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WO1999067347A3 - Oligodecenes produits par catalyse au metallocene, leur production et leur utilisation comme composants dans des lubrifiants - Google Patents

Oligodecenes produits par catalyse au metallocene, leur production et leur utilisation comme composants dans des lubrifiants Download PDF

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Publication number
WO1999067347A3
WO1999067347A3 PCT/EP1999/003809 EP9903809W WO9967347A3 WO 1999067347 A3 WO1999067347 A3 WO 1999067347A3 EP 9903809 W EP9903809 W EP 9903809W WO 9967347 A3 WO9967347 A3 WO 9967347A3
Authority
WO
WIPO (PCT)
Prior art keywords
oligodecenes
lubricants
linear
metallocene
catalyzed
Prior art date
Application number
PCT/EP1999/003809
Other languages
German (de)
English (en)
Other versions
WO1999067347A2 (fr
Inventor
Hans Peter Rath
Helmut Mach
Original Assignee
Basf Ag
Hans Peter Rath
Helmut Mach
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Hans Peter Rath, Helmut Mach filed Critical Basf Ag
Priority to AU45046/99A priority Critical patent/AU4504699A/en
Priority to JP2000555993A priority patent/JP2002518582A/ja
Priority to EP99927838A priority patent/EP1088049A2/fr
Priority to KR1020007014401A priority patent/KR20010053003A/ko
Publication of WO1999067347A2 publication Critical patent/WO1999067347A2/fr
Publication of WO1999067347A3 publication Critical patent/WO1999067347A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/08—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C10M107/10—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne des oligodécènes obtenus par oligomérisation de 1-décène linéaire, sachant que 40 % en mole maximum, par rapport à la quantité de 1-décène linéaire, d'autres 1-alcènes C8 à C12 linéaires peuvent être inclus par polymérisation, en présence d'un catalyseur de titane, de zirconium ou de hafnium et d'un activeur à base de composés aluminium-organiques, bore-organiques ou carbo-cationiques. Après oligomérisation, ces oligodécènes peuvent être hydrogénés. Ces oligodécènes ont un poids moléculaire moyen compris entre 500 et 200.000. L'invention concerne également leur utilisation comme composants de lubrifiants, notamment d'huiles pour moteurs et d'huiles à engrenages.
PCT/EP1999/003809 1998-06-19 1999-06-02 Oligodecenes produits par catalyse au metallocene, leur production et leur utilisation comme composants dans des lubrifiants WO1999067347A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU45046/99A AU4504699A (en) 1998-06-19 1999-06-02 Metallocene-catalyzed oligodecenes, their production and their use as component in lubricants
JP2000555993A JP2002518582A (ja) 1998-06-19 1999-06-02 メタロセン触媒を使用して製造されるオリゴデセン、その製造および潤滑剤における成分としてのその使用
EP99927838A EP1088049A2 (fr) 1998-06-19 1999-06-02 Oligodecenes produits par catalyse au metallocene, leur production et leur utilisation comme composants dans des lubrifiants
KR1020007014401A KR20010053003A (ko) 1998-06-19 1999-06-02 메탈로센 촉매 반응에 의해 제조된 올리고데켄 및 그 제조방법과, 윤활유 성분으로서의 그 용도

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19827323.1 1998-06-19
DE19827323A DE19827323A1 (de) 1998-06-19 1998-06-19 Verwendung von metallocenkatalysiert hergestellten Oligodecenen als Komponenten in Schmierstoffen

Publications (2)

Publication Number Publication Date
WO1999067347A2 WO1999067347A2 (fr) 1999-12-29
WO1999067347A3 true WO1999067347A3 (fr) 2000-02-17

Family

ID=7871379

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1999/003809 WO1999067347A2 (fr) 1998-06-19 1999-06-02 Oligodecenes produits par catalyse au metallocene, leur production et leur utilisation comme composants dans des lubrifiants

Country Status (6)

Country Link
EP (1) EP1088049A2 (fr)
JP (1) JP2002518582A (fr)
KR (1) KR20010053003A (fr)
AU (1) AU4504699A (fr)
DE (1) DE19827323A1 (fr)
WO (1) WO1999067347A2 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8865959B2 (en) 2008-03-18 2014-10-21 Exxonmobil Chemical Patents Inc. Process for synthetic lubricant production
US8921291B2 (en) 2005-07-19 2014-12-30 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
US9409834B2 (en) 2005-07-19 2016-08-09 Exxonmobil Chemical Patents Inc. Low viscosity poly-alpha-olefins
US9469704B2 (en) 2008-01-31 2016-10-18 Exxonmobil Chemical Patents Inc. Utilization of linear alpha olefins in the production of metallocene catalyzed poly-alpha olefins

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10041345A1 (de) * 2000-08-23 2002-03-07 Basf Ag Verfahren zur Synthese von terminalen Olefinen mit enger Molgewichtsverteilung
MY139205A (en) * 2001-08-31 2009-08-28 Pennzoil Quaker State Co Synthesis of poly-alpha olefin and use thereof
US6713582B2 (en) 2001-12-14 2004-03-30 Uniroyal Chemical Company, Inc. Process for the oligomerization of α-olefins having low unsaturation, the resulting polymers, and lubricants containing same
US6680417B2 (en) 2002-01-03 2004-01-20 Bp Corporation North America Inc. Oligomerization using a solid, unsupported metallocene catalyst system
DE60333171D1 (de) * 2002-02-21 2010-08-12 Idemitsu Kosan Co Kristallines polymer von höherem alpha-olefin und herstellungsverfahren dafür
US6706828B2 (en) 2002-06-04 2004-03-16 Crompton Corporation Process for the oligomerization of α-olefins having low unsaturation
JP2005200452A (ja) * 2004-01-13 2005-07-28 Mitsui Chemicals Inc α−オレフィン（共）重合体の製造方法
JP2005200453A (ja) * 2004-01-13 2005-07-28 Mitsui Chemicals Inc α−オレフィン（共）重合体の製造方法
CN100390256C (zh) * 2004-11-26 2008-05-28 三井化学株式会社 合成润滑油和润滑油组合物
JP4933089B2 (ja) 2005-05-12 2012-05-16 出光興産株式会社 潤滑油組成物の製造方法
KR101316983B1 (ko) * 2005-08-31 2013-10-11 이데미쓰 고산 가부시키가이샤 냉동기유 조성물
JP5390738B2 (ja) * 2005-11-15 2014-01-15 出光興産株式会社 内燃機関用潤滑油組成物
US8268762B2 (en) 2005-11-15 2012-09-18 Idemitsu Kosan Co., Ltd. Transmission fluid composition
CN101400769B (zh) * 2006-03-10 2013-12-25 出光兴产株式会社 冷冻机油组合物
US8834705B2 (en) 2006-06-06 2014-09-16 Exxonmobil Research And Engineering Company Gear oil compositions
US8535514B2 (en) * 2006-06-06 2013-09-17 Exxonmobil Research And Engineering Company High viscosity metallocene catalyst PAO novel base stock lubricant blends
US8501675B2 (en) 2006-06-06 2013-08-06 Exxonmobil Research And Engineering Company High viscosity novel base stock lubricant viscosity blends
US8921290B2 (en) 2006-06-06 2014-12-30 Exxonmobil Research And Engineering Company Gear oil compositions
US8299007B2 (en) 2006-06-06 2012-10-30 Exxonmobil Research And Engineering Company Base stock lubricant blends
JP5613416B2 (ja) * 2006-07-19 2014-10-22 エクソンモービル・ケミカル・パテンツ・インク 高粘度流体の生成プロセス
JP5285218B2 (ja) * 2006-12-28 2013-09-11 出光興産株式会社 金属加工用潤滑油組成物
US8227392B2 (en) 2008-01-25 2012-07-24 Exxonmobil Research And Engineering Company Base stocks and lubricant blends containing poly-alpha olefins
CN102015798B (zh) 2008-05-07 2014-03-05 巴斯夫欧洲公司 α-烯烃/异丁烯二嵌段共聚物
JP2011121990A (ja) * 2008-11-17 2011-06-23 Idemitsu Kosan Co Ltd 潤滑油組成物
JP5555478B2 (ja) * 2008-11-17 2014-07-23 出光興産株式会社 変速機用潤滑油組成物
US8389625B2 (en) 2008-12-23 2013-03-05 Exxonmobil Research And Engineering Company Production of synthetic hydrocarbon fluids, plasticizers and synthetic lubricant base stocks from renewable feedstocks
JP5357605B2 (ja) * 2009-04-02 2013-12-04 出光興産株式会社 α−オレフィン重合体の製造方法及び潤滑油
CN105061644B (zh) 2009-12-24 2017-10-27 埃克森美孚化学专利公司 用于生产新型合成基础油料的方法
EP2609125B1 (fr) 2010-08-25 2019-12-04 ExxonMobil Chemical Patents Inc. Hydrocarbures synthétiques fluides pouvant être fonctionnalisés et leur procédé intégré de production
US9815915B2 (en) 2010-09-03 2017-11-14 Exxonmobil Chemical Patents Inc. Production of liquid polyolefins
EP2669301A4 (fr) * 2010-11-26 2014-07-09 Idemitsu Kosan Co POLYMÈRE a-OLÉFINE ET SON PROCÉDÉ DE PRODUCTION
US20140323665A1 (en) 2011-03-30 2014-10-30 Exxonmobil Chemical Patents Inc. Polyalphaolefins by Oligomerization and Isomerization
KR101449474B1 (ko) * 2012-11-23 2014-10-13 아주대학교산학협력단 알파-올레핀 트리머리제이션용 촉매, 이를 이용한 알파-올레핀 트리머리제이션 방법 및 이를 이용한 윤활유의 제조 방법
US10968290B2 (en) 2017-03-28 2021-04-06 Exxonmobil Chemical Patents Inc. Metallocene-catalyzed polyalpha-olefins

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4282392A (en) * 1976-10-28 1981-08-04 Gulf Research & Development Company Alpha-olefin oligomer synthetic lubricant
EP0613873A2 (fr) * 1993-02-23 1994-09-07 Shell Internationale Researchmaatschappij B.V. Procédé d'oligomérisation
WO1996023751A1 (fr) * 1995-02-01 1996-08-08 Basf Aktiengesellschaft Procede de preparation d'oligomeres d'olefine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4282392A (en) * 1976-10-28 1981-08-04 Gulf Research & Development Company Alpha-olefin oligomer synthetic lubricant
EP0613873A2 (fr) * 1993-02-23 1994-09-07 Shell Internationale Researchmaatschappij B.V. Procédé d'oligomérisation
WO1996023751A1 (fr) * 1995-02-01 1996-08-08 Basf Aktiengesellschaft Procede de preparation d'oligomeres d'olefine

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8921291B2 (en) 2005-07-19 2014-12-30 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
US9409834B2 (en) 2005-07-19 2016-08-09 Exxonmobil Chemical Patents Inc. Low viscosity poly-alpha-olefins
US9593288B2 (en) 2005-07-19 2017-03-14 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
US9469704B2 (en) 2008-01-31 2016-10-18 Exxonmobil Chemical Patents Inc. Utilization of linear alpha olefins in the production of metallocene catalyzed poly-alpha olefins
US8865959B2 (en) 2008-03-18 2014-10-21 Exxonmobil Chemical Patents Inc. Process for synthetic lubricant production

Also Published As

Publication number Publication date
KR20010053003A (ko) 2001-06-25
AU4504699A (en) 2000-01-10
JP2002518582A (ja) 2002-06-25
EP1088049A2 (fr) 2001-04-04
WO1999067347A2 (fr) 1999-12-29
DE19827323A1 (de) 1999-12-23

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