WO2000037511A3 - Olefin polymerization catalyst system, polymerization process and polymer therefrom - Google Patents
Olefin polymerization catalyst system, polymerization process and polymer therefrom Download PDFInfo
- Publication number
- WO2000037511A3 WO2000037511A3 PCT/US1999/027502 US9927502W WO0037511A3 WO 2000037511 A3 WO2000037511 A3 WO 2000037511A3 US 9927502 W US9927502 W US 9927502W WO 0037511 A3 WO0037511 A3 WO 0037511A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- represented
- formula
- transition metal
- catalyst system
- bidentate ligands
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000002685 polymerization catalyst Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000003446 ligand Substances 0.000 abstract 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 3
- 125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 abstract 3
- 229910052723 transition metal Inorganic materials 0.000 abstract 3
- 150000003624 transition metals Chemical class 0.000 abstract 3
- 239000012190 activator Substances 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 230000002902 bimodal effect Effects 0.000 abstract 1
- 229920001903 high density polyethylene Polymers 0.000 abstract 1
- 239000004700 high-density polyethylene Substances 0.000 abstract 1
- 229920013716 polyethylene resin Polymers 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Abstract
This invention relates to an olefin polymerization catalyst system comprising at least one activator and one of: a) at least two transition metal catalysts based on bidentate ligands containing pyridine or quinoline moieties, as described below as represented by formula (I), (II), (III) or (IV); b) the product of the combination of an activator and a transition metal catalyst based on bidentate ligands containing pyridine or quinolines moieties, such as those described as represented by formula (III) or (IV), that has been allowed to react prior to the introduction into the reactor, preferably for at least 15 minutes, and/or c) the product of combination of an additive and a transition metal catalyst based on bidentate ligands containing pyridine or quinoline moieties, such as those described below as represented by formula (I) or (II). This invention further relates to a polymer produced therefrom, particularly to unique polyethylene resins, more preferably bimodal high density polyethylene resins produced by this invention.
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP99963936A EP1144465A2 (en) | 1998-12-18 | 1999-11-19 | Olefin polymerization catalyst system, polymerization process and polymer therefrom |
| BR9916313-6A BR9916313A (en) | 1998-12-18 | 1999-11-19 | Catalyst system for olefin polymerization, polymerization process and polymer thereof |
| JP2000589580A JP2002533483A (en) | 1998-12-18 | 1999-11-19 | Olefin polymerization catalyst systems, polymerization processes and polymers from them |
| MXPA01006185A MXPA01006185A (en) | 1998-12-18 | 1999-11-19 | Olefin polymerization catalyst system, polymerization process and polymer therefrom. |
| AU20272/00A AU756833B2 (en) | 1998-12-18 | 1999-11-19 | Olefin polymerization catalyst system, polymerization process and polymer therefrom |
| PL99348825A PL348825A1 (en) | 1998-12-18 | 1999-11-19 | Olefin polymerization catalyst system, polymerization process and polymer therefrom |
| CA002350451A CA2350451A1 (en) | 1998-12-18 | 1999-11-19 | Olefin polymerization catalyst system, polymerization process and polymer therefrom |
| NO20012982A NO20012982L (en) | 1998-12-18 | 2001-06-15 | Olefin polymerization catalyst system, polymerization process and polymer therefrom |
Applications Claiming Priority (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/216,163 US6265513B1 (en) | 1997-07-02 | 1998-12-18 | Polyolefin |
| US09/215,706 US6268447B1 (en) | 1998-12-18 | 1998-12-18 | Olefin polymerization catalyst |
| US09/215,706 | 1998-12-18 | ||
| US09/216,163 | 1998-12-18 | ||
| US09/213,627 US6320002B1 (en) | 1997-07-02 | 1998-12-18 | Olefin polymerization catalyst |
| US09/216,215 | 1998-12-18 | ||
| US09/216,215 US6303719B1 (en) | 1998-12-18 | 1998-12-18 | Olefin polymerization catalyst system |
| US09/213,627 | 1998-12-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2000037511A2 WO2000037511A2 (en) | 2000-06-29 |
| WO2000037511A3 true WO2000037511A3 (en) | 2000-11-09 |
Family
ID=27498942
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1999/027502 WO2000037511A2 (en) | 1998-12-18 | 1999-11-19 | Olefin polymerization catalyst system, polymerization process and polymer therefrom |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP1144465A2 (en) |
| JP (1) | JP2002533483A (en) |
| CN (1) | CN1241953C (en) |
| AR (1) | AR025281A1 (en) |
| AU (1) | AU756833B2 (en) |
| BR (1) | BR9916313A (en) |
| CA (1) | CA2350451A1 (en) |
| CZ (1) | CZ20012224A3 (en) |
| MX (1) | MXPA01006185A (en) |
| NO (1) | NO20012982L (en) |
| PL (1) | PL348825A1 (en) |
| WO (1) | WO2000037511A2 (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6706829B2 (en) * | 2000-11-07 | 2004-03-16 | Symyx Technologies, Inc. | Methods of polymerizing ethylene and styrene copolymers with substituted pyridyl amine catalysts and catalysts therefor |
| KR100445185B1 (en) * | 2000-11-20 | 2004-09-13 | 충남대학교산학협력단 | A Catalyst for Olefin Polymerization |
| BR0214138A (en) * | 2001-11-15 | 2004-10-19 | Exxonmobil Chem Patents Inc | Polymerization monitoring and control using guide indicators |
| US7094848B2 (en) | 2003-05-13 | 2006-08-22 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalyst system |
| US7288596B2 (en) | 2003-12-22 | 2007-10-30 | Univation Technologies, Llc | Polyethylene compositions having improved tear properties |
| EP2112175A1 (en) | 2008-04-16 | 2009-10-28 | ExxonMobil Chemical Patents Inc. | Activator for metallocenes comprising one or more halogen substituted heterocyclic heteroatom containing ligand coordinated to an alumoxane |
| TW200936619A (en) | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom |
| RU2012130155A (en) | 2009-12-18 | 2014-01-27 | Юнивейшн Текнолоджиз, Ллк | METHODS FOR PRODUCING POLYOLEFIN PRODUCTS HAVING VARIOUS SHIFT THINNING AND VARIOUS HAZELNESS |
| CN102453157B (en) * | 2010-10-22 | 2014-12-10 | 中国石油化工股份有限公司 | Catalyst system for preparing broad-peak/dimodal polyethylene in single reactor |
| AT510547B1 (en) | 2011-01-03 | 2012-05-15 | Aba Hoertnagl Gmbh | BUCKLE |
| WO2012158260A1 (en) * | 2011-05-13 | 2012-11-22 | Univation Technologies, Llc | Spray-dried catalyst compositions and polymerization processes employing the same |
| ES2798272T3 (en) | 2011-11-08 | 2020-12-10 | Univation Tech Llc | Methods of preparing a catalytic system |
| AT512540B1 (en) | 2012-06-28 | 2013-09-15 | Aba Hoertnagl Gmbh | Clamping device for clamping at least one belt |
| AT512541B1 (en) | 2012-06-28 | 2013-09-15 | Aba Hoertnagl Gmbh | jig |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0619325A1 (en) * | 1993-04-07 | 1994-10-12 | Fina Research S.A. | Catalyst and process for producing polyolefins |
| WO1998049208A1 (en) * | 1997-04-25 | 1998-11-05 | Bp Chemicals Limited | Novel compounds and their use in polymerisation |
| WO1999001460A1 (en) * | 1997-07-02 | 1999-01-14 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
-
1999
- 1999-11-19 BR BR9916313-6A patent/BR9916313A/en not_active IP Right Cessation
- 1999-11-19 WO PCT/US1999/027502 patent/WO2000037511A2/en not_active Application Discontinuation
- 1999-11-19 PL PL99348825A patent/PL348825A1/en not_active Application Discontinuation
- 1999-11-19 AU AU20272/00A patent/AU756833B2/en not_active Ceased
- 1999-11-19 CA CA002350451A patent/CA2350451A1/en not_active Abandoned
- 1999-11-19 JP JP2000589580A patent/JP2002533483A/en active Pending
- 1999-11-19 EP EP99963936A patent/EP1144465A2/en not_active Withdrawn
- 1999-11-19 CZ CZ20012224A patent/CZ20012224A3/en unknown
- 1999-11-19 MX MXPA01006185A patent/MXPA01006185A/en unknown
- 1999-11-19 CN CN 99814533 patent/CN1241953C/en not_active Expired - Lifetime
- 1999-12-17 AR ARP990106514 patent/AR025281A1/en unknown
-
2001
- 2001-06-15 NO NO20012982A patent/NO20012982L/en not_active Application Discontinuation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0619325A1 (en) * | 1993-04-07 | 1994-10-12 | Fina Research S.A. | Catalyst and process for producing polyolefins |
| WO1998049208A1 (en) * | 1997-04-25 | 1998-11-05 | Bp Chemicals Limited | Novel compounds and their use in polymerisation |
| WO1999001460A1 (en) * | 1997-07-02 | 1999-01-14 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
Non-Patent Citations (1)
| Title |
|---|
| GIBSON V C ET AL: "Synthesis and structural characterisation of aluminium imino-amide and pyridyl-amide complexes: bulky monoanionic N,N chelate ligands via methyl group transfer", JOURNAL OF ORGANOMETALLIC CHEMISTRY,CH,ELSEVIER-SEQUOIA S.A. LAUSANNE, vol. 550, no. 1-2, 15 January 1998 (1998-01-15), pages 453 - 456, XP004109893, ISSN: 0022-328X * |
Also Published As
| Publication number | Publication date |
|---|---|
| CZ20012224A3 (en) | 2001-09-12 |
| JP2002533483A (en) | 2002-10-08 |
| MXPA01006185A (en) | 2005-04-19 |
| WO2000037511A2 (en) | 2000-06-29 |
| BR9916313A (en) | 2001-10-02 |
| AU2027200A (en) | 2000-07-12 |
| NO20012982L (en) | 2001-08-14 |
| PL348825A1 (en) | 2002-06-17 |
| CN1241953C (en) | 2006-02-15 |
| EP1144465A2 (en) | 2001-10-17 |
| NO20012982D0 (en) | 2001-06-15 |
| AR025281A1 (en) | 2002-11-20 |
| CN1335860A (en) | 2002-02-13 |
| CA2350451A1 (en) | 2000-06-29 |
| AU756833B2 (en) | 2003-01-23 |
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