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WO1999006489A1 - Procede de revetement d'un substrat - Google Patents

Procede de revetement d'un substrat Download PDF

Info

Publication number
WO1999006489A1
WO1999006489A1 PCT/SE1998/001309 SE9801309W WO9906489A1 WO 1999006489 A1 WO1999006489 A1 WO 1999006489A1 SE 9801309 W SE9801309 W SE 9801309W WO 9906489 A1 WO9906489 A1 WO 9906489A1
Authority
WO
WIPO (PCT)
Prior art keywords
coating
substrate
lamp
curing
lamps
Prior art date
Application number
PCT/SE1998/001309
Other languages
English (en)
Inventor
Nigel Lambert
Adrian Strachan
Roger Wallis
Vincent Wright
Original Assignee
Perstorp Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Perstorp Ab filed Critical Perstorp Ab
Priority to EP98934030A priority Critical patent/EP1000125B1/fr
Priority to US09/463,560 priority patent/US6808757B1/en
Priority to BRPI9811715-7A priority patent/BR9811715B1/pt
Priority to AU83638/98A priority patent/AU8363898A/en
Priority to DE1998628057 priority patent/DE69828057D1/de
Priority to AT98934030T priority patent/ATE284434T1/de
Publication of WO1999006489A1 publication Critical patent/WO1999006489A1/fr
Priority to HK01101228A priority patent/HK1030233A1/xx

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]

Definitions

  • the present invention relates to a method of coating a substrate.
  • a photo-initiator in this process is a material that absorbs light, and generates free radicals.
  • the free radicals initiate the polymerisation of the coating.
  • Photo-initiators are generally expensive, and can give rise to problems. For example, they can create an undesirable odour or taste (which may be relevant when the coating is going to be in contact with a food product) and can also cause "yellowing", which is a tendency for the cured coating to adopt a yellow colour over the course of time.
  • a further disadvantage of this technique is that it requires a combination of electron donating monomers and electron accepting monomers of relatively low molecular weight, and monomers in general are regarded as being prone to shrinkage during cure and are also regarded as being toxic since they may relatively easily penetrate the skin.
  • the present invention seeks to provide a UV cured coating in which the disadvantages of prior proposals are obviated or reduced.
  • a method of coating a substrate comprising the steps of applying a coating composition to at least selected areas of the substrate, exposing the coated substrate to ultra-violet light from at least one lamp having a power output of at least 140 watts per linear centimetre in a curing zone, to initiate curing of the coating, the coating composition comprising a mixture including at least a reactive part comprising between 30% and 100% multi-functional material and being photo-initiator-free, including the step of maintaining a substantially inert atmosphere in the curing zone where the substrate is exposed to said ultra-violet light.
  • the preferred multi-functional materials have a functionality of at least three.
  • the inert atmosphere is obtained by purging the curing zone with inert gas such as nitrogen.
  • the oxygen concentration in the curing zone is less than 1,000 ppm and preferably less than 100 ppm.
  • the multi-functional material comprises one or more reactive diluents.
  • the multi-functional material comprises one or more materials, each material having a molecular weight in excess of 480.
  • the multi-functional material comprises one or more materials which have three or more functional acrylate groups.
  • the coating material contains a pre- polymer, and may comprise polyester acrylate, polyurethane acrylate, epoxyacrylate or a full acrylic material.
  • the pre-polymer is multi-functional.
  • the coating composition comprises, in addition to the reactive part, a filler, and the filler may comprises clay, silica or magnetisable particles.
  • the power output of the lamp is at least 180 watts/cm and may be substantially 240 watts/cm.
  • UV light from the lamp has a substantial spectral content in the range 200-300 nm.
  • UV light from the lamp has additional spectral content with peaks of approximately 370 nm, 408 nm and 438 nm.
  • Two or more lamps may be provided in the curing zone.
  • the lamps may have different spectral properties or may have substantially identical spectral properties.
  • the invention relates to a substrate when coated by a method as described above.
  • FIGURE 1 is a diagrammatic view of an apparatus for use in curing a coating on a substrate
  • FIGURE 2 is a graphical indication of the spectral output of a preferred UV lamp
  • FIGURE 3 is a graphical representation of the spectral output of an alternative preferred UV lamp.
  • FIGURE 4 shows the chemical structure of a reactant.
  • An apparatus which comprises a pair of rollers 1,2 adapted to guide a substrate 3, such as a sheet of aluminium foil or a sheet of paper, through the illustrated apparatus.
  • the substrate 3 is coated, before entering the apparatus, completely or partially, with a curable composition which will be described in greater detail hereinafter.
  • the curable composition may be applied as an un-broken coating or may be applied in the form of printing.
  • the rollers 1,2 guide the substrate 3 through a channel 4 defined between a cooled backing plate 5, and a super-imposed cover 6.
  • the cover 6 supports two lamps 7,8.
  • the lamp 7 can be a "D" lamp, as supplied by Fusion Inc.
  • the lamp 7 is located above a quartz window 9 that is sealed against the cover 6 so that light from the lamp 7 may shine through the quartz window 9 on to the substrate 3 as it passes through a curing zone formed by the channel 4.
  • the lamp 8 can be a "H" lamp as supplied by Fusion Inc. and is also associated with a quartz window 10 which is formed integrally with the cover 6 so that light from the lamp 8 can pass through the quartz window 10 into the curing zone in channel 4, and thus on to the substrate 3.
  • the lamps 7,8 each have a focussing reflector.
  • the position of the lamps may be interchanged. In an alternative embodiment, only one lamp may be used, or two lamps of the same type may be used.
  • the lamps 7 and 8 emit UV light with wavelengths in the band 200 to 550 nm.
  • the light is directed on to the substrate in a region in the central part of the channel 4.
  • the channel 4 is flushed with nitrogen in order to ensure that there is an inert atmosphere having a minimum quantity of oxygen within the channel.
  • nitrogen is introduced through an inlet conduit 11 and passes to a dispersing nozzle 12 known as the "inlet knife" which is located on the under-side of the cover 6 above the roller 1, and which is adapted to prevent oxygen entering the channel 4.
  • the nitrogen flows along the channel 4, past the region where the UV light is directed on to the substrate, in the same direction as the direction of movement of the substrate 3.
  • Nitrogen may also be injected into the channel 4 via nozzles located around the periphery -1- of each quartz window.
  • nitrogen flowing through a conduit 13 is passed through a nozzle 14 on the underside of the cover into the channel 4.
  • the concentration of oxygen within the channel 4 is less than 1,000 ppm and preferably less than 100 ppm.
  • nitrogen is preferred because it is the least expensive inert gas.
  • the lamps 7 and 8 are supplied in a modular form, each module is 25.4 mm wide and extends transversely across the direction of movement of the web 3 through the channel 4.
  • the lamps are high intensity lamps using medium pressure mercury vapour bulbs operating at a power level in excess of 140 watts per linear centimetre, preferably in excess of 180 watts per linear centimetre, and most preferably in the region of 240 watts per linear centimetre.
  • the output spectrum of the "D" lamp 7 is illustrated in Figure 2. It can be observed that the spectrum has a substantial spectral content within the range of 350-450 nm, with specific peaks at 355, 370, 383 and 408 nm. There is spectral content in the region of 200-350 nm, although the spectral content in the 200-250 nm range is minimal.
  • the spectrum of the "H" lamp 8 is illustrated in Figure 3. It can be seen that the spectrum has substantial spectral content in the region of 200-300 nm, with the spectral content at the longer wavelengths being restricted to isolated peaks at 312 nm, 370 nm, 408 nm and 438 nm.
  • the spectral content in the region of 200-300 nm comprises a very broad peak centred on 225 nm and spanning the area from 210-240 nm and a further relatively broad peak, which is less clearly defined, but which is substantially centred on 262 nm and effectively spans the range of 240-280 nm. It is believed that this very substantial spectral content at these very short wavelengths plays a significant role in creating free radicals to initiate polymerisation. The very high energy present in the well defined peaks at higher frequencies may also contribute.
  • a multi-functional radiation curable element is a radiation curable element which comprises two or more functional groups.
  • the radiation curable elements are preferably of low viscosity and can be considered to be reactive diluents, not only providing reactive capabilities, but also maintaining, in the unreacted state, the desired liquid properties of the coating material.
  • the average molecular weight of any single multi-functional radiation curable element utilised in the curable coating should be greater than 480. It has been found that relatively low molecular weight radiation curable elements may give rise to skin irritation. It is, however, believed that by utilising a molecular weight greater than 480, the risk of skin irritation arising is substantially reduced or obviated.
  • Typical examples of multi-functional radiation curable reactive diluents are propoxylated pentaerythritol tetra- acrylate or ethoxylated pentaerythritol tetra-acrylate.
  • An alternative material comprises "OTA 480", a triacrylated low viscosity material available from UCB Chemicals of Anderlecht Str. 33, B-1620 Drogenbos, Belgium. The structure of OTA 480 is shown in Figure 4.
  • the curable coating may optionally comprise, in addition to the reactive part, a non-reactive part or filler that may comprise clay or silica.
  • the filler may comprise metal particles that may be magnetised.
  • a pre-polymer which preferably contains some unsaturation.
  • a pre-polymer is a reactive material of relatively high viscosity.
  • a pre-polymer when used alone, does not exhibit liquid properties that are appropriate for a coating material that could be used for example in a direct gravure coating process.
  • suitable pre-polymers are polyester acrylates, polyurethane acrylates and epoxy acrylates. The functionality of these materials is normally 2 or 3 but can be up to 6. It is thought that the higher the functionality of the pre- polymers, the faster the curing performance of the coating.
  • the coated foil was passed through a curing apparatus, similar to that shown in Figure 1, but with only one lamp at a speed of 20 m/min. Initially, the lamp was an "H" lamp, and subsequently the experiment was repeated using a "D" lamp. The lamps were each operated at a power level of 240 watts/centimetre. The cured coating was subsequently tested using an acetone rub test utilising a SATRA rub tester. Such a tester provides an indication of the degree of curing. Solvent resistance is indicated as the number of double rubs effected before the coating applied to the aluminium foil is removed. The greater the number of rubs, the more solvent resistant is the coating. The results are set out in Table 1
  • Ebecryl 40 is a tetra-functional acrylated reactive diluent available from UCB Chemicals.
  • the ethoxylated pentaerythritol tetra-acrylate was obtained from Croda Resins Ltd. of Crabtree Manorway, South Belvedere, Kent DA17 6BA.
  • Actilane 320 PP 50 is obtained from Ackros Chemicals, Eccles Site, Bentcliffe Way, P.O. Box 1, Eccles, Manchester M30 0BH.
  • Example 1 shows that when the coating composition comprises only a di-acrylate, the solvent resistance has a very low value. When tri-acrylates or tetra-acrylates are utilised, a much greater degree of solvent resistance is achieved.
  • Example 2 illustrates that the degree of curing of the coating is improved when the coating is provided with a substantial energy input in the UV spectrum.
  • the best results are achieved with a relatively low speed of movement of the substrate through the curing apparatus and with the application of very intense high energy light. It can be seen that it is important, for a satisfactory cure to be achieved, for there to be a sufficient power input for a sufficient period of time.
  • the degree of cure achieved does not increase linearly with lower speed of passage through the curing zone (i.e. does not increase linearly with the exposure time to intense UV light) . As can be seen, especially at 240 watts per centimetre, the degree of cure achieved increases very substantially, almost exponentially, with increased residence time in the curing zone.
  • a coating of HH52-0103 02 EBC foil coating material was coated on to a printed paper (Paper 13-2606) , using a gravure coating unit at a coat weight of approximately 8
  • the coated paper was passed through a UV curing apparatus of a type illustrated in Figure 1 flushed with nitrogen gas to as to achieve a residual oxygen level within the curing region of less than 100 ppm.
  • the curing zone was illuminated, through quartz windows, by two high intensity UV lamps, one "H” bulb and one "D” bulb utilising focus-reflectors to direct UV light on to the coating to cure it to form a dry film, the two lamps operating at a power of 240 watts per linear centimetre.
  • the solvent resistance was greater than 50 acetone rubs (measured as in Example 2) .
  • Example 3 indicates that a coating composition in accordance with the present invention, with no photoinitiator, provides a superior performance to a coating composition which does include a photo-initiator.
  • the performance achieved by the material of the present invention is very similar to the performance achieved by the industry-acceptable-standard utilised for comparison purposes.
  • the process can operate at higher speeds.
  • the present invention provides a method of producing an industry- acceptable material without the use of photo-initiators, but whilst still providing the other advantages of UV curing.
  • the coating techniques described above have been found to be particularly suitable for applying coatings to flexible papers or films, such as papers or films produced on high speed coating and printing machines.
  • the coatings have been found to be especially valuable for use on surfaces that are found in the home environment.
  • the coatings may be applied to surfacing materials intended for application to furniture, walls, floors and ceilings.
  • the method described above may be utilised for less demanding coating applications, such as varnishes for books, magazines or record sleeves.
  • the method described above may also be utilised for fabricating coated materials for use in packaging where low odour coatings, or coatings which do not impart a "taste" to products, are of particular value.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Non-Metallic Protective Coatings For Printed Circuits (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

L'invention porte sur un procédé de revêtement d'un substrat consistant à appliquer une composition de revêtement sur des zones sélectionnées du substrat. La composition de revêtement comprend un mélange constitué d'au moins une partie réactive. Cette partie réactive comprend entre 30 % et 100 % de matériau multifonctionnel et est exempte de photoamorceur. Le substrat recouvert est exposé, dans une zone de durcissement, à la lumière ultraviolette provenant d'au moins une lampe ayant une puissance de sortie d'au moins 140 watts par centimètre linéaire. La lumière ultraviolette provoque le durcissement du revêtement. Une atmosphère pratiquement inerte est maintenue dans la zone de durcissement où le substrat est exposé à la lumière ultraviolette.
PCT/SE1998/001309 1997-07-31 1998-07-03 Procede de revetement d'un substrat WO1999006489A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP98934030A EP1000125B1 (fr) 1997-07-31 1998-07-03 Procede de revetement d'un substrat
US09/463,560 US6808757B1 (en) 1997-07-31 1998-07-03 Method of coating a substrate
BRPI9811715-7A BR9811715B1 (pt) 1997-07-31 1998-07-03 mÉtodo para revestir um substrato.
AU83638/98A AU8363898A (en) 1997-07-31 1998-07-03 A method of coating a substrate
DE1998628057 DE69828057D1 (de) 1997-07-31 1998-07-03 Verfahren zur beschichtung eines substrates
AT98934030T ATE284434T1 (de) 1997-07-31 1998-07-03 Verfahren zur beschichtung eines substrates
HK01101228A HK1030233A1 (en) 1997-07-31 2001-02-21 A method of coating a substrate.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9716194.7 1997-07-31
GB9716194A GB2327892B (en) 1997-07-31 1997-07-31 Improvements in or relating to curable coating

Publications (1)

Publication Number Publication Date
WO1999006489A1 true WO1999006489A1 (fr) 1999-02-11

Family

ID=10816765

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1998/001309 WO1999006489A1 (fr) 1997-07-31 1998-07-03 Procede de revetement d'un substrat

Country Status (10)

Country Link
US (1) US6808757B1 (fr)
EP (1) EP1000125B1 (fr)
CN (1) CN1156540C (fr)
AT (1) ATE284434T1 (fr)
AU (1) AU8363898A (fr)
BR (1) BR9811715B1 (fr)
DE (1) DE69828057D1 (fr)
GB (1) GB2327892B (fr)
HK (1) HK1030233A1 (fr)
WO (1) WO1999006489A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6720042B2 (en) 2001-04-18 2004-04-13 3M Innovative Properties Company Primed substrates comprising radiation cured ink jetted images
US6846075B2 (en) 2001-06-29 2005-01-25 3M Innovative Properties Company Imaged articles comprising a substrate having a primed surface
US6881458B2 (en) 2002-06-03 2005-04-19 3M Innovative Properties Company Ink jet receptive coating

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MXPA03002383A (es) * 2000-09-18 2003-10-15 Ecolab Inc Aparato portatil de endurecimiento con radiacion.
US6866899B2 (en) * 2001-12-21 2005-03-15 3M Innovative Properties Company Polymerization method comprising sequential irradiation
US7638780B2 (en) * 2005-06-28 2009-12-29 Eastman Kodak Company UV cure equipment with combined light path
CN101045833B (zh) * 2007-04-11 2010-09-08 江苏工业学院 原位法改性紫外光固化木器涂料的制备方法
US20140001181A1 (en) * 2012-07-02 2014-01-02 Pramod K. Sharma UV-Cured Strengthening Coating For Glass Containers
JP6774013B2 (ja) * 2016-06-28 2020-10-21 ウシオ電機株式会社 光照射装置、及びこれを備えた光硬化装置
JP6774012B2 (ja) * 2016-06-28 2020-10-21 ウシオ電機株式会社 光照射装置、及びこれを備えた光硬化装置
CN112427208B (zh) * 2019-08-16 2021-11-26 江苏长实基业电气科技有限公司 凝固装置
CN113634464B (zh) * 2021-05-14 2024-05-24 邦弗特新材料股份有限公司 一种用于uv油漆固化的mec组合光源系统
EP4422840B1 (fr) * 2021-12-22 2025-02-05 Transitions Optical, Ltd. Appareil de durcissement par ultraviolets sous atmosphère inerte

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US5047261A (en) * 1989-06-29 1991-09-10 Societe Nationale Des Pourdres Et Explosifs Process for the manufacture of coatings by radiocrosslinking
US5188900A (en) * 1989-10-18 1993-02-23 Dow Corning Corporation Substrates having an abrasion-resistant coating formed thereon
EP0549116A2 (fr) * 1991-12-20 1993-06-30 W.R. Grace & Co.-Conn. Composition à deux types de réticulation et leur utilisation
US5446073A (en) * 1993-03-31 1995-08-29 Fusion Systems Corporation Photopolymerization process employing a charge transfer complex without a photoinitiator

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Publication number Priority date Publication date Assignee Title
US4557975A (en) * 1983-12-30 1985-12-10 General Electric Company Photocurable acrylate-acrylonitrile coated plastic articles
US5047261A (en) * 1989-06-29 1991-09-10 Societe Nationale Des Pourdres Et Explosifs Process for the manufacture of coatings by radiocrosslinking
US5188900A (en) * 1989-10-18 1993-02-23 Dow Corning Corporation Substrates having an abrasion-resistant coating formed thereon
EP0549116A2 (fr) * 1991-12-20 1993-06-30 W.R. Grace & Co.-Conn. Composition à deux types de réticulation et leur utilisation
US5446073A (en) * 1993-03-31 1995-08-29 Fusion Systems Corporation Photopolymerization process employing a charge transfer complex without a photoinitiator

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6720042B2 (en) 2001-04-18 2004-04-13 3M Innovative Properties Company Primed substrates comprising radiation cured ink jetted images
US6846075B2 (en) 2001-06-29 2005-01-25 3M Innovative Properties Company Imaged articles comprising a substrate having a primed surface
US6896944B2 (en) 2001-06-29 2005-05-24 3M Innovative Properties Company Imaged articles comprising a substrate having a primed surface
US7025453B2 (en) 2001-06-29 2006-04-11 3M Innovative Properties Company Imaged articles comprising a substrate having a primed surface
US6881458B2 (en) 2002-06-03 2005-04-19 3M Innovative Properties Company Ink jet receptive coating

Also Published As

Publication number Publication date
CN1268157A (zh) 2000-09-27
HK1030233A1 (en) 2001-04-27
DE69828057D1 (de) 2005-01-13
GB9716194D0 (en) 1997-10-08
BR9811715A (pt) 2000-08-29
GB2327892B (en) 2001-11-14
CN1156540C (zh) 2004-07-07
ATE284434T1 (de) 2004-12-15
US6808757B1 (en) 2004-10-26
EP1000125B1 (fr) 2004-12-08
BR9811715B1 (pt) 2008-11-18
EP1000125A1 (fr) 2000-05-17
GB2327892A (en) 1999-02-10
AU8363898A (en) 1999-02-22

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