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WO1999065700A1 - Substrat pour impression par jet d'encre revetu d'un enduit anti-tuilage - Google Patents

Substrat pour impression par jet d'encre revetu d'un enduit anti-tuilage Download PDF

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Publication number
WO1999065700A1
WO1999065700A1 PCT/US1999/013458 US9913458W WO9965700A1 WO 1999065700 A1 WO1999065700 A1 WO 1999065700A1 US 9913458 W US9913458 W US 9913458W WO 9965700 A1 WO9965700 A1 WO 9965700A1
Authority
WO
WIPO (PCT)
Prior art keywords
colorant
improved substrate
base layer
layer
substrate
Prior art date
Application number
PCT/US1999/013458
Other languages
English (en)
Inventor
Kelly D. Branham
Leonid A. Turkevich
Bruce G. Stokes
John Gavin Macdonald
Ronald Sinclair Nohr
Russell L. Dolsey
Frank J. Kronzer
Alison S. Bagwell
Original Assignee
Kimberly-Clark Worldwide, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kimberly-Clark Worldwide, Inc. filed Critical Kimberly-Clark Worldwide, Inc.
Priority to BR9911092-0A priority Critical patent/BR9911092A/pt
Priority to CA002333568A priority patent/CA2333568A1/fr
Priority to AU46842/99A priority patent/AU4684299A/en
Priority to KR1020007014167A priority patent/KR20010052837A/ko
Priority to JP2000554559A priority patent/JP2002518212A/ja
Priority to EP99930270A priority patent/EP1089881A1/fr
Publication of WO1999065700A1 publication Critical patent/WO1999065700A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/504—Backcoats
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose

Definitions

  • the present invention relates to improved substrates containing an anticurl layer.
  • the improved substrates are capable of improving print quality and contributing to the light stabilization of a colorant on the substrate, when the colorant is exposed to electromagnetic radiation. Further, the improved substrates of the present invention provide superior print quality and colorant stabilization with minimal curling. The improved substrates enable the production of a printed substrate having superior print quality and minimal curl compared to conventional substrates.
  • a major problem with colorants is that they tend to fade when exposed to electromagnetic radiation such as sunlight or artificial light and the like. It is believed that most of the fading of colorants when exposed to light is due to photodegradation mechanisms. These degradation mechanisms include oxidation or reduction of the colorants depending upon the environmental conditions in which the colorant is placed. Fading of a colorant also depends upon the substrate upon which they reside. Product analysis of stable photoproducts and intermediates has revealed several important modes of photodecomposition.
  • the ability of a light source to cause photochemical change in a colorant is also dependent upon the spectral distribution of the light source, in particular the proportion of radiation of wavelengths most effective in causing a change in the colorant and the quantum yield of colorant degradation as a function of wavelength.
  • light of higher energy short wavelengths
  • light of lower energy long wavelengths
  • the influence of a substrate on colorant stability can be extremely important. Colorant fading may be retarded or promoted by one or more chemical groups within the substrate. Such a group can be a ground-state species or an excited-state species.
  • the porosity of the substrate is also an important factor in colorant stability. A high porosity can promote fading of a colorant by facilitating penetration of moisture and gaseous reactants into the substrate.
  • a substrate may also act as a protective agent by screening the colorant from light of wavelengths capable of causing degradation.
  • the purity of the substrate is also an important consideration whenever the photochemistry of dyed technical polymers is considered.
  • technical-grade cotton, viscose rayon, polyethylene, polypropylene, and polyisoprene are known to contain carbonyl group impurities. These impurities absorb light of wavelengths greater than 300 nm, which are present in sunlight, and so, excitation of these impurities may lead to reactive species capable of causing colorant fading (van Beek, H.C.A., Col. Res. Appl., 1983, 8(3), 176).
  • print substrates result in acceptable print quality; however, certain print defects still exist resulting in less than desirable print quality.
  • Printing defects such as "feathering” and “wicking”, undesirably spread the colorant or colorant composition beyond the desired print pattern and/or pull the colorant or colorant composition into the print substrate. The result is a smeared print pattern, wherein a substantial portion of the colorant or colorant composition migrates below and beyond the intended area of the print substrate.
  • one or more coatings are applied to the colorant-receiving surface of the substrate.
  • the coatings contain anti-wicking and anti-feathering components, as well as, colorant stabilizers in a solvent such as water.
  • the substrate has a tendency to curl toward the coated surface.
  • a polyethylene/paper/polyethylene base substrate coated with a coating on the colorant-receiving surface of the substrate will have a tendency to curl toward the colorant- receiving surface (i.e., when the colorant-receiving coating is facing upward, the edges of the substrate have a tendency to curl upward).
  • Various attempts have been made in the art to minimize the tendency of print substrates to curl. However, these attempts have not been fully successful to date.
  • the present invention addresses the needs described above by providing an improved substrate for colorants and colorant compositions.
  • the improved substrates possess an anticurl layer, which imnirnizes the tendency of the substrate to curl.
  • the improved substrates of the present invention enable the production of superior print quality while providing enhanced lightfastness for colorants and colorant compositions against radiation including radiation in the visible wavelength range.
  • the present invention also relates to improved substrates comprising an anticurl layer on a back surface of the substrate and a colorant-receiving composition of the front surface of the substrate.
  • the colorant-receiving composition provides superior print quality and colorant stability to the substrate.
  • the present invention is also directed to improved substrates comprising an anticurl layer on a back surface of the substrate and a colorant or colorant composition on a face surface of the substrate.
  • the colorant or colorant composition may contain one or more colorant stabilizers.
  • the colorant stabilizers are represented by porphines having an extremely short triplet state lifetime.
  • Unsurpassed substrate stability is achieved by combining the anticurl layer of the present invention with a variety of print substrates.
  • unsurpassed print quality, print vibrance, colorant stability, and substrate stability is achieved by combining the aforementioned improved substrates and colorant compositions.
  • the present invention is directed to improved substrates having an anticurl layer thereon.
  • the improved substrates possess superior substrate stability, while enabling the production of superior print quality and providing enhanced lightfastness for colorants and colorant compositions against radiation including radiation in the visible wavelength range.
  • the improved substrates are suitable for use with any colorant or colorant composition, and especially colorant or colorant compositions containing one or more light stabilizers.
  • the improved substrate of the present invention comprises a base layer coated with an anticurl layer.
  • the anticurl layer contains one or more polymeric binders and optionally one or more sugars and/or starches.
  • the base layer, to which the anticurl layer is applied includes, but is not limited to, paper, ' wood, a wood product or composite, woven fabric, nonwoven fabric, textile, plastic, glass, metal, or any other substrate capable of maintaining the binder composition thereon.
  • suitable substrates are disclosed in U.S. Patent Application Serial No. 08/843,410, assigned to
  • the base layer may comprise one or more of the above- mentioned layers.
  • the base layer is a coated or uncoated fiber- containing substrate such as Photoglossy Base, Presentation Matte Photobase, and High Quality Matte papers and Wetstrength Media; a film such as White Opaque Films (e.g. KIMDURA®, K-C), Clears Films (e.g. MELINEX®, ICI) Backlit Films, and Vinyl; or a nonwoven such as TYVEK®.
  • the base layer is a coated or uncoated paper. More desirably, the base layer is a coated paper comprising a cellulose sheet coated with a polymeric film, such as polyethylene, on both sides of the paper.
  • a coated paper comprising polyethylene/paper/polyethylene is available from Jen-coat Papers.
  • the base layer is a coated paper comprising a cellulose sheet coated with a polyethylene film on both sides of the paper
  • one or more treatments may be used to improve the wettability of the base layer with subsequently applied water- based coatings.
  • One such treatment is a corona discharge treatment of the base layer.
  • Another treatment is a gel coating applied to one or both sides of the base layer.
  • Particularly suitable base layers having one or more of the above treatments are commercially available papers from Schoeller Paper, designated SN1435 and SN1436.
  • SN1435 is a 7.3 mil paper having a satin finish and a face side gel coating.
  • SN1436 is a 6.2 mil paper having a high gloss finish, a face side gel coating and a back side gel coat.
  • the anticurl layer may contain one or more polymeric binders.
  • Suitable binder materials include, but are not limited to, naturally-occurring polymers, synthetically-modified naturally-occurring polymers or synthetic polymers as exemplified in Water-Soluble Polymers, C. L. McCormick, J. Bock, and D. N. Schulz, in Vol. 17, Encyclopedia of Polymer
  • the binder composition contains one or more of the following polymers: polyvinylpyrrolidone (PVP), polyvinylalcohol (PVOH), polyhydroxy ethyl acrylate, polyhydroxyethyl methacrylate, poly aery lamide, polymethacrylamide, polyethylene glycol, carboxymethyl cellulose, sodium carboxymethyl cellulose, hydroxypropyl cellulose, hydroxyethyl cellulose, polyacrylic acid and polyacrylic acid salts, polymethacrylic acid and polymethacrylic acid salts, polyvinylsulfonate and polyvinylsulfonate salts, poly-2-acrylamido-2- methylpropanesulfonic acid and poly-2-acrylamido-2- methylpropanesulfonic acid salts, polyacryloxy- trimethylammonium chloride, polymethacryloxytrimethyl- ammonium chloride
  • the anticurl layer may also contain one or more sugars and/or starches.
  • the one or more sugars and/or starches comprise one or more dextrins.
  • Suitable dextrins include linear dextrins and cyclodextrins.
  • Suitable linear dextrins include, but are not limited to, linear dextrin available from Archer Daniel Midland Corporation, Clinton, Iowa, under the tradename CLINTON 926TM.
  • Suitable cyclodextrins include, but are not limited to, -cyclodextrin, ⁇ -cyclodextrin, ⁇ -cyclodextrin, ⁇ -cyclodextrin, hydroxypropyl ⁇ -cyclodextrin, hydroxyethyl ⁇ -cyclodextrin, hydroxyethyl ⁇ cyclodextrin, carboxymethyl cyclodextrin, carboxymethyl ⁇ cyclodextrin, carboxymethyl ⁇ cyclodextrin, octyl succinated ⁇ cyclodextrin, octyl succinated ⁇ ' cyclodextrin, octyl succinated ⁇ cyclodextrin and sulfated ⁇ cyclodextrin and sulfated ⁇ -cyclodextrin (Cerestar USA Incorporated, Hammond, Indiana).
  • the anticurl layer contains a
  • the anticurl layer contains from about 100 to about 10 weight percent polymeric binder and from about 0 to about 90 weight percent dextrin. More desirably, the binder composition contains from about 75 to about 25 weight percent polymeric binder and from about 25 to about 75 weight percent dextrin. Most desirably, the binder composition contains from about 65 to about 25 weight percent polymeric binder and from about 35 to about 75 weight percent dextrin.
  • the anticurl layer of the present invention may also contain additional components.
  • additional components include, but are not limited to, charge carriers; stabilizers against thermal oxidation; viscoelastic properties modifiers; cross-linking agents; plasticizers; charge control additives such as a quaternary ammonium salt; flow control additives such as hydrophobic silica, zinc stearate, calcium stearate, lithium stearate, polyvinylstearate, and polyethylene powders; fillers such as calcium carbonate, clay and talc; surfactants; detackifiers; chelating agents; and TINUVIN® compounds; among other additives used by those having ordinary skill in the art.
  • Desirable surfactants include, but are not limited to, Cl2 to Cl8 surfactants such as cetyl trimethyl ammonium chloride and carboxymethylamylose, and other surfactants such as Triton X-100 and SURFYNOL® 420.
  • TINUVIN® compounds are a class of compounds produced by Ciba-Geigy Corporation, which includes benzophenones, benzotriazoles and hindered amines.
  • Desirable TINUVIN® compounds include, but are not limited to, 2-(2'-hydroxy-3'- sec-butyl-S'-t ⁇ rt-butylpheny ⁇ -benzo-triazole, poly-(N- ⁇ - hydroxyethyl-2,2,6,6-tetramethyl-4-hydroxy-piperidyl succinate and 2-(2'-hydroxy-3',5'-ditertbutylphenyl)-5- chloro-benzotriazole.
  • the identities and amounts of such additional components in the colored composition are well known to one of ordinary skill in the art.
  • one or more of the above additives are present in the anticurl layer in an amount of from about 1 to 14 weight percent based on the total weight of the anticurl layer.
  • the anticurl layer contains filler material in the form of particles.
  • the incorporation of selected particulate material in the anticurl layer results in a rougher outer coating surface, which improves processibility (i.e., printer rolls grab the substrate more readily), and prevents "set-off" (i.e., prevents extensive contact between the anticurl layer and an adjacent sheet or substrate).
  • Particles having a particle size than less or equal to the anticurl layer have been found to provide desirable print quality. Any particle may be used in the anticurl layer provided that the particle does not negatively affect the anti- curling properties of the improved substrate. Suitable particles include, but are not limited to, starch particles, polyamide particles, polyethylene particles and aluminum trihydrate particles.
  • the particles comprise polyamide particles having a particle size of about 12 to about 50 microns.
  • the anticurl layer is coated onto the base layer by any conventional coating method including, but not limited to, rod coating, dip coating, spray coating, gravure coating, knife coating, slot coating, nip coating and roller coating.
  • the anticurl layer is applied to the base layer by a process wherein the anticurl layer is transferred from a bath onto a roller which extends into the bath, and onto at least one surface of the base layer.
  • the coated base layer then passes under or over a rod, which meters excess coating from the base layer. Once coated, the base layer is dried in a conventional oven or by any other means.
  • the amount of anticurl layer coated onto a surface of the base layer may vary depending upon the type of base layer used and the application of the final product.
  • a base layer in the form of an uncoated paper may require more anticurl layer coating than a base layer in the form of a coated paper or film due to the increased porosity of the base layer.
  • the anticurl layer is applied to a base layer to produce a coating weight of from about 3.0 to about 60.0 g/m 2 of base layer surface area. More desirably, the coating weight is from about 9.0 to about 23.0 g/m 2 of base layer surface area. More desirably, the coating weight is from about 15.0 to about 20.0 g/m 2 of base layer surface area.
  • the present invention is also directed to an improved substrate having an anticurl layer thereon and a colorant- receiving layer on an opposite side of the base layer.
  • the improved substrate of the present invention comprises a colorant-receiving layer as described in U.S. patent application no. 09/058,385, filed on April 9, 1998 and assigned to Kimberly Clark Worldwide, Inc., the entire content of which is hereby incorporated by reference.
  • the improved substrate comprises a base layer, an anticurl layer on a back surface of the base layer, and a colorant-receiving layer comprising hydroxypropyl cellulose, carboxymethyl cellulose, hydroxypropyl-beta-cyclodextrin, and Triton X-100 on a front surface of the base substrate.
  • the amount of the colorant-receiving layer applied to a surface of the base layer may vary as with the anticurl layer. Similar to the anticurl layer, a base layer in the form of an uncoated paper may require more colorant-receiving layer coating than a base layer in the form of a coated paper or film due to the increased porosity of the base layer. Desirably, the colorant-receiving layer is applied to a base layer to produce a coating weight of from about 3.0 to about 60.0 g/m 2 of base layer surface area. More desirably, the coating weight is from about 9.0 to about 23.0 g/m 2 of base layer surface area.
  • the coating weight is from about 15.0 to about 20.0 g/m 2 of base layer surface area.
  • the amount of colorant-receiving layer coating applied to the base layer is equal to the amount of anticurl layer coating applied to the base layer.
  • the improved substrate of the present invention comprises an anticurl layer and a colorant-receiving layer as described above
  • the improved substrate may be formed by any of the conventional coating methods described above.
  • the anticurl layer may be applied to the base layer first, dried, and followed by the colorant-receiving layer, which is subsequently dried.
  • the colorant-receiving layer may be applied to the base layer first, dried, and followed by the anticurl layer, which is subsequently dried.
  • the anticurl layer and colorant-receiving layer are applied to the base layer and dried simultaneously. Care should be taken to avoid contamination of one coating composition with the other coating composition.
  • a particularly suitable method for forming the improved substrate of the present invention comprises a process wherein an anticurl layer is applied to a back surface of the base layer; a colorant-receiving layer is applied to an opposite surface of the base layer; the base layer is passed between upper and lower Meyer rods, which meter excess coating from both sides of the base layer; and the base layer is dried in a conventional oven.
  • the improved substrates of the present invention may be used as a print substrate for any colorant or colorant composition.
  • the colorant or colorant composition for use with the improved substrates of the present invention comprises a colorant or colorant composition having improved light stability, wherein a colorant stabilizer is associated with the colorant.
  • a colorant stabilizer is associated with the colorant.
  • Such colorant and colorant compositions are disclosed in U.S. Patent Application Serial No. 08/843,410, assigned to Kimberly Clark Worldwide, Inc., the entire content of which is hereby incorporated by reference. More desirably, the colorant or colorant composition contains one or more colorant stabilizers represented by po hines having an extremely short triplet state lifetime.
  • porphines having the following structure:
  • R is any proton-donating moiety and M is cobalt, copper or iron.
  • R is SO3H,
  • the colorant stabilizer is represented by the porphines Cu-meso-tetra-(4-sulfanatophenyl)-porphine
  • CuTPPS4 Cu-meso-tetra-(N-methyl-4- pyridyl)-porphine
  • CuTMPS4 Cu-meso-tetra-(N-methyl-4- pyridyl)-porphine
  • the copper ion can also be substituted with a cobalt or iron ion.
  • the sulfuric acid moieties may be substituted with salts when in solution, such as sodium salts.
  • the colorant solution may be stabilized with about 0.1% to 10% wt/wt po ⁇ hine, more preferably about 0.3% to 1 % wt/wt porphine, and more preferably about 0.5% wt/wt porphine.
  • the improved substrates of the present invention along with the above stabilizing compounds act by quenching the excited state of a dye molecule by efficiently returning it to a ground state. This reduces the likelihood of an oxidative or other chemical reaction occurring which would render the dye chromophore colorless.
  • the improved substrates of the present invention in combination with the above stabilizing compounds provide stability to any dye or colorant.
  • suitable dyes and colorants are disclosed in U.S. Patent Application Serial No. 08/843,410, assigned to Kimberly Clark Worldwide, Inc., the entire content of which is hereby incorporated by reference.
  • the colorant compositions applied to the improved substrates of the present invention may also contain additional components, depending upon the application for which it is intended.
  • additional components include, but are not limited to, one or more molecular includants; charge carriers; stabilizers against thermal oxidation; viscoelastic properties modifiers; cross-linking agents; plasticizers; charge control additives such as a quaternary ammonium salt; flow control additives such as hydrophobic silica, zinc stearate, calcium stearate, lithium stearate, polyvinylstearate, and polyethylene powders; fillers such as calcium carbonate, clay and talc; surfactants; buffer/pH adjusters; chelating agents; wetting agents; corrosion inhibitors; biocides; and TINUVIN® compounds; among other additives used by those having ordinary skill in the art.
  • Desirable surfactants include, but are not limited to, Cl2 to Cl8 surfactants such as cetyl trimethyl ammonium chloride, carboxymethylamylose, and acetylene glycols such as SURFYNOL® 104E.
  • Desirable buffer/pH adjusters include, but are not limited to, borax, hydrochloric acid and sodium hydroxide.
  • Desirable chelating agents include, but are not limited to, EDTA and EDTA complexes or salts.
  • Desirable wetting agents include, but are not limited to, ethylene glycol and glycerine.
  • Desirable corrosion inhibitors include, but are not limited to, a benzotriazole sold under the tradename COBRATEC® 99.
  • Desirable biocides include, but are not limited to, 2,6- dimethyl-m-dioxan-4-ol acetate sold under the tradename GIV- GARD DXN®.
  • TINUVIN® compounds are a class of compounds produced by Ciba-Geigy Corporation, which includes benzophenones, benzotriazoles and hindered amines.
  • Desirable TINUVIN® compounds include, but are not limited to, 2-(2'-hydroxy-3'-sec-butyl-5'-t ⁇ - > rt-butylphenyl)-benzo- triazole, poly-(N- ⁇ -hydroxyethyl-2,2,6,6-tetramethyl-4- hydroxy-piperidyl succinate and 2-(2'-hydroxy-3',5'-ditert butylphenyl)-5-chloro-benzotriazole.
  • the identities and amounts of such additional components in the colored composition are well known to one of ordinary skill in the art.
  • the improved substrates of the present invention may also be suitable for use with colored compositions within a carrier.
  • the carrier will be a polymer, typically a thermosetting or thermoplastic polymer, with the latter being the more common. Examples of suitable thermosetting and thermoplastic polymers are disclosed in U.S.
  • Patent Application Serial No. 08/843,410 assigned to Kimberly Clark Worldwide, Inc., the entire content of which is hereby incorporated by reference.
  • the present invention is further illustrated by the following examples, which are not to be construed in any way as imposing limitations upon the scope thereof. On the contrary, it is to be clearly understood that resort may be had to various other embodiments, modifications, and equivalents thereof which, after reading the description herein, may suggest themselves to those skilled in the art without departing from the spirit of the present invention.
  • An anticurl coating composition was formulated by adding the following components to 1470 parts of deionized water: 25 parts of hydroxypropyl cellulose (Hercules Chemicals), 75 parts of carboxymethyl cellulose (Hercules Chemicals), 42 parts of linear dextrin CLINTON 926TM
  • Triton X-100 (Rohm and Haas). The composition was agitated and heated, as necessary, to obtain a clear solution. The solution was allowed to cool to room temperature before being applied to a substrate.
  • EXAMPLE 2 The anticurl coating composition of Example 1 was applied onto 7 mil Jen-coat ink-jet photoglossy base sheets using a rod coating method and oven dried. The Meyer rods used were chosen so as to obtain a relatively fixed dry coat weight of about 15 g/m 2 .
  • EXAMPLE 3 The anticurl coating composition of Example 1 was applied onto a 6.2 mil Schoeller paper having a high gloss finish, a face side gel coating and a back side gel coat (Schoeller Paper, designation SN1436). A rod coating method was used so as to obtain a relatively fixed dry coat weight of about 15 g/m 2 .
  • EXAMPLE 4 The anticurl coating composition of Example 1 was applied onto a back surface of Schoeller SN1436 paper and a colorant-receiving composition was coated onto an opposite surface of the paper. A rod coating method was used so as to obtain a relatively fixed dry coat weight of about 15 g/m 2 on both surfaces. The coated paper was subsequently dried in a conventional oven.

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  • Paper (AREA)
  • Ink Jet (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Laminated Bodies (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Abstract

Cette invention a trait à des substrats améliorés revêtus d'un enduit anti-tuilage minorant la tendance qu'à le substrat à se cintrer. Elle porte également sur des substrats améliorés revêtus au dos d'un enduit anti-tuilage et dont la face est revêtue d'une composition de réception de colorant. Cette composition assure au substrat une qualité d'impression et une stabilité des colorants supérieures. Les substrats améliorés de cette invention permettent d'obtenir une impression de qualité supérieure tout en conférant aux colorants et aux compositions de colorants une solidité à la lumière leur permettant de résister aux rayonnements, notamment aux rayonnements de la gamme de longueurs d'onde du visible.
PCT/US1999/013458 1998-06-15 1999-06-15 Substrat pour impression par jet d'encre revetu d'un enduit anti-tuilage WO1999065700A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BR9911092-0A BR9911092A (pt) 1998-06-15 1999-06-15 Substrato aperfeiçoado para emprego com colorantes e processo para fabricação do mesmo
CA002333568A CA2333568A1 (fr) 1998-06-15 1999-06-15 Substrat pour impression par jet d'encre revetu d'un enduit anti-tuilage
AU46842/99A AU4684299A (en) 1998-06-15 1999-06-15 Ink-jet printable substrate with anticurl layer
KR1020007014167A KR20010052837A (ko) 1998-06-15 1999-06-15 뒤틀림방지 층이 있는 잉크 제트 인쇄성 기질
JP2000554559A JP2002518212A (ja) 1998-06-15 1999-06-15 アンチカール層を有するインキジェット印刷可能な支持体
EP99930270A EP1089881A1 (fr) 1998-06-15 1999-06-15 Substrat pour impression par jet d'encre revetu d'un enduit anti-tuilage

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8952898P 1998-06-15 1998-06-15
US60/089,528 1998-06-15

Publications (1)

Publication Number Publication Date
WO1999065700A1 true WO1999065700A1 (fr) 1999-12-23

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Application Number Title Priority Date Filing Date
PCT/US1999/013458 WO1999065700A1 (fr) 1998-06-15 1999-06-15 Substrat pour impression par jet d'encre revetu d'un enduit anti-tuilage

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EP (1) EP1089881A1 (fr)
JP (1) JP2002518212A (fr)
KR (1) KR20010052837A (fr)
CN (1) CN1305414A (fr)
AU (1) AU4684299A (fr)
BR (1) BR9911092A (fr)
CA (1) CA2333568A1 (fr)
WO (1) WO1999065700A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6934969B2 (en) 2002-12-27 2005-08-30 Kimberly-Clark Worldwide, Inc. Anti-wicking protective workwear and methods of making and using same
US6957884B2 (en) 2002-12-27 2005-10-25 Kinberly-Clark Worldwide, Inc. High-speed inkjet printing for vibrant and crockfast graphics on web materials or end-products
WO2006011799A1 (fr) 2004-07-30 2006-02-02 Fuji Photo Film B.V. Support d'enregistrement
US7155746B2 (en) 2002-12-27 2007-01-02 Kimberly-Clark Worldwide, Inc. Anti-wicking protective workwear and methods of making and using same
US9006509B2 (en) 2003-07-18 2015-04-14 Kimberly-Clark Worldwide, Inc. Absorbent article with high quality ink jet image produced at line speed

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060233975A1 (en) * 2005-04-13 2006-10-19 Tran Hai Q Inkjet anti-curl compositions for media and systems for processing the media
CN102493280A (zh) * 2011-12-02 2012-06-13 牡丹江恒丰纸业股份有限公司 一种具有阻燃带的卷烟纸的制造装置及制备方法
JP6181976B2 (ja) * 2013-05-24 2017-08-16 独立行政法人国立高等専門学校機構 吸水によりゲル状の形態を呈する複合ポリマー

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US6957884B2 (en) 2002-12-27 2005-10-25 Kinberly-Clark Worldwide, Inc. High-speed inkjet printing for vibrant and crockfast graphics on web materials or end-products
US7155746B2 (en) 2002-12-27 2007-01-02 Kimberly-Clark Worldwide, Inc. Anti-wicking protective workwear and methods of making and using same
US9006509B2 (en) 2003-07-18 2015-04-14 Kimberly-Clark Worldwide, Inc. Absorbent article with high quality ink jet image produced at line speed
US9901492B2 (en) 2003-07-18 2018-02-27 Kimberly-Clark Worldwide, Inc. Absorbent article with high quality ink jet image produced at line speed
WO2006011799A1 (fr) 2004-07-30 2006-02-02 Fuji Photo Film B.V. Support d'enregistrement

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BR9911092A (pt) 2001-02-20
CN1305414A (zh) 2001-07-25
CA2333568A1 (fr) 1999-12-23
EP1089881A1 (fr) 2001-04-11
KR20010052837A (ko) 2001-06-25
JP2002518212A (ja) 2002-06-25
AU4684299A (en) 2000-01-05

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