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WO1999008785A3 - Membranes en oxyde d'aluminium nano-poreuses contenant des clathrates de metaux precieux ou des nanoparticules de metaux precieux - Google Patents

Membranes en oxyde d'aluminium nano-poreuses contenant des clathrates de metaux precieux ou des nanoparticules de metaux precieux Download PDF

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Publication number
WO1999008785A3
WO1999008785A3 PCT/EP1998/004863 EP9804863W WO9908785A3 WO 1999008785 A3 WO1999008785 A3 WO 1999008785A3 EP 9804863 W EP9804863 W EP 9804863W WO 9908785 A3 WO9908785 A3 WO 9908785A3
Authority
WO
WIPO (PCT)
Prior art keywords
noble metal
aluminium oxide
clusters
nano
oxide membranes
Prior art date
Application number
PCT/EP1998/004863
Other languages
German (de)
English (en)
Other versions
WO1999008785A2 (fr
Inventor
Alfred Hagemeyer
Harald Werner
Uwe Dingerdissen
Klaus Kuehlein
Guenter Schmid
Original Assignee
Celanese Gmbh
Alfred Hagemeyer
Harald Werner
Uwe Dingerdissen
Klaus Kuehlein
Guenter Schmid
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Gmbh, Alfred Hagemeyer, Harald Werner, Uwe Dingerdissen, Klaus Kuehlein, Guenter Schmid filed Critical Celanese Gmbh
Publication of WO1999008785A2 publication Critical patent/WO1999008785A2/fr
Publication of WO1999008785A3 publication Critical patent/WO1999008785A3/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58—Fabrics or filaments
    • B01J35/59—Membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne des membranes en oxyde d'aluminium nano-poreuses contenant des clathrates de métaux précieux ou bien des nanoparticules de métaux précieux, ces membranes ayant été obtenues par oxydation anodique et présentant une distribution serrée des rayons des pores. La fabrication s'effectue par revêtement des membranes avec une solution colloïdale de nanoparticules ou de clathrates de métaux précieux stabilisés avec des ligands, séchage et ensuite calcination en présence d'un gaz contenant de l'oxygène. Ces membranes en oxyde d'aluminium présentent un rayon de pore moyen de 1-500 nm avec un écart type de la distribution des rayons des pores de 0-20 %, de préférence de 0-10%. Ces membranes en oxyde d'aluminium contenant des clathrates ou des nanoparticules de métaux précieux conviennent notamment comme catalyseurs lors de la synthèse en présence d'acétate de vinyle.
PCT/EP1998/004863 1997-08-13 1998-08-05 Membranes en oxyde d'aluminium nano-poreuses contenant des clathrates de metaux precieux ou des nanoparticules de metaux precieux WO1999008785A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19734973A DE19734973A1 (de) 1997-08-13 1997-08-13 Edelmetallcluster enthaltende nano-poröse Aluminium-oxid-Membranen
DE19734973.0 1997-08-13

Publications (2)

Publication Number Publication Date
WO1999008785A2 WO1999008785A2 (fr) 1999-02-25
WO1999008785A3 true WO1999008785A3 (fr) 1999-05-27

Family

ID=7838783

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1998/004863 WO1999008785A2 (fr) 1997-08-13 1998-08-05 Membranes en oxyde d'aluminium nano-poreuses contenant des clathrates de metaux precieux ou des nanoparticules de metaux precieux

Country Status (2)

Country Link
DE (1) DE19734973A1 (fr)
WO (1) WO1999008785A2 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1255894C (zh) 2000-01-18 2006-05-10 特拉维夫大学未来技术发展有限合伙公司 燃料
US6447943B1 (en) 2000-01-18 2002-09-10 Ramot University Authority For Applied Research & Industrial Development Ltd. Fuel cell with proton conducting membrane with a pore size less than 30 nm
WO2003046265A2 (fr) * 2001-11-26 2003-06-05 Massachusetts Institute Of Technology Production de films epais d'alumine anodique poreuse et de reseaux de nanocables sur un substrat solide
US7472576B1 (en) 2004-11-17 2009-01-06 State Of Oregon Acting By And Through The State Board Of Higher Education On Behalf Of Portland State University Nanometrology device standards for scanning probe microscopes and processes for their fabrication and use
JP4654083B2 (ja) * 2005-07-20 2011-03-16 富士フイルム株式会社 金属粒子型反応触媒およびその製造方法、並びに該触媒を用いた有機合成反応装置
JP4769595B2 (ja) 2005-08-12 2011-09-07 富士フイルム株式会社 重合体、該重合体を含有する膜形成用組成物、該組成物を用いて形成した絶縁膜及び電子デバイス
DE102005044913A1 (de) * 2005-09-20 2007-03-22 Technische Universität Darmstadt Verfahren zur selektiven Herstellung von Dihydroxyaceton aus Glycerin sowie ein Verfahren zur Herstellung eines Metallkatalysators zur selektiven Oxidation von Glycerin
DE102014003508A1 (de) * 2014-03-14 2015-09-17 Airbus Defence and Space GmbH Verfahren zur Herstellung sowie Verwendung einer polierten nanostrukturierten metallischen Oberfläche mit wasser- und eisabweisenden Eigenschaften

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4087622A (en) * 1974-06-27 1978-05-02 Bayer Aktiengesellschaft Method of producing vinyl acetate
US5213895A (en) * 1990-09-11 1993-05-25 Daiso Co., Ltd. Particle-bearing composite and a method for producing the same

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4087622A (en) * 1974-06-27 1978-05-02 Bayer Aktiengesellschaft Method of producing vinyl acetate
US5213895A (en) * 1990-09-11 1993-05-25 Daiso Co., Ltd. Particle-bearing composite and a method for producing the same

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
GOKHALE Y V ET AL: "Effects of reactant loss and membrane selectivity on a dehydrogenation reaction in a membrane-enclosed catalytic reactor", JOURNAL OF MEMBRANE SCIENCE, vol. 103, no. 3, 31 July 1995 (1995-07-31), pages 235-242, XP004041338 *
HORNYAK G L ET AL: "Optical properties of a family of Au-nanoparticle-containing alumina membranes in which the nanoparticle shape is varied from needle-like (prolate) to spheroid, to pancake-like (oblate)", THIN SOLID FILMS, vol. 303, no. 1-2, 15 July 1997 (1997-07-15), pages 84-88, XP004087616 *

Also Published As

Publication number Publication date
WO1999008785A2 (fr) 1999-02-25
DE19734973A1 (de) 1999-02-25

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