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WO2003052040A1 - Bloc hydrosoluble comprenant un detergent a lessive liquide en couches - Google Patents

Bloc hydrosoluble comprenant un detergent a lessive liquide en couches Download PDF

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Publication number
WO2003052040A1
WO2003052040A1 PCT/EP2002/012624 EP0212624W WO03052040A1 WO 2003052040 A1 WO2003052040 A1 WO 2003052040A1 EP 0212624 W EP0212624 W EP 0212624W WO 03052040 A1 WO03052040 A1 WO 03052040A1
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WO
WIPO (PCT)
Prior art keywords
water
package
composition
component
weight
Prior art date
Application number
PCT/EP2002/012624
Other languages
English (en)
Inventor
Feng-Lung Hsu
Neeraj Gupta
Kwang Ho Lee
John Leslie Storey
Original Assignee
Unilever N.V.
Unilever Plc
Hindustan Lever Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever N.V., Unilever Plc, Hindustan Lever Limited filed Critical Unilever N.V.
Priority to AU2002358498A priority Critical patent/AU2002358498A1/en
Priority to AT02792755T priority patent/ATE298784T1/de
Priority to EP02792755A priority patent/EP1453941B1/fr
Priority to DE60204914T priority patent/DE60204914T2/de
Publication of WO2003052040A1 publication Critical patent/WO2003052040A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/043—Liquid or thixotropic (gel) compositions

Definitions

  • a water-soluble single-use package comprising a layered liquid detergent in the water-soluble body portion and a process of its preparation.
  • Detergent compositions are provided in many forms, of which granular' and liquid compositions are the most prevalent. More recently, unit dose forms of detergent have been proposed in the form of compressed tablets of detergent powder or water-soluble packages, which are consumed during a single cleaning application. The unit dose forms are preferred by some consumers, in that the dose is pre-measured and, consequently, the unit dose form is faster, easier and less messy to use. Water-soluble packages filled with liquid detergent composition are desired especially by consumers who are used to liquid detergents.
  • Water-soluble unit dose packages containing liquids are known. See, for instance, Kennedy (US Patent 4,973,416), Dickler et al. (US Patent 6,037,319), Haq (US Patent 4,416,791) and Richardson (US Patent 4,115,292).
  • the packages may contain various amounts, including relatively high, amounts of water. See for instance WO 94/14941, EP 518 689, WO 97/27743, and JP 06/340,899.
  • EP 116422, EP 175485, GB 1247189, WO 99/47635, and Ginn disclose dual layer liquid cleaning compositions in a bottle or a water insoluble package.
  • the layers are achieved by employing an electrolyte, which when added to an aqueous surfactant solution, forces the separation of the surfactant from the aqueous phase.
  • electrolyte which when added to an aqueous surfactant solution, forces the separation of the surfactant from the aqueous phase.
  • the phenomenon of separating an organic component from an aqueous layer, by the addition of a salt (electrolyte) is known as "salting out.”
  • the salt increases the ionic character of water and drives the organic, less polar, component away.
  • the present invention includes a layered liquid detergent composition in a water-soluble single use package, the composition comprising at least two layers, with a surfactant and an organic electrolyte distributed within the layers.
  • the preferred inventive compositions include water, yet the water-soluble package remains intact on storage.
  • Water-soluble body as used herein means soluble in cold water, i.e. soluble at 5°C and above.
  • Liquid as used herein means that a continuous phase or predominant part of the composition is liquid and that a composition is flowable at 20°C.
  • Organic cation as used herein means a non-metal, positively charged ionic entity.
  • Organic electrolyte as used herein means an electrolyte containing an organic cation.
  • Transparent as used herein includes both transparent and translucent and means that an ingredient, or a mixture, or a phase, or a composition, or a package according to the invention preferably has a transmittance of more than 25%, more preferably more than 30%, most preferably more than 40%, optimally more than 50% in the visible part of the spectrum (approx. 410-800 nm).
  • absorbency may be measured as less than 0.6 (approximately equivalent to 25% transmitting) or by having transmittance greater than 25% wherein % transmittance equals: ⁇ j ⁇ (f hsorbmcy x 100%.
  • % transmittance equals: ⁇ j ⁇ (f hsorbmcy x 100%.
  • composition or "liquid detergent composition” as used herein means the final detergent composition (i.e., the detergent composition itself, but not the water-soluble body), including at least two layers.
  • the at least two layers comprise between them a surfactant and an organic electrolyte.
  • the package is preferably made of a clear, sealable, cold water soluble film such as polyvinyl alcohol. Thickness could range from 25 to 100 ⁇ m, more preferably from 35 to 80 ⁇ m, most preferably from 45 to 55 ⁇ m. Other materials from which the package can be made include but are not limited to methyl hydroxy propyl cellulose and polyethylene oxide. Polyvinyl alcohol is preferred due to its ready availability and low cost.
  • One supplier of polyvinyl alcohol film is Monosol Inc. European suppliers of suitable films include but are not limited to Monosol supplied by Monosol Inc. or PT supplied by Aicello or K-series supplied by Kurary or Hydrafilm supplied by Rainier Specialty polymers ltd, or QSA series by Polymer Films, Inc.
  • the water-soluble film of the base wall is the same material as that used to make the body wall. Both thermoforming and cold forming (e.g., with water) are possible.
  • the essential ingredients of the inventive laundry compositions are surfactant and organic electrolyte.
  • compositions of the invention contain one or more surface active agents (surfactants) selected from the group consisting of anionic, nonionic, cationic, ampholytic and zwitterionic surfactants or mixtures thereof.
  • surfactants selected from the group consisting of anionic, nonionic, cationic, ampholytic and zwitterionic surfactants or mixtures thereof.
  • the preferred surfactant detergents for use in the present invention are mixtures of anionic and nonionic surfactants although it is to be understood that any surfactant may be used alone or in combination with any other surfactant or surfactants.
  • the surfactant should comprise at least 5%, e.g., 5% to 80%, preferably at least 10% to 80%, more preferably 15% to 40%; even more preferably 15% to 35% of the composition.
  • Nonionic synthetic organic detergents which can be used with the invention, alone or in combination with other surfactants, are described below. Nonionic surfactants are typically included.
  • Nonionics surfactants are nonionic surfactants whch are pourable liquids, gels or pastes at 25°C.
  • Nonionic detergent surfactants normally have molecular weights of from about 300 to about 11,000. Mixtures of different nonionic detergent surfactants may also be used, provided the mixture is a liquid gel or paste at 25 °C.
  • the composition may comprise one or more nonionic surfactants which are solid at 25 °C. These dissolved and/or dispersed in either or both liquid layers.
  • nonionic detergents are characterized by the presence of an organic hydrophobic group and an organic hydrophilic group and are typically produced by the condensation of an organic aliphatic or alkyl aromatic hydrophobic compound with ethylene oxide (hydrophilic in nature).
  • suitable nonionic surfactants are those disclosed in U.S. Pat. Nos. 4,316,812 and 3,630,929 and applicants' published European specification EP-A- 225,654.
  • the nonionic detergents are polyalkoxylated lipophiles wherein the desired hydrophile-lipophile balance is obtained from addition of a hydrophilic polyalkoxy group to a lipophilic moiety.
  • a preferred class of nonionic detergent is the alkoxylated alkanols wherein the alkanol is of 9 to 18 carbon atoms and wherein the number of moles of alkylene oxide (of 2 or 3 carbon atoms) is from 3 to 12. Of such materials it is preferred to employ those wherein the alkanol is a fatty alcohol of 9 to 11 or 12 to 15 carbon atoms and which contain from 5 to 8 or 5 to 9 alkoxy groups per mole.
  • Exemplary of such compounds are those wherein the alkanol is of 12 to 15 carbon atoms and which contain about 7 ethylene oxide groups per mole, e.g. Neodol® 25-7 and Neodol® 23®- 6.5, which products are made by Shell Chemical Company, Inc.
  • the former is a condensation product of a mixture of higher fatty alcohols averaging about 12 to 15 carbon atoms, with about 7 moles of ethylene oxide and the latter is a corresponding mixture wherein the carbon atoms content of the higher fatty alcohol is 12 to 13 and the number of ethylene oxide groups present averages about 6.5.
  • the higher alcohols are primary alkanols.
  • Nonionics are represented by the commercially well- known class of nonionics sold under the trademark Plurafac®.
  • the Plurafacs® are the reaction products of a higher linear alcohol and a mixture of ethylene and propylene oxides, containing a mixed chain of ethylene oxide and propylene oxide, terminated by a hydroxyl group. Examples include C 13 - C 15 fatty alcohol condensed with 6 moles ethylene oxide and 3 moles propylene oxide, C 13 - C 15 fatty alcohol condensed with 7 moles propylene oxide and 4 moles ethylene oxide, C 13 - C 15 fatty alcohol condensed with 5 moles propylene oxide and 10 moles ethylene oxide, or mixtures of any of the above.
  • Nonionic surfactants include the C 12 -C 15 primary fatty alcohols with relatively narrow contents of ethylene oxide in the range of from about 7 to 9 moles, and the C 9 to C ⁇ fatty alcohols ethoxylated with about 5-6 moles ethylene oxide.
  • Another class of nonionic surfactants which can be used in accordance with this invention are glycoside surfactants.
  • Glycoside surfactants suitable for use in accordance with the present invention include those of the formula:
  • R is a monovalent organic radical containing from about 6 to about 30
  • R' is a divalent hydrocarbon radical containing from about 2 to 4 carbons atoms
  • 0 is an oxygen atom
  • y is a number which can have an average value of from 0 to about 12 but which is most preferably zero
  • Z is a moiety derived from a reducing saccharide containing 5 or 6 carbon atoms
  • x is a number having an average value of from 1 to about 10 (preferably from about 1.5 to about 10).
  • a particularly preferred group of glycoside surfactants for use in the practice of this invention includes those of the formula above in which R is a monovalent organic radical (linear or branched) containing from about 6 to about 1 8(especially from about 8 to about 18) carbon atoms; y is zero; z is glucose or a moiety derived therefrom; x is a number having an average value of from 1 to about 4 (preferably from about 1 to 4).
  • Nonionic surfactants particularly useful for this application include, but are not limited to: alcohol ethoxylates (e.g. Neodol® 25-9 from Shell Chemical Co.), alkyl phenol ethoxylates (e.g. Tergitol® NP-9 from Union Carbide Corp.), alkylpolyglucosides (e.g. Glucapon® 600CS from Henkel Corp.), polyoxyethylenated polyoxypropylene glycols
  • sorbitol esters e.g. Emsorb® 2515 from Henkel Corp.
  • polyoxyethylenated sorbitol esters e.g. Emsorb® 6900 from Henkel Corp.
  • alkanolamides e.g. Alkamide® DC212/SE from Rhone-Poulenc Co.
  • N- alkypyrrolidones e.g. Surfadone® LP-100 from ISP Technologies Inc.
  • Mixtures of two or more of the nonionic surfactants can be used.
  • Anionic Surfactant Anionic surface active agents which may be used in the present invention are those surface active compounds which contain a long chain hydrocarbon hydrophobic group in their molecular structure and a hydrophilic group, i.e.; water solubilizing group such as sulfonate, sulfate or carboxylate group.
  • the anionic surface active agents include the alkali metal (e.g. sodium and potassium) water soluble higher alkyl benzene sulfonates, alkyl sulfonates, alkyl sulfates and the alkyl polyether sulfates. They may also include fatty acid or fatty acid soaps.
  • the preferred anionic surface active agents are the alkali metal, ammonium or alkanolamide salts of higher alkyl benzene sulfonates and alkali metal, ammonium or alkanolamide salts of higher alkyl sulfonates.
  • Preferred higher alkyl sulfonates are those in which the alkyl groups contain 8 to 26 carbon atoms, preferably 12 to 22 carbon atoms and more preferably 14 to 18 carbon atoms.
  • the alkyl group in the alkyl benzene sulfonate preferably contains 8 to 16 carbon atoms and more preferably 10 to 15 carbon atoms.
  • a particularly preferred alkyl benzene sulfonate is the sodium or potassium dodecyl benzene sulfonate, e.g. sodium linear dodecyl benzene sulfonate.
  • the primary and secondary alkyl sulfonates can be made by reacting long chain alpha-olefins with sulfites or bisulfites, e.g. sodium bisulfite.
  • the alkyl sulfonates can also be made by reacting long chain normal paraffin hydrocarbons with sulfur dioxide and oxygen as described in U.S. Pat. Nos. 2,503,280, 2,507,088, 3,372, 188 and 3,260,741 to obtain normal or secondary higher alkyl sulfonates suitable for use as surfactant detergents.
  • the alkyl substituent is preferably linear, i.e. normal alkyl, however, branched chain alkyl sulfonates can be employed, although they are not as good with respect to biodegradability.
  • the alkane, i.e. alkyl, substituent may be terminally sulfonated or may be joined, for example, to the carbon atom of the chain, i.e. may be a secondary sulfonate. It is understood in the art that the substituent may be joined to any carbon on the alkyl chain.
  • the higher alkyl sulfonates can be used as the alkali metal salts, such as sodium and potassium.
  • the preferred salts are the sodium salts.
  • the preferred alkyl sulfonates are the C 10 to C 18 primary normal alkyl sodium and potassium sulfonates, with the C 10 to C 15 primary normal alkyl sulfonate salt being more preferred.
  • normal alkyl and branched chain alkyl sulfates e.g., primary alkyl sulfates
  • anionic component e.g., sodium sulfate
  • the higher alkyl polyether sulfates used in accordance with the present invention can be normal or branched chain alkyl and contain lower alkoxy groups which can contain two or three carbon atoms.
  • the normal higher alkyl polyether sulfates are preferred in that they have a higher degree of biodegradability than the branched chain alkyl and the lower poly alkoxy groups are preferably ethoxy groups.
  • R' is C 8 to C 20 alkyl, preferably Cio to C ⁇ 8 and more preferably C 12 to C ⁇ 5 ; p is 2 to 8, preferably 2 to 6, and more preferably 2 to 4;and M is an alkali metal, such as sodium and potassium, or an ammonium cation.
  • the sodium and potassium salts are preferred.
  • a preferred higher alkyl poly ethoxylated sulfate is the sodium salt of a triethoxy C 1 to C 15 alcohol sulfate having the formula:
  • alkyl ethoxy sulfates examples include C 12-15 normal or primary alkyl triethoxy sulfate, sodium salt; n-decyl diethoxy sulfate, sodium salt; C 12 primary alkyl diethoxy sulfate, ammonium salt; C 12 primary alkyl triethoxy sulfate, sodium salt: C 15 primary alkyl tetraethoxy sulfate, sodium salt, mixed C ⁇ 4-15 normal primary alkyl mixed tri- and tetraethoxy sulfate, sodium salt; stearyl pentaethoxy sulfate, sodium salt; and mixed C 10- ⁇ 8 normal primary alkyl triethoxy sulfate, potassium salt.
  • the normal alkyl ethoxy sulfates are readily biodegradable and are preferred.
  • the alkyl poly- lower alkoxy sulfates can be used in mixtures with each other and/or in mixtures with the above discussed higher alkyl benzene, alkyl sulfonates, or alkyl sulfates.
  • the alkali metal higher alkyl poly ethoxy sulfate can be used with the alkylbenzene sulfonate and/or with an alkyl sulfonate or sulfonate, in an amount of 0 to 70%, preferably 10 to 50% and more preferably 10 to 20% by weight of entire composition.
  • Anionic surfactants particularly useful for this application include, but are not limited to: linear alkyl benzene sulfonates (e.g. Vista® C-500 from Vista Chemical Co.), alkyl sulfates (e.g. Polystep® B-5 from Stepan Co.), polyoxyethylenated alkyl sulfates (e.g. Standapol® ES- 3 from Stepan Co.), alpha olefin sulfonates (e.g. Witconate® AOS from Witco Corp.), alpha sulfo methyl esters (e.g. Alpha-Step® MC-48 from Stepan Co.), alkyl ether sulfates and isethionates (e.g. Jordapon® CI from PPG Industries Inc.).
  • linear alkyl benzene sulfonates e.g. Vista® C-500 from Vista Chemical Co.
  • alkyl sulfates e.g.
  • Anionic surfactants may be added pre-neutralized or, preferably, may be formed in situ, by neutralizing a precursor acid (fatty acid in the case of soaps). Further, the anionic precursor or fatty acid should be over-neutralised (i.e. there should be an excess of the alkaline material used to form the counter-ion). Further still, it is preferable to use the organic counter-ion used for the organic electrolyte. Preferably, monoethanolamine salt of the anionic precursor acid is employed.
  • cationic surfactants are known in the art, and almost any cationic surfactant having at least one long chain alkyl group of about 10 to 24 carbon atoms is suitable in the present invention. Such compounds are described in "Cationic Surfactants", Jungermann, 1970, incorporated by reference.
  • compositions of the invention may use cationic surfactants alone or in combination with any of the other surfactants known in the art.
  • compositions may contain no cationic surfactants at all.
  • Ampholytic synthetic detergents can be broadly described as derivatives of aliphatic or aliphatic derivatives of heterocyclic secondary and tertiary amines in which the aliphatic radical may be a straight chain or a branched and wherein one of the aliphatic substituents contains from about 8 to 18 carbon atoms and at least one contains an anionic water- solubilizing group, e.g. carboxylate, sulfonate, sulfate.
  • an anionic water- solubilizing group e.g. carboxylate, sulfonate, sulfate.
  • Examples of compounds falling within this definition are sodium 3(dodecylamino)propionate, sodium 3-(dodecylamino)propane-l- sulfonate, sodium 2-(dodecylamino)ethyl sulfate, sodium 2-(dimethylamino)octadecanoate, disodium 3-(N- carboxymethyldodecylamino)propane 1 -sulfonate, disodium octadecyl- imminodiacetate, sodium l-carboxymethyl-2-undecylimidazole, and sodium N, N-bis(2- hydroxyethyl)-2-sulfato-3-dodecoxypropylamine.
  • Zwitterionic surfactants can be broadly described as derivatives of secondary and tertiary amines, derivatives of heterocyclic secondary and tertiary amines, or derivatives of quaternary ammonium, quaternary phosphonium or tertiary sulfonium compounds.
  • the cationic atom in the quaternary compound can be part of a heterocyclic ring. In all of these compounds there is at least one aliphatic group, straight chain or branched, containing from about 3 to 18 carbon atoms and at least one aliphatic substituent containing an anionic water solubilizing group, e. g., carboxy, sulfonate, sulfate, phosphate, or phosphonate.
  • zwitterionic surfactants which may be used are set forth in U.S. Pat. No. 4,062,647, hereby incorporated by reference.
  • the surfactant in the laundry compositions of the invention is anionic and/or nonionic, especially linear alkylbenzene sulfonate, alkyl ether sulfate, alcohol ethoxylates and mixtures thereof.
  • mixtures of anionic and nonionc surfactants are especially preferred, for optimum greasy stain and particulate soil removal.
  • the most effective mixtures employ anionic to nonionic ratio of from 10: 1 to 1:10, preferably from 5:1 to 1:5, most preferably from 3:1 to 1:3.
  • nonionic surfactants are employed, in the absence of, or lower levels of, anionic surfactants, alone or in combination with cationic surfactants and/or antifoams.
  • Electrolyte The electrolyte employed in the present invention contains an organic (i.e. non-metal) cation. Suitable cations include but are not limited to ammonium, ammonium hydroxide, amines, more preferably alkanolamines (e.g., monoethanolamine, diethanolamine, triethanolamine, isopropylamine) . It has been found, as part of the present invention, that the use of an electrolyte containing an organic cation results in formulations which may contain more water, yet by virtue of much reduced water activity level, without damaging the water-soluble package, resulting in more cost-effective product. Higher amounts of water are also advantageous to accommodate hydrophilic functional ingredients.
  • organic electrolyte resulted in improved transparency of the compositions, compared to the same compositions containing an inorganic electrolyte (i.e., inorganic cation).
  • organic electrolytes decrease the potential for surfactant crystallizing out during storage.
  • Suitable anions include but are not limited to sulphate, nitrate, fluoride, chloride, bromide, iodide, acetate, tartrate, ammonium tartrate, benzenesulphonate, benzoate, bicarbonate, carbonate, bisulphate, bisulphite, sulphate, sulphite, borate, borotartrate, bromate, butyrate, chlorate, camphorate, chlorite, cinnamate, citrate, disilicate, dithionate, ethylsulphate, ferricyanide, ferrocyanide, fluorosilicate, formate, glycerophosphate, hydrogenphosphate, hydroxostannate, hypochlorite, hyponitrite, hypophosphite, iodate, isobutyrate, lactate, laurate, metaborate, metasilicate, methionate, methylsulphate, nitrite, oleate, orthophosphate, orthopho
  • Electrolyte may be pre- formed or formed in situ.
  • organic electrolytes suitable for use in the present invention meet both of the following criteria:
  • Preferred electrolytes are selected from the group consisting of monoethanolamine, triethanolamine, and ammonium oxide salts of citrate, carbonate, bicarbonate, borate and sulfate.
  • Monoethanolamme salt is the most effective.
  • Monoethanolamine citrate, monoethanolamine carbonate and monoethanolamine borate are the most preferred, due to their ability to also function as builders and/or buffering agents in the detergent composition.
  • Monoethanolamine citrate is optimum, due to its optimum ability to salt out a surfactant and/or reduce the water activity.
  • the liquid detergent composition of the invention generally includes from 1 to 50%, more preferably from 5 to 40%, most preferably from 5 to 35%, and optimally from 10 to 30% of the organic electrolyte, in order to attain a stable layered composition, at optimum cost.
  • concentration of electrolyte to create a two-layered composition depends on the surfactant concentration, the water amount and the identity of the electrolyte.
  • the concentration needed may be predicted by calculating the ionic strength of the electrolyte at a particular concentration. It has been found as part of the present invention that the preferred electrolytes and preferred concentrations are those that have a calculated ionic strength of at least 4.2, preferably at least 4.4, more preferably at least 5.
  • Ionic strength represents interactions of ions with water molecules and other ions in the solution. Ionic strength may be calculated as follows:
  • the liquid laundry detergent according to the invention comprises at least two layers. Both layers are preferably isotropic (a single phase when viewed macroscopically), after standing still for at least 24 hours at 20°C. "Isotropic" is used herein to describe each layer of the inventive composition, since the composition overall contains at least two layers and thus could not be isotropic overall. Both layers are preferably transparent/translucent. Preferably, at least one layer is colored. Generally, the layers are attained when the sufficient amount of the electrolyte is added to the surfactant. The amount differs in each specific case, depending on the identity and the amount of the surfactant(s), water and electrolyte(s). The discussion of ionic strength in the immediately preceding paragraph is relevant here, since the electrolyte should be present in a sufficient concentration to force surfactant salting out, thus creating layers.
  • organic electrolytes are or could be liquid. Furthermore, they can be liquid, in the presence of extra organic neutralizing agent (as is the case with monoethanolamine citrate in the presence of extra monoethanolamine). Since the surfactant may also be liquid, it is possible to prepare a layered liquid composition in the absence of water. Such is not a case with inorganic electrolytes, which are solid salts.
  • compositions comprise two layers, with the top layer containing majority, preferably all, of the surfactant, and the bottom layer containing the majority, preferably all, of the electrolyte.
  • compositions of the resultant layers do not necessarily correspond with the compositions of the respective layers prior to their being combined into a single composition. This is because of reaction between ingredients, in particular the acidic ingredients and the basic ingredients (e.g., monoethanolamine) and also, because of possible migration of material between the two layers, or emulsif ⁇ cation of some of the layers within each other. Consequently, it is to be understood that the composition of the components as herein described pertains to the compositions prior to their being combined into a single composition. By virtue of employing a surfactant and an organic electrolyte in the amounts as herein described (and optional ingredients, including those described below), the composition separates into at least two layers, wherein the composition of the layers may differ from the composition of the initial components.
  • a surfactant and an organic electrolyte in the amounts as herein described (and optional ingredients, including those described below)
  • the ranges of the surfactant, electrolyte, and water content within the respective components or layers are as follows (% by weight of the relevant component):
  • the volume ratio of the two components in the final composition is generally in the range of from 10:90 to 90:10, more preferably from 20:80 to 80:20, most preferably from 70:30 to 30:70, and optimally from 40:60 to 60:40, in order to provide the most pleasing appearance and optimum cleaning benefits.
  • the resulting layers have the volume ratios in the same ranges as described above (but the layer ratio may not be the same as the component ratio). More than two layers may be present.
  • the additional layer may be a capsule, dispersion or emulsion layer, as described below under Optional Ingredients.
  • a surfactant component may include both highly polar and highly non-polar ingredients, which might separate into more than one organic-rich layer.
  • the preferred laundry composition may include one or more well-known laundry ingredients, such as builders (from 0.1 to 20%), anti- redeposition agents, fluorescent dyes, perfumes, soil-release polymers, colorant, enzymes, buffering agents, antifoam agents, UV-absorber, etc. Electrolytes may serve as builders in the composition, yet additional builders maybe present.
  • Water A particularly preferred optional ingredient is water.
  • the liquid detergent compositions of the invention may (but do not have to) contain significant amounts of water. Relatively high water amount is beneficial, in order to incorporate hydrophilic ingredients into the composition.
  • the layered composition is attained which may contain high amounts of water, yet the water present in the composition does not dissolve the water-soluble package enveloping the composition.
  • the liquid detergent composition of the invention generally includes from 0 to 70% of total (free and bound) water, more preferably from 5 to 50%, most preferably from 10 to 50%, and optimally from 25 to 40%, in order to obtain clarity and ease of the dispersion of the composition during use (% by weight of the composition). Yet, by virtue of employing the electrolyte as taught herein the water activity of the inventive compositions is generally low: typically less than 0.94, preferably less than 0.93, more preferably less than 0.9, optimally less than 0.8. in order to obtain compositions which contain optimum amounts of water, yet may be stored safely in a water-soluble package.
  • Water activity is the ratio of the vapor pressure of a solution to that of pure water. It is related to the inverse of the relative humidity of the atmosphere above the sample at equilibrium. Apparatus: Aqualab CX-2 Water Activity meter; Sample containers; Transfer pipets
  • Salt standards should be prepared in deionized water every six months, or as needed. They are stored at room temperature, and are used to calibrate the water activity machine with each use.
  • the Aqualab measures the inverse of the relative humidity of a solution, by evaluating the condensation that forms on a mirror within the machine. Samples containing high levels of propylene glycol are not usually run with the Aqualab because PPG coats the mirror.
  • Hydrotrope Another particularly preferred optional ingredient is a hydrotrope, which prevents liquid crystal formation.
  • the hydrotrope is typically included in the surfactant layer. The addition of the hydrotrope thus aids the clarity/transparency of the composition.
  • Suitable hydrotropes include but are not limited to propylene glycol, ethanol, salts of benzene sulphonate, toluene sulphonate, xylene sulphonate or cumene sulphonate.
  • Suitable salts include but are not limited to sodium, potassium, ammonium, monoethanolamine, triethanolamine.
  • the hydrotrope is selected from the group consisting of propylene glycol, xylene sulfonate, ethanol, and urea to provide optimum performance.
  • the amount of the hydrotrope is generally in the range of from 0 to 30%, preferably from 0.5 to 20%, most preferably from 1 to 15%.
  • Dye Another particularly preferred ingredient is a dye, in order to create a composition with visually appealing colored layer or layers.
  • a dye is an organic molecule and so will partition into the organic (surfactant) layer. It is possible, although less usual that a dye may partition into the electrolyte layer.
  • Suitable dyes include but are not limited to:
  • Xanthene Of these, the Azo and Pyrene families of dyes are suitable for inclusion into an electrolyte layer (i.e. these dyes will likely partition into the electrolyte layer — but may do so along with the surfactant layer).
  • One of the preferred embodiments is to include both a dye that will partition into a surfactant layer and a dye that will partition into an electrolyte layer, in order to provide a 2-colored composition.
  • the inventive compositions generally include from 0.0001 to 1%, more preferably from 0.0005 to 0.1%, most preferably from 0.0001 to 0.1% of the dye, in order to provide a pleasing appearance (% by weight of the composition).
  • the liquid compositions may include encapsulated ingredients, preferably in the form of transparent or colored capsules or an emulsion, or a dispersion. These capsules, emulsion, or dispersion, may be distributed in one or more layers of the inventive compositions, or may be present as an additional layer.
  • Preferred ingredients to be encapsulated are enzymes, bleaches, colorants, perfumes, and mixtures thereof to minimize the damage to these ingredients from water or surfactant, or alkaline ingredients, and/or to enhance the appearance of the product.
  • Preferred inventive compositions comprise from 0.5 to 20%, more preferably from 0.1 to 10%, most preferably from 0.3 to 6%, and optimally from 0.5 to 5%, in order to attain optimum performance and/or appearance (% by weight of the composition).
  • the pH of the inventive compositions is generally in the range of from 2.5 to 12.5, preferably in the range of from 4 to 10, most preferably from 6 to 9, in order to attain optimum laundry cleaning.
  • the composition of the components employed for making the inventive layered composition is as follows: Ingredients of component 1 (% by weight of the component):
  • the detergent composition is a transparent/translucent composition packaged in the transparent/translucent body.
  • the packages of the invention may be prepared from polyvinyl alcohol film, or other suitable material, which is filled, then sealed, preferably heat-sealed or water-sealed.
  • the packages may be filled in any suitable way.
  • the liquid detergent composition is pre-mixed (both components) and filled in the same manner as a single phase composition would be.
  • the composition may also be filled component by component.
  • the package may take many shapes as viewed in a plan view, such as rectangular, square, triangle, round, etc.
  • the package is in a polyhedral shape (e.g., tetrahedron or a pyramid).
  • the package is mixed with water (e.g., inside a laundry machine), in order to dissolve the body and to release the contents of the package.
  • water e.g., inside a laundry machine
  • composition as in Table 1, within the scope of the invention was prepared by mixing the ingredients in the order listed for each component.
  • the product was a stable-two-layered liquid. 25 grams of each component were added into a polyvinyl alcohol pouch made of 75.6 microns thickness of polyvinyl alcohol film ex. Monosol and sealed. The pouch was stable for at least 3 weeks, with no visible impact on the film. Two transparent layers were visible in the pouch and separated easily after shaking.
  • the composition contained no water.
  • the product was a stable two-layered, clear liquid.
  • the product separated into layers easily, even after shaking.
  • 25 grams of each component were added into a polyvinyl alcohol pouch made of 75.6 microns thickness of polyvinyl alcohol film ex. Monosol and sealed.
  • the pouch was stable for at least 3 weeks, with no visible impact on the film. Two transparent layers were visible in the pouch and separated easily after shaking.
  • Example 3 The two components each of Examples 3 and 4 were respectively dosed at 25ml per each package sealed by VFFS (vertical form film system), the package being formed of MONOSOL T film.
  • VFFS vertical form film system
  • compositions of Examples 3 and 4 showed superior clarity, separation between the layers and storage stability over several weeks at room temperature, as evidenced by lack of precipitation.
  • the packages were filled and sealed by HFFS (horizontal form film system) with no difference in performance.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Wrappers (AREA)

Abstract

La présente invention concerne une composition détergente liquide en couches comprise dans un bloc hydrosoluble à usage unique. La composition décrite dans cette invention comprend au moins deux couches. Deux couches au moins contiennent un tensioactif et un électrolyte organique. Les compositions privilégiées dans cette invention contiennent de l'eau, elles sont transparentes et elles sont encapsulées dans un corps transparent, une couche au moins étant colorée.
PCT/EP2002/012624 2001-12-14 2002-11-12 Bloc hydrosoluble comprenant un detergent a lessive liquide en couches WO2003052040A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU2002358498A AU2002358498A1 (en) 2001-12-14 2002-11-12 Water-soluble package with layered liquid laundry detergent
AT02792755T ATE298784T1 (de) 2001-12-14 2002-11-12 Wasserlösliche verpackung enthaltend ein mehrphasiges flüssiges waschmittel
EP02792755A EP1453941B1 (fr) 2001-12-14 2002-11-12 Bloc hydrosoluble comprenant un detergent a lessive liquide en couches
DE60204914T DE60204914T2 (de) 2001-12-14 2002-11-12 Wasserlösliche verpackung enthaltend ein mehrphasiges flüssiges waschmittel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US2046201A 2001-12-14 2001-12-14
US10/020,462 2001-12-14

Publications (1)

Publication Number Publication Date
WO2003052040A1 true WO2003052040A1 (fr) 2003-06-26

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PCT/EP2002/012624 WO2003052040A1 (fr) 2001-12-14 2002-11-12 Bloc hydrosoluble comprenant un detergent a lessive liquide en couches

Country Status (6)

Country Link
EP (1) EP1453941B1 (fr)
AT (1) ATE298784T1 (fr)
AU (1) AU2002358498A1 (fr)
DE (1) DE60204914T2 (fr)
ES (1) ES2244828T3 (fr)
WO (1) WO2003052040A1 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006130647A1 (fr) * 2005-06-01 2006-12-07 The Procter & Gamble Company Sachet hydrosoluble contenant un liquide
EP1854869A1 (fr) * 2006-05-09 2007-11-14 The Procter and Gamble Company Sachet contenant du liquide, soluble dans l'eau
US8455417B2 (en) 2004-07-02 2013-06-04 The Procter & Gamble Company Personal care compositions with improved hyposensitivity
US9006169B2 (en) 2005-06-03 2015-04-14 The Procter & Gamble Company Personal care compositions with improved hyposensitivity
EP3134501A4 (fr) * 2014-04-22 2018-01-17 Henkel IP & Holding GmbH Compositions détergentes en doses unitaires
EP2404988B1 (fr) 2010-07-07 2018-01-24 Dalli-Werke GmbH & Co. KG Composition d'application locale en pré-traitement de taches sur du linge
WO2018140565A1 (fr) 2017-01-27 2018-08-02 Henkel IP & Holding GmbH Compositions de doses unitaires stables à teneur élevée en eau
EP3363888A1 (fr) * 2017-02-21 2018-08-22 The Procter & Gamble Company Utilisation d'une composition détergente liquide pour le lavage afin de réduire au minimum les effets défavorables lors d'une exposition accidentelle à des contenus d'articles de dose unitaire solubles dans l'eau

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11028352B2 (en) 2013-03-14 2021-06-08 Novozymes A/S Detergent pouch with enzymatic water-soluble film
CN109266467A (zh) * 2018-08-20 2019-01-25 四川建元天地环保科技有限公司 有机电解液在产品表面去污的用途

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1247189A (en) * 1967-12-28 1971-09-22 Unilever Nv Liquid compositions for the treatment of natural or synthetic fibres
DE19951635A1 (de) * 1999-10-26 2001-05-17 Henkel Kgaa Wäßriges mehrphasiges Reinigungsmittel

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1247189A (en) * 1967-12-28 1971-09-22 Unilever Nv Liquid compositions for the treatment of natural or synthetic fibres
DE19951635A1 (de) * 1999-10-26 2001-05-17 Henkel Kgaa Wäßriges mehrphasiges Reinigungsmittel

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10682383B2 (en) 2004-07-02 2020-06-16 The Procter & Gamble Company Personal care compositions with improved hyposensitivity
US8455417B2 (en) 2004-07-02 2013-06-04 The Procter & Gamble Company Personal care compositions with improved hyposensitivity
US10183051B2 (en) 2004-07-02 2019-01-22 The Procter & Gamble Company Personal care compositions with improved hyposensitivity
WO2006130647A1 (fr) * 2005-06-01 2006-12-07 The Procter & Gamble Company Sachet hydrosoluble contenant un liquide
US9585866B2 (en) 2005-06-03 2017-03-07 The Procter & Gamble Company Personal care compositions with improved hyposensitivity
US9006169B2 (en) 2005-06-03 2015-04-14 The Procter & Gamble Company Personal care compositions with improved hyposensitivity
EP1854869A1 (fr) * 2006-05-09 2007-11-14 The Procter and Gamble Company Sachet contenant du liquide, soluble dans l'eau
EP2404988B1 (fr) 2010-07-07 2018-01-24 Dalli-Werke GmbH & Co. KG Composition d'application locale en pré-traitement de taches sur du linge
EP3134501A4 (fr) * 2014-04-22 2018-01-17 Henkel IP & Holding GmbH Compositions détergentes en doses unitaires
US10047328B2 (en) 2014-04-22 2018-08-14 Hekel IP & Holding GmbH Unit dose detergent compositions
AU2015249760B2 (en) * 2014-04-22 2018-08-30 Henkel IP & Holding GmbH Unit dose detergent compositions
WO2018140565A1 (fr) 2017-01-27 2018-08-02 Henkel IP & Holding GmbH Compositions de doses unitaires stables à teneur élevée en eau
US10696926B2 (en) 2017-01-27 2020-06-30 Henkel IP & Holding GmbH Stable unit dose compositions with high water content and structured surfactants
EP3574078A4 (fr) * 2017-01-27 2020-08-19 Henkel IP & Holding GmbH Compositions de doses unitaires stables à teneur élevée en eau
US10760034B2 (en) 2017-01-27 2020-09-01 Henkel IP & Holding GmbH Stable unit dose compositions with high water content
EP3363888A1 (fr) * 2017-02-21 2018-08-22 The Procter & Gamble Company Utilisation d'une composition détergente liquide pour le lavage afin de réduire au minimum les effets défavorables lors d'une exposition accidentelle à des contenus d'articles de dose unitaire solubles dans l'eau

Also Published As

Publication number Publication date
EP1453941A1 (fr) 2004-09-08
AU2002358498A1 (en) 2003-06-30
ES2244828T3 (es) 2005-12-16
EP1453941B1 (fr) 2005-06-29
DE60204914T2 (de) 2006-04-27
DE60204914D1 (de) 2005-08-04
ATE298784T1 (de) 2005-07-15

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