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WO2003059067A1 - Melanges fongicides a base de derives d'ether d'oxime et de derives de guanidine - Google Patents

Melanges fongicides a base de derives d'ether d'oxime et de derives de guanidine Download PDF

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Publication number
WO2003059067A1
WO2003059067A1 PCT/EP2003/000012 EP0300012W WO03059067A1 WO 2003059067 A1 WO2003059067 A1 WO 2003059067A1 EP 0300012 W EP0300012 W EP 0300012W WO 03059067 A1 WO03059067 A1 WO 03059067A1
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WO
WIPO (PCT)
Prior art keywords
compound
weight
plants
mixtures
parts
Prior art date
Application number
PCT/EP2003/000012
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German (de)
English (en)
Inventor
Thomas Grote
Eberhard Ammermann
Reinhard Stierl
Gisela Lorenz
Gerd Stammler
Klaus Schelberger
Egon Haden
Original Assignee
Basf Aktiengesellschaft
Sumitomo Chemical Takeda Agro Company, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Aktiengesellschaft, Sumitomo Chemical Takeda Agro Company, Ltd. filed Critical Basf Aktiengesellschaft
Priority to KR1020047011059A priority Critical patent/KR100955966B1/ko
Priority to JP2003559243A priority patent/JP4463558B2/ja
Priority to AU2003205564A priority patent/AU2003205564A1/en
Publication of WO2003059067A1 publication Critical patent/WO2003059067A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3

Definitions

  • the present invention relates to mixtures for controlling harmful fungi and insects, which are active components
  • R 1 , R 3 independently of one another hydrogen, cyano, C 1 -C 4 -alkyl, cyclopropyl or C 1 -C 4 -haloalkyl;
  • R 2 , R 4 independently of one another hydrogen, Ci-C ⁇ alkyl, C 3 -C 6 alkenyl, Ca-C ß alkynyl, -C-C 4 haloalkyl, C ß -Cg haloalkenyl or C 3 -C 6 haloalkynyl;
  • the object of the present invention was to provide mixtures which, on the one hand, have a good fungicidal action, in particular against fungus diseases in rice, and at the same time have a good insecticidal action (synergistic mixtures) when the total amount of active compounds applied is reduced. Since pests are usually found in large numbers in the climatic regions in which rice is grown, a combination of fungicidal and insecticidal activity is desirable.
  • This object is achieved according to the invention by the mixtures according to claim 1.
  • compound II which itself is not fungicidally active, enhances the fungicidal activity of the oxime ether derivatives of the formula I. Compound II thus acts as an adjuvant.
  • the insecticide of formula II is also known (common name: clothianidin) and described in the literature (EP-A 376 279).
  • R 1 and R 3 represent hydrogen, cyano, cyclopropyl, methyl, ethyl, 1-methylethyl or CF 3 .
  • R 1 and R 3 are C 1 -C 4 -alkyl.
  • R 1 is CF 3 .
  • R 2 and R 4 represent hydrogen, cyclopropyl, methyl, ethyl, isopropyl.
  • R 4 represents ethyl or isopropyl.
  • Oxime ether derivatives of the formula I in which X represents NH are particularly preferred.
  • the compounds I contained in the mixtures according to the invention are distinguished by an excellent action against a broad spectrum of phytopathogenic fungi, in particular against fungi from the classes of the Ascomycetes, Deuteromycetes, Phycomycetes and Basidiomycetes. They are particularly important for combating a large number of fungi on various crops such as cotton, vegetables (eg cucumbers, beans, tomatoes, potatoes and squashes), barley, grass, oats, bananas, coffee, corn, fruit plants, rice, rye , Soy, wine, wheat, ornamental plants, sugar cane and a variety of seeds.
  • vegetables eg cucumbers, beans, tomatoes, potatoes and squashes
  • barley grass, oats, bananas, coffee, corn, fruit plants, rice, rye , Soy, wine, wheat, ornamental plants, sugar cane and a variety of seeds.
  • Botrytis cinera (gray mold) on strawberries, vegetables, ornamental plants and vines, Cercospora arachidicola on peanuts, Pseudo-cercosporella herpotrichoides on wheat and barley, Pyricularia oryzae on rice and lawn, Phytophthora infestans on potatoes and tomatoes, Plasmopara viticola on vines, pseudoperon - in hops and cucumbers, Alternaria species in vegetables and fruits, Mycosphaerella species in bananas and Fusarium and Verticillium species.
  • the compound of formula II is used to control animal pests from the class of the insects, arachnids and nematodes. It can be used in crop protection as well as in the hygiene, storage protection and veterinary sectors to control animal pests. It is particularly suitable for controlling the following animal pests:
  • Beetles (Coleoptera), e.g. Agrilus sinuatus, Agriotes lineatus, Agriotes obscurus, Amphimallus solstitialis, Anisandrus dispar, Anthonomus grandis, Anthonomus pomoru, Atomaria linearis, Blastophagus piniperda, Blitophaga undata, Bruchus rufimanus, Bruechus pisorum, Bruchus lentisu- losa, Byisc , Cerotoma trifurcata, Ceuthorrhynchus assimilis, Ceuthorr- hynchus napi, Chaetocnema tibialis, Conoderus vespertinus, Crioceris asparagi, Diabrotica longicornis, Diabrotica 12-punc- tata, Diabrotica virgiferisisobirisisinutinis, thilobisinisis, epilachinisis, epilachnis
  • Two-winged e.g. Aedes aegypti, Aedes vexans, Anas- trepha ludens, Anopheles maculipennis, Ceratitis capitata, Chrysomya bezziana, Chrysomya hominivorax, Chrysomya macella- ria, Contarinia sorghicola, Cordylobia anthropophaga, Culex pi piens, Dacus cucurbitae, Dacus oleae, Dasineura brassicae, fan- nia canicularis, Gasterophilus intestinalis, Glossina orsitans, Haematobia irritans, Haplodiplosis equestris, Hylemyia platura, Hypoderma lineata, Liriomyza sativae, Liriomyza trifolii, Lucilia caprina, Lucilia cuprina, Lucilia cuprina, Luc
  • Phorbia antiqua Phorbia brassicae, Phorbia coarctata, Rhagoletis cerasi, Rhagoletis pomonella, Tabanus bovinus, Tipula ole-racea and Tipula paludosa,
  • Thrips for example Frankliniella fusca, Frankliniella occidentalis, Frankliniella tritici, Scirtothrips citri, Thrips oryzae, Thrips pal i and Thrips tabaci, Hymenoptera (Hymenoptera), for example Athalia rosae, Atta cephalotes, Atta sexdens, Atta texana, Hoplocampa minuta, Hoplocampa testudinea, Monomorium pharaonis, Solenopsis geminata and Solenopsis invicta,
  • Heteroptera e.g. Acrosternum hilare, Blissus leucopterus, Cyrtopeltis notatus, Dysdercus cingulatus, Dysdercus intermedius, Eurygaster integriceps, Euschistus impictiventris, Leptoglossus phyllopus, Lygus lineolaris, Lygus pratensis, Nezara quadrodisulais, and Pyanma viridula, Pies
  • Plant suckers e.g. Acyrthosiphon onobrychis, Adelges laricis, Aphidula nasturtii, Aphis fabae, Aphis pomi, Aphis sambuci, Brachycaudus cardui, Brevicoryne brassicae, Ce- rosipha gossypii, Dreyfusia Nordmannianae, Dreyfusia picisacumaolapiolausolaapiaaculapiaolusiapiaaciae, dyfusia picisaciae, dyfusia pod Macrosiphon rosae, Megoura viciae, Metopolophium dirhodum, Myzodes persicae, Myzus cerasi, Nilaparvata lugens, Pemphigus bursarius, Perkinsiella saccharicida, Phorodon humuli, Psyll
  • Termites e.g. Calotermes flavicollis, Leucotermes flavipes, Reticulitermes lucifugus and Termes natalensis,
  • Straight wing aircraft e.g. Acheta domestica, Blatta orien- talis, Blattella germanica, Forficula auricularia, Gryllotalpa gryllotalpa, Locusta migratoria, Melanoplus bivittatus, Melanoplus femur-rübrum, Melanoplus mexicanus, Melanoplus sanguini- pes, Melanoplus spretus, Ameranascocentina, peranfacetana, nomadascacrata america, Nomadascocentica, nomanascetacanae, Nomadascacratae, Nomadascacetana, Nomadascacratae, Nomadascacratae, Nomadascacrata america, Nomadascocentiae, Nomadascacrata se, Nomadascecentica, Peranaceticus periculum , Stauronotus maroccanus and Tachycines asynamorus,
  • Arachnoidea such as arachnids (Acarina), for example Amblyomma america- num, Amblyomma variegatum, Argas persicus, Boophilus annulatus, Boophilus decoloratus, Boophilus microplus, Brevipalpus phoeni- eis, Bryobia praetiosa, Dermacentor silvarum shini, Eotetronii, Iotetranyi ricinus, Ixodes rubieundus, Ornithodorus moubata, Otobius me- gnini, Paratetranychus pilosus, Dermanyssus gallinae, Phyllo- coptruta oleivora, Polyphagotarsonemus latus, Psoroptes ovis, Rhipicephalus appendiculchinus tibiiecantinus, Thipiophychinus, Rhipicephysinabus Te
  • Nematodes such as root-bile nematodes, eg Meloidogyne hapla, Meloidogyne incognita, Meloidogyne javanica, cyst-forming nematodes, eg Globodera rostochiensis, Heterodera avenae, Heterodera glycines, Heterodera schachtii, Heterodera trifolius, longica-lenticular, and lenticular chelitis, long- and lenticular chelitis dipsaci, Heliocotylenchus mul- ticinctus, Longidorus elongatus, Radopholus similis, Rotylen- chus robustus, Trichodorus primitivus, Tylenchorhynchus clay- toni, Tylenchorhynchus dubius, Pratylenchus neglectus, Praty- lenchuschususatati curatusi, Praty
  • the compounds I and II are usually used in a weight ratio of 20: 1 to 1: 200, in particular 10: 1 to 1: 180, preferably 2: 1 to 1: 160.
  • the amount of active ingredient used to control animal pests is generally from 0.01 to 2.0, preferably from 0.02 to 1.0, kg / ha under field conditions.
  • the mixtures according to the invention can particularly preferably be used to control plant diseases and insect pests in rice.
  • the compounds I and the compound II can be applied simultaneously, that is jointly or separately, or in succession, the sequence in the case of separate application generally not having any effect on the success of the control measures.
  • the application rates of the mixtures according to the invention, especially for agricultural crop areas, are from 0.01 to 8 kg / ha, preferably 0.1 to 5 kg / ha, in particular 0.5 to 3.0 kg / ha, depending on the type of effect desired ,
  • the application rates for the compounds I are 0.01 to 2.5 kg / ha, preferably 0.05 to 2.5 kg / ha, in particular 0.1 to 1.0 kg / ha.
  • application rates of mixture of 0.001 to 250 g / kg of seed preferably 0.01 to 100 g / kg, in particular 0.01 to 50 g / kg, are generally used.
  • the compounds I and the compound II or the mixtures of the compounds I and the compound II are applied separately or together by spraying or dusting the seeds, the plants or the soil before or after sowing the plants or before or after the emergence of the plants.
  • the mixtures according to the invention can be prepared, for example, in the form of directly sprayable solutions, powders and suspensions or in the form of high-strength aqueous, oily or other suspensions, dispersions, emulsions, oil dispersions, pastes, dusts, scattering agents or granules and by spraying, atomizing, dusting, scattering or pouring can be used.
  • the form of application depends on the intended use; in any case, it should ensure that the mixture according to the invention is as fine and uniform as possible.
  • the formulations are prepared in a known manner, e.g. by stretching the active ingredient with solvents and / or carriers, if desired using emulsifiers and dispersants, and in the case of water as diluent other organic solvents can also be used as auxiliary solvents.
  • auxiliaries solvents such as aromatics (eg xylene), chlorinated aromatics (eg chlorobenzenes), paraffins (eg petroleum fractions), alcohols (eg methanol, butanol), ketones (eg cyclohexanone), amines (eg ethanolamine , Dimethylformamide) and water;
  • Carriers such as natural stone powder (e.g.
  • kaolins, clays, talc, chalk) and synthetic stone powder e.g. highly disperse silica, silicates
  • Emulsifiers such as non-ionic and anionic emulsifiers (e.g. polyoxyethylene fatty alcohol ethers, alkyl sulfonates and aryl sulfonates) and dispersants such as lignin sulfite waste liquors and methyl cellulose.
  • the surface-active substances are the alkali metal, alkaline earth metal and ammonium salts of aromatic sulfonic acids, for example lignin, phenol, naphthalene and dibutylnaphthalenesulfonic acid, and of fatty acids, alkyl and alkylarylsulfonates, alkyl, lauryl ether and fatty alcohol sulfates, and salts of sulfated hexa- , Hepta- and octadecanols or fatty alcohol glycol ethers, condensation products of sulfonated naphthalene and its derivatives with formaldehyde, condensation products of naphthalene or naphthalenesulfonic acids with phenol and formaldehyde, polyoxyethylene octyl phenol ether, ethoxylated isooctyl, octyl or nonyl phenol ether, phenyl or alkyl phenol
  • Granules e.g. coating, impregnation or homogeneous granules
  • a solid carrier e.g., a wax, a wax, or a wax.
  • the following fillers or solid carriers are used, for example: • Mineral earths such as silica gel, silicas, silica gels, silicates, talc, kaolin, limestone, lime, chalk, boluses, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground plastics, and Fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products such as cereal flour, tree bark, wood and nutshell flour, cellulose powder or other solid carriers.
  • Mineral earths such as silica gel, silicas, silica gels, silicates, talc, kaolin, limestone, lime, chalk, boluses, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground plastics
  • Fertilizers such as ammonium sulfate, ammonium phosphat
  • the formulations generally contain 0.1 to 95% by weight, preferably 0.5 to 90% by weight, of one of the compounds I and the compound II or the mixture of the compounds I and the compound II used in a purity of 90% to 100%, preferably 95% to 100% (according to the NMR or HPLC spectrum).
  • the compounds I and compound II, the mixtures or the corresponding formulations are used in such a way that the harmful fungi, their habitat or the plants, seeds, soils, areas, materials or spaces to be kept free of them are mixed with a fungicidally effective amount of the mixture, or the
  • the application can take place before or after the infestation by the harmful fungi.
  • V a mixture of 80 parts by weight of the active ingredients, 3 parts by weight of the sodium salt of diisobutylnaphthalene-1-sulfonic acid, 10 parts by weight of the sodium salt of a lignosulfonic acid from a sulfite waste liquor and 7 parts by weight of powder silica gel; a spray mixture is obtained by finely distributing the mixture in water;
  • VI an intimate mixture of 3 parts by weight of the active ingredients and 97 parts by weight of finely divided kaolin; this dust contains 3% by weight of active ingredient;
  • a stable aqueous dispersion of 40 parts by weight of the active ingredients, 10 parts by weight of the sodium salt of a phenolsulfonic acid-urea-formaldehyde condensate, 2 parts by weight of silica gel and 48 parts by weight of water, which is further diluted can be;
  • IX a stable oily dispersion of 20 parts by weight of the active ingredients, 2 parts by weight of the calcium salt of dodecylbenzenesulfonic acid, 8 parts by weight of fatty alcohol polyglycol ether,
  • the active ingredients are prepared separately or together as a 10% emulsion in a mixture of 63% by weight cyclohexanone and 27% by weight emulsifier and according to the desired concentration diluted with water.
  • the evaluation is carried out by determining the affected leaf areas in percent. These percentages are converted into efficiency levels.
  • ⁇ corresponds to the fungal attack of the treated plants in% and ß corresponds to the fungal attack of the untreated (control) plants in%
  • the infection of the treated plants corresponds to that of the untreated control plants; at an efficiency of 100, the treated plants showed no infection.
  • Nong 67 "were sprayed to runoff point with aqueous preparation of active compound, which was prepared with a stock solution consisting of 10% active compound, 85% cyclohexanone and 5% emulsifier. The following day, the plants were inoculated with an aqueous spore suspension of Pyricularia oryzae. The test plants were then placed in climatic chambers at 22 to 24 ° C. and 95 to 99% relative atmospheric humidity for 6 days, and the extent of the development of the infestation on the leaves was then determined visually. The visually determined values for the percentage of leaf areas affected were converted into efficiencies as% of the untreated control.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne des mélanges servant à lutter contre des champignons nuisibles et des insectes et contenant comme constituants actifs (A) des dérivés d'éther d'oxime de formule (I) et (B) le composé de formule (II) en une quantité synergiquement active. Dans la formule (I), X représente NH ou oxygène, R1 et R3 représentent indépendamment l'un de l'autre hydrogène, cyano, alkyle, cyclopropyle ou halogénure d'alkyle, et R2 et R4 représentent indépendamment l'un de l'autre hydrogène, alkyle, alcényle, alcynyle, halogénure d'alkyle, halogénure d'alcényle ou halogénure d'alcynyle. L'invention concerne également des procédés pour lutter contre des champignons nuisibles à l'aide de mélanges des composés I et II.
PCT/EP2003/000012 2002-01-17 2003-01-03 Melanges fongicides a base de derives d'ether d'oxime et de derives de guanidine WO2003059067A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR1020047011059A KR100955966B1 (ko) 2002-01-17 2003-01-03 옥심 에테르 유도체 및 구아니딘 유도체를 기재로 한살진균성 혼합물
JP2003559243A JP4463558B2 (ja) 2002-01-17 2003-01-03 オキシムエーテル誘導体系殺菌混合物
AU2003205564A AU2003205564A1 (en) 2002-01-17 2003-01-03 Fungicidal mixtures on the basis of oxime ether derivatives and guanidine derivatives

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10201794 2002-01-17
DE10201794.8 2002-01-17

Publications (1)

Publication Number Publication Date
WO2003059067A1 true WO2003059067A1 (fr) 2003-07-24

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PCT/EP2003/000012 WO2003059067A1 (fr) 2002-01-17 2003-01-03 Melanges fongicides a base de derives d'ether d'oxime et de derives de guanidine

Country Status (5)

Country Link
JP (1) JP4463558B2 (fr)
KR (1) KR100955966B1 (fr)
CN (1) CN1320855C (fr)
AU (1) AU2003205564A1 (fr)
WO (1) WO2003059067A1 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006066810A3 (fr) * 2004-12-20 2006-09-21 Basf Ag Procede pour lutter contre les mycoses chez les legumineuses
JP2008525338A (ja) * 2004-12-24 2008-07-17 バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト 選択されたネオニコチノイド類とストロビルリン類を主成分とする殺虫剤
WO2008092819A3 (fr) * 2007-02-01 2008-12-31 Basf Se Mélanges pesticides
WO2009098228A3 (fr) * 2008-02-05 2010-11-18 Basf Se Mélanges pesticides
WO2009098210A3 (fr) * 2008-02-05 2011-01-20 Basf Se Mélanges pesticides
US20110086888A1 (en) * 2003-07-23 2011-04-14 Peter Dahmen Fungicidally Active Compound Combinations
WO2012117572A1 (fr) * 2011-03-01 2012-09-07 Sumitomo Chemical Company, Limited Composition pesticide et procédé de lutte contre les parasites
US8546304B2 (en) 2005-02-22 2013-10-01 Basf Se Composition and method for improving plant health

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0376279A2 (fr) * 1988-12-27 1990-07-04 Takeda Chemical Industries, Ltd. Dérivés de guanidine, leur préparation et insecticides
WO1997015552A1 (fr) * 1995-10-23 1997-05-01 Basf Aktiengesellschaft Derives d'acide phenylacetique, procede et intermediaires utilises pour leur production et agents les contenant
WO1999063826A2 (fr) * 1998-06-10 1999-12-16 Bayer Aktiengesellschaft Agents pour lutter contre des parasites de vegetaux

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0376279A2 (fr) * 1988-12-27 1990-07-04 Takeda Chemical Industries, Ltd. Dérivés de guanidine, leur préparation et insecticides
WO1997015552A1 (fr) * 1995-10-23 1997-05-01 Basf Aktiengesellschaft Derives d'acide phenylacetique, procede et intermediaires utilises pour leur production et agents les contenant
WO1999063826A2 (fr) * 1998-06-10 1999-12-16 Bayer Aktiengesellschaft Agents pour lutter contre des parasites de vegetaux

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
OKAUCHI, TETSUO: "Insecticidal and fungicidal compositions containing guanidines", STN CAPLUS, AN:1992:607190, XP002900601 *

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110086888A1 (en) * 2003-07-23 2011-04-14 Peter Dahmen Fungicidally Active Compound Combinations
US20140080820A1 (en) * 2003-07-23 2014-03-20 Bayer Cropscience Ag Fungicidal agent combinations
US8609589B2 (en) * 2003-07-23 2013-12-17 Bayer Cropscience Fungicidal agent combinations
EA012612B1 (ru) * 2004-12-20 2009-10-30 Басф Акциенгезельшафт Способ борьбы с грибковыми заболеваниями бобовых культур
WO2006066810A3 (fr) * 2004-12-20 2006-09-21 Basf Ag Procede pour lutter contre les mycoses chez les legumineuses
JP2012087134A (ja) * 2004-12-24 2012-05-10 Bayer Cropscience Ag 選択されたネオニコチノイド類とストロビルリン類を主成分とする殺虫剤
JP2008525338A (ja) * 2004-12-24 2008-07-17 バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト 選択されたネオニコチノイド類とストロビルリン類を主成分とする殺虫剤
JP2014221792A (ja) * 2004-12-24 2014-11-27 バイエル・クロップサイエンス・アーゲーＢａｙｅｒ Ｃｒｏｐｓｃｉｅｎｃｅ Ａｇ 選択されたネオニコチノイド類とストロビルリン類を主成分とする殺虫剤
US8546304B2 (en) 2005-02-22 2013-10-01 Basf Se Composition and method for improving plant health
US9326509B2 (en) 2005-02-22 2016-05-03 Basf Se Composition and method for improving plant health
WO2008092819A3 (fr) * 2007-02-01 2008-12-31 Basf Se Mélanges pesticides
WO2009098228A3 (fr) * 2008-02-05 2010-11-18 Basf Se Mélanges pesticides
WO2009098210A3 (fr) * 2008-02-05 2011-01-20 Basf Se Mélanges pesticides
WO2012117572A1 (fr) * 2011-03-01 2012-09-07 Sumitomo Chemical Company, Limited Composition pesticide et procédé de lutte contre les parasites

Also Published As

Publication number Publication date
CN1615079A (zh) 2005-05-11
JP2005524623A (ja) 2005-08-18
CN1320855C (zh) 2007-06-13
KR20040105703A (ko) 2004-12-16
JP4463558B2 (ja) 2010-05-19
AU2003205564A1 (en) 2003-07-30
KR100955966B1 (ko) 2010-05-04

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