine
JPH06157285A (ja) * 1992-11-27 1994-06-03 Sanwa Kagaku Kenkyusho Co Ltd 植物油配合白濁入浴剤
WO1995022312A1 (fr) * 1994-02-18 1995-08-24 Henkel Kommanditgesellschaft Auf Aktien Produits de soins capillaires
WO1995034282A1 (fr) * 1994-06-13 1995-12-21 Institut Français Du Petrole Utilisation des sophorolipides et compositions cosmetiques et dermatologiques
WO1997009028A1 (fr) * 1995-09-09 1997-03-13 Wella Aktiengesellschaft Preparation pour les soins et le conditionnement des cheveux et utilisation de ladite preparation
JPH1135421A (ja) * 1997-07-17 1999-02-09 Shiseido Co Ltd 液状油性皮膚洗浄料
JPH11116462A (ja) * 1997-10-09 1999-04-27 Inabata Koryo Kk 自己乳化型液体入浴剤組成物
US6162834A (en) * 1995-04-25 2000-12-19 L'oreal Foaming oil-in-water emulsion based on nonionic surfactants, a fatty phase and a crosslinked cationic or anionic polymer, and its use in topical applications

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Publication number Priority date Publication date Assignee Title
EP0502616A1 (fr) * 1991-02-14 1992-09-09 Unilever Plc Compositions cosmétique
EP0507047A2 (fr) * 1991-03-30 1992-10-07 Hüls Aktiengesellschaft Emulsifiants pour la préparation d'emulsions d'huiles étherées du type huile dans l'eau d'utilisables en cosmétique ou en médicine
JPH06157285A (ja) * 1992-11-27 1994-06-03 Sanwa Kagaku Kenkyusho Co Ltd 植物油配合白濁入浴剤
WO1995022312A1 (fr) * 1994-02-18 1995-08-24 Henkel Kommanditgesellschaft Auf Aktien Produits de soins capillaires
EP0744936B1 (fr) * 1994-02-18 2001-06-06 Henkel Kommanditgesellschaft auf Aktien Produits de soins capillaires
WO1995034282A1 (fr) * 1994-06-13 1995-12-21 Institut Français Du Petrole Utilisation des sophorolipides et compositions cosmetiques et dermatologiques
US6162834A (en) * 1995-04-25 2000-12-19 L'oreal Foaming oil-in-water emulsion based on nonionic surfactants, a fatty phase and a crosslinked cationic or anionic polymer, and its use in topical applications
WO1997009028A1 (fr) * 1995-09-09 1997-03-13 Wella Aktiengesellschaft Preparation pour les soins et le conditionnement des cheveux et utilisation de ladite preparation
JPH1135421A (ja) * 1997-07-17 1999-02-09 Shiseido Co Ltd 液状油性皮膚洗浄料
JPH11116462A (ja) * 1997-10-09 1999-04-27 Inabata Koryo Kk 自己乳化型液体入浴剤組成物

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PATENT ABSTRACTS OF JAPAN vol. 1999, no. 05 31 May 1999 (1999-05-31) *
PATENT ABSTRACTS OF JAPAN vol. 1999, no. 09 30 July 1999 (1999-07-30) *

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009071945A2 (fr) * 2007-12-03 2009-06-11 Neal's Yard (Natural Remedies) Ltd Préparation de savon pour la peau et les cheveux
WO2009071945A3 (fr) * 2007-12-03 2009-07-23 Neal S Yard Natural Remedies L Préparation de savon pour la peau et les cheveux
GB2455294B (en) * 2007-12-03 2011-12-21 Neal S Yard Natural Remedies Ltd Skin and hair wash preparation
FR2956975A1 (fr) * 2010-03-03 2011-09-09 Rhodia Operations Nouvel agent pour ameliorer le depot d'huile sur les cheveux
WO2011107713A2 (fr) * 2010-03-03 2011-09-09 Rhodia Operations Nouvel agent pour améliorer le dépôt d'huile sur les cheveux
WO2011107713A3 (fr) * 2010-03-03 2012-10-26 Rhodia Operations Nouvel agent pour améliorer le dépôt d'huile sur les cheveux
CN102821745A (zh) * 2010-03-03 2012-12-12 罗地亚管理公司 改善油在头发上的沉积的新试剂
WO2017194339A1 (fr) 2016-05-10 2017-11-16 Basf Se Microémulsions concentrées comprenant des tensioactifs amphotères
CN109069355A (zh) * 2016-05-10 2018-12-21 巴斯夫欧洲公司 具有两性表面活性剂的微乳液浓缩物
US20190083365A1 (en) * 2016-05-10 2019-03-21 Basf Se Micro-emulsion concentrates with amphoteric surfactants
JP2019514989A (ja) * 2016-05-10 2019-06-06 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 両性界面活性剤を有するマイクロエマルション濃縮物

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