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WO1999037390A1 - Appareil comprenant une enveloppe souple ainsi qu'une membrane tubulaire en elastomere prise a l'interieur de cette enveloppe et technique d'utilisation de cet appareil aux fins de la separation de substances - Google Patents

Appareil comprenant une enveloppe souple ainsi qu'une membrane tubulaire en elastomere prise a l'interieur de cette enveloppe et technique d'utilisation de cet appareil aux fins de la separation de substances Download PDF

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Publication number
WO1999037390A1
WO1999037390A1 PCT/GB1999/000186 GB9900186W WO9937390A1 WO 1999037390 A1 WO1999037390 A1 WO 1999037390A1 GB 9900186 W GB9900186 W GB 9900186W WO 9937390 A1 WO9937390 A1 WO 9937390A1
Authority
WO
WIPO (PCT)
Prior art keywords
shell
membrane
aqueous liquid
tubular membrane
tubular
Prior art date
Application number
PCT/GB1999/000186
Other languages
English (en)
Inventor
Andrew Guy Livingston
Andrew Timothy Boam
Jean-Pierre Arcangeli
Shengfu Zhang
Original Assignee
Membrane Extraction Technology Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9801272.7A external-priority patent/GB9801272D0/en
Priority claimed from GBGB9811185.9A external-priority patent/GB9811185D0/en
Priority claimed from GB9823963A external-priority patent/GB2333473B/en
Application filed by Membrane Extraction Technology Ltd. filed Critical Membrane Extraction Technology Ltd.
Priority to AU21756/99A priority Critical patent/AU2175699A/en
Publication of WO1999037390A1 publication Critical patent/WO1999037390A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/08—Prevention of membrane fouling or of concentration polarisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/24—Dialysis ; Membrane extraction
    • B01D61/246—Membrane extraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/24—Dialysis ; Membrane extraction
    • B01D61/28—Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06—Tubular membrane modules
    • B01D63/068—Tubular membrane modules with flexible membrane tubes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/20—By influencing the flow
    • B01D2321/2008—By influencing the flow statically

Definitions

  • the present invention relates to a method for contacting two aqueous liquids and an apparatus useful in that method. Specifically, the present invention relates to a method for contacting liquid streams for the purposes of allowing specific chemical species to selectively permeate across a non porous elastomeric membrane from one stream to another.
  • US-A-4,988,443 discloses a method for contacting an aqueous waste stream containing organic toxicants with a nutrient-containing aqueous stream using a porous hollow fibre membrane.
  • the pores of the membrane are filled with water immiscible solvent.
  • the two streams do not mix but the organic toxicants may be transferred from the waste stream across the membrane to the nutrient stream.
  • Micro-organisms growing associated with the outside of the hollow fibres utilise the nutrients and organic toxicants as growth substrates and proliferate.
  • SU-Al-1263654 discloses a treatment of wastewaters containing heavy metals.
  • a microbial culture capable of producing hydrogen sulphide is contacted with one side of a membrane, while a wastewater containing heavy metals is contacted with the opposite side.
  • Microbially produced hydrogen sulphide permeates across the membrane causing the metals in the wastewater to precipitate as insoluble sulphides.
  • Membrane based extraction systems have also been disclosed in connection with extraction of alcohol from beverages. For example see WO 87/02380.
  • methods are generally well known for contacting two liquid streams in order to effect permeation of specific chemical species between the streams.
  • EP-A-0120285 discloses a porous membrane system designed to effect catalysis of a reaction utilising a hydrophobic substrate by an enzyme present in a hydrophilic phase.
  • the porous membrane is used to separate two liquids, one an aqueous phase containing the enzyme and one an organic phase comprising the hydrophobic substrate. When the two phases make contact at the pore-membrane surface interface, the reaction proceeds.
  • EP-A-0112812 describes a system in which two liquid zones are separated by a semi-permeable membrane.
  • the membrane is permeable to predetermined reactant and product materials while being impermeable to catalytically active cell material that is essentially confluently packed in the second zone.
  • the reactant material supplied to the first zone permeates the membrane and contacts the catalyst in the second zone, thereby forming product material.
  • Product material permeates across the membrane and is removed from the first zone.
  • tubular means having a hollow body which defines an internal volume.
  • the body may or may not have a circular cross-section.
  • the body may or may not be continuous in any particular plane or direction.
  • modules which comprise a rigid shell which contains a bundle of porous hollow fibre membranes.
  • the hollow fibre membranes may be composite membranes.
  • Composite membranes comprise a porous support coated with a thin layer of a non porous polymer which effects the separation (see Wijmans et al, Environmental Progress, 1990 9 p262).
  • tubular elastomeric non porous homogeneous membranes for example silicone rubber (cross-linked polydimethoxysiloxane) tubes, have been used.
  • Elastomeric non porous homogeneous membranes provide separation by allowing specific chemical species (for example, oxygen or hydrophobic organic molecules such as benzene, toluene, or their derivatives) to preferentially dissolve in the membrane and permeate across the membrane by diffusion under the influence of a chemical activity driving force.
  • US-A-5585004 discloses a system wherein a waste stream containing toxic organic compounds is fed into the inside of selectively permeable silicone rubber membrane tubes which are suspended in a bioreactor receptacle filled with a biologically active medium. The toxic organic compounds diffuse across the silicone rubber membrane and into the biologically active medium. In the biologically active medium the toxic organic compounds are degraded by the microbial culture.
  • tubular elastomeric membranes oxygenation of microbial systems (Cote et al, Journal of Membrane Science 1989 47 pi 07), and pervaporation (Raghunath and Hwang, Journal of Membrane Science 1992 65. p
  • Coiled membranes are known in the art for improving mass transfer and ease of construction of membrane systems.
  • GB-A-1435985, GB-A- 13628742, GB-A- 1181934, WO-A-97/05946 and US-A-4,568,648 all disclose coiled tubular membranes.
  • GB-A-1435985 and GB-A-1181934 describe devices for dialysis in which coiled dialysis membranes are contained within a shell which is a sealed circular box.
  • GB-A-1362874 describes a process for producing polymeric reverse osmosis membranes by winding the tubular membranes around a spool. A module is later formed by sealing this coiled membrane inside a suitable circular box.
  • WO-A-97/05946 describes a system in which porous membranes are tightly coiled so as to produce Dean vortices. The coiled membranes are held in a conventional straight shell.
  • US-A-4,568,648 discloses a coiled silicone rubber membrane tube for use in a deoxygenating device. The coiled membrane tube is held in a straight cylinder.
  • GB-A-1510486 discloses a filtration system in which a composite membrane is formed by attaching a layer of membrane to either the internal or external surface of a flexible porous support elements. These porous support elements are held within a flexible shell which is coiled.
  • US-A-5202023 discloses a system in which hollow fibre membranes are formed into bundles which are then optionally placed inside a casing. This casing may be flexible, allowing the whole module to be coiled into various shapes.
  • the fibres being substantially rigid olefinic materials, are potted using flexible elastomers for the headsheets, and are preferably twisted so that different fibres are on the outside portion of the bend radius at different points along the bundle length, in an attempt to minimise the tendency to stretch or break fibres if the module casing is coiled.
  • US-A-5202023 teaches that these modules have utility in filtration operations, where a pressure driving force is used to separate fluids. In cases where fluid is fed to the bore side of the fibres, a pressure casing is not needed.
  • the present invention aims to overcome the problems of the prior art.
  • an apparatus comprising an elastomeric tubular membrane and a shell, wherein the membrane is partially or completely enclosed by the shell; wherein the shell is constructed from a flexible material which is circular in cross section; and wherein the ratio of the fully extended length of the shell relative to its internal diameter is greater than 200.
  • elastomeric tubular membrane it is meant a tubular membrane which has a tendency to recover its size and shape after deformation.
  • elastomeric is given its accepted meaning.
  • tubular membrane when referred to in the singular this term may also encompass a plurality of tubular membranes.
  • Each reference to a singular tubular membrane or preferred feature thereof includes one or some or all of the plurality of tubular membranes encompassed by the term.
  • the length of the shell has little or no effect on the mass transfer coefficient.
  • a longer shell provides a smaller cross sectional area for flow of the shellside aqueous liquid.
  • the velocity in the shell side will be greater than for a module which has the same membrane area per shell volume and the same shellside flowrate, but which is shorter in length.
  • Sep.Sci.Tech. 28 p343 describe how problems with poor flow distribution on the shell side of modules reduce mass transfer coefficients in hollow fibre bundles.
  • the present invention is further advantageous because modules which for any given area of membrane relative to the shell volume, and any given flowrate of aqueous liquid on the shell side of the membrane module, have longer shells, the pressure drop per length of shell will be higher. This increased pressure drop per length may tend to provide more uniform distribution of flow across the shell side cross section of the module.
  • the substance is present in either the first aqueous liquid or in the second aqueous liquid in amount of no greater than 2 wt.%, more preferably in amount of no greater than 1 wt.%, more preferably in amount of no greater than 0.5 wt.%.
  • the substance to be transferred is one or more organic compounds.
  • the one or more organic compounds may be aromatic or aliphatic, halogenated or non-halogenated.
  • the one or more organic compounds may be selected from chlorinated hydrocarbons such as dichloromethane, trichloroethylene, chloroform, perchloroethylene, dichloroethane, carbon tetrachloride, chlorinated benzenes, chlorinated toluenes, non-chlorinated hydrocarbons such as benzene, toluene, xylene, ethylbenzene, styrene, cyclohexane, hexane, nitrobenzene, derivatives and mixtures thereof.
  • the present inventors have appreciated that increasing shell length and membrane tube length, leads to a higher pressure drop per tube at equal flow of aqueous liquid within the tube. This higher pressure drop, provided by longer tubes, will make the distribution of the total flow of aqueous liquid within the tubes across the plurality more even.
  • modules utilising hollow fibres use rigid materials for the shell of the module, and are typically not more than 10 metres in length.
  • the prior art teaches that the mass transfer on the shell side of the module will be reduced in proportion to the length of the shell.
  • a person skilled in the art has been taught to minimise the length of shell.
  • the present invention provides an apparatus or method wherein the shell is coiled such that the maximum linear dimension of the coiled shell is no greater than one tenth of the maximum linear dimension of the shell in an uncoiled configuration.
  • the elastomeric membrane is a non porous membrane.
  • the elastomeric membrane may be formed from any suitable elastomer or elastomers.
  • the elastomer is selected from polydimethylsiloxane (PDMS) and other modified polysiloxanes, ethylene-propylene diene (EPDM), polyolefin elastomers, polynorbornene, polyoctenamer, polyurethane, butadiene and nitrile butadiene rubber, natural rubber, butyl rubber, polychloroprene (Neoprene), epichlorohydrin, polyacrylate, elastomers based thereon, derivatives thereof, mixtures thereof and composites thereof.
  • PDMS polydimethylsiloxane
  • EPDM ethylene-propylene diene
  • polyolefin elastomers polynorbornene
  • polyoctenamer polyurethane
  • butadiene and nitrile butadiene rubber natural rubber, butyl rubber
  • An external surface of the membrane may be braided with a support material such as by way of non-limiting example mesh comprising metal wire, polymer strands, or natural or synthetic cotton. Braiding will increase the internal pressure which can be applied inside the membrane tube. This may be particularly important when long membranes are used in the coiled shell of the present invention in which the pressure drop created by the aqueous liquid passing down the tube may be greater than the burst pressure of the unbraided elastomer tube.
  • the substance to be transferred from the first aqueous liquid is selected from any one or more of: a heavy metal, a concentrated acid stream, a concentrated alkali stream, or an aqueous medium which contains at least one organic material.
  • the first aqueous liquid and/or the second aqueous liquid contains a chemical oxidising agent, for example hydrogen peroxide or ozone, with or without catalysts such as the well known Fentons reagent, or titanium dioxide combined with UN light, chemical reducing reagents, for example palladised iron in an anoxic environment or a microbiological material.
  • a chemical oxidising agent for example hydrogen peroxide or ozone
  • catalysts such as the well known Fentons reagent, or titanium dioxide combined with UN light
  • chemical reducing reagents for example palladised iron in an anoxic environment or a microbiological material.
  • the microbiological material is selected from catalytically active biological material, in particular whole cells (viable or non-viable), cell fragments, enzymes, or any combinations thereof .
  • the or each microbiological containing aqueous liquid may also contain an oxygen containing gas.
  • the oxygen containing gas is air.
  • the first aqueous liquid is selected from water; and aqueous solutions containing organic material(s) and/or inorganic material(s).
  • the organic material(s) may be selected from hexane, hexadecane, decanol, toluene, benzene, dichloromethane, dimethylsulfoxide, dimethylformamide, tetrahydrofuran, silicone oil, hydrocarbon oil; derivative and mixtures thereof.
  • the inorganic material(s) may be selected from mineral acids; alkalis, derivative and mixtures thereof.
  • the second aqueous liquid is selected from water; and aqueous solutions containing organic material(s) and/or inorganic material(s).
  • the organic material(s) may be selected from hexane, hexadecane, decanol, toluene, benzene, dichloromethane, dimethylsulfoxide, dimethylformamide, tetrahydrofuran, silicone oil, hydrocarbon oil; derivative and mixtures thereof.
  • the inorganic material(s) may be selected from mineral acids; alkalis, derivative and mixtures thereof. The velocities of the aqueous liquids will be dependent on a number of factors including the cross-sectional area for flow.
  • the relative velocity of the first and second aqueous liquids is in the range
  • the velocity of the first aqueous liquid is in the range 0.01 to 5 ms "1 . More preferably, the velocity of the first aqueous liquid is in the range 0.05 to 2 ms "1 .
  • the velocity of the second aqueous liquid is in the range 0.01 to 5 ms "1 . More preferably, the velocity of the second aqueous liquid is in the range 0.05 to 2 ms " .
  • the transmembrane pressure differential is in the range -2.0 to 5.0 bar. More preferably, the transmembrane pressure differential is in the range -1.0 to 3.0 bar.
  • transmembrane pressure differential we mean the difference between the pressure exerted on each of the two sides of a membrane at any given point on the membrane.
  • transmembrane pressure differential is the difference between the pressure exerted on the internal and external walls of the tube at any given point along the length of the membrane tube.
  • the tubular membrane is of circular cross-section.
  • the tubular membrane is from 10 to 200, more preferably 10 to 100 metres in length. More preferably, the tubular membrane is from 15 to 50 metres in length.
  • the tubular membrane has an inner diameter of at least 0.5 mm. More preferably, the tubular membrane has an inner diameter of from 0.5 to 10.0 mm. Preferably the tubular membrane has a length to diameter ratio of greater than 1,000. More preferably the tubular membrane has a length to diameter ratio of from 2,000 to 100,000. Yet more preferably the tubular membrane has a length to diameter ratio of from 2,000 to 20,000.
  • the tubular membranes are preferably packed into a shell at a packing fraction 0.2 to 0.8. More preferably, the tubular membranes are packed into a shell at a packing fraction 0.4 to 0.6.
  • the "packing fraction" is defined by the following equation
  • Packing fraction volume of shell occupied by tubes volume of shell
  • a tube having a length to diameter ratio of greater than 3000 and having an inner diameter of at least 0.5 mm is used to prepare a system of modules for subsequent operation.
  • the module requires a low amount of potting per length of tube, and therefore can be constructed more economically.
  • potting refers to the method which is used seal the membrane tubes into the shell, and is generally known to those skilled in the art of module manufacture.
  • the tubular membrane may be looped one or more times within the shell.
  • the looped tubular membrane(s) may run substantially parallel to itself and/or each other and/or to the axis of the shell.
  • each looped tube runs a number of times through the shell or a portion thereof.
  • the path length of the tubular membrane through the shell is increased and, if a plurality of membranes are provided, the number of tubular membranes in a shell may be reduced. This is advantageous because the amount of potting per length of tubular membrane may be reduced.
  • a shell such as a shell of 50 NB, may contain up to 50 passes of a tubular membrane having an internal diameter of 3 mm and operate effectively.
  • the shell may contain 5 to 10 tubular membranes looped in this manner and therefore only 5 to 10 will have to be potted into or otherwise connected to the endpieces of the shell.
  • tubular membrane may be coiled within the shell.
  • the coiled tubular membrane may be substantially perpendicular to the axis of the shell.
  • the number of tubular membrane in a shell may be reduced. This is advantageous because the amount of potting per length of tubular membrane may also be reduced.
  • Installation of systems comprising membrane tubes having the preferred features described above also confer the advantage of a more even distribution of flow of the aqueous liquid within the plurality of tubes in the bundle through a higher pressure drop per tube.
  • the material from which the shell is formed is preferably selected from polyethylene, polyvinylchloride, polypropylene, or composites made from combinations of metals and plastics.
  • the composite comprises a helically wound metal or metal mesh supporting polymer layers.
  • the metal is stainless steel mesh.
  • the polymer is a PTFE liner.
  • Containers comprising composite materials made from combinations of metals and plastics confer the advantage that they may be readily rolled into a compact shape, for example a helix or spiral. Such shapes allow ease of handling and installation while simultaneously allowing for the use inside the container of long membrane tubes i.e. tubes having a length to diameter ratio greater than 1000, with an internal diameter at least 0.5 mm.
  • the shell may be constructed from a material which is sufficiently flexible that it can be coiled, preferably in a helical or spiral configuration, such that the maximum linear dimension of the coiled shell is less than one tenth of the full extended length of the shell.
  • the shell is constructed from a flexible material which is circular in cross section and the ratio of the fully extended length of the shell relative to its internal diameter is greater than 200.
  • the ratio of the fully extended length of the shell relative to its internal diameter may be greater than 300.
  • the ratio of the fully extended length of the shell relative to its internal diameter may be 300 to 600.
  • the ratio of the fully extended length of the shell relative to its internal diameter may be 400 to 500.
  • the shell may be constructed from a material which is sufficiently flexible that it can be coiled into a helix with a radius of preferably less than 50 times, more preferably 40 times, yet more preferably 30 times, the internal diameter of the shell.
  • transmembrane pressure differential may result from the difference between the pressure applied to aqueous liquids on different sides of the membrane.
  • the prior art teaches three principle configurations for using tubular membranes for contacting two aqueous liquids between which transfer of chemical species can take place. These configurations are (i) a counter-current manner, for example see US-A- 4988443 (see Figure 1 thereof); (ii) a cross-flow configuration, for example see Yang and Cussler AlChE Journal, 1986 21 p 1910 (see Figure 1); and (iii) a co-current configuration, for example EP-A-0120285 (see Figure 1). It is known, such as from the prior art discussed above, that in many systems use of a counter-current operation is desirable because it maximises the concentration gradient between the two streams. In other words, the concentration driving force for transfer of chemical species is maximised.
  • Counter-current operation is not always desirable, For example, counter-current flow is not desirable when porous membranes are utilised to contact two immiscible phases, as in EP-A-0120285.
  • the transmembrane pressure differential does not exceed the breakthrough pressure of the pores. If the breakthrough pressure is exceeded, then a (i.e. the first) phase which is under higher pressure may breakthrough the membrane and enter another (i.e. a second) phase.
  • the second phase will be contaminated with the first phase and, in the case of the two phases being aqueous and hydrophobic respectively, an emulsion will be formed.
  • co-current we mean two aqueous liquids are flowing in substantially the same direction.
  • Elastomeric tubes can possess a relatively low intrinsic strength and rigidity, and so may collapse inwards if subjected to modest transmembrane pressure differentials - such as when the external pressure is slightly greater than the internal pressure. If subjected to an internal pressure which is slightly greater than the external pressure, the tubes may rupture.
  • silicone rubber tubes with an internal diameter (i.d.) of 3 mm and wall thickness of 0.3 mm may collapse inwards when the external pressure is 0.5 bar greater than the internal pressure i.e.
  • such tubes can rupture when the internal pressure is more than 2.0 bar greater than the external pressure i.e. under a transmembrane pressure differential of more than 2.0 bar greater pressure inside the tube.
  • the method of the present invention comprises the step of passing the first aqueous liquid and the second aqueous liquid in a co-current manner with respect to each other.
  • the flow of each of the first aqueous liquid and the second aqueous liquid is maintained at a constant level and wherein the pressure differential across the tubular membrane is maintained by change in cross-sectional area of the tubular membrane.
  • This aspect of the present invention is advantageous in that it provides a system wherein at least two aqueous liquid streams flow through a shell packed with elastomeric tubes in such a way that the tubes will not collapse inwards or rupture under the effect of the transmembrane pressure differentials created by the flows.
  • This aspect of the present invention is further advantageous because if one is to increase the length of the shell to provide the increased mass transfer described above, the shell may reach a length which prohibits or renders difficult its industrial use. This may be overcome by coiling the shell as described above. However, if a shell is coiled one is presented with the problem of the choice of the material of the tubular membranes. If a non-elastomeric material is used, the membrane tubes may fracture on coiling of the shell. In contrast, if an elastomer is used, rupture or collapse of the tube may result because of the problems of transmembrane pressure differentials described above. The use of co-current flow overcomes both of these problems and allows for the use of long coiled shells.
  • Self regulation is achieved even in conditions where the membrane becomes heavily coated with material which increases the axial pressure drop on one side.
  • the flows of two aqueous liquids are fixed, for example by the use of appropriate pumps, if one of the surfaces of the membrane becomes coated with material, for example biological material, this will tend to increase the axial pressure drop of the aqueous liquid flowing on the side of the membrane which is being coated.
  • Scenario 1 (External Growth): if biological growth occurs on the outside of a membrane tube, the cross-section for flow of the aqueous liquid outside the tubes
  • the external aqueous liquid will decrease. This will result in an increase in the axial pressure drop of the external aqueous liquid along the length of the membrane. This axial pressure drop increase will be transmitted inwards through a tendency to make the tubes partially collapse. The partial collapse of the tubes will in turn reduce the flow area for aqueous liquid within the tubes (the internal aqueous liquid), and so cause an increase in the axial pressure drop of the internal aqueous liquid along the length of the membrane. The net effect of the two axial pressure drop increases will be that the axial transmembrane pressure differential will not be significantly altered from its original profile.
  • the self regulatory pressure effect of the present invention is a preferred feature for elastomeric membrane tubes which have a lower intrinsic strength and rigidity than porous hollow fibres, and so would otherwise be more susceptible to collapse or rupture.
  • the applicant has recognised that when two or more elastomer tubes are packed in a coiled shell, they tend to bunch together at the inside radius of the shell. Furthermore, elastomer tubes, for example silicone rubber tubes, tend to bunch together when surrounded with aqueous solution due to their hydrophobicity. All of these factors exacerbate the poor distribution of flow outside of the tubes which is known from the prior art to reduce mass transfer performance.
  • a further problem of closely packed tubes which is also acknowledged by the prior art is that irregularities in the flow pattern in a shell packed with hollow fibres may adversely affect mass transfer.
  • Costello et al. Journal of Membrane Science 1993 80 p9 describe how at high packing densities of fibres in a shell, the fibres are close together and may even touch, leading to dead zones where mass transfer is poor.
  • Other reports also describe how problems with poor flow distribution reduce mass transfer coefficients in hollow fibre bundles (Noda et al . Journal of Membrane Science 1979 5 p209, Siebert et al. Sep.Sci.Tech. 21 p343).
  • EP-A-0186293 disclose polymeric membranes with external surfaces containing protrusions which run longitudinally down the membrane, and where the protrusions are formed as an integral part of the membrane material during moulding. EP-A-0186293 claims these protrusions hold membranes apart when the membranes are packed in a cylindrical shell.
  • tubular membrane has protrusions extending from the external surface thereof.
  • a plurality of tubular membranes comprising protrusions in accordance with the present invention avoids the bunching together of the tubes, or the tube walls touching and reducing the flow or mass transfer local to the tube.
  • the protrusions which are provided hold the tubes apart, at preferably a predetermined distance.
  • the present invention also encompasses a method and an apparatus comprising combinations of one or more tubular membranes according to the present invention comprising protrusions and one or more tubular membranes according to the present invention which do not include protrusions.
  • the protrusions may be produced at the time of extrusion of the elastomer tube, or affixed at some point after the tube is produced.
  • the protrusions may take any form which produces the desired effect.
  • the protrusions may take the form of ridges protruding radially out from the tube walls. These types of protrusions confer the advantage of providing clear flow channels through the fibre bundle even when the tubes are packed at their maximum density in the shell. Such protrusions achieve this effect even when multiple tubes are packed at random into a shell.
  • the protrusions may be continuous or discontinuous along the length of the tubular membrane. Preferably, the protrusions are continuous along the length of the tubular membrane.
  • At least two tubes are joined side by side (in parallel).
  • the tubes are joined to each other by at least one of their protrusions.
  • the invention provides an effective means for contacting two aqueous liquids by passing them across surfaces of a tubular elastomeric membrane.
  • the invention may be utilised for any process in which the desired chemical species permeate across the elastomeric membrane.
  • Figure 1 is a cross-section of a shell, in accordance with the present invention, packed with tubes provided with protrusions.
  • Figure 2 is a cross-section of a membrane tube with protrusions in accordance with the present invention.
  • Figure 3 is a coiled shell containing elastomer tubes in accordance with the present invention.
  • Figure 1 illustrates a preferred exchange system for use in accordance with the present invention.
  • the exchange system comprises tubular membranes (2) with protrusions (3).
  • the membranes are packed into a shell (1) and a first aqueous liquid (4) is passed through the shell (1).
  • a second aqueous liquid (5) is passed through the membrane tubes (2).
  • the first aqueous liquid (4) and the second aqueous liquid (5) are passed in a direction co-current with respect to each other.
  • Figure 2 shows a cross-section of a membrane tube (2) used in the exchange system of Figure 1.
  • the tube is formed from an elastomeric membrane and has a circular cross-section.
  • Four continuous protrusions (3) running the length of the tube are provided. These equally are spaced on the circumference of the tube (2).
  • FIG. 3 shows an exchange system in accordance with a preferred embodiment of the present invention.
  • a flexible shell (11) is provided which is coiled into a helix.
  • a plurality of elastomeric membrane tubes (2) are provided within the shell.
  • the membrane tubes are packed as described above using potting (6).
  • a first aqueous liquid (5) is passed through the elastomeric membrane tubes (2).
  • a second aqueous liquid (4) is passed through the shell (1).
  • the aqueous liquids flow co-currently with respect to each other.
  • An aqueous process stream (5) containing organic compounds was passed through a plurality of elastomeric membrane tubes (2).
  • the organic compounds present in the process stream (5) diffused across the membrane tubes (2) and were consumed by the micro-organisms in the microorganism containing stream (4), thus maintaining the driving force for the mass transfer.
  • An aqueous process stream (5) containing heavy metals was passed through a plurality of elastomeric membrane tubes (2).
  • a second aqueous stream (4) containing a hydrogen sulphide producing micro-organism was passed through a flexible shell (11).
  • the hydrogen sulphide passed through the membrane (2) and precipitated the heavy metals as metal sulphides. These were then collected from the process stream (5) by sedimentation after it passed out of the flexible shell (11).
  • the micro-organism was replaced by a chemical means for producing hydrogen sulphide, a combination of reagents sodium sulphite and hydrochloric acid.
  • An aqueous process stream (5) containing organic compounds was passed through a plurality of elastomeric membrane tubes (2).
  • a second aqueous stream (4) containing chemical oxidising agents was passed through a flexible shell (11).
  • the organic compounds present in the process stream (5) diffused across the elastomeric membrane (2) and were oxidised by chemical oxidation reactions, thus maintaining the driving force for the mass transfer.

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  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

Cette invention a trait à un appareil comprenant une membrane tubulaire en élastomère et une enveloppe emprisonnant totalement ou en partie cette membrane. L'enveloppe est faite d'un matériau souple à section transversale circulaire. Le rapport de la longueur en pleine extension de l'enveloppe à son diamètre est supérieur à (200).
PCT/GB1999/000186 1998-01-21 1999-01-20 Appareil comprenant une enveloppe souple ainsi qu'une membrane tubulaire en elastomere prise a l'interieur de cette enveloppe et technique d'utilisation de cet appareil aux fins de la separation de substances WO1999037390A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU21756/99A AU2175699A (en) 1998-01-21 1999-01-20 Apparatus comprising a flexible shell and an elastomeric tubular membrane enclosed by the shell; and method of using the apparatus for separating substances

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
GBGB9801272.7A GB9801272D0 (en) 1998-01-21 1998-01-21 Method
GB9801272.7 1998-01-21
GB9811185.9 1998-05-22
GBGB9811185.9A GB9811185D0 (en) 1998-05-22 1998-05-22 Method
GB9823963A GB2333473B (en) 1998-01-21 1998-11-02 Separation using a coiled elastomeric membrane
GB9823963.5 1998-11-02

Publications (1)

Publication Number Publication Date
WO1999037390A1 true WO1999037390A1 (fr) 1999-07-29

Family

ID=27269181

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1999/000186 WO1999037390A1 (fr) 1998-01-21 1999-01-20 Appareil comprenant une enveloppe souple ainsi qu'une membrane tubulaire en elastomere prise a l'interieur de cette enveloppe et technique d'utilisation de cet appareil aux fins de la separation de substances

Country Status (2)

Country Link
AU (1) AU2175699A (fr)
WO (1) WO1999037390A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1820559A1 (fr) * 2006-02-09 2007-08-22 Sataco Co., LTD. Appareil de séparation d'éléments dans l'air
CN101863570A (zh) * 2010-05-31 2010-10-20 武汉尚远环保技术有限公司 含重金属废水处理与回用方法及设备

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1510486A (en) * 1974-07-04 1978-05-10 Rhone Poulenc Ind Membrane apparatus for the treatment of fluids
GB2036595A (en) * 1978-11-29 1980-07-02 Atomic Energy Authority Uk A semi-permeable membrane separation apparatus
EP0186293A2 (fr) * 1984-11-16 1986-07-02 Teijin Limited Dispositif de traitement du sang
WO1993012866A1 (fr) * 1991-12-20 1993-07-08 The Dow Chemical Company Module de separation de fluide souple a fibres creuses
EP0670177A1 (fr) * 1994-03-03 1995-09-06 Applikations- Und Technikzentrum Für Energieverfahrens-, Umwelt-, Und Strömungstechnik Procédé de filtrage de liquides ainsi qu'un dispositif pour celà

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1510486A (en) * 1974-07-04 1978-05-10 Rhone Poulenc Ind Membrane apparatus for the treatment of fluids
GB2036595A (en) * 1978-11-29 1980-07-02 Atomic Energy Authority Uk A semi-permeable membrane separation apparatus
EP0186293A2 (fr) * 1984-11-16 1986-07-02 Teijin Limited Dispositif de traitement du sang
WO1993012866A1 (fr) * 1991-12-20 1993-07-08 The Dow Chemical Company Module de separation de fluide souple a fibres creuses
EP0670177A1 (fr) * 1994-03-03 1995-09-06 Applikations- Und Technikzentrum Für Energieverfahrens-, Umwelt-, Und Strömungstechnik Procédé de filtrage de liquides ainsi qu'un dispositif pour celà

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1820559A1 (fr) * 2006-02-09 2007-08-22 Sataco Co., LTD. Appareil de séparation d'éléments dans l'air
CN101863570A (zh) * 2010-05-31 2010-10-20 武汉尚远环保技术有限公司 含重金属废水处理与回用方法及设备

Also Published As

Publication number Publication date
AU2175699A (en) 1999-08-09

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