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WO2002004538A3 - Anionic waterborne polyurethane dispersions containing polyfluorooxetanes - Google Patents

Anionic waterborne polyurethane dispersions containing polyfluorooxetanes Download PDF

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Publication number
WO2002004538A3
WO2002004538A3 PCT/US2001/019725 US0119725W WO0204538A3 WO 2002004538 A3 WO2002004538 A3 WO 2002004538A3 US 0119725 W US0119725 W US 0119725W WO 0204538 A3 WO0204538 A3 WO 0204538A3
Authority
WO
WIPO (PCT)
Prior art keywords
polyfluorooxetanes
polymers
polymer
waterborne polyurethane
polyurethane dispersions
Prior art date
Application number
PCT/US2001/019725
Other languages
French (fr)
Other versions
WO2002004538A8 (en
WO2002004538A2 (en
Inventor
Garcia C Guillermina
Raymond J Weinert
Pamela L Cadile
Rodney Cuevas
Original Assignee
Omnova Solutions Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/610,743 external-priority patent/US6465565B1/en
Application filed by Omnova Solutions Inc filed Critical Omnova Solutions Inc
Priority to BR0112219A priority Critical patent/BR0112219A/en
Priority to EP20010948526 priority patent/EP1297047B1/en
Priority to DE2001624548 priority patent/DE60124548T2/en
Priority to MXPA02012667A priority patent/MXPA02012667A/en
Priority to JP2002509396A priority patent/JP2004502844A/en
Publication of WO2002004538A2 publication Critical patent/WO2002004538A2/en
Publication of WO2002004538A8 publication Critical patent/WO2002004538A8/en
Publication of WO2002004538A3 publication Critical patent/WO2002004538A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
    • C08G18/3804—Polyhydroxy compounds
    • C08G18/3812—Polyhydroxy compounds having fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
    • C08G18/4607—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen having halogens
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Medicinal Preparation (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)

Abstract

Anionic waterborne polyurethane dispersions are formed in the presence of polyfluorooxetane oligomers, polymers, or copolymers so that the polyfluorooxetanes are incorporated in the polyurethane. Coatings made from such polyurethanes have good low temperature flexibility, good chemical resistance, stain resistance, and abrasion resistance, as well as a low coefficient of friction. Alternatively, the anionic water borne polyurethane dispersion can be blended with vinyl ester monomers such as various acrylates and subsequently polymerized by radiation, for example ultraviolet light, to form a comingled blend of at least two different types of polymers. Another embodiment relates to a preformed copolymer made by reacting the polyfluorooxetane oligomer, polymer, or copolymer with a polycarboxylic acid such as a dicarboxylic acid and subsequently reacting the same with a polyol intermediate, such as a polymer, or with monomers forming the polyol intermediate.
PCT/US2001/019725 2000-07-06 2001-06-20 Anionic waterborne polyurethane dispersions containing polyfluorooxetanes WO2002004538A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BR0112219A BR0112219A (en) 2000-07-06 2001-06-20 Waterborne polyurethane dispersion, composition, laminate, process for forming a urethane polyester, waterborne polyurethane, coating, and process for making a waterborne polyurethane dispersion
EP20010948526 EP1297047B1 (en) 2000-07-06 2001-06-20 Anionic waterborne polyurethane dispersions containing polyfluorooxetanes
DE2001624548 DE60124548T2 (en) 2000-07-06 2001-06-20 AQUEOUS POLYURETHANE ISOLATIONS CONTAINING POLYFLUOROXETANE
MXPA02012667A MXPA02012667A (en) 2000-07-06 2001-06-20 Anionic waterborne polyurethane dispersions containing polyfluorooxetanes.
JP2002509396A JP2004502844A (en) 2000-07-06 2001-06-20 Anionic aqueous polyurethane dispersion containing polyfluorooxetane

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US09/610,743 US6465565B1 (en) 2000-07-06 2000-07-06 Anionic waterborne polyurethane dispersions containing polyfluorooxetanes
US09/610,743 2000-07-06
US09/833,383 US6465566B2 (en) 2000-07-06 2001-04-12 Anionic waterborne polyurethane dispersions containing polyfluorooxetanes
US09/833,383 2001-04-12

Publications (3)

Publication Number Publication Date
WO2002004538A2 WO2002004538A2 (en) 2002-01-17
WO2002004538A8 WO2002004538A8 (en) 2002-02-21
WO2002004538A3 true WO2002004538A3 (en) 2002-08-22

Family

ID=27086342

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/019725 WO2002004538A2 (en) 2000-07-06 2001-06-20 Anionic waterborne polyurethane dispersions containing polyfluorooxetanes

Country Status (8)

Country Link
US (1) US6465566B2 (en)
EP (1) EP1297047B1 (en)
JP (1) JP2004502844A (en)
AT (1) ATE345358T1 (en)
BR (1) BR0112219A (en)
DE (1) DE60124548T2 (en)
MX (1) MXPA02012667A (en)
WO (1) WO2002004538A2 (en)

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Also Published As

Publication number Publication date
US6465566B2 (en) 2002-10-15
MXPA02012667A (en) 2003-05-14
WO2002004538A8 (en) 2002-02-21
WO2002004538A2 (en) 2002-01-17
BR0112219A (en) 2003-05-06
EP1297047A2 (en) 2003-04-02
JP2004502844A (en) 2004-01-29
DE60124548D1 (en) 2006-12-28
US20020026006A1 (en) 2002-02-28
ATE345358T1 (en) 2006-12-15
EP1297047B1 (en) 2006-11-15
DE60124548T2 (en) 2007-05-24

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