WO2001096506A1 - Procede servant a produire de la graisse - Google Patents
Procede servant a produire de la graisse Download PDFInfo
- Publication number
- WO2001096506A1 WO2001096506A1 PCT/JP2001/004880 JP0104880W WO0196506A1 WO 2001096506 A1 WO2001096506 A1 WO 2001096506A1 JP 0104880 W JP0104880 W JP 0104880W WO 0196506 A1 WO0196506 A1 WO 0196506A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oil
- fats
- ascorbic acid
- oils
- fat
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 9
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 142
- 239000003925 fat Substances 0.000 claims abstract description 108
- 229960005070 ascorbic acid Drugs 0.000 claims abstract description 67
- 235000010323 ascorbic acid Nutrition 0.000 claims abstract description 66
- 239000011668 ascorbic acid Substances 0.000 claims abstract description 66
- 239000000787 lecithin Substances 0.000 claims abstract description 31
- 235000010445 lecithin Nutrition 0.000 claims abstract description 31
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims abstract description 30
- 229940067606 lecithin Drugs 0.000 claims abstract description 30
- 150000007524 organic acids Chemical class 0.000 claims abstract description 20
- 239000007864 aqueous solution Substances 0.000 claims abstract description 17
- 239000003921 oil Substances 0.000 claims description 114
- 235000019197 fats Nutrition 0.000 claims description 101
- 239000002253 acid Substances 0.000 claims description 23
- 238000004519 manufacturing process Methods 0.000 claims description 12
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 claims description 10
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 claims description 10
- 235000005487 catechin Nutrition 0.000 claims description 10
- 229950001002 cianidanol Drugs 0.000 claims description 10
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 claims description 8
- 235000010350 erythorbic acid Nutrition 0.000 claims description 8
- 239000004318 erythorbic acid Substances 0.000 claims description 8
- 229940026239 isoascorbic acid Drugs 0.000 claims description 8
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 7
- 235000020778 linoleic acid Nutrition 0.000 claims description 7
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 claims description 7
- 235000014593 oils and fats Nutrition 0.000 claims description 7
- 230000018044 dehydration Effects 0.000 claims description 4
- 238000006297 dehydration reaction Methods 0.000 claims description 4
- 229960004232 linoleic acid Drugs 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 239000000796 flavoring agent Substances 0.000 abstract description 63
- 235000019634 flavors Nutrition 0.000 abstract description 63
- 239000000203 mixture Substances 0.000 abstract description 20
- 230000006866 deterioration Effects 0.000 abstract description 13
- 238000010438 heat treatment Methods 0.000 abstract description 9
- 235000013305 food Nutrition 0.000 abstract description 5
- 235000019198 oils Nutrition 0.000 description 103
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 25
- 235000010384 tocopherol Nutrition 0.000 description 25
- 229960001295 tocopherol Drugs 0.000 description 25
- 229930003799 tocopherol Natural products 0.000 description 25
- 239000011732 tocopherol Substances 0.000 description 25
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 25
- 238000011156 evaluation Methods 0.000 description 24
- 235000012424 soybean oil Nutrition 0.000 description 22
- 239000003549 soybean oil Substances 0.000 description 22
- 238000012360 testing method Methods 0.000 description 21
- 239000000047 product Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 16
- 238000003756 stirring Methods 0.000 description 15
- 229940088594 vitamin Drugs 0.000 description 12
- 229930003231 vitamin Natural products 0.000 description 12
- 230000000694 effects Effects 0.000 description 9
- 235000000072 L-ascorbyl-6-palmitate Nutrition 0.000 description 8
- 239000011786 L-ascorbyl-6-palmitate Substances 0.000 description 8
- QAQJMLQRFWZOBN-LAUBAEHRSA-N L-ascorbyl-6-palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](O)[C@H]1OC(=O)C(O)=C1O QAQJMLQRFWZOBN-LAUBAEHRSA-N 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 8
- 235000006708 antioxidants Nutrition 0.000 description 8
- 235000019484 Rapeseed oil Nutrition 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 235000016746 Heteromeles arbutifolia var arbutifolia Nutrition 0.000 description 6
- 235000016747 Heteromeles arbutifolia var macrocarpa Nutrition 0.000 description 6
- 244000236947 Photinia arbutifolia Species 0.000 description 6
- 235000012847 Photinia arbutifolia var cerina Nutrition 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 240000007594 Oryza sativa Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 230000002542 deteriorative effect Effects 0.000 description 4
- -1 lipid peroxide Chemical class 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 208000005156 Dehydration Diseases 0.000 description 3
- 238000003556 assay Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 235000010199 sorbic acid Nutrition 0.000 description 3
- 229940075582 sorbic acid Drugs 0.000 description 3
- 239000004334 sorbic acid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 235000013601 eggs Nutrition 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 229940093915 gynecological organic acid Drugs 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000011002 quantification Methods 0.000 description 2
- 235000005713 safflower oil Nutrition 0.000 description 2
- 239000003813 safflower oil Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000005809 transesterification reaction Methods 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000002211 L-ascorbic acid Substances 0.000 description 1
- 235000000069 L-ascorbic acid Nutrition 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 230000003631 expected effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 239000005417 food ingredient Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 235000019629 palatability Nutrition 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 230000003244 pro-oxidative effect Effects 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B5/00—Preserving by using additives, e.g. anti-oxidants
- C11B5/0021—Preserving by using additives, e.g. anti-oxidants containing oxygen
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings or cooking oils
- A23D9/007—Other edible oils or fats, e.g. shortenings or cooking oils characterised by ingredients other than fatty acid triglycerides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings or cooking oils
- A23D9/02—Other edible oils or fats, e.g. shortenings or cooking oils characterised by the production or working-up
Definitions
- the present invention relates to a method for producing fats and oils, and more particularly to frying fats and oils having improved heat odor and heat deterioration odor and frying fats and oils having improved lecithin odor.
- ascorbic acid is a synergist with excellent antioxidant properties.
- P.68 describes ascorbic acid as follows: "Ascorbic acid is mentioned above. Judging from the poor solubility in oil, the tendency to cause thermal decomposition, and the fact that little chelating effect can be expected for metals, it is not suitable for preventing the oxidation of frying oil in liquid vegetable oils and the like. Care must be taken in such cases, as they may act as pro-oxidants. "Ascorbic acid is mentioned above. Judging from the poor solubility in oil, the tendency to cause thermal decomposition, and the fact that little chelating effect can be expected for metals, it is not suitable for preventing the oxidation of frying oil in liquid vegetable oils and the like. Care must be taken in such cases, as they may act as pro-oxidants. "
- lecithin has a unique flavor, which increases the flavor applied when heated and adversely affects the flavor of the product, limiting its use.
- lecithin can be treated with enzymes or purified to high purity. There have been proposals such as separation and fractionation, but in all cases, the cost will be significantly higher than that of crude lecithin. Disclosure of the invention
- An object of the present invention is to make a fat and oil easily contain an oil or fat insoluble organic acid such as ascorbic acid, to improve the heating odor of the frying fat, and to improve the heat deterioration odor of the frying product.
- Another object of the present invention is to provide a stir-fat with improved lecithin odor.
- the present inventors have conducted intensive studies to solve the above-mentioned problems, and as a result, at least one organic acid selected from ascorbic acid, erythorbic acid, and linoleic acid in the form of an aqueous solution.
- Ascorbic acid is easily oxidized and thermally decomposed in water in terms of its tendency to thermally decompose, but surprisingly, it was found that ascorbic acid can stably exist in non-aqueous fats and oils. It has been confirmed that it can be used as an antioxidant.
- At least one organic acid selected from ascorbic acid, erythorbic acid and linoleic acid is added to oils and fats in the form of an aqueous solution at 50 to 180 ° C.
- a method for producing fats and oils which is characterized by dehydration under reduced pressure of 5 to 100 Torr, and fats and oils for frying produced by the method, and further adding lecithin to the fats and oils.
- the organic acid used in the present invention is preferably ascorbic acid, erythorbic acid, or linoleic acid. These organic acids may be those commonly used for foods and pharmaceuticals or may be used alone. However, two or more kinds may be used in combination.
- the amount of the organic acid is preferably 2 to 28 ppm in the fat or oil. If the amount of the organic acid is less than 2 ppm, the expected effect cannot be obtained. Also, if an attempt is made to add an amount of an organic acid exceeding 28 ppm to fats and oils, it is unfortunate that organic acid crystals precipitate and are contained in fats and oils.
- oils and fats used in the present invention include soybean oil, rapeseed oil, corn oil, cottonseed oil, peanut oil, sunflower oil, rice oil, safflower oil, safflower oil, olive oil, sesame oil, palm oil, and coconut oil.
- Vegetable oils such as palm kernel oil, animal fats such as beef tallow, lard, and processed oils that have been subjected to separation, hydrogenation, transesterification, etc., or in combination. It is also good, but especially in the case of soybean oil or rapeseed oil, the effect of suppressing deterioration odor is great.
- an oil or fat containing the organic acid of the present invention for example, in order to obtain an oil or fat containing ascorbic acid, 1% oil or fat is heated to 70 ° C. A prescribed amount of an aqueous solution of scorbic acid is added, and at 50 to 180 ° C and 0.5 to: Treatment is performed for 15 minutes to 1 hour while stirring under reduced pressure of LOOT orr to sufficiently dehydrate Thus, an oil or fat containing ascorbic acid can be obtained.
- the concentration of the aqueous solution of ascorbic acid can be 0.1 to 22%, preferably 1 to 10%. If the amount is less than the lower limit, the amount of water with respect to fats and oils increases, resulting in poor efficiency.
- the pressure can be reduced under a condition of 0.5 to 100 Torr, and the lower pressure is preferably as low as possible.
- the effect of improving the heating odor of oils and fats containing at least one organic acid selected from among asconolebic acid, elisonolevic acid and lingoic acid is as follows: extracted tocopherol, ascorbic acid palmitate, It can be increased by using it in combination with other antioxidants such as catechin. These antioxidants can be easily contained in fats and oils simply by adding them to fats and oils. That is, 2 to 28 ppm of organic acid and extraction It is preferable to contain at least one of coferonore, vasconorelenoic acid norremitate, catechin, and 10 to 2000 ppm.
- the fats and oils obtained by the production method of the present invention are suitable for frying, which has a high chance of coming into contact with oxygen at high temperatures.
- Organic acids are uniformly dissolved and dispersed in oils and fats to prevent oxidation due to the effect of improving the heating odor of oils and fats for frying and the heat deterioration odor of frying products when the amount of organic acid is as small as 2 to 28 ppm. It is inferred that the efficiency of the effect has been enhanced.
- Lecithin may be lecithin that has been subjected to any of enzymatic treatment, hydrogenation treatment, fractionation treatment, etc., but it is particularly advantageous to use crowded lecithin because it is inexpensive.
- the amount of lecithin to be added is 0.05 to 5% by weight, preferably 0.2 to 3% by weight, based on the amount of fats and oils.
- other emulsifiers can be used in addition to these lecithins.
- Ascorbic acid manufactured by Wako Pure Chemical Industries, Ltd., trade name: L-ascorbic acid, purity: 99.5%
- Eri sorbic acid manufactured by Wako Pure Chemical Industries, Ltd., trade name: eri sorbic acid, purity: 97.0%)
- Lingoic acid (Wako Pure Chemical Industries, Ltd., trade name: Lingoic acid, purity 97.0%)
- Extracted tocopherol (manufactured by Riken Vitamin Co., Ltd., trade name: E oil 805D, extracted tocopherol 70%, vegetable-oil 30%)
- Ascorbic acid palmitate manufactured by Riken Vitamin Co., Ltd., trade name: EC—100, ascorbic acid panolemitate 10%, extracted tocoffe mouth 10%, glycerin fatty acid ester 51 1) %, Food ingredients 29%)
- Catechin (manufactured by Taiyo Kagaku Co., Ltd., trade name: Sankyotoru, catechin 10%, extracted tocopherol 9%, glycerin fatty acid ester 64%, food material 17%)
- Table 1 summarizes the flavor evaluation of the fats and oils for frying of Examples 1 to 4.
- Example 1 Example 2 Example 3 Example 4 Soybean oil 100 parts 100 parts 100 parts 100 parts 100 parts ascorbic acid 10.4 ppm 2.9 ppm 7.6 ppm 14.5 ppm Average score 4.2 3.1 3 4 4.3 Overall judgment ⁇ ⁇ ⁇ ⁇ Comparative Example 1
- Example 2 The same frying test as in Example 1 was performed with only 100 parts by weight of soybean oil and no addition. When the flavor of the fried croquettes was evaluated, the average evaluation score was 1.2 and the flavor felt a very deteriorating odor.
- soybean oil To 100 parts by weight of soybean oil was added 0.1 parts by weight of extracted tocohue jar (trade name: E-oil 805D, manufactured by Riken Vitamin Co., Ltd.) to extract the extracted tocofunirole-containing fat and oil. They were fabricated and fly-tested. When the flavor of the fried croquettes was evaluated, the average evaluation score was 1.3 and the flavor felt a very deteriorating odor.
- extracted tocohue jar trade name: E-oil 805D, manufactured by Riken Vitamin Co., Ltd.
- Table 2 summarizes the flavor evaluation of the frying fats of Comparative Examples 1 to 4.
- Example 6 0.015 parts by weight (product name: E-oil 805D, manufactured by Riken Vitamin Co., Ltd.) was added to prepare ascorbic acid 'extracted tocopherol-containing oils and fats, and subjected to frying test. When the flavor of the fried croquettes was evaluated, the evaluation average point was 3.6 and the flavor was good.
- E-oil 805D manufactured by Riken Vitamin Co., Ltd.
- 0.1 parts by weight of a 1% aqueous scorbic acid solution was added to 10 parts by weight of soybean oil heated to 70 ° C and mixed, and the mixture was mixed at 70 ° C and a reduced pressure of 40 Torr. Dewatering treatment was performed for 20 minutes while stirring. Thereafter, the mixture was filtered through TOYON o.5C filter paper (corresponding to 1 ⁇ m) to obtain an ascorbic acid-containing oil and fat. To this oil and fat, 0.015 parts by weight of ascorbic acid / ascorbic acid palmitate 'extracted tocophere' (trade name: EC-100, manufactured by Riken Vitamin Co., Ltd.) was added.
- Table 3 summarizes the flavor evaluations of the fats and oils for frying of Examples 5 to 10.
- Example 8 Example 9 Example 10 Soybean oil 100 parts 100 parts 100 parts Ascorbic acid 7.4 ppm 7.5 ppm 7.6 ppm Tocopherol extracted 150 ppm 14 ppm 135 ppm Ascorbic acid palmitate 150 ppm
- Example 13 0.1 parts by weight of linoleic acid-extracted tocopherol (manufactured by Riken Vitamin Co., Ltd., trade name: E-oil 805D) was added to this oil and fat to add the linoleic acid-extracted tocopherol-containing oil and fat. It was prepared and subjected to a frit test. The flavor of the fried croquettes was evaluated, and the average evaluation score was 3.2, indicating that the flavor was good.
- linoleic acid-extracted tocopherol manufactured by Riken Vitamin Co., Ltd., trade name: E-oil 805D
- Example 11 A fly test similar to that of Example 11 was performed without adding anything in only 100 parts by weight of rapeseed oil. When the flavor of the fried croquettes was evaluated, the average evaluation score was 1.2 and the flavor felt a very deteriorating odor. Table 4 summarizes the flavor evaluations of the fats and oils for fly of Examples 11 to 14 and Comparative Example 5.
- Rapeseed oil 100 parts 100 parts
- test oil 5 g was put in an iron frying pan, heated by an induction cooker, poured 40 g of melted eggs, and the number of thinly baked eggs continuously burned without being scorched was compared. At the same time, the flavor was evaluated during heating of the fat.
- test fats and oils are shown in Table 5, and the fats and oils containing ascorbic acid were obtained by the methods of Examples 1 and 2. The presence or absence of ascorbic acid and the presence or absence of lecithin were examined.
- Flavor evaluation ⁇ : No lecithin odor, ⁇ : Almost no lecithin odor, ⁇ : Feel lecithin odor, X: Lecithin odor strongly felt,
- Table 5 summarizes the results of Examples 15 to 17 and Comparative Examples 6 to 9.
- a acid ascorbic acid
- Examples 15 to 17 and Comparative Examples 6 to 9 were subjected to a stir-fry test using the same fats and oils.
- Table 6 summarizes the results of Examples 18 to 20 and Comparative Examples 10 to 13.
- a fat and oil for frying which improves the heating odor of the fat and oil for frying and the heat-deteriorating odor of the frying product, and a good-tasting fat and oil which is non-burnt and excellent in releasability. I can do it.
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Edible Oils And Fats (AREA)
Abstract
Procédé permettant d'incorporer sans difficulté dans de la graisse un acide organique peu soluble dans les graisses, tel qu'acide ascorbique. Graisse servant à frire des aliments, ce qui produit peu d'odeurs au réchauffement, ainsi que sous l'effet de la dégradation thermique. Graisse servant à faire sauter des aliments, tout en évitant de les brûler et qui possède d'excellentes propriétés de détachement et un goût satisfaisant. On ajoute un acide organique sous forme de solution aqueuse à la graisse et on déshydrate ce mélange entre 50 et 180 °C, à une pression limitée de 0,5 à 100 Torr. On ajoute, de plus, de la lécithine à ce mélange. On obtient une graisse de friture exempte de l'odeur de la lécithine.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002510626A JP5168749B2 (ja) | 2000-06-12 | 2001-06-08 | 油脂の製造法 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000-174647 | 2000-06-12 | ||
JP2000174647 | 2000-06-12 | ||
JP2001-15432 | 2001-01-24 | ||
JP2001015432 | 2001-01-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001096506A1 true WO2001096506A1 (fr) | 2001-12-20 |
Family
ID=26593713
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2001/004880 WO2001096506A1 (fr) | 2000-06-12 | 2001-06-08 | Procede servant a produire de la graisse |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP5168749B2 (fr) |
CN (1) | CN1298825C (fr) |
WO (1) | WO2001096506A1 (fr) |
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JP2008167685A (ja) * | 2007-01-11 | 2008-07-24 | Fuji Oil Co Ltd | 風味付けされた油脂の製造法 |
WO2010109737A1 (fr) * | 2009-03-27 | 2010-09-30 | 日清オイリオグループ株式会社 | Huile et matière grasse de cuisson comestibles et leur procédé de préparation |
WO2011122339A1 (fr) * | 2010-03-29 | 2011-10-06 | 株式会社J-オイルミルズ | Composition d'huile et de graisse pour friture |
JP2012201771A (ja) * | 2011-03-25 | 2012-10-22 | Fuji Oil Co Ltd | 有機酸及び/又はその塩類を含有する油脂の製造方法 |
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JPWO2011102477A1 (ja) * | 2010-02-18 | 2013-06-17 | 不二製油株式会社 | 呈味強化用油脂ならびに呈味含有含油食品の呈味を強化する方法 |
WO2013172348A1 (fr) | 2012-05-16 | 2013-11-21 | 不二製油株式会社 | Huile ou graisse comestible, aliment la contenant, et son procédé de fabrication |
JP2014103908A (ja) * | 2012-11-28 | 2014-06-09 | Riken Vitamin Co Ltd | ミネラル類、ビタミンeおよび乳化剤を含有する飲食品の風味劣化抑制方法 |
WO2015005128A1 (fr) * | 2013-07-09 | 2015-01-15 | 不二製油株式会社 | Confiserie congelée et huile et graisse pour produire cette confiserie |
JP2015015907A (ja) * | 2013-07-09 | 2015-01-29 | 不二製油株式会社 | 冷菓用油脂 |
JP2015033335A (ja) * | 2013-08-08 | 2015-02-19 | 不二製油株式会社 | 製菓用油脂及びそれを利用した食品 |
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JP2016152782A (ja) * | 2015-02-20 | 2016-08-25 | 日本食研ホールディングス株式会社 | 食用オイルソース |
WO2017150558A1 (fr) | 2016-03-02 | 2017-09-08 | 不二製油グループ本社株式会社 | Composition de graisse ou d'huile présentant des propriétés anti-oxydation |
JP2018070887A (ja) * | 2011-11-01 | 2018-05-10 | ディーエスエム アイピー アセッツ ビー.ブイ. | 酸化安定性多価不飽和脂肪酸を含有する油 |
WO2019187242A1 (fr) | 2018-03-28 | 2019-10-03 | 不二製油グループ本社株式会社 | Composition de matière grasse |
KR20210038582A (ko) | 2018-08-09 | 2021-04-07 | 후지세유 그룹 혼샤 가부시키가이샤 | 유지 조성물 |
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JP4095111B1 (ja) * | 2007-08-29 | 2008-06-04 | 株式会社J−オイルミルズ | 加熱耐性に優れた揚げ物用油脂組成物の製造方法 |
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JP6758754B2 (ja) * | 2016-04-19 | 2020-09-23 | 日清オイリオグループ株式会社 | 食用油脂組成物 |
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Cited By (29)
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JP2008163202A (ja) * | 2006-12-28 | 2008-07-17 | Mitsui Norin Co Ltd | カテキン類が添加された油脂の着色抑制方法 |
JP2008167685A (ja) * | 2007-01-11 | 2008-07-24 | Fuji Oil Co Ltd | 風味付けされた油脂の製造法 |
WO2010109737A1 (fr) * | 2009-03-27 | 2010-09-30 | 日清オイリオグループ株式会社 | Huile et matière grasse de cuisson comestibles et leur procédé de préparation |
JP4560590B1 (ja) * | 2009-03-27 | 2010-10-13 | 日清オイリオグループ株式会社 | 加熱調理用食用油脂およびその製造方法 |
JP2011055825A (ja) * | 2009-03-27 | 2011-03-24 | Nisshin Oillio Group Ltd | 加熱調理用食用油脂およびその製造方法 |
JP5884726B2 (ja) * | 2010-02-18 | 2016-03-15 | 不二製油株式会社 | 呈味強化用油脂ならびに呈味含有含油食品の呈味を強化する方法 |
JPWO2011102477A1 (ja) * | 2010-02-18 | 2013-06-17 | 不二製油株式会社 | 呈味強化用油脂ならびに呈味含有含油食品の呈味を強化する方法 |
WO2011122339A1 (fr) * | 2010-03-29 | 2011-10-06 | 株式会社J-オイルミルズ | Composition d'huile et de graisse pour friture |
JP2011205924A (ja) * | 2010-03-29 | 2011-10-20 | J-Oil Mills Inc | 揚げ物用油脂組成物 |
JP2012201771A (ja) * | 2011-03-25 | 2012-10-22 | Fuji Oil Co Ltd | 有機酸及び/又はその塩類を含有する油脂の製造方法 |
WO2013018430A1 (fr) * | 2011-07-29 | 2013-02-07 | 日清オイリオグループ株式会社 | Procédé pour la production d'une composition de glycérides |
JP2018070887A (ja) * | 2011-11-01 | 2018-05-10 | ディーエスエム アイピー アセッツ ビー.ブイ. | 酸化安定性多価不飽和脂肪酸を含有する油 |
JP2020002364A (ja) * | 2011-11-01 | 2020-01-09 | ディーエスエム アイピー アセッツ ビー.ブイ.Dsm Ip Assets B.V. | 酸化安定性多価不飽和脂肪酸を含有する油 |
JPWO2013172348A1 (ja) * | 2012-05-16 | 2016-01-12 | 不二製油株式会社 | 食用油脂及びそれを含有する食品並びにその製造方法 |
JP5652557B2 (ja) * | 2012-05-16 | 2015-01-14 | 不二製油株式会社 | 食用油脂及びそれを含有する食品並びにその製造方法 |
WO2013172348A1 (fr) | 2012-05-16 | 2013-11-21 | 不二製油株式会社 | Huile ou graisse comestible, aliment la contenant, et son procédé de fabrication |
JP2014103908A (ja) * | 2012-11-28 | 2014-06-09 | Riken Vitamin Co Ltd | ミネラル類、ビタミンeおよび乳化剤を含有する飲食品の風味劣化抑制方法 |
WO2015005128A1 (fr) * | 2013-07-09 | 2015-01-15 | 不二製油株式会社 | Confiserie congelée et huile et graisse pour produire cette confiserie |
JP2015015907A (ja) * | 2013-07-09 | 2015-01-29 | 不二製油株式会社 | 冷菓用油脂 |
JP2015033335A (ja) * | 2013-08-08 | 2015-02-19 | 不二製油株式会社 | 製菓用油脂及びそれを利用した食品 |
JP2016026487A (ja) * | 2014-06-24 | 2016-02-18 | 花王株式会社 | 油相及び水相を含有する液体調味料の製造方法 |
US11147301B2 (en) | 2014-06-24 | 2021-10-19 | Kao Corporation | Manufacturing method for liquid seasoning containing oil phase and water phase |
JP2016152782A (ja) * | 2015-02-20 | 2016-08-25 | 日本食研ホールディングス株式会社 | 食用オイルソース |
KR20180121940A (ko) | 2016-03-02 | 2018-11-09 | 후지세유 그룹 혼샤 가부시키가이샤 | 항산화 유지 조성물 |
WO2017150558A1 (fr) | 2016-03-02 | 2017-09-08 | 不二製油グループ本社株式会社 | Composition de graisse ou d'huile présentant des propriétés anti-oxydation |
US11957135B2 (en) | 2016-03-02 | 2024-04-16 | Fuji Oil Holdings Inc. | Chocolate-like food containing polyunsaturated fatty acid |
WO2019187242A1 (fr) | 2018-03-28 | 2019-10-03 | 不二製油グループ本社株式会社 | Composition de matière grasse |
KR20200132862A (ko) | 2018-03-28 | 2020-11-25 | 후지세유 그룹 혼샤 가부시키가이샤 | 유지 조성물 |
KR20210038582A (ko) | 2018-08-09 | 2021-04-07 | 후지세유 그룹 혼샤 가부시키가이샤 | 유지 조성물 |
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CN1446253A (zh) | 2003-10-01 |
CN1298825C (zh) | 2007-02-07 |
JP5168749B2 (ja) | 2013-03-27 |
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