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WO2001060332A1 - Mousse nettoyante contenant des monoesters d'acide sulfosuccinique et des tensioactifs ampholytiques ou betainiques sortant de recipients distributeurs exempts de gaz propulseurs - Google Patents

Mousse nettoyante contenant des monoesters d'acide sulfosuccinique et des tensioactifs ampholytiques ou betainiques sortant de recipients distributeurs exempts de gaz propulseurs Download PDF

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Publication number
WO2001060332A1
WO2001060332A1 PCT/EP2001/001348 EP0101348W WO0160332A1 WO 2001060332 A1 WO2001060332 A1 WO 2001060332A1 EP 0101348 W EP0101348 W EP 0101348W WO 0160332 A1 WO0160332 A1 WO 0160332A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
foam
cleaning
surfactants
atoms
Prior art date
Application number
PCT/EP2001/001348
Other languages
German (de)
English (en)
Inventor
Heike Schelges
Wolfhard Scholz
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Priority to AU2001231713A priority Critical patent/AU2001231713A1/en
Publication of WO2001060332A1 publication Critical patent/WO2001060332A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the invention relates to a foam cleaning product for personal care, consisting of an aqueous cleaning agent and a propellant-free foam dispensing container, which is characterized by particular skin friendliness and a particularly creamy consistency of the foam.
  • a particularly interesting class of skin-friendly anionic surfactants is that of sulfosuccinates. These surfactants are rarely used for liquid personal cleansing agents because they are difficult to thicken in dilute aqueous solution. Combination with betaine surfactants achieves somewhat higher viscosities, but this no longer applies when using the particularly low-irritation C 8 -C ⁇ o-acylamidobetaines. It has now been found that sulfosuccinate surfactants and their combination with surface-active ampho- or betaine surfactants are outstandingly suitable for the production of foam cleaning products which are used as cleaning foam from propellant-free dispensing containers with a foam valve (so-called airfoamers).
  • the foam produced from such foam dispensers when applied even with water-thin preparations is particularly fine-bubble and creamy and is therefore ideal for distribution on the skin and for gentle, low-irritation cleaning.
  • Sulfosuccinates are used as surfactants for skin cleansers e.g. B. from WO 84/03622 AI known.
  • Cleaning foams based on a mixture of anionic and amphoteric surfactants are known from WO 99/39689 A2.
  • WO 93/00089 AI also describes body cleansing foams which are used from propellant-free dispensing containers with a foam valve.
  • the invention therefore relates to a foam cleaning product for personal hygiene, consisting of an aqueous cleaning agent and a propellant-free dispensing container with a foam valve, the cleaning agent at least
  • Suitable dispensing containers with foam nozzles are known, e.g. B. from US 3,709,437; US 3,937,364; US 5,635,469 or WO 94/09345 AI.
  • the cleaning liquid is conveyed to the foam valve either by pressure on the flexible container wall (squeeze bottle) or by a manually operated pump.
  • the liquid is then mixed with air in the foam valve and discharged as foam.
  • the surface-active sulfosuccinic acid monoester salts are the salts of sulfosuccinic acid monoesters of fatty alcohols or fatty alcohol polyglycol ethers of the general formula
  • Particularly preferred sulfosuccinic acid monoester salts correspond to the formula
  • R is an alkyl group with 12-16 C atoms and n has an average value of 1-6.
  • Ampholytic surfactants are surface-active compounds which, in addition to a C 8 -alkyl or acyl group, contain at least one free amino group and at least one -COOH or -SO 3 H group in the molecule and are capable of forming internal salts.
  • suitable ampholytic surfactants are N-alkylglycines, N-alkylaminopropionic acids, N-alkylaminobutyric acids,
  • N-alkyliminodipropionic acids H-hydroxyethyl-N-alkylamidopropylglycine, N-
  • Particularly preferred ampholytic surfactants are the N-cocoalkylaminopropionate and the cocoacylaminoethylaminopropionate.
  • Zwitterionic surfactants are those surface-active compounds that have at least one quaternary ammonium group and at least one -COO - or -SO 3 (_) group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example coconut acylaminopropyl dimethylammonium glycinate, and 2-alkyl-3 -carboxymethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylethyloxycarboxymethylglycinate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known under the CTFA name Cocamidopropyl Betaine.
  • Particularly suitable for the purposes of the present invention are those ampho- and betaine surfactants which have an alkyl or acyl group with 8-10 C atoms, in particular the betaine surfactant of the formula (II)
  • Such a surfactant is commercially available as a skin and mucous membrane-friendly and low-irritation beta surfactant with the name Tego Betain 810 (Goldschmidt).
  • the foam cleaning agents according to the invention can also contain nonionic surfactants.
  • Suitable nonionic surfactants are, for example, the alkyl (oligo) glucosides, which are obtainable by reacting alcohols with 8-16 carbon atoms with, for example, butylglucoside by transacetalization or by direct acetalization from glucose and fatty alcohol and of the formula RO- (Z) x correspond in which R is a C 8 -C 6 alkyl group and Z is a monosaccharide residue, in particular a glucose residue, and x is its average degree of oligomerization, a number from 1-5, preferably from 1-2.
  • Other suitable nonionic surfactants are, for example,
  • - Amine oxide surfactants for example alkylamine oxides with 12-18 C atoms and acylamido propyl dimethylamine oxide with 12-18 C atoms in the acyl group.
  • non-water-soluble surfactants but which are solubilized in the presence of water-soluble surfactants and then contribute to improving the feeling on the skin and to the fine bubbles and creaminess of the foam, can be present in the hair cleansing agents according to the invention in amounts of up to 5% by weight.
  • Such products are, for example
  • Fatty acid partial glycerides (monoglycerides and mono- / diglyceride mixtures) and sorbitan mono- and difatty acid esters
  • the foam cleaning product according to the invention contains a cleaning agent which additionally
  • a product which is commercially available under the name Lamesoft PO 65 (Cognis Germany) and which contains a combination of an alkyl (oligo) glucoside and a glycerol monooleate with more than 95% monoester content is particularly suitable as a moisturizing and moisturizing component.
  • the skin cleanser according to the invention can contain up to 10% by weight of further anionic surfactants.
  • foam-rich and skin-friendly surfactants are particularly preferred.
  • Suitable anionic surfactants such.
  • the detergent composition is low viscosity and can be easily transported to the foam valve by the pump mechanism of the dispensing container.
  • the viscosity of the cleaning agent is therefore preferably in a range below 500 m • Pa s (20 ° C.), preferably below 200 m • Pa s (20 ° C.), measured with a Brookfield rotary viscometer (type RTV, spindle 2 at 20 rpm).
  • the viscosity can be reduced by a content of glycols or polyols. These products also have a skin-moisturizing and sensory beneficial effect.
  • the liquid cleaning agent therefore contains 0.5 to 5% by weight of a water-soluble glycol or polyol with 2-6 C atoms, or a polyalkylene glycol.
  • Suitable glycols are e.g. B. ethylene glycol, 1, 2-propylene glycol, pentandol-1,4 or hexanediol-1,6.
  • Suitable polyols are e.g. B. glycerin, erythritol, sorbitol.
  • Suitable water-soluble polyalkylene glycols are e.g. B. the polyethylene glycols with molecular weights up to about 800 and the water-soluble ethylene oxide / propylene oxide copolymers with a proportion of more than 50% by weight of ethylene glycol ether groups.
  • the foam cleaning product according to the invention contains an aqueous cleaning agent which contains 8-12% by weight of a sulfosuccinate of the formula:
  • R' ⁇ - (CH 2 CH 2 O) n -CO-CH 2 -CH (SO 3 Na) -COONa in which R 1 is an alkyl group with 12-18 C atoms and n is one
  • R 2 -CO NH- (CH 2 ) m -N (+) (CH 3 ) 2 -COO (") , in which R CO is an acyl group with 8-10 C atoms and m 2 or 3
  • Lipid components e.g. cosmetic oil components, fats, waxes and lipid-soluble vitamins (tocophenols, retinol palmitate) can be contained in emulsified microemulsified or solubilized form in amounts of 0.01-3% by weight.
  • the foam cleaning products according to the invention can contain other cosmetically and sensorially active or stabilizing additives, e.g.
  • skin moisturizers such as pyrrolidone carboxylic acid, lactic acid, sodium lactate, citric acid, sodium citrate, urea, allantoin, ascorbic acid, water-soluble protein derivatives and protein hydrolysates, plant extracts, panthenol, preservatives such as.
  • the foam cleaning products of the invention produce a cleaning foam that is not only excellent for skin cleaning, e.g. B. is suitable for removing the face or for cleaning the hands or sensitive areas of skin, but leaves the skin in a refreshed and well-groomed state.
  • B skin cleaning

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un produit de nettoyage moussant comprenant un nettoyant aqueux et un récipient distributeur exempt de gaz propulseur, muni d'une soupape de moussage. Le nettoyant aqueux contient entre 5 et 20 % en poids d'un sel d'ester d'acide sulfosuccinique tensioactif, entre 1 et 10 % en poids d'un agent de surface ampholytique ou bétaïnique tensioactif et entre 60 et 90 % en poids d'eau. Ce produit de nettoyage moussant s'utilise pour produire une mousse nettoyante particulièrement crémeuse et à bulles particulièrement fines, bien tolérée par la peau. Cette mousse nettoyante contient en outre de préférence entre 1 et 10 % en poids de tensioactifs non ioniques et entre 0,1 et 1 % en poids de monoglycéride d'un acide gras ayant entre 12 et 18 atomes de C.
PCT/EP2001/001348 2000-02-17 2001-02-08 Mousse nettoyante contenant des monoesters d'acide sulfosuccinique et des tensioactifs ampholytiques ou betainiques sortant de recipients distributeurs exempts de gaz propulseurs WO2001060332A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001231713A AU2001231713A1 (en) 2000-02-17 2001-02-08 Cleaning foam containing sulfosuccinic acid monoesters and amphoteric surfactants or betaine surfactants dispensed from dispensing containers without a propellant gas

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2000107321 DE10007321A1 (de) 2000-02-17 2000-02-17 Reinigungsschaum
DE10007321.2 2000-02-17

Publications (1)

Publication Number Publication Date
WO2001060332A1 true WO2001060332A1 (fr) 2001-08-23

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PCT/EP2001/001348 WO2001060332A1 (fr) 2000-02-17 2001-02-08 Mousse nettoyante contenant des monoesters d'acide sulfosuccinique et des tensioactifs ampholytiques ou betainiques sortant de recipients distributeurs exempts de gaz propulseurs

Country Status (3)

Country Link
AU (1) AU2001231713A1 (fr)
DE (1) DE10007321A1 (fr)
WO (1) WO2001060332A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002097022A1 (fr) * 2001-05-30 2002-12-05 Cognis Deutschland Gmbh & Co. Kg Compositions tensioactives contenant des acides alpha-hydroxy
CN100519725C (zh) * 2003-02-28 2009-07-29 宝洁公司 包含泡沫生成分配器和包含高含量表面活性剂组合物的泡沫生成套件
WO2010108756A3 (fr) * 2009-03-27 2011-09-29 Evonik Goldschmidt Gmbh Compositions aqueuses pour le nettoyage des cheveux et de la peau

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10147049A1 (de) * 2001-09-25 2003-04-10 Beiersdorf Ag Verwendung von Tensiden mit einem Quotienten aus Hämolysewert und Denaturierungsindex von größer oder gleich 1 zum Erzielen oder Erhöhen der Selektivität von Reinigungszubereitungen
DE10148392A1 (de) * 2001-09-29 2003-04-30 Beiersdorf Ag Kosmetische Reinigungsschäume
DE10205190B4 (de) * 2002-02-08 2017-06-08 Beiersdorf Ag 2-Methyl-1,3-propandiol haltige Zubereitungen
WO2004032895A1 (fr) * 2002-09-26 2004-04-22 Beiersdorf Ag Utilisation de tensioactifs dont le quotient de la valeur d'hemolyse et de l'indice de denaturation est superieur ou egal a 1 pour obtenir ou augmenter la selectivite de preparations nettoyantes
US7402554B2 (en) 2003-02-28 2008-07-22 The Procter & Gamble Company Foam-generating kit containing a foam-generating dispenser and a composition containing a high level of surfactant
US7651992B2 (en) 2003-02-28 2010-01-26 The Procter & Gamble Company Foam-generating kit containing a foam-generating dispenser and a composition containing a high level of surfactant
FR2871373B1 (fr) * 2004-06-11 2006-12-01 Oreal Procede de lavage des cheveux frises ou crepus
DE102004031668A1 (de) * 2004-06-25 2006-02-09 Beiersdorf Ag Produkte zur Reinigung der Intimregion
CN104768523B (zh) 2012-10-29 2017-08-15 宝洁公司 10℃下具有0.30或更大损耗角正切值的个人护理组合物
DE102013226426A1 (de) * 2013-12-18 2015-06-18 Henkel Ag & Co. Kgaa Konservierungsmittelsystem für Waschmittel
DE102015111957A1 (de) * 2015-07-22 2017-01-26 WAREG Verpackungs-GmbH Mittel zum Schutz der Kopfhaut

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0217250A2 (fr) * 1985-09-28 1987-04-08 Henkel Kommanditgesellschaft auf Aktien Préparations moussantes tensio-actives ayant des composants huileux insolubles dans l'eau, solubilisés clairement
WO1991013610A1 (fr) * 1990-03-10 1991-09-19 Beiersdorf Ag Produits cosmetiques de nettoyage
EP0453238A1 (fr) * 1990-04-20 1991-10-23 Unilever Plc Composition de nettoyage
GB2245281A (en) * 1990-05-29 1992-01-02 Kao Corp Less irritative detergent composition
WO1993000089A1 (fr) * 1991-06-21 1993-01-07 The Procter & Gamble Company Produits nettoyants
DE4139935A1 (de) * 1991-12-04 1993-06-09 Kao Corporation Gmbh, 4000 Duesseldorf, De Fluessiges koerperreinigungsmittel
US5422031A (en) * 1991-09-09 1995-06-06 Kao Corporation Hair tinting shampoo
US5490955A (en) * 1992-02-27 1996-02-13 Elizabeth Arden Company, Division Of Conopco, Inc. Cleansing compositions based on C10 -C16 acyl lactylate
US5883068A (en) * 1994-10-04 1999-03-16 Henkel Kommanditgesellschaft Auf Aktien Pumpable water-containing surfactant concentrates
WO1999039689A2 (fr) * 1998-02-03 1999-08-12 Unilever Plc Produit moussant pour le nettoyage de la peau

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0217250A2 (fr) * 1985-09-28 1987-04-08 Henkel Kommanditgesellschaft auf Aktien Préparations moussantes tensio-actives ayant des composants huileux insolubles dans l'eau, solubilisés clairement
WO1991013610A1 (fr) * 1990-03-10 1991-09-19 Beiersdorf Ag Produits cosmetiques de nettoyage
EP0453238A1 (fr) * 1990-04-20 1991-10-23 Unilever Plc Composition de nettoyage
GB2245281A (en) * 1990-05-29 1992-01-02 Kao Corp Less irritative detergent composition
WO1993000089A1 (fr) * 1991-06-21 1993-01-07 The Procter & Gamble Company Produits nettoyants
US5422031A (en) * 1991-09-09 1995-06-06 Kao Corporation Hair tinting shampoo
DE4139935A1 (de) * 1991-12-04 1993-06-09 Kao Corporation Gmbh, 4000 Duesseldorf, De Fluessiges koerperreinigungsmittel
US5490955A (en) * 1992-02-27 1996-02-13 Elizabeth Arden Company, Division Of Conopco, Inc. Cleansing compositions based on C10 -C16 acyl lactylate
US5883068A (en) * 1994-10-04 1999-03-16 Henkel Kommanditgesellschaft Auf Aktien Pumpable water-containing surfactant concentrates
WO1999039689A2 (fr) * 1998-02-03 1999-08-12 Unilever Plc Produit moussant pour le nettoyage de la peau

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002097022A1 (fr) * 2001-05-30 2002-12-05 Cognis Deutschland Gmbh & Co. Kg Compositions tensioactives contenant des acides alpha-hydroxy
US7253139B2 (en) 2001-05-30 2007-08-07 Cognis Deutschland Gmbh & Co. Kg Surfactant preparations comprising α-hydroxy acids
CN100519725C (zh) * 2003-02-28 2009-07-29 宝洁公司 包含泡沫生成分配器和包含高含量表面活性剂组合物的泡沫生成套件
WO2010108756A3 (fr) * 2009-03-27 2011-09-29 Evonik Goldschmidt Gmbh Compositions aqueuses pour le nettoyage des cheveux et de la peau
CN102365079A (zh) * 2009-03-27 2012-02-29 赢创高施米特有限公司 毛发和皮肤用水性清洁组合物

Also Published As

Publication number Publication date
AU2001231713A1 (en) 2001-08-27
DE10007321A1 (de) 2001-08-23

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