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WO2000023553A1 - Formulation permettant de nettoyer des surfaces sans frotter - Google Patents

Formulation permettant de nettoyer des surfaces sans frotter Download PDF

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Publication number
WO2000023553A1
WO2000023553A1 PCT/US1999/023505 US9923505W WO0023553A1 WO 2000023553 A1 WO2000023553 A1 WO 2000023553A1 US 9923505 W US9923505 W US 9923505W WO 0023553 A1 WO0023553 A1 WO 0023553A1
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WO
WIPO (PCT)
Prior art keywords
composition
surfactant
weight
water
cleaning
Prior art date
Application number
PCT/US1999/023505
Other languages
English (en)
Inventor
Kent B. Mcreynolds
Jeffrey D. Michalowski
Original Assignee
S.C. Johnson & Son, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by S.C. Johnson & Son, Inc. filed Critical S.C. Johnson & Son, Inc.
Priority to AU11062/00A priority Critical patent/AU1106200A/en
Publication of WO2000023553A1 publication Critical patent/WO2000023553A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

Definitions

  • the present invention is directed generally to an improved composition for cleaning surfaces, and more particularly, to an aqueous, rinsable composition for cleaning the surfaces of showers, bathtubs and the like without scrubbing or wiping and without water-spotting or streaking.
  • shower stalls and bathtubs typically accumulate organic and inorganic deposits, residues, or other foulants during use.
  • Such materials include insoluble soap scum, washed off body dirt and/or body oils, insoluble metal salts, and mildew and other microorganisms that grow in such an environment. These accumulated materials are obviously undesirable due to concerns over cleanliness, hygiene and aesthetics.
  • the cleaning of such surfaces may be performed with numerous cleaning compositions commercially available to consumers, this task is typically difficult and an undesirable chore.
  • cleaning of the surfaces in a shower stall is in most cases difficult due to the small enclosed area and multiple surface shapes found therein. As a result, considerable labor is required to clean such surfaces using conventional cleaners.
  • the formulation is pH adjusted to 4 to 8 with pH 5 being preferred.
  • this composition appears to be effective for its intended purpose, it has several disadvantages. For example, although an alcohol solvent helps in keeping soil and various oils dispersed, exposure to some shower and/or bath surfaces is not recommended. For example, acrylic knobs could stress crack if exposed to certain solvents. In addition, most solvents have a strong odor and are not recommended for skin, nasal or throat contact. Also, solvent odors are very difficult to mask with a fragrance, and may linger in the tub or shower enclosure after the fragrance has dissipated. Therefore, a solvent-free formulation would be strongly preferred. pH is also an important consideration in the design of a shower or bath principle formulation. The '452 patent uses an acidic-based formulation having a pH of between 4 to 8. Acidic pH is not recommended for contact with some shower and bath surfaces, such as natural marble, and therefore, a formulation neutral or alkaline in pH would be preferred.
  • the present invention provides a surface cleaner which may be used to mist surfaces such as shower stalls and bathtubs so as to prevent organic and inorganic deposits, residues and foulants from building up on these surfaces.
  • the cleaner is aqueous-based and may be rinsed from the surfaces without scrubbing or wiping of the surfaces and when dry does not spot or streak.
  • the scrub-free formula is composed of up to 1% by weight of a wetting agent or surfactant, or blends thereof, which upon drying leaves a clear film, up to about 2% by weight of a chelating agent, and the remaining ingredient being water.
  • the pH of the formula is from about 5 to about 12, preferably about 9 to about 12, and most preferably
  • Optional additives such as fragrances, colorants, additional surfactants, bactericides, moldicides, fungicides, additives for pH adjustment, hydrophilic additives for surface effects and silicones for surface gloss and water repellency may also be added.
  • Preferred wetting agents or surfactants are alkyl polyglucoside nonionic surfactants or any other surfactant which demonstrates a "gloss loss" for the composition in the range of only 0-25%, preferably 0-10%, after application.
  • the above formulation is particularly effective when the surface on which it is applied is wet, and as a result, maintains the surface foulants in suspension and rinsable during the next shower or bath.
  • the formulation of the present invention is free of any organic solvent, especially alcohol-free, and thus has minimal odor, and is safe for skin, nasal or throat contact.
  • This formulation preferably also has a neutral to alkaline pH which is safe for use in most shower and bath surfaces.
  • alkaline pH levels aluminum corrosion can be inhibited by the addition of a compound such as sodium metasilicate in an amount of about 0.1% by weight.
  • a compound such as sodium metasilicate in an amount of about 0.1% by weight.
  • aluminum corrosion is eliminated.
  • the present formulation eliminates mold and fungus growth since potential food sources are conveniently rinsed away during each subsequent use.
  • the present formula is particularly advantageous for use in connection with cleaning surfaces in shower stalls or baths, the composition is not limited to such applications.
  • the composition may also be used as an exterior home cleaner for siding and windows where drying is difficult, or as an excellent automobile cleaner that does not need to be dried.
  • the formula advantageously dries without spotting or streaking and thus provides a wax-like appearance which is particularly desirable for automobile paint.
  • the formulation may be used in any application where it is desired to maintain surfaces clean without the action of scrubbing or wiping of surface deposits, residue or foulants.
  • the composition of the present invention also provides a method of cleaning drains in showers, bathtubs and the like.
  • the cleaning composition prevents clogging or slow running of water in the drain due to the buildup of organic materials and inorganic salts on the drainpipe's interior surfaces.
  • the present composition provides a drain cleaning product which is easy to use and reduces the frequency at which drain clogs must be treated.
  • an aqueous, rinsable cleaning composition having ingredients in the following ranges provides advantages over current rinsing compositions when evaluated for its cleansing ability, anti-streaking and anti-spotting abilities as well as consumer acceptance.
  • the cleaning composition of the present invention includes from about 0.1% to about 1% by weight of a wetting agent or surfactant, or blends thereof, which upon drying leaves a clear film, from about 0.1% to about 2% by weight of a chelating or sequestering agent, and from about 99.8% to about 97% by weight water.
  • the formulation may include up to 5% by weight of other additives conventionally added to cleaning compositions for specific effects.
  • the specific amount of each ingredient in the formulation may vary depending upon the specific end use and properties desired. Obviously, however, the ingredients must comprise 100% by weight of the composition, and the percentages set forth herein are based on the weight of the entire cleaning composition.
  • a preferred embodiment of the cleaner has the following composition expressed in percent by weight:
  • the above composition has a pH of 12.
  • Surfactants that may be employed in the present invention include anionic, nonionic and amphoteric, and mixtures thereof.
  • the surfactant used in the formulation of the present invention advantageously wets the surface to be cleaned at a pH of 5-12, and upon drying on the surface leaves no visible residue and/or deposit.
  • the "gloss loss" of the composition utilizing such surfactants is less than 25%, and most preferably less than 10%.
  • the present cleaning composition contains a surfactant, or blend of surfactants, in the range of about 0.1 % to about 1 % by weight, more preferably 0.2% to 1% by weight, and most preferably about 0.5% by weight.
  • a composition containing less than about 0.1% by weight of such a surfactant results in decreased effectiveness while a composition containing greater than about 1% by weight does not significantly increase the cleaning and anti-streaking/anti-spotting ability of the composition. Also, at lower surfactant levels care must be taken to insure the fragrance and other minor additives are kept in solution.
  • Preferred surfactants are those that have low odor, high wetability performance, low volatile organic components, dry to a clear film, reduced streaking upon drying and retain a glossy appearance when dry.
  • Suitable nonionic surfactants include the ethylene oxide esters of alkyl phenols such as (nonylphenoxy) polyoxyethylene ether, the ethylene oxide ethers of fatty alcohols such as tridecyl alcohol polyoxyethylene ether, the propylene oxide ethers of fatty alcohols, the ethylene oxide ethers of alkyl mercaptans such as dodecyl mercaptan polyoxyethylene thioester, the ethylene oxide esters of acids such as the lauric ester of methoxy polyethylene glycol, the ethylene oxide ethers of fatty acid amides, the condensation products of ethylene oxide with partial fatty acid esters of sorbitol such as the lauric ester of sorbitan polyethylene glycol ether, and other similar materials.
  • alkyl phenols such as (nonylphenoxy) polyoxyethylene ether
  • the ethylene oxide ethers of fatty alcohols such as tridecyl alcohol polyoxyethylene ether
  • the preferred nonionic surfactant is an alkyl polyglycoside available under the trade designation Glucopon from Henkel Chemical Company. These polyglycosides have the following general formula:
  • the Glucopon family of surfactants provides numerous performance advantages, namely, (1) high solubility with no gel phase or cloud point while also providing an effective hydrotrope or coupling agent; (2) electrolyte tolerance; (3) good grease cutting ability; (4) easy rinsing with little or no streaking or spotting; (5) high gloss retention; and (6) biodegradability.
  • the following table illustrates the characteristics of the Glucopon surfactants product line. Each is a suitable nonionic surfactant for use in the present composition.
  • Suitable anionic surfactants include alpha olefin sulfonates, the alkyl aryl sulfonic acids and their alkali metal and alkaline earth metal salts such as sodium dodecyl benzene sulfonate, magnesium dodecyl benzene sulfonate, disodium dodecyl benzene disulfonate and the like as well as the alkali metal salts of fatty alcohol esters of sulfuric and sulfonic acids, the alkali salts of alkyl aryl (sulfothioic acid) ethers, alkyl thiosulfuric acid and soaps such as coco or tallow, etc.
  • alkali metal salts of fatty alcohol esters of sulfuric and sulfonic acids the alkali salts of alkyl aryl (sulfothioic acid) ethers, alkyl thiosulfuric acid and soaps such as coco or t
  • Preferred anionics include sodium dodecyl benzene sulfonate available under the tradename Nacconal 40-G from Stepan Company, Northfield, IL; and sodium lauryl sulfate ("SLS") because of its detergency, wetting, foam enhancing and emulsifying properties.
  • SLS is available in dry form under the trade designation Stepanol ME-Dry from the Stepan Chemical Company.
  • Particularly preferred anionic surfactants are the Dowfax compounds available from Dow Chemical, which are hereinafter described.
  • Suitable amphoteric surfactants include the fatty imidazo lines, such as 2-coco-l- hydroxyethyl- 1 -carboxymethyl- 1 -hydroxylimidazoline and similar compounds made by reacting monocarboxylic fatty acids having chain lengths of 10 to 24 carbon atoms with 2- hydroxy ethyl ethylene diamine and with monohalo monocarboxylic fatty acids.
  • An additional class of surfactants which may be used are amine oxides which demonstrate cationic surfactant properties in acidic pH and nonionic surfactant properties in alkaline pH.
  • Exemplary amine oxides include dihydroxyethyl cocamine oxide, tallowamidopropylamine oxide, lauramine oxide, and lauryldimethylamine oxide.
  • Ammonyx CIO available from Stepan.
  • Quaternary surfactants such as dialkyl dimethyl ammonium chloride, alkyl dimethyl benzyl ammonium chloride and alkyl dimethyl ethyl benzyl ammonium chloride may also be employed.
  • a particularly preferred quaternary surfactant is BTC 2125M available from Stepan.
  • hydrotropes may be added to the composition to increase the solubilization of a relatively insoluble substance in the aqueous cleaning composition. These hydrotropes aid in solubilizing the organic and inorganic deposits normally accumulating on the surface of shower stalls, bathtubs and the like.
  • hydrotropes having a C 6 . 10 average length are employed in the present composition. Examples of such hydrotropes include the following compounds:
  • Chelating agents are typically added to the composition to bind metal or metal ions in the form of a soluble complex for the purpose of preventing precipitation of the metal or metal ion in water solution by agents that would normally result in precipitation.
  • the chelating agent may be present in the composition in amounts from about 0.1% to about 2% by weight, with the preferred range being 0.25% to about 0.75%, and the most referred being 0.5% by weight. Less than 0.1% chelating agent decreases the effectiveness of the composition while greater than about 2% by weight of the chelating agent results in no further increased cleaning effects. Also, above about 2% chelating agents may cause a rainbow-like appearance on chrome components in a tube or shower.
  • Chelating agents such as, but not limited to, ethylene diamine tetraacetic acid (EDTA), hydroxyethyl ethylene diaminetriacetic acid (HEEDTA), diethylenetriamine pentaacetic acid (DTP A), nitrilotriacetic acid (NT A), and salts thereof, can be used to obtain the chelating property desired.
  • the preferred chelating agent is a tetrasodium salt of ethylenediamine tetraacedic acid (tetrasodium EDTA), such as Versene 100 available from Dow Chemical Company.
  • Other chelating agents such as, but not limited to the following list can be substituted for tetrasodium EDTA on an equivalent chelating strength basis:
  • the pH of the end product should be between 5 and 12, preferably between 9 and 12, and most preferably 11 to 12.
  • the composition of the present invention can be adjusted using any number of agents.
  • pH adjustment is accomplished with any compatible alkaline agent such as ammonium hydroxide if the composition is too acidic, or alternately, with any common compatible acid such as versinic acid if the composition is too alkaline.
  • Inorganic acids should not be used to adjust pH as such acids may precipitate various salts upon drying leaving an unsightly appearance on shower or tub components.
  • the composition also preferably contains a fragrance such as pine, lemon, etc. to mask any undesirable odors from the ingredients and to provide a desired scent to the user.
  • fragrance is not necessary, generally about 0.01% to about 0.1% of fragrance is added to the composition. Any of the number of commercially available fragrances may be used to provide the desired scent as is well known to those skilled in the art. For example, 6517-HAY available from International Flavors and Fragrances provides a pleasant, fresh scent and is particularly desirable for use in the present composition.
  • the water used in the present composition preferably has negligible amounts of metal ions so as to provide the least amount of residue or deposits upon evaporation from a surface resulting in minimal spotting.
  • Distilled water or deionized water is preferred as the source of water for dilution of the components described herein.
  • any water source may be used depending upon the degree of water hardness.
  • the amount of surfactant and chelating agent may be increased or decreased to account for water hardness and soils with different degrees of metal ions, particularly calcium and magnesium.
  • coloring agents may also be added to the cleaning composition.
  • the coloring agent is present in any amount less than about 1% by weight of the cleaning composition.
  • Additional optional components include corrosion inhibitors, disinfectants, preservatives, bactericides, moldicides, fungicides, and the like. If utilized, these components are typically present from about 0.1% to about 1% by weight of the cleaning composition.
  • a water repellant such as a silicone compound, may also be added for surface gloss and water repellency.
  • hydrophilic additives such as fluorocarbon surfactants, are particularly effective in reducing the number of applications or mistings necessary to be applied. Levels of less than 500 ppm is typically all that is necessary to obtain this hydrophilic effect.
  • the cleaning composition may be prepared using any of the methods known in the art involving the formation of liquid aqueous cleaning compositions.
  • the cleaning composition is prepared by blending all of the ingredients together in a vat or other container.
  • the composition of the present invention is best applied by being sprayed onto the surface to be cleaned with a pump or pressurized sprayer, and for best results, the solution is applied to the surfaces before the surface is dry.
  • the rinsing solution is particularly effective in the removal of deposits that are still wet.
  • the composition keeps the surface deposits, residues, and foulants in suspension and rinsable from the surfaces during the next shower. As a result, during subsequent showers, the solution transports these undesirable materials down the wet shower surfaces and into the shower drain.
  • the present composition is not an aggressive cleaner, but is more in the realm of a rinsing solution for maintaining a shower clean.
  • the present composition provides this cleaning action without scrubbing or wiping and without spotting or streaking.
  • the composition of the present invention also provides a method of cleaning a drain pipe of a basin.
  • the word "basin” is intended to define a bathtub, a shower enclosure, a sink, and the like.
  • the cleaning composition prevents clogging or slow running of water in the drain due to the buildup of organic materials and inorganic salts on the drainpipe's interior surfaces. This is accomplished by spraying the exposed surfaces of a basin surrounding an opening to a drain pipe, i.e., the upstanding and/or sloping walls of a shower enclosure, sink or tub, with the aqueous composition, and then wetting these exposed surfaces immediately thereafter or during a subsequent use.
  • the composition thus contacts the interior surfaces of the drain pipe causing foulants thereon to be held in suspension and rinsed away. Preferably, these steps are repeated on a daily basis. Also, the exposed surfaces surrounding the drain opening may be wetted prior to spraying the composition thereon, if desired. Accordingly, as an added benefit, the present composition provides a drain cleaning product which is easy to use and reduces the frequency at which drain clogs must be treated.
  • the above formulation was used to treat the shower walls after a shower had been finished. Prior to the shower, black tiles with suction cups glued to the back of the tiles were placed on all four walls of the shower. The cleaning and anti-streaking ability of this composition was determined by using the difference in reflectivity between the treated tiles and the original prewashed clean tiles. Measurements were taken using the CIE L*a*b color scale. The black tiles were prewashed with Formula 409 hard surface cleaner and the L*a*b* readings were taken using a Miniscan from HunterLab. The coating of the black tile by soap scum and hard water stains has a pronounced effect particularly on the lightness (L) reading of the L*a*b* scale. The initial readings appear in column 1 of Table 1.
  • the above formula had a pH of 12 and was tested for its cleaning and anti-streaking abilities as in Example 1 and was found to provide a preferred composition.
  • the following mixture was prepared, and aluminum coupon testing data demonstrated that this formula eliminates aluminum corrosion.
  • the composition had a pH of 12.
  • the change in gloss is typically expressed in terms of % gloss loss so that a low percentage is obviously more desirable with 0% being the most desirable.
  • Example 3 The formula described in Example 3 showed a change in gloss or gloss loss of 9%.
  • compositions of the present invention reduces the amount of labor and the number of cleaning compositions required to clean multiple surfaces in the shower stall.
  • the compositions may be dispensed utilizing commercially available packaging typically utilized for liquid cleaning compositions.
  • the compositions may be prepared using any of the methods typically used for forming liquid aqueous cleaning compositions.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne un détergent pour surface qui peut être utilisé pour être pulvérisé sur des surfaces telles que des parois de douche et des baignoires lorsqu'elles sont encore humides de manière à empêcher les dépôts indésirables de s'accumuler sur ces surfaces. Le détergent est constitué d'une base aqueuse et dépourvu d'alcool, on peut le rincer sur les surfaces sans qu'il soit nécessaire de frotter ou d'essuyer ces dernières, et une fois sec il ne laisse pas de taches ou de traînées. La formule sans frotter est constituée au maximum de 1 % en poids d'un agent mouillant ou d'un tensioactif, ou de mélanges de ces derniers, qui lors du séchage laisse un film transparent, de préférence d'un polyglycoside d'alkyle représentant jusqu'à 2 % en poids d'un agent chélateur, l'ingrédient restant étant de l'eau. La composition présente de manière avantageuse une perte de brillance inférieure à 25 %. Le pH de la formule se situe entre environ 5 et environ 12, mais il est de préférence alcalin avec un pH compris entre 9 et 12.
PCT/US1999/023505 1998-10-16 1999-10-13 Formulation permettant de nettoyer des surfaces sans frotter WO2000023553A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU11062/00A AU1106200A (en) 1998-10-16 1999-10-13 Scrub free formulation for cleaning surfaces

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US17393798A 1998-10-16 1998-10-16
US09/173,937 1998-10-16

Publications (1)

Publication Number Publication Date
WO2000023553A1 true WO2000023553A1 (fr) 2000-04-27

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AR (1) AR018964A1 (fr)
AU (1) AU1106200A (fr)
WO (1) WO2000023553A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2401875A (en) * 2003-05-22 2004-11-24 Reckitt Benckiser Nv Aqueous cleaning compositions
WO2006017922A1 (fr) * 2004-08-18 2006-02-23 Villa Frank L Solution de rinçage pour le nettoyage et la protection de surfaces
WO2014039302A1 (fr) 2012-09-04 2014-03-13 Lubrizol Advanced Materials, Inc. Dispersions hybrides de polyuréthane/polyacrylique pour applications brillantes d'entretien domestique
WO2018013523A1 (fr) * 2016-07-11 2018-01-18 Ecolab Usa Inc. Composition durable ne laissant pas de traînées pour le nettoyage et la désinfection de surfaces dures
WO2020039846A1 (fr) * 2018-08-23 2020-02-27 ショーワ株式会社 Détergent pour dispositif de drainage

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US3709825A (en) * 1967-11-06 1973-01-09 Colgate Palmolive Co Cleaning composition
US4690779A (en) * 1983-06-16 1987-09-01 The Clorox Company Hard surface cleaning composition
US5061395A (en) * 1990-01-04 1991-10-29 Ques Industries, Inc. Hard surface cleaning composition
WO1996013342A1 (fr) * 1994-11-01 1996-05-09 The Clorox Company Amelioration de l'elimination des corps gras dans les conduites d'evacuation des eaux usees
US5536452A (en) * 1993-12-07 1996-07-16 Black; Robert H. Aqueous shower rinsing composition and a method for keeping showers clean
WO1999013036A1 (fr) * 1997-09-10 1999-03-18 Albemarle Corporation Substance permettant de nettoyer les surfaces dures sans frotter
WO1999064548A1 (fr) * 1998-06-12 1999-12-16 The Clorox Company Composition de rinçage pour surfaces de douche

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3709825A (en) * 1967-11-06 1973-01-09 Colgate Palmolive Co Cleaning composition
US4690779A (en) * 1983-06-16 1987-09-01 The Clorox Company Hard surface cleaning composition
US5061395A (en) * 1990-01-04 1991-10-29 Ques Industries, Inc. Hard surface cleaning composition
US5536452A (en) * 1993-12-07 1996-07-16 Black; Robert H. Aqueous shower rinsing composition and a method for keeping showers clean
WO1996013342A1 (fr) * 1994-11-01 1996-05-09 The Clorox Company Amelioration de l'elimination des corps gras dans les conduites d'evacuation des eaux usees
WO1996022346A1 (fr) * 1995-01-19 1996-07-25 Black Robert H Composition pour le rinçage de douches et procede pour maintenir la proprete des douches
WO1999013036A1 (fr) * 1997-09-10 1999-03-18 Albemarle Corporation Substance permettant de nettoyer les surfaces dures sans frotter
WO1999064548A1 (fr) * 1998-06-12 1999-12-16 The Clorox Company Composition de rinçage pour surfaces de douche

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2401875A (en) * 2003-05-22 2004-11-24 Reckitt Benckiser Nv Aqueous cleaning compositions
WO2006017922A1 (fr) * 2004-08-18 2006-02-23 Villa Frank L Solution de rinçage pour le nettoyage et la protection de surfaces
WO2014039302A1 (fr) 2012-09-04 2014-03-13 Lubrizol Advanced Materials, Inc. Dispersions hybrides de polyuréthane/polyacrylique pour applications brillantes d'entretien domestique
WO2018013523A1 (fr) * 2016-07-11 2018-01-18 Ecolab Usa Inc. Composition durable ne laissant pas de traînées pour le nettoyage et la désinfection de surfaces dures
JP2019526533A (ja) * 2016-07-11 2019-09-19 エコラボ ユーエスエー インコーポレイティド 硬質表面を洗浄および消毒するための、ストリークを付けない耐久性組成物
US10433545B2 (en) 2016-07-11 2019-10-08 Ecolab Usa Inc. Non-streaking durable composition for cleaning and disinfecting hard surfaces
AU2017296193B2 (en) * 2016-07-11 2020-07-09 Ecolab Usa Inc. Non-streaking durable composition for cleaning and disinfecting hard surfaces
US10945431B2 (en) 2016-07-11 2021-03-16 Ecolab Usa Inc. Non-streaking durable composition for cleaning and disinfecting hard surfaces
WO2020039846A1 (fr) * 2018-08-23 2020-02-27 ショーワ株式会社 Détergent pour dispositif de drainage
CN112585251A (zh) * 2018-08-23 2021-03-30 昭和工业株式会社 排水装置用清洗剂

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