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WO2002018929A3 - Chromatography and other adsorptions using modified carbon adsorbents - Google Patents

Chromatography and other adsorptions using modified carbon adsorbents Download PDF

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Publication number
WO2002018929A3
WO2002018929A3 PCT/US2001/027347 US0127347W WO0218929A3 WO 2002018929 A3 WO2002018929 A3 WO 2002018929A3 US 0127347 W US0127347 W US 0127347W WO 0218929 A3 WO0218929 A3 WO 0218929A3
Authority
WO
WIPO (PCT)
Prior art keywords
chromatography
adsorptions
stationary phase
separations
modified carbon
Prior art date
Application number
PCT/US2001/027347
Other languages
French (fr)
Other versions
WO2002018929A2 (en
Inventor
Agathagelos Kyrlidis
Steven R Reznek
James A Belmont
Original Assignee
Cabot Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cabot Corp filed Critical Cabot Corp
Priority to CA002421517A priority Critical patent/CA2421517A1/en
Priority to EP01968422A priority patent/EP1314026A2/en
Priority to JP2002523599A priority patent/JP2004522142A/en
Priority to AU2001288672A priority patent/AU2001288672A1/en
Publication of WO2002018929A2 publication Critical patent/WO2002018929A2/en
Publication of WO2002018929A3 publication Critical patent/WO2002018929A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0093—Chemical modification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D57/00—Separation, other than separation of solids, not fully covered by a single other group or subclass, e.g. B03C
    • B01D57/02—Separation, other than separation of solids, not fully covered by a single other group or subclass, e.g. B03C by electrophoresis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/1411—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing dispersed material in a continuous matrix
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/021—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/286—Phases chemically bonded to a substrate, e.g. to silica or to polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • B01J20/3251—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulphur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
    • B01J20/3253—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such comprising a cyclic structure not containing any of the heteroatoms nitrogen, oxygen or sulfur, e.g. aromatic structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3285—Coating or impregnation layers comprising different type of functional groups or interactions, e.g. different ligands in various parts of the sorbent, mixed mode, dual zone, bimodal, multimodal, ionic or hydrophobic, cationic or anionic, hydrophilic or hydrophobic
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/416—Systems
    • G01N27/447—Systems using electrophoresis
    • G01N27/44704—Details; Accessories
    • G01N27/44747—Composition of gel or of carrier mixture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/54—Sorbents specially adapted for analytical or investigative chromatography

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Molecular Biology (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Biochemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Electrostatic Separation (AREA)

Abstract

Separation devices and systems are described which have a stationary phase and a mobile phase, wherein the stationary phase contains carbonaceous material having attached at least one organic group. The stationary phase which is used in the present invention has the ability to dial in the selectivity by attaching the proper organic groups onto the carbonaceous material in order to achieve the desired separation. Various separation processes are described such as chromatography, electrophoresis, magnetic separations, membrane separations, and the like. The processes to accomplish these types of separations are also described.
PCT/US2001/027347 2000-09-01 2001-08-31 Chromatography and other adsorptions using modified carbon adsorbents WO2002018929A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA002421517A CA2421517A1 (en) 2000-09-01 2001-08-31 Chromatography and other adsorptions using modified carbon adsorbents
EP01968422A EP1314026A2 (en) 2000-09-01 2001-08-31 Chromatography and other adsorptions using modified carbon adsorbents
JP2002523599A JP2004522142A (en) 2000-09-01 2001-08-31 Chromatography and other adsorption methods using modified carbonaceous adsorbents
AU2001288672A AU2001288672A1 (en) 2000-09-01 2001-08-31 Chromatography and other adsorptions using modified carbon adsorbents

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US65418200A 2000-09-01 2000-09-01
US09/654,182 2000-09-01

Publications (2)

Publication Number Publication Date
WO2002018929A2 WO2002018929A2 (en) 2002-03-07
WO2002018929A3 true WO2002018929A3 (en) 2002-10-31

Family

ID=24623790

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/027347 WO2002018929A2 (en) 2000-09-01 2001-08-31 Chromatography and other adsorptions using modified carbon adsorbents

Country Status (5)

Country Link
EP (1) EP1314026A2 (en)
JP (1) JP2004522142A (en)
AU (1) AU2001288672A1 (en)
CA (1) CA2421517A1 (en)
WO (1) WO2002018929A2 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002024310A1 (en) * 2000-09-20 2002-03-28 Chevron U.S.A. Inc. Mixed matrix membranes with pyrolized carbon sieve particles and methods of making and using the same
US7250147B2 (en) 2001-01-29 2007-07-31 Tour James M Process for derivatizing carbon nanotubes with diazonium species
WO2005092013A2 (en) * 2004-03-19 2005-10-06 Perkinelmer Las, Inc. Separations platform based upon electroosmosis-driven planar chromatography
JP5389342B2 (en) * 2007-08-09 2014-01-15 デンカ生研株式会社 Adsorption carrier and production method of adsorption carrier
EP2570181A1 (en) * 2011-09-15 2013-03-20 InstrAction GmbH Sorbent comprising its surface an aliphatic unit having an anionic or deprotonizable group for the purfication of organic molecules
EP2570185A1 (en) * 2011-09-15 2013-03-20 InstrAction GmbH Sorbent comprising an aromatic ring system on its surface for the purification of organic molecules
EP2570184A1 (en) * 2011-09-15 2013-03-20 InstrAction GmbH Sorbent comprising on its surface an aromatic ring system having an anionic or deprotonizable group for the purification of organic molecules
JP5961395B2 (en) * 2012-02-03 2016-08-02 株式会社ブリヂストン Natural rubber, method for producing the same, rubber composition, and tire
US11253839B2 (en) 2014-04-29 2022-02-22 Archer-Daniels-Midland Company Shaped porous carbon products
RU2016145854A (en) 2014-04-29 2018-05-30 Ренновия Инк. FORMED POROUS PRODUCTS BASED ON CARBON SOOT
WO2017027796A1 (en) * 2015-08-13 2017-02-16 Waters Technologies Corporation Nickel-cobalt alloy material devices and components
US10722867B2 (en) 2015-10-28 2020-07-28 Archer-Daniels-Midland Company Porous shaped carbon products
US10464048B2 (en) 2015-10-28 2019-11-05 Archer-Daniels-Midland Company Porous shaped metal-carbon products
CN108939880B (en) * 2018-06-15 2021-07-02 华南理工大学 A kind of formaldehyde scavenger and preparation method thereof
CN110441454B (en) * 2019-08-14 2021-07-23 国家烟草质量监督检验中心 Method for measuring cis-trans isomer of metoclopramide
CN115551824A (en) 2020-05-18 2022-12-30 阿彻丹尼尔斯米德兰公司 Process for the hydrogenolysis of glycerol
EP4213986A1 (en) * 2020-09-16 2023-07-26 Waters Technologies Corporation A sorbent used to improve chromatographic separations in size exclusion chromatography via reduced secondary interactions

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5841351A (en) * 1981-09-04 1983-03-10 Hiroshi Takahashi Filler for liquid chromatography column
EP0300448A2 (en) * 1987-07-21 1989-01-25 Mitsubishi Kasei Corporation Separation medium
JPH02193066A (en) * 1989-01-20 1990-07-30 Osaka Gas Co Ltd Column packing agent for liquid chromatography
WO1991004095A1 (en) * 1989-09-15 1991-04-04 Sandoval Junior E Stable, covalently-bonded supports for chemical separation apparatus made through a hydride intermediate
JPH04346830A (en) * 1991-05-23 1992-12-02 Tonen Corp Packing material for chromatography
US5264137A (en) * 1990-09-11 1993-11-23 The Dow Chemical Company Method for separating fluids using a carbonaceous polymeric filter having a LOI greater than 40
EP0635301A2 (en) * 1990-03-22 1995-01-25 Regents Of The University Of Minnesota Carbon-clad inorganic oxide particles with a polymer coating thereon
WO1996018456A2 (en) * 1994-12-15 1996-06-20 Cabot Corporation Gel composition containing carbonaceous compound
WO1997047382A1 (en) * 1996-06-14 1997-12-18 Cabot Corporation Modified carbon adsorbents and processes for adsorption using the same
DE10024312A1 (en) * 2000-01-17 2001-07-26 Fraunhofer Ges Forschung Process for modifying the surfaces of fine porous adsorbents

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5841351A (en) * 1981-09-04 1983-03-10 Hiroshi Takahashi Filler for liquid chromatography column
EP0300448A2 (en) * 1987-07-21 1989-01-25 Mitsubishi Kasei Corporation Separation medium
JPH02193066A (en) * 1989-01-20 1990-07-30 Osaka Gas Co Ltd Column packing agent for liquid chromatography
WO1991004095A1 (en) * 1989-09-15 1991-04-04 Sandoval Junior E Stable, covalently-bonded supports for chemical separation apparatus made through a hydride intermediate
EP0635301A2 (en) * 1990-03-22 1995-01-25 Regents Of The University Of Minnesota Carbon-clad inorganic oxide particles with a polymer coating thereon
US5264137A (en) * 1990-09-11 1993-11-23 The Dow Chemical Company Method for separating fluids using a carbonaceous polymeric filter having a LOI greater than 40
JPH04346830A (en) * 1991-05-23 1992-12-02 Tonen Corp Packing material for chromatography
WO1996018456A2 (en) * 1994-12-15 1996-06-20 Cabot Corporation Gel composition containing carbonaceous compound
WO1997047382A1 (en) * 1996-06-14 1997-12-18 Cabot Corporation Modified carbon adsorbents and processes for adsorption using the same
DE10024312A1 (en) * 2000-01-17 2001-07-26 Fraunhofer Ges Forschung Process for modifying the surfaces of fine porous adsorbents

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 198316, Derwent World Patents Index; Class J04, AN 1983-37697K, XP002192134 *
DATABASE WPI Section Ch Week 199036, Derwent World Patents Index; Class J04, AN 1990-272346, XP002192133 *
PATENT ABSTRACTS OF JAPAN vol. 017, no. 200 (C - 1050) 20 April 1993 (1993-04-20) *

Also Published As

Publication number Publication date
WO2002018929A2 (en) 2002-03-07
EP1314026A2 (en) 2003-05-28
AU2001288672A1 (en) 2002-03-13
JP2004522142A (en) 2004-07-22
CA2421517A1 (en) 2002-03-07

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