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WO1999034768A2 - Composition capillaire revitalisante - Google Patents

Composition capillaire revitalisante Download PDF

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Publication number
WO1999034768A2
WO1999034768A2 PCT/EP1999/000149 EP9900149W WO9934768A2 WO 1999034768 A2 WO1999034768 A2 WO 1999034768A2 EP 9900149 W EP9900149 W EP 9900149W WO 9934768 A2 WO9934768 A2 WO 9934768A2
Authority
WO
WIPO (PCT)
Prior art keywords
silicone
composition
composition according
dimethylamine
acid
Prior art date
Application number
PCT/EP1999/000149
Other languages
English (en)
Other versions
WO1999034768A3 (fr
Inventor
Sachie Ishikawa
Masahiro Kasai
Shin Sato
Original Assignee
Unilever Plc
Unilever N.V.
Hindustan Lever Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever Plc, Unilever N.V., Hindustan Lever Ltd filed Critical Unilever Plc
Priority to AU24209/99A priority Critical patent/AU2420999A/en
Priority to JP2000527223A priority patent/JP2002500173A/ja
Publication of WO1999034768A2 publication Critical patent/WO1999034768A2/fr
Publication of WO1999034768A3 publication Critical patent/WO1999034768A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic

Definitions

  • This invention relates to hair conditioning compositions intended to be rinsed off.
  • the invention relates to hair conditioning compositions having improved wet-stage conditioning performance and incorporating tertiary amidoamine salts in conjunction with a specific mixture of silicones as an auxiliary conditioning agent.
  • Hair conditioning compositions such as cre e rinses, are well known in the art for improving the combing properties of wet hair and dry hair.
  • conditioning compositions typically are aqueous emulsions including a cationic compound, like a quaternary ammonium compound, as the principal conditioning agent.
  • the prior art also describes hair conditioning compositions as including tertiary amidoamine salts.
  • a pearlescent hair conditioner composition including a quaternised tertiary amidoamine, a quaternary ammonium compound and, optionally, a tertiary amidoamine (stearamidoethyldiethylamine) .
  • US 4,777,037 discloses a hair conditioner composition comprising a polydimethylcyclosiloxane, a quaternary-nitrogen conditioning agent having two long alkyl chains and two short alkyl chains, a long chain fatty alcohol and a tertiary amidoamine.
  • hair conditioning compositions based on tertiary amidoamine salts tend to perform poorly with regard to wet stage attributes such as smoothness, slippery feel and ease of combing at the wet stage. These particular properties are generally very important conditioner attributes for consumers.
  • wet stage performance of a hair conditioning composition based on tertiary amidoamine salt can be surprisingly enhanced by inclusion therein of a silicone gum as an auxiliary conditioning agent.
  • the present invention provides a hair conditioning composition having improved wet stage conditioning performance comprising:
  • Rl is a fatty acid chain containing from 12 to 22 carbon atoms
  • R2 is an alkylene group containing from one to four carbon atoms
  • R3 and R4 are, independently, an alkyl group having from one to four carbon atoms
  • a silicone component which comprises a silicone gum with a viscosity greater than 1 Mcs, a silicone fluid with a viscosity of less than 100 kcs, and an amino functionalised silicone, and
  • compositions of the invention is an acid-neutralised amidoamine compound, wherein the amidoamine compound has the general structural formula (I) :
  • Rl is a fatty acid chain containing from 12 to 22 carbon atoms
  • R2 is an alkylene group containing from one to four carbon atoms
  • R3 and R4 are, independently, an alkyl group having from one to four carbon atoms .
  • amidoamine compounds of general structural formula (I) include stearamidopropyl dimethylamine , stearamidopropyl diethylamine, stearamidoethyl dimethylamine, stearamidoethyl diethylamine, palmitamidopropyl dimethylamine, behenamidopropyl dimethylamine, myristamidopropyl dimethylamine, oleamidopropyl dimethylamine, ricinoleamidopropyl dimethylamine, and combinations thereof.
  • composition of the present invention suitably includes from 0.1 to 10%, preferably from 0.1 to 5.0%, ideally from 0.1 to 2.0% by weight of the amidoamine compound, based on the total weight of the composition.
  • the acid used to neutralise the amidoamine compound can be essentially any organic acid or mineral acid of sufficient acid strength to neutralise a free amine nitrogen.
  • Such acids include hydrochloric acid, sulphuric acid, nitric acid, phosphoric acid, lactic acid, citric acid, tartaric acid, acetic acid, gluconic acid, glycolic acid and propionic acid, or combinations thereof.
  • a preferred acid is lactic acid, since neutralisation of the amidoamine compound with this acid yields an exceptionally stable composition.
  • a sufficient amount of acid is added to neutralise the amidoamine compound and to adjust the final pH of the composition to within a range of from about 2.5 to about 6, preferably in a pH range of from about 3 to about 5.
  • auxiliary conditioning agent in compositions of the invention is a silicone component which comprises a silicone gum with a viscosity greater than 1 Mcs, a silicone fluid with a viscosity of less than 100 kcs, and an amino functionalised silicone.
  • the total silicone content of the composition of the invention is in the region of 0.1 to 20%, based on the total weight of the composition.
  • the silicone gum of viscosity greater than lMcs comprises less than 50% by weight
  • the silicone fluid of viscosity less than lOOkcs comprises greater than 30% by weight
  • the amino functionalised silicone comprises less than 10% by weight, based on the total silicone content of the silicone component of the composition.
  • the silicone component of the composition may be provided as a single blend, which may be added to the composition during manufacture.
  • This single blend may simply be in the form of a silicone mixture which can be added to the composition during manufacture, or it may be in an alternative form such as an aqueous emulsion which may itself be added to the composition during manufacture.
  • Pre-formed aqueous emulsions of silicone may have advantages in that they themselves may be easier to handle or process than the "raw" silicone ingredients of the silicone component.
  • the silicone component when added to the hair treatment composition, the silicone component becomes the internal phase of an emulsion which itself constitutes the composition, and which is preferably water based.
  • a further feature of the invention is that the silicone present in the composition, by virtue of having been added as an already homogenised mixture, is present in the hair treatment composition as a homogeneous mixture of silicones. That is, each silicone droplet in the composition will have essentially the same composition and will comprise a mixture (typically a solution) of the three types of silicone which together make up the silicone component of the composition, i.e silicone gum, silicone fluid and amino functionalised silicone.
  • the silicone component of the composition of the invention comprises three types of silicone, which may broadly be stated as being a silicone gum, a silicone fluid, and an amino functionalised silicone. These three types of silicone may be further characterised as follows.
  • the silicone gum is typically present in the silicone component at a level of from 0.01 to 50%, preferably from 1 to 40%, ideally from 10 to 35% by weight based on the total weight of the silicone component.
  • Preferred silicone gums are polydiorganosiloxanes, preferably derived from suitable combinations of R3Si ⁇ Q .5 and R2SiO units, where each R independently represents an alkyl, alkenyl (e.g. vinyl), alkaryl, aralkyl or aryl (e.g. phenyl) group. R is most preferably methyl.
  • the silicone gum has a viscosity of greater than 1 Mcs.
  • the viscosity can be measured by means of a glass capillary viscometer as set out further in Dow Corning Corporate Test Method CTM004, July 20 1970.
  • Preferred silicone gums for use in the silicone component of compositions of the invention are polydimethylsiloxanes (which have the CTFA designation dimethicone) , optionally having end groups such as hydroxyl . Good results have been obtained with dimethicone. Suitable materials include gums SE30, SE54 and SE76, available from General Electric Silicones .
  • a further ingredient of the silicone component of the composition of the invention is a silicone fluid.
  • the silicone fluid is typically present in the silicone component at a level of from 30 to 95%, preferably from 40 to 80%, ideally from 50 to 70% by weight based on the total weight of the silicone component.
  • Preferred silicone fluids are polydiorganosiloxanes, preferably also derived from suitable combinations of R3Si ⁇ Q .5 and R2SiO units, where each R independently represents an alkyl, alkenyl (e.g. vinyl), alkaryl, aralkyl or aryl (e.g. phenyl) group. R is most preferably methyl.
  • the silicone fluid has a viscosity of less than 100 kcs.
  • the viscosity can be measured by means of a glass capillary viscometer as described above under "Silicone Gum”.
  • Preferred silicone fluids for use in the silicone component of compositions of the invention are polydimethylsiloxanes (which have the CTFA designation dimethicone) , optionally having end groups such as hydroxyl. Good results have been obtained with dimethicone.
  • Suitable materials include the DC200 series of silicone fluids, available from Dow Corning (e.g. DC200, viscosity 350 cst) , or SF96 or the VISCASIL series of silicones, available from General Electric Silicones .
  • silicone gum and silicone fluid may be sourced as a single pre-prepared solution.
  • Such solutions may themselves have benfits in terms of ease of handling.
  • pre-prepared blends include Q2-1403 available from Dow Corning, or CF 1251, available from General Electric Silicones.
  • the third ingredient of the silicone component of the composition is an amino functionalised silicone.
  • the amino functionalised silicone is typically present in the silicone component at a level of from 0.1 to 10 %, preferably from 1 to 10% by weight based on the total weight of the silicone component.
  • the amino functionalised silicone comprises no more than 10% by weight of the silicone component, firstly in order to minimise the cost of the silicone component, but also to ease emulsification of the silicone component.
  • Suitable amino functionalised silicones are described in EP 455,185. Suitable amino functionalised silicones include trimethylsilylamodimethicone as depicted below, and are sufficiently water insoluble so as to be useful in compositions of the invention:
  • x + y is a number from about 50 to about 500, and the mole % amine functionality is in the range of from about 0.7 to about 8%, and wherein R is an alkylene group having from 2 to 5 carbon atoms.
  • the number x + y is in the range of from about 100 to about 300, and the mole % amine functionality is in the range of from about 2 to about 6%.
  • amino functionalised silicones useful in the silicone component of the composition of the invention are Q2-8220 and Q2-8466 fluids, available from Dow Corning, and also SF-1708-D1, available from General Electric Silicones.
  • the silicone component of the composition is provided as a single blend, which may be added to the composition during manufacture.
  • This single blend may simply be in the form of a silicone mixture which can be added to the composition during manufacture, or it may be in an alternative form such as an aqueous emulsion which may itself be added to the composition during manufacture.
  • aqueous emulsion is the preferred form for such a single blend, most preferably a mechanically-formed aqueous emulsion.
  • the emulsion additionally includes at least one emulsifier in order to stabilise the silicone emulsion.
  • Suitable emulsifiers are well known in the art and include anionic and nonionic surfactants.
  • anionic surfactants used as emulsifiers for the silicone particles are alkylarylsulphonates, e.g., sodium dodecylbenzene sulphonate, alkyl sulphates e.g., sodium lauryl sulphate, alkyl ether sulphates, e.g., sodium lauryl ether sulphate nEO, where n is from 1 to 20 alkylphenol ether sulphates, e.g., octylphenol ether sulphate nEO where n is from 1 to 20, and sulphosuccinates, e.g., sodium dioctylsulphosuccinate .
  • nonionic surfactants used as emulsifiers for the silicone particles are alkylphenol ethoxylates, e.g., nonylphenol ethoxylate nEO, where n is from 1 to 50, alcohol ethoxylates, e.g., lauryl alcohol nEO, where n is from 1 to 50, ester ethoxylates, e.g., polyoxyethylene monostearate where the number of oxyethylene units is from 1 to 30.
  • alkylphenol ethoxylates e.g., nonylphenol ethoxylate nEO, where n is from 1 to 50
  • alcohol ethoxylates e.g., lauryl alcohol nEO, where n is from 1 to 50
  • ester ethoxylates e.g., polyoxyethylene monostearate where the number of oxyethylene units is from 1 to 30.
  • the average particle size of the silicone droplets in the emulsion and also in the final composition is less than 20 microns, more preferably less than 10 microns.
  • a smaller silicone particle size enables a more uniform distribution of silicone on the hair for the same amount of silicone in the composition.
  • Silicone particle size may be measured by means of a laser light scattering technique, for example using a 2600D Particle Sizer from Malvern Instruments.
  • a particularly suitable emulsion for use as the silicone component of the composition of the invention is an emulsion containing silicone gum, silicone fluid and an aminofunctionalised silicone in a nonionic surfactant base, of silicone particle size 5 microns.
  • the carrier of the composition of the invention is predominantly water, but non-aqueous solvents also can be used in order to help solubilise ingredients that are not sufficiently soluble in water.
  • Suitable non-aqueous solvents include the lower alcohols like ethyl alcohol and propyl alcohol; polyols like glycerol; glycols or glycol ethers, like 2-butoxyethanol, ethylene glycol, ethylene glycol monoethyl ether, propylene glycol and diethylene glycol monoethyl ether or monomethyl ether and mixtures thereof .
  • These non-aqueous solvents can be present in the composition of the invention in an amount of from 1 to 100%, preferably 5 to 50%, by weight based on the total weight of the vehicle of the composition of the invention.
  • composition of the invention may, optionally, also comprise a cationic polymer to enhance conditioning performance.
  • the cationic polymer may be a homopolymer or be formed from two or more types of monomers.
  • the molecular weight of the polymer will generally be between 5 000 and 10 000 000, typically at least 10 000 and preferably in the range
  • the polymers will have cationic nitrogen containing groups such as quaternary ammonium or protonated amino groups, or a mixture thereof.
  • the cationic charge density of the cationic polymer which is defined as the reciprocal of the molecular weight of a monomeric unit of the polymer containing 1 charge, has been found to need to be at least 0.1 meq/g, preferably above 0.8 or higher.
  • the cationic charge density should not exceed 4 meq/g, it is preferably less than 3 and more preferably less than 2 meq/g.
  • the charge density can be measured using conductimetric analysis and should be within the above limits at the desired pH of use, which will in general be from about 3 to 9 and preferably between 4 and 8.
  • the cationic nitrogen-containing group will generally be present as a substituent on a fraction of the total monomer units of the cationic polymer. Thus when the polymer is not a homopolymer it can contain spacer non- cationic monomer units. Such polymers are described in the CTFA Cosmetic Ingredient Directory, 3rd edition. The ratio of the cationic to non-cationic monomer units is selected to give a polymer having a cationic charge density in the required range.
  • a preferred type of cationic polymer in compositions of the invention is a cationic guar gum derivative, such as guar hydroxypropyltrimonium chloride (Commercially available from Celanese Corp. in their Jaguar trademark series).
  • Examples are JAGUAR C13S, which has a low degree of substitution of the cationic groups and high viscosity.
  • JAGUAR C15 having a moderate degree of substitution and a low viscosity
  • JAGUAR C17 high degree of substitution, high viscosity
  • JAGUAR C16 which is a hydroxypropylated cationic guar gum derivative containing a low level of substituent groups as well as cationic quaternary ammonium groups
  • JAGUAR 162 which is a high transparency, medium viscosity cationic guar gum derivative having a low degree of substitution.
  • a particularly preferred cationic guar gum derivative is JAGUAR C13S with a cationic charge density of 0.8meq/g.
  • the cationic polymer may be present in an amount of from 0.01 to 10%, preferably from 0.01 to 2.0%, more preferably from 0.1 to 1.0% by weight based on the total weight of the composition.
  • Long chain fatty alcohols having from about 10 to about 18 carbon atoms in the alkyl chain also can be included, optionally, in the composition of the present invention to enhance consumer appeal and provide thickening.
  • the fatty alcohols can be used alone, or in admixture with each other.
  • Suitable fatty alcohols include lauryl alcohol, oleyl alcohol, cetyl alcohol, myristyl alcohol, stearyl alcohol, and mixtures thereof. Mixtures of cetyl and stearyl alcohol are particularly preferred.
  • Alkoxylated, (e.g. ethoxylated or propoxylated) fatty alcohols having from about 12 to about 18 carbon atoms in the alkyl chain can be used in place of, or in addition to, the fatty alcohols themselves. Suitable examples include ethylene glycol cetyl ether, polyoxyethylene (2) stearyl ether, polyoxyethylene (24) cetyl ether, and mixtures thereof .
  • the fatty alcohol and/or alkoxylated fatty alcohol may be present in an amount of from 0.5 to 10%, preferably from 1 to 5% by weight based on the total weight of the composition.
  • compositions of this invention may contain any other ingredient normally used in hair treatment formulations.
  • these other ingredients may include viscosity modifiers, preservatives, colouring agents, polyols such as glycerine and polypropylene glycol, chelating agents such as EDTA, antioxidants, fragrances, antimicrobials and sunscreens.
  • chelating agents such as EDTA, antioxidants, fragrances, antimicrobials and sunscreens.
  • compositions of this invention also contain adjuvants suitable for hair care.
  • adjuvants suitable for hair care Generally such ingredients are included individually at a level of up to 2%, preferably up to 1%, by weight of the total composition.
  • Suitable hair care adjuvants are:
  • natural hair root nutrients such as amino acids and sugars.
  • suitable amino acids include arginine, cysteine, glutamine, glutamic acid, isoleucine, leucine, methionine, serine and valine, and/or precursors and derivatives thereof.
  • the amino acids may be added singly, in mixtures, or in the form of peptides, e.g. di- and tripeptides.
  • the amino acids may also be added in the form of a protein hydrolysate, such as a keratin or collagen hydrolysate.
  • Suitable sugars are glucose, dextrose and fructose. These may be added singly or in the form of, e.g. fruit extracts .
  • a particularly preferred combination of natural hair root nutrients for inclusion in compositions of the invention is isoleucine and glucose.
  • a particularly preferred amino acid nutrient is arginine.
  • Ceramides for moisturising the fibre and maintaining cuticle integrity.
  • Ceramides are available by extraction from natural sources, or as synthetic ceramides and pseudoceramides .
  • a preferred ceramide is Ceramide II, ex Quest.
  • Mixtures of ceramides may also be suitable, such as Ceramides LS, ex Laboratoires Serobi unanimouss .
  • compositions of the invention are primarily intended for topical application to the hair and/or scalp of a human subject to improve hair fibre surface properties such as smoothness, softness, manageability, cuticle integrity, and shine .
  • a hair rinse was prepared having the ingredients as shown in the following table:
  • a hair treatment was prepared having the ingredients as shown in the following table:

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
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  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne une composition capillaire revitalisante présentant des performances de revitalisation des cheveux à l'état humide. Cette composition comprend: (a) comme agent revitalisant principal, un composé amidoamine à acide neutralisé, correspondant à la formule développée (I): R1 - C (O) - NH - R2 - N(R3) (R4), dans laquelle R1 représente une chaîne d'acide gras comportant 12 à 22 atomes de carbone, R2 représente un groupe alkylène comportant 1 à 4 atomes de carbone, et R3 et R4 représentent, indépendamment l'un de l'autre, un groupe alkyle comportant 1 à 4 atomes de carbone; (b) comme agent revitalisant auxiliaire, un composant siliconé comprenant une gomme de silicone présentant une viscosité supérieure à 1 Mcs, un fluide de silicone présentant une viscosité inférieure à 100 kcs, et une silicone à fonctionnalisation amino; et (c) un support aqueux.
PCT/EP1999/000149 1998-01-12 1999-01-06 Composition capillaire revitalisante WO1999034768A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU24209/99A AU2420999A (en) 1998-01-12 1999-01-06 Hair conditioning composition
JP2000527223A JP2002500173A (ja) 1998-01-12 1999-01-06 ヘアコンディショニング組成物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9800591.1 1998-01-12
GBGB9800591.1A GB9800591D0 (en) 1998-01-12 1998-01-12 Hair conditioning composition

Publications (2)

Publication Number Publication Date
WO1999034768A2 true WO1999034768A2 (fr) 1999-07-15
WO1999034768A3 WO1999034768A3 (fr) 2000-08-24

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Country Link
JP (1) JP2002500173A (fr)
AR (1) AR014276A1 (fr)
AU (1) AU2420999A (fr)
GB (1) GB9800591D0 (fr)
WO (1) WO1999034768A2 (fr)

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US6287547B1 (en) * 1999-10-12 2001-09-11 Sanyo Chemical Industries, Ltd. Hair treatment composition
JP2002322035A (ja) * 2001-02-20 2002-11-08 Nakano Seiyaku Kk ヘアカラー用前処理剤およびヘアカラー用処理剤並びに毛髪処理方法
JP2003146846A (ja) * 2001-11-14 2003-05-21 Kao Corp 毛髪処理剤組成物
WO2002096375A3 (fr) * 2001-04-06 2003-08-21 Unilever Plc Compositions de traitement capillaire
WO2003092637A1 (fr) * 2002-05-03 2003-11-13 Unilever Plc Apres-shampooings ameliores contenant un melange a base de silicone
WO2003092639A1 (fr) * 2002-05-03 2003-11-13 Unilever Plc Compositions de conditionnement des cheveux contenant un melange de silicones
WO2003092638A1 (fr) * 2002-05-03 2003-11-13 Unilever Plc Compositions d'apres-shampooings ameliores contenant un melange a base de silicone
DE10224025A1 (de) * 2002-05-31 2003-12-11 Beiersdorf Ag Pflegendes Haarshampoo
WO2004030646A1 (fr) * 2002-10-02 2004-04-15 The Procter & Gamble Company Composition de traitement capillaire comprenant trois sortes de silicones
US6808701B2 (en) 2000-03-21 2004-10-26 Johnson & Johnson Consumer Companies, Inc. Conditioning compositions
WO2006000258A1 (fr) * 2004-06-25 2006-01-05 Henkel Kommanditgesellschaft Auf Aktien Agents de conditionnement des cheveux contenant des silicones a fonction amine
EP1754517A1 (fr) 2005-08-17 2007-02-21 The Procter and Gamble Company Composition conditionnante pour les fibres et les fibres capillaires
US7601339B2 (en) 2004-04-15 2009-10-13 Kao Corporation Hair cosmetic composition
EP2138160A2 (fr) 2008-06-27 2009-12-30 Beiersdorf AG Après-shampoing doté d'une émulsion de silicone
US7887787B2 (en) 2004-02-13 2011-02-15 The Procter & Gamble Hair conditioning composition comprising pre-mixture of three kinds of silicones
US7892526B2 (en) 2002-12-25 2011-02-22 Kao Corporation Hair cosmetic composition
EP1870080A4 (fr) * 2005-04-11 2013-05-15 Kao Corp Cosmetique capillaire
KR20130068519A (ko) * 2011-12-15 2013-06-26 주식회사 케이씨씨 고기능성 실리콘 에멀젼 조성물 및 제조 방법
WO2013148904A1 (fr) * 2012-03-30 2013-10-03 The Procter & Gamble Company Composition d'après-shampoing comportant un système tensioactif cationique monoalkylamine, un polymère de dépôt et une silicone
EP2444057A3 (fr) * 2010-07-09 2014-07-09 Beiersdorf AG Produit de traitement capillaire ayant une teneur en eau liée élevée
US20140356306A1 (en) * 2012-01-31 2014-12-04 Conopco, Inc., D/B/A Unilever Hair composition with improved rheology
US20170252279A1 (en) * 2006-04-10 2017-09-07 Inolex Investment Corporation Hair Conditioning Cosmetic Compositions Containing a Mixture of Amidoamines
WO2018228898A1 (fr) * 2017-06-15 2018-12-20 Unilever Plc Composition capillaire ayant des propriétés de rinçage améliorées

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DE19904359A1 (de) * 1999-02-04 2000-08-10 Wella Ag Haarpflegemittel
JP4648188B2 (ja) * 2005-12-28 2011-03-09 花王株式会社 染毛剤組成物
JP4584826B2 (ja) * 2005-12-28 2010-11-24 花王株式会社 毛髪形状制御剤

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US5198209A (en) * 1992-02-11 1993-03-30 Amway Corporation Conditioning shampoo
AU1883595A (en) * 1994-03-01 1995-09-18 Procter & Gamble Company, The Hair care compositions providing hair conditioning and style retention

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US6287547B1 (en) * 1999-10-12 2001-09-11 Sanyo Chemical Industries, Ltd. Hair treatment composition
US6808701B2 (en) 2000-03-21 2004-10-26 Johnson & Johnson Consumer Companies, Inc. Conditioning compositions
JP2002322035A (ja) * 2001-02-20 2002-11-08 Nakano Seiyaku Kk ヘアカラー用前処理剤およびヘアカラー用処理剤並びに毛髪処理方法
WO2002096375A3 (fr) * 2001-04-06 2003-08-21 Unilever Plc Compositions de traitement capillaire
US6610280B2 (en) 2001-04-06 2003-08-26 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Hair treatment compositions
JP2003146846A (ja) * 2001-11-14 2003-05-21 Kao Corp 毛髪処理剤組成物
WO2003092637A1 (fr) * 2002-05-03 2003-11-13 Unilever Plc Apres-shampooings ameliores contenant un melange a base de silicone
WO2003092638A1 (fr) * 2002-05-03 2003-11-13 Unilever Plc Compositions d'apres-shampooings ameliores contenant un melange a base de silicone
WO2003092639A1 (fr) * 2002-05-03 2003-11-13 Unilever Plc Compositions de conditionnement des cheveux contenant un melange de silicones
DE10224025A1 (de) * 2002-05-31 2003-12-11 Beiersdorf Ag Pflegendes Haarshampoo
WO2004030646A1 (fr) * 2002-10-02 2004-04-15 The Procter & Gamble Company Composition de traitement capillaire comprenant trois sortes de silicones
US7892526B2 (en) 2002-12-25 2011-02-22 Kao Corporation Hair cosmetic composition
US7887787B2 (en) 2004-02-13 2011-02-15 The Procter & Gamble Hair conditioning composition comprising pre-mixture of three kinds of silicones
EP1713435B1 (fr) 2004-02-13 2016-04-13 The Procter and Gamble Company Composition d'apres-shampooing comprenant un premelange constitue de trois types de silicones
US7601339B2 (en) 2004-04-15 2009-10-13 Kao Corporation Hair cosmetic composition
WO2006000258A1 (fr) * 2004-06-25 2006-01-05 Henkel Kommanditgesellschaft Auf Aktien Agents de conditionnement des cheveux contenant des silicones a fonction amine
EP1870080A4 (fr) * 2005-04-11 2013-05-15 Kao Corp Cosmetique capillaire
EP1754517A1 (fr) 2005-08-17 2007-02-21 The Procter and Gamble Company Composition conditionnante pour les fibres et les fibres capillaires
US10272023B2 (en) * 2006-04-10 2019-04-30 Inolex Investment Corporation Hair conditioning cosmetic compositions containing a mixture of amidoamines
US20170252279A1 (en) * 2006-04-10 2017-09-07 Inolex Investment Corporation Hair Conditioning Cosmetic Compositions Containing a Mixture of Amidoamines
EP2138160A2 (fr) 2008-06-27 2009-12-30 Beiersdorf AG Après-shampoing doté d'une émulsion de silicone
DE102008030139A1 (de) 2008-06-27 2009-12-31 Beiersdorf Ag Haarspülung mit Silikonemulsion
EP2444057A3 (fr) * 2010-07-09 2014-07-09 Beiersdorf AG Produit de traitement capillaire ayant une teneur en eau liée élevée
EP2444057B1 (fr) 2010-07-09 2018-05-30 Beiersdorf AG Produit de traitement capillaire ayant une teneur en eau liée élevée
KR20130068519A (ko) * 2011-12-15 2013-06-26 주식회사 케이씨씨 고기능성 실리콘 에멀젼 조성물 및 제조 방법
KR101961487B1 (ko) 2011-12-15 2019-03-25 주식회사 케이씨씨 고기능성 실리콘 에멀젼 조성물 및 제조 방법
US20140356306A1 (en) * 2012-01-31 2014-12-04 Conopco, Inc., D/B/A Unilever Hair composition with improved rheology
US9351917B2 (en) * 2012-01-31 2016-05-31 Conopco, Inc. Hair composition with improved rheology
WO2013148904A1 (fr) * 2012-03-30 2013-10-03 The Procter & Gamble Company Composition d'après-shampoing comportant un système tensioactif cationique monoalkylamine, un polymère de dépôt et une silicone
WO2018228898A1 (fr) * 2017-06-15 2018-12-20 Unilever Plc Composition capillaire ayant des propriétés de rinçage améliorées

Also Published As

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GB9800591D0 (en) 1998-03-11
AR014276A1 (es) 2001-02-07
JP2002500173A (ja) 2002-01-08
WO1999034768A3 (fr) 2000-08-24
AU2420999A (en) 1999-07-26

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