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WO2000050550A2 - Compositions pour lave-vaisselle a systeme mixte de tensio-actifs - Google Patents

Compositions pour lave-vaisselle a systeme mixte de tensio-actifs Download PDF

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Publication number
WO2000050550A2
WO2000050550A2 PCT/US2000/003456 US0003456W WO0050550A2 WO 2000050550 A2 WO2000050550 A2 WO 2000050550A2 US 0003456 W US0003456 W US 0003456W WO 0050550 A2 WO0050550 A2 WO 0050550A2
Authority
WO
WIPO (PCT)
Prior art keywords
surfactant
automatic dishwashing
nonionic surfactant
weight
compositions
Prior art date
Application number
PCT/US2000/003456
Other languages
English (en)
Other versions
WO2000050550A3 (fr
Inventor
Glenn Thomas Jordan, Iv
William Michael Scheper
Mark Robert Sivik
Donna Jean Haeggberg
Bernard William Kluesener
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to EP00907253A priority Critical patent/EP1190026A2/fr
Priority to JP2000601114A priority patent/JP2002537483A/ja
Priority to AU28777/00A priority patent/AU2877700A/en
Priority to CA002362841A priority patent/CA2362841A1/fr
Publication of WO2000050550A2 publication Critical patent/WO2000050550A2/fr
Publication of WO2000050550A3 publication Critical patent/WO2000050550A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/755—Sulfoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/79—Phosphine oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • Automatic dishwashing with bleaching chemicals is different from fabric bleaching.
  • use of bleaching chemicals involves promotion of soil removal from dishes, though soil bleaching may also occur. Additionally, soil antiredeposition and anti-spotting effects from bleaching chemicals are desirable.
  • Some bleaching chemicals (such as a hydrogen peroxide source, alone or together with tetraacetylethylenediamine, aka "TAED") can, in certain circumstances, be helpful for cleaning dishware
  • adjunct materials wherein the weight ratio of the low foaming nonionic surfactant to the oxide surfactant is from about 2:1 to about 30:1.
  • Amounts of the essential ingredients can vary within wide ranges, however preferred automatic dishwashing detergent compositions herein (which typically have a 1% aqueous solution pH of above about 8, more preferably from about 9.5 to about 12, most preferably from about 9.5 to about 10.5) are those wherein there is present: from about 5% to about 90%, preferably from about 5% to about 75%, of builder; from about 0.1%) to about 15%, preferably from about 0.2% to about 10%, of the nonionic surfactant.
  • preferred automatic dishwashing detergent compositions herein which typically have a 1% aqueous solution pH of above about 8, more preferably from about 9.5 to about 12, most preferably from about 9.5 to about 10.5 are those wherein there is present: from about 5% to about 90%, preferably from about 5% to about 75%, of builder; from about 0.1%) to about 15%, preferably from about 0.2% to about 10%, of the nonionic surfactant.
  • the amount of dimer and trimer present in the glyceryl ether containing surfactant is dependent upon the process used to produce the surfactant.
  • the preferred method for minimizing or eliminating the formation of dimer and trimer maybe controlled by the stoichiometry of the reactants or via typical purification methods (e.g. Chromatography, crystallization, fictionalization etc.).
  • a preferred combination is a detergent composition having a cocktail of conventional applicable enzymes like protease, amylase, lipase, cutinase and or cellulase. Enzymes when present in the compositions, at from about 0.0001%> to about 5% of active enzyme by weight of the detergent composition. Highly preferred for automatic dishwashing are amylases and/or proteases, including both current commercially available types and improved types which, though more bleach compatible, have a remaining degree of bleach deactivation susceptibility. 15
  • Protease enzyme may be incorporated into the compositions in accordance with the invention at a level of from 0.0001%> to 2% active enzyme by weight of the composition.
  • Amylase - Amylases can be included for removal of carbohydrate- based stains.
  • Suitable amylases are Termamyl® (Novo Nordisk), Fungamyl® and BAN® (Novo Nordisk).
  • the enzymes may be of any suitable origin, such as vegetable, animal, bacterial, fungal and yeast origin.
  • Amylase enzymes are normally incorporated in the detergent composition at levels from 0.0001%> to 2%, preferably from about 0.0001% to about 0.5%, more preferably from about 0.0005% to about 0.1%, even more preferably from about 0.001 % to about 0.05%> of active enzyme by weight of the detergent composition.
  • Suitable polymers are preferably at least partially neutralized or alkali metal, ammonium or substituted ammonium (e.g., mono-, di- or triethanolammonium) salts of 24
  • Highly preferred silicone suds suppressors are the compounded types known for use in laundry detergents such as heavy-duty granules, although types hitherto used only in heavy-duty liquid detergents may also be incorporated in the instant compositions.
  • polydimethylsiloxanes having trimethylsilyl or alternate endblocking units may be used as the silicone.
  • These may be compounded with silica and or with surface-active nonsilicon components, as illustrated by a suds suppressor comprising 12%> silicone/silica, 18% stearyl alcohol and 70%> starch in granular form.
  • a suitable commercial source of the silicone active compounds is Dow Corning Corp.
  • Neodol 91-8 (30.00 g, 58.7 mmol) is placed into a 250 ml three-necked round- bottomed flask, fitted with a heating mantle, magnetic stirrer, internal thermometer and argon inlet, and dried under vacuum at 75°C. After cooling to ambient and releasing the vacuum with argon, methylene chloride (12ml) and 2 -methyl- 1-butene (4.53 g, 64.6 mmol) are added. Then boron trifluoride diethyl etherate (0.83 g, 5.9 mmol) is added all at once. This mixture is stirred 5 days at ambient.
  • Polymer 2 4.0 Dibenzoyl Peroxide 0.2 0.15 Paraffin 0.5 0.5 Benzotriazole 0.10 0.3 Ci6 Amine Oxide 0.5 0.5 Nonionic Surfactant 3 2.0 2.0
  • Nonionic surfactant according to Example 1.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention porte sur des compositions détergentes pour lave-vaisselle consistant en un système mixte de tensio-actifs composé d'un tensio-actif non ionique à faible pouvoir moussant d'un indice X/Y supérieur à 1,00 et d'un tensio-actif d'oxyde.
PCT/US2000/003456 1999-02-22 2000-02-10 Compositions pour lave-vaisselle a systeme mixte de tensio-actifs WO2000050550A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP00907253A EP1190026A2 (fr) 1999-02-22 2000-02-10 Compositions pour lave-vaisselle a systeme mixte de tensio-actifs
JP2000601114A JP2002537483A (ja) 1999-02-22 2000-02-10 混合界面活性剤系を含有する自動食器洗浄用組成物
AU28777/00A AU2877700A (en) 1999-02-22 2000-02-10 Automatic dishwashing compositions comprising mixed surfactants systems
CA002362841A CA2362841A1 (fr) 1999-02-22 2000-02-10 Compositions pour lave-vaisselle a systeme mixte de tensio-actifs

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12103299P 1999-02-22 1999-02-22
US60/121,032 1999-02-22

Publications (2)

Publication Number Publication Date
WO2000050550A2 true WO2000050550A2 (fr) 2000-08-31
WO2000050550A3 WO2000050550A3 (fr) 2002-01-24

Family

ID=22394071

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/003456 WO2000050550A2 (fr) 1999-02-22 2000-02-10 Compositions pour lave-vaisselle a systeme mixte de tensio-actifs

Country Status (5)

Country Link
EP (1) EP1190026A2 (fr)
JP (1) JP2002537483A (fr)
AU (1) AU2877700A (fr)
CA (1) CA2362841A1 (fr)
WO (1) WO2000050550A2 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6365785B1 (en) * 1997-08-02 2002-04-02 Therprocter & Gamble Company Process for preparing ether-capped poly(oxyalkylated) alcohol surfactants
WO2007098831A1 (fr) * 2006-02-24 2007-09-07 Henkel Ag & Co. Kgaa Agent de lavage ou de nettoyage
JP2014503664A (ja) * 2011-01-13 2014-02-13 ビーエーエスエフ ソシエタス・ヨーロピア 洗剤及び清浄剤における、ポリアルキレングリコールの場合によって酸化されたチオエーテルの使用
EP2746376A1 (fr) * 2012-12-21 2014-06-25 The Procter & Gamble Company Composition pour laver la vaisselle
RU2564033C2 (ru) * 2010-08-05 2015-09-27 Аксесс Бусинесс Гроуп Интернатионал Ллс Бесфосфатное и бесфосфонатное гелевое моющее средство для автоматического мытья посуды, обеспечивающее улучшенные характеристики пятно- и пленкообразования
WO2017076802A1 (fr) * 2015-11-02 2017-05-11 Henkel Ag & Co. Kgaa Mélange de tensioactifs contenant de l'oxyde d'amine destiné à améliorer l'efficacité de rinçage
US9951304B2 (en) 2012-12-21 2018-04-24 The Procter & Gamble Company Cleaning pack
US10774291B2 (en) 2016-06-16 2020-09-15 Dow Global Technologies Llc Automatic dishwashing compositions with spot prevention surfactant

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5337371B2 (ja) * 2007-11-28 2013-11-06 花王株式会社 自動食器洗浄機用洗浄剤組成物
JP5491773B2 (ja) * 2009-06-10 2014-05-14 花王株式会社 自動食器洗浄機用洗浄剤組成物
EP2338961A1 (fr) * 2009-12-22 2011-06-29 The Procter & Gamble Company Composition détergente liquide alcaline de lavage de la vaisselle à la main
EP2915873A1 (fr) * 2014-03-06 2015-09-09 The Procter and Gamble Company Composition pour laver la vaisselle
JP6375129B2 (ja) * 2014-04-01 2018-08-15 株式会社Adeka 食器類の洗浄方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU66053A1 (fr) * 1972-09-11 1974-03-14
US3953382A (en) * 1973-05-30 1976-04-27 Lever Brothers Company Detergent compositions
US6020296A (en) * 1993-08-04 2000-02-01 Colgate Palmolive Company All purpose liquid cleaning composition comprising anionic, amine oxide and EO-BO nonionic surfactant
DE4327327A1 (de) * 1993-08-13 1995-02-16 Henkel Kgaa Detergensgemische
EP0713521B1 (fr) * 1993-08-13 1998-07-15 The Procter & Gamble Company Detergent granuleux pour lave-vaisselle contenant des oxydes d'amines a longue chaine
CA2297829A1 (fr) * 1997-08-02 1999-02-11 The Procter & Gamble Company Compositions renfermant des tensioactifs a base d'alcools poly(oxyalkyles) coiffes par un ether

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6365785B1 (en) * 1997-08-02 2002-04-02 Therprocter & Gamble Company Process for preparing ether-capped poly(oxyalkylated) alcohol surfactants
WO2007098831A1 (fr) * 2006-02-24 2007-09-07 Henkel Ag & Co. Kgaa Agent de lavage ou de nettoyage
RU2564033C2 (ru) * 2010-08-05 2015-09-27 Аксесс Бусинесс Гроуп Интернатионал Ллс Бесфосфатное и бесфосфонатное гелевое моющее средство для автоматического мытья посуды, обеспечивающее улучшенные характеристики пятно- и пленкообразования
JP2014503664A (ja) * 2011-01-13 2014-02-13 ビーエーエスエフ ソシエタス・ヨーロピア 洗剤及び清浄剤における、ポリアルキレングリコールの場合によって酸化されたチオエーテルの使用
EP2746376A1 (fr) * 2012-12-21 2014-06-25 The Procter & Gamble Company Composition pour laver la vaisselle
WO2014099853A1 (fr) * 2012-12-21 2014-06-26 The Procter & Gamble Company Composition de détergent pour lave-vaisselle
US9951304B2 (en) 2012-12-21 2018-04-24 The Procter & Gamble Company Cleaning pack
WO2017076802A1 (fr) * 2015-11-02 2017-05-11 Henkel Ag & Co. Kgaa Mélange de tensioactifs contenant de l'oxyde d'amine destiné à améliorer l'efficacité de rinçage
US10774291B2 (en) 2016-06-16 2020-09-15 Dow Global Technologies Llc Automatic dishwashing compositions with spot prevention surfactant
EP3472295B1 (fr) 2016-06-16 2021-07-21 Dow Global Technologies, LLC Compositions pour lave-vaisselle automatique avec un tensioactif de prévention de tache

Also Published As

Publication number Publication date
EP1190026A2 (fr) 2002-03-27
CA2362841A1 (fr) 2000-08-31
AU2877700A (en) 2000-09-14
JP2002537483A (ja) 2002-11-05
WO2000050550A3 (fr) 2002-01-24

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