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WO2000064952A3 - Polyethene non reticule - Google Patents

Polyethene non reticule Download PDF

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Publication number
WO2000064952A3
WO2000064952A3 PCT/FI2000/000366 FI0000366W WO0064952A3 WO 2000064952 A3 WO2000064952 A3 WO 2000064952A3 FI 0000366 W FI0000366 W FI 0000366W WO 0064952 A3 WO0064952 A3 WO 0064952A3
Authority
WO
WIPO (PCT)
Prior art keywords
rac
frequencies
zirconium dichloride
ethylene bis
difference
Prior art date
Application number
PCT/FI2000/000366
Other languages
English (en)
Other versions
WO2000064952A2 (fr
Inventor
Anneli Malmberg
Barbro Loefgren
Original Assignee
Borealis Tech Oy
Anneli Malmberg
Barbro Loefgren
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Tech Oy, Anneli Malmberg, Barbro Loefgren filed Critical Borealis Tech Oy
Priority to AU42992/00A priority Critical patent/AU4299200A/en
Publication of WO2000064952A2 publication Critical patent/WO2000064952A2/fr
Publication of WO2000064952A3 publication Critical patent/WO2000064952A3/fr

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Silicon Polymers (AREA)

Abstract

La présente invention concerne un polyéthène non réticulé dont la valeur de la différence normalisée entre son module de stockage G' et son module de perte G'', déterminée par mesure rhéologique dynamique, est continuellement inférieure à 0,5 sous des fréquences allant de 0,01 à 100 rad/s et à une température de 190 °C. Cette différence est de préférence sensiblement constante sous lesdites fréquences. On prépare de préférence ces polyéthènes en utilisant des catalyseurs métallocènes, et dans un mode de réalisation préférée ces catalyseurs sont à base de rac-éthylène bis(3-tri-isopropylsiloxy)indenyl zirconium dichloride ou de rac-éthylène bis(3-tert-butyldiméthylsiloxy)indenyl zirconium dichloride.
PCT/FI2000/000366 1999-04-27 2000-04-27 Polyethene non reticule WO2000064952A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU42992/00A AU4299200A (en) 1999-04-27 2000-04-27 Non-crosslinked polyethene

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI990948 1999-04-27
FI990948A FI990948A0 (fi) 1999-04-27 1999-04-27 Ei-ristisilloitettu polyeteeni

Publications (2)

Publication Number Publication Date
WO2000064952A2 WO2000064952A2 (fr) 2000-11-02
WO2000064952A3 true WO2000064952A3 (fr) 2001-02-01

Family

ID=8554530

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI2000/000366 WO2000064952A2 (fr) 1999-04-27 2000-04-27 Polyethene non reticule

Country Status (3)

Country Link
AU (1) AU4299200A (fr)
FI (1) FI990948A0 (fr)
WO (1) WO2000064952A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7279536B2 (en) 2002-09-20 2007-10-09 Exxonmobil Chemical Patents Inc. Polymer production at supercritical conditions

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006500470A (ja) 2002-09-20 2006-01-05 エクソンモービル・ケミカル・パテンツ・インク 超臨界重合方法およびこれにより製造したポリマー
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
CN101855250B (zh) 2007-09-13 2013-01-02 埃克森美孚研究工程公司 增塑剂与基础聚合物的在线共混
WO2009035580A1 (fr) 2007-09-13 2009-03-19 Exxonmobil Research And Engineering Company Procede de production en ligne de polymeres plastifies et melanges de polymeres plastifies
CN101945940B (zh) 2007-12-20 2014-04-09 埃克森美孚研究工程公司 聚丙烯乙烯-丙烯共聚物共混物和生产它的在线方法
US7910679B2 (en) 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
CN101945942B (zh) 2007-12-20 2012-08-08 埃克森美孚研究工程公司 生产粒料稳定的聚烯烃的在线方法
US20110172354A1 (en) * 2010-01-04 2011-07-14 Dow Global Technologies Inc. Ethylene-based polymer compositions for use in fiber applications

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0676421A1 (fr) * 1994-04-07 1995-10-11 BP Chemicals Limited Procédé de polymérisation et polyoléfines ainsi obtenues
WO1996007680A1 (fr) * 1994-09-07 1996-03-14 The Dow Chemical Company Polyethylene basse densite, lineaire et malleable
EP0729978A1 (fr) * 1995-03-03 1996-09-04 Phillips Petroleum Company Polyethylène et méthode pour sa production
EP0743324A2 (fr) * 1995-05-16 1996-11-20 Union Carbide Chemicals & Plastics Technology Corporation Production de polyéthylène utilisant des métallocènes stéréoisomériques
WO1997029138A1 (fr) * 1996-02-09 1997-08-14 Exxon Chemical Patents Inc. Procede de polymerisation
WO1997044371A1 (fr) * 1996-05-17 1997-11-27 The Dow Chemical Company Composition polyolefinique presentant un poids moleculaire maximum dans sa partie ayant la teneur la plus elevee en comonomeres

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0676421A1 (fr) * 1994-04-07 1995-10-11 BP Chemicals Limited Procédé de polymérisation et polyoléfines ainsi obtenues
WO1996007680A1 (fr) * 1994-09-07 1996-03-14 The Dow Chemical Company Polyethylene basse densite, lineaire et malleable
EP0729978A1 (fr) * 1995-03-03 1996-09-04 Phillips Petroleum Company Polyethylène et méthode pour sa production
EP0743324A2 (fr) * 1995-05-16 1996-11-20 Union Carbide Chemicals & Plastics Technology Corporation Production de polyéthylène utilisant des métallocènes stéréoisomériques
WO1997029138A1 (fr) * 1996-02-09 1997-08-14 Exxon Chemical Patents Inc. Procede de polymerisation
WO1997044371A1 (fr) * 1996-05-17 1997-11-27 The Dow Chemical Company Composition polyolefinique presentant un poids moleculaire maximum dans sa partie ayant la teneur la plus elevee en comonomeres

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7279536B2 (en) 2002-09-20 2007-10-09 Exxonmobil Chemical Patents Inc. Polymer production at supercritical conditions

Also Published As

Publication number Publication date
AU4299200A (en) 2000-11-10
WO2000064952A2 (fr) 2000-11-02
FI990948A0 (fi) 1999-04-27

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