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WO2000051829A3 - Decorative sheet material with chlorinated polyolefin adhesive layer - Google Patents

Decorative sheet material with chlorinated polyolefin adhesive layer Download PDF

Info

Publication number
WO2000051829A3
WO2000051829A3 PCT/US2000/003919 US0003919W WO0051829A3 WO 2000051829 A3 WO2000051829 A3 WO 2000051829A3 US 0003919 W US0003919 W US 0003919W WO 0051829 A3 WO0051829 A3 WO 0051829A3
Authority
WO
WIPO (PCT)
Prior art keywords
sheet material
decorative sheet
adhesive layer
chlorinated
chlorinated polyolefin
Prior art date
Application number
PCT/US2000/003919
Other languages
French (fr)
Other versions
WO2000051829A2 (en
Inventor
Scott Huffer
Quan Song
Original Assignee
Rexam Ind Corp
Scott Huffer
Quan Song
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rexam Ind Corp, Scott Huffer, Quan Song filed Critical Rexam Ind Corp
Priority to CA002360504A priority Critical patent/CA2360504A1/en
Priority to EP00919306A priority patent/EP1144205A3/en
Priority to AU40014/00A priority patent/AU4001400A/en
Publication of WO2000051829A2 publication Critical patent/WO2000051829A2/en
Publication of WO2000051829A3 publication Critical patent/WO2000051829A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
    • B29C45/14811—Multilayered articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/04—External Ornamental or guard strips; Ornamental inscriptive devices thereon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/26—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment
    • C09J123/28—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2791/00—Shaping characteristics in general
    • B29C2791/001—Shaping in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2791/00—Shaping characteristics in general
    • B29C2791/004—Shaping under special conditions
    • B29C2791/006—Using vacuum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/08—Deep drawing or matched-mould forming, i.e. using mechanical means only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/14—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor using multilayered preforms or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2715/00—Condition, form or state of preformed parts, e.g. inserts
    • B29K2715/006—Glues or adhesives, e.g. hot melts or thermofusible adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/002—Coloured
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/0026—Transparent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3044—Bumpers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3055—Cars
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51—Elastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/712—Weather resistant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/10—Polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00—Decorative or ornamental articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/08—Cars
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Laminated Bodies (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)

Abstract

The flexible, weatherable decorative sheet material provided by the present invention comprises a thermoformable decorative paint film having an inner surface and a weatherable outer surface suitable for forming an exterior finish for a part, such as an automobile body part. The decorative sheet material includes an adhesive layer overlying the inner surface of the decorative paint film, wherein the adhesive layer comprises a chlorinated polypropylene component and a chlorinated polyolefin component. The chlorinated polypropylene component has a peel strength of at least about 0.8 lbs./in. at 100 °C and the chlorinated polyolefin component has a peel strength of at least about 5 lbs./in. at room temperature. The two chlorinated components have similar chlorine contents, such as between about 20 to about 40 weight percent chlorine. A method of constructing the decorative sheet material and a composite shaped part including the decorative sheet material are also provided.
PCT/US2000/003919 1999-03-01 2000-02-16 Decorative sheet material with chlorinated polyolefin adhesive layer WO2000051829A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CA002360504A CA2360504A1 (en) 1999-03-01 2000-02-16 Decorative sheet material with chlorinated polyolefin adhesive layer
EP00919306A EP1144205A3 (en) 1999-03-01 2000-02-16 Decorative sheet material with chlorinated polyolefin adhesive layer
AU40014/00A AU4001400A (en) 1999-03-01 2000-02-16 Decorative sheet material with chlorinated polyolefin adhesive layer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US25997599A 1999-03-01 1999-03-01
US09/259,975 1999-03-01

Publications (2)

Publication Number Publication Date
WO2000051829A2 WO2000051829A2 (en) 2000-09-08
WO2000051829A3 true WO2000051829A3 (en) 2001-09-20

Family

ID=22987278

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/003919 WO2000051829A2 (en) 1999-03-01 2000-02-16 Decorative sheet material with chlorinated polyolefin adhesive layer

Country Status (4)

Country Link
EP (1) EP1144205A3 (en)
AU (1) AU4001400A (en)
CA (1) CA2360504A1 (en)
WO (1) WO2000051829A2 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020164466A1 (en) * 2000-08-18 2002-11-07 Jaekel Federico G. Exterior vacuum molded body panels
ES2364752T3 (en) * 2003-01-20 2011-09-13 Compagnie Plastic Omnium EXTERNAL PART OF AUTOMOBILE VEHICLE THAT INCLUDES A DECORATIVE FILM AND A MANUFACTURING PROCEDURE OF THE SUCH PART.
DE60309661T2 (en) * 2003-03-27 2007-09-13 Taiyi Precision Tech Corp. Screen printing process for use in injection molding
US20050164023A1 (en) * 2004-01-26 2005-07-28 Davis Scott M. Structurally reinforced resinous article and method of making
US7854985B2 (en) 2005-11-18 2010-12-21 Soliant Llc Decorative paint film laminate
GB2449597B (en) * 2006-02-16 2011-01-12 Kansai Paint Co Ltd Water-based primer composition and coating method of plastic shaped articles using the composition
US7678469B2 (en) 2006-05-22 2010-03-16 Yamaha Hatsudoki Kabushiki Kaisha Decorative sheet, formed product and transportation apparatus
CN101687046B (en) 2007-07-10 2012-12-26 株式会社美地拓斯 Pharmaceutical liquid composition of botulinum toxin with improved stability
WO2009012602A1 (en) * 2007-07-20 2009-01-29 Celfa Ag Method for the production of decorated plastic parts
KR101698638B1 (en) * 2010-09-15 2017-01-20 도레이 카부시키가이샤 Decorative molding film
FR3039803B1 (en) * 2015-08-04 2017-08-25 Peugeot Citroen Automobiles Sa DECORATION ELEMENT FOR MOTOR VEHICLE
FR3098162B1 (en) * 2019-07-03 2024-07-26 Cie Plastic Omnium Se Body part element comprising an orifice covered with a protective coating

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5127974A (en) * 1989-05-15 1992-07-07 Kansai Paint Co., Ltd. Method of protecting coating film
WO1994003337A2 (en) * 1992-07-31 1994-02-17 Minnesota Mining And Manufacturing Company Paint film and methods for its manufacture
US5385979A (en) * 1994-01-11 1995-01-31 Lord Corporation Primer and adhesive compositions based on chlorinated polyolefins having high chlorine contents
US5725712A (en) * 1987-03-27 1998-03-10 Avery Dennison Corporation Dry paint transfer process for making high DOI automotive body panels
WO1999008870A1 (en) * 1997-08-18 1999-02-25 Minnesota Mining And Manufacturing Company Paint film assembly with masking film

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5725712A (en) * 1987-03-27 1998-03-10 Avery Dennison Corporation Dry paint transfer process for making high DOI automotive body panels
US5127974A (en) * 1989-05-15 1992-07-07 Kansai Paint Co., Ltd. Method of protecting coating film
WO1994003337A2 (en) * 1992-07-31 1994-02-17 Minnesota Mining And Manufacturing Company Paint film and methods for its manufacture
US5385979A (en) * 1994-01-11 1995-01-31 Lord Corporation Primer and adhesive compositions based on chlorinated polyolefins having high chlorine contents
WO1999008870A1 (en) * 1997-08-18 1999-02-25 Minnesota Mining And Manufacturing Company Paint film assembly with masking film

Also Published As

Publication number Publication date
CA2360504A1 (en) 2000-09-08
WO2000051829A2 (en) 2000-09-08
EP1144205A3 (en) 2002-01-23
EP1144205A2 (en) 2001-10-17
AU4001400A (en) 2000-09-21

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