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WO2002066370A3 - Reforming catalysts and methods of alcohol steam reforming - Google Patents

Reforming catalysts and methods of alcohol steam reforming Download PDF

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Publication number
WO2002066370A3
WO2002066370A3 PCT/US2002/004527 US0204527W WO02066370A3 WO 2002066370 A3 WO2002066370 A3 WO 2002066370A3 US 0204527 W US0204527 W US 0204527W WO 02066370 A3 WO02066370 A3 WO 02066370A3
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WO
WIPO (PCT)
Prior art keywords
reforming
methods
catalysts
alcohol steam
steam reforming
Prior art date
Application number
PCT/US2002/004527
Other languages
French (fr)
Other versions
WO2002066370A2 (en
Inventor
Yong Wang
Anna Lee Y Tonkovich
Jianli Hu
Ya-Huei Chin
Robert A Dagle
Chunshe Cao
Original Assignee
Battelle Memorial Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/788,294 external-priority patent/US6936237B2/en
Priority claimed from US10/076,881 external-priority patent/US7335346B2/en
Application filed by Battelle Memorial Institute filed Critical Battelle Memorial Institute
Publication of WO2002066370A2 publication Critical patent/WO2002066370A2/en
Publication of WO2002066370A3 publication Critical patent/WO2002066370A3/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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    • B01J2219/00819—Materials of construction
    • B01J2219/00835—Comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
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    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
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    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
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    • C01B2203/1041—Composition of the catalyst
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    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
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    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
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    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
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    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1094—Promotors or activators
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    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
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    • C01B2203/1217—Alcohols
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    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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    • C01B2203/1223—Methanol
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    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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    • C01B2203/1205—Composition of the feed
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    • C01B2203/1247—Higher hydrocarbons
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    • C01B2203/1288—Evaporation of one or more of the different feed components
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    • C01B2203/16—Controlling the process
    • C01B2203/1614—Controlling the temperature
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    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
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    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)

Abstract

The present invention provides catalysts, reactors, and methods of steam reforming alcohols over a catalyst. Surprisingly superior results and properties obtained in methods and catalysts of the present invention are also described.
PCT/US2002/004527 2001-02-16 2002-02-15 Reforming catalysts and methods of alcohol steam reforming WO2002066370A2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/788,294 US6936237B2 (en) 1999-08-17 2001-02-16 Reforming catalysts and methods of alcohol steam reforming
US09/788,294 2001-02-16
US10/076,881 US7335346B2 (en) 1999-08-17 2002-02-13 Catalyst and method of steam reforming

Publications (2)

Publication Number Publication Date
WO2002066370A2 WO2002066370A2 (en) 2002-08-29
WO2002066370A3 true WO2002066370A3 (en) 2003-04-03

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WO (1) WO2002066370A2 (en)

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Publication number Priority date Publication date Assignee Title
WO2005030390A1 (en) * 2003-05-07 2005-04-07 Battelle Memorial Institute Alcohol steam reforming catalysts and methods of alcohol steam reforming
US7208136B2 (en) 2003-05-16 2007-04-24 Battelle Memorial Institute Alcohol steam reforming catalysts and methods of alcohol steam reforming
KR20060080385A (en) * 2005-01-05 2006-07-10 삼성에스디아이 주식회사 Fuel Cell System, Reformer, Reaction Board and Manufacturing Method of Reaction Board
JP4654083B2 (en) * 2005-07-20 2011-03-16 富士フイルム株式会社 METAL PARTICLE TYPE REACTION CATALYST, PROCESS FOR PRODUCING THE SAME, AND ORGANIC SYNTHETIC REACTION DEVICE USING THE CATALYST
JP4769595B2 (en) 2005-08-12 2011-09-07 富士フイルム株式会社 Polymer, film-forming composition containing the polymer, insulating film and electronic device formed using the composition
WO2007029872A2 (en) 2005-09-08 2007-03-15 Casio Computer Co., Ltd. Reformer for power supply of a portable electronic device
EP2216093A1 (en) * 2009-01-30 2010-08-11 Corning Incorporated In situ formation and deposition of palladium Pd(0) in reactors
CN114984864B (en) * 2022-05-05 2023-09-01 华东理工大学 High-energy-efficiency low-carbon-emission internal electric heating fixed bed hydrogen production reactor

Citations (3)

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Publication number Priority date Publication date Assignee Title
JPS6082137A (en) * 1983-10-14 1985-05-10 Mitsubishi Heavy Ind Ltd Reforming catalyst of methanol
EP0278749A1 (en) * 1987-02-12 1988-08-17 Ngk Insulators, Ltd. Cordierite honeycomb-structural body and a method for producing the same
EP1063011A1 (en) * 1999-05-22 2000-12-27 Degussa-Hüls Aktiengesellschaft Catalyst for the steam reforming of alcohols

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6082137A (en) * 1983-10-14 1985-05-10 Mitsubishi Heavy Ind Ltd Reforming catalyst of methanol
EP0278749A1 (en) * 1987-02-12 1988-08-17 Ngk Insulators, Ltd. Cordierite honeycomb-structural body and a method for producing the same
EP1063011A1 (en) * 1999-05-22 2000-12-27 Degussa-Hüls Aktiengesellschaft Catalyst for the steam reforming of alcohols

Non-Patent Citations (3)

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Title
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