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WO1999060074A1 - Composition intumescente - Google Patents

Composition intumescente Download PDF

Info

Publication number
WO1999060074A1
WO1999060074A1 PCT/GB1999/001529 GB9901529W WO9960074A1 WO 1999060074 A1 WO1999060074 A1 WO 1999060074A1 GB 9901529 W GB9901529 W GB 9901529W WO 9960074 A1 WO9960074 A1 WO 9960074A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
weight
mixture
product according
intumescent
Prior art date
Application number
PCT/GB1999/001529
Other languages
English (en)
Inventor
Geoffrey Edward Ashling
Robert Glyn Coulter
Original Assignee
Pfc Surechem Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pfc Surechem Limited filed Critical Pfc Surechem Limited
Priority to CA2332147A priority Critical patent/CA2332147C/fr
Priority to AU39414/99A priority patent/AU3941499A/en
Priority to EP99922308A priority patent/EP1084210A1/fr
Publication of WO1999060074A1 publication Critical patent/WO1999060074A1/fr

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/14—Macromolecular materials

Definitions

  • This invention relates to intumescent materials which find application as fire-stop materials, for example fire penetration seals and cavity fire-stops, and otherwise.
  • Known intumescent fire-stop or penetration-sealing products include: sealants and mastics which comprise exfoliating graphite in a suitable carrier material; intumescent pipe bands, collars and wraps; intumescent blocks, grills and strips; intumescent fire pillows; intumescent expansion joints; intumescent cavity and lap-jointing seals; intumescent paints; lightweight cavity barriers; and doorstrips which comprise intumescent material . All the intumescent products mentioned may contain exfoliating graphite .
  • the products are however subject to disadvantages in that their incorporation into or onto the structure of a building is a time-consuming operation or, in certain cases, the products themselves (e.g. cavity seals, lap joints, lightweight cavity barriers and doorstrips) are difficult to manufacture as they consist of assemblies of two or more component parts.
  • a material comprising one or more of polyvinyl chloride, polyethylene, polypropylene, polyethylene-polypropylene copolymers, acrylic polymers and copolymers, metallocene polymers, silicone rubbers and polymers and natural and synthetic polymer and rubber latexes (preferably comprising one or more of the foregoing) is used as a carrier for exfoliating graphite in an intumescent composition.
  • the invention also provides an intumescent composition which comprises the said carrier material and exfoliating graphite .
  • Intumescent compositions according to the invention can be produced by extrusion of a mixture of the said carrier material and exfoliating graphite, the extrusion process preferably being a melt-extrusion process.
  • the invention accordingly provides an extrudable mixture comprising the said carrier material and exfoliating graphite and a composition produced by extrusion, preferably melt-extrusion, of a mixture of the said carrier material and exfoliating graphite.
  • the intumescent composition according to the invention can be produced by mixing of the carrier material (preferably in the form of a latex) with the exfoliating graphite.
  • the invention accordingly provides such a mixture .
  • the amount of carrier material in the composition or extrudable mixture is preferably from 30 to 45% by weight of the composition or mixture.
  • the amount of exfoliating graphite is preferably from 5 to 50 % by weight, more preferably 15 to 45% by weight, most preferably 25 to 35% by weight of the composition or mixture.
  • Compositions and extrudable mixtures of the invention preferably contain one or more plasticisers , at least one of which preferably has a fire-retardant effect.
  • the or at least one of the plasticisers is preferably a phthalate plasticiser.
  • the plasticiser (s) are suitably present in an amount of up to 35% by weight of the composition or mixture, preferably from 10 to 30% by weight, more preferably 20 to 30% by weight.
  • compositions and extrudable mixtures of the invention preferably also contain one or more stabilisers, preferably of low toxicity, suitably in a total amount of up 0.05% by weight of the composition or mixture, preferably 0.015 to 0.025% by weight .
  • compositions and extrudable mixtures of the invention may contain an inert filler, preferably in an amount of 4 to 6% by weight of the composition or mixture.
  • Suitable exfoliating graphite materials are those sold under the names "Callotek 50", “Callotek 100” , “Callotek 200", “Callotek 500” and “Callotek 600” and available from P.F.C. Surechem Limited of Davis Road, Chessington, Surrey, KT9 1TV, United Kingdom.
  • the present invention provides a composite product comprising a co-extrusion of first and second materials, the first material being an intumescent composition comprising exfoliating graphite in a carrier material .
  • the carrier material is polyvinyl chloride, polyethylene, polypropylene or a polyethylene-polypropylene copolymer
  • the first material preferably containing from 5 to 50% by weight of exfoliating graphite, more preferably 15 to 45% by weight, most preferably 25 to 35% by weight, based on the weight of the first material.
  • the amount of carrier material in the first material is preferably from 30 to 45% by weight of the first material.
  • the first material may contain one or more plasticisers and/or one or more stabilisers and/or an inert filler, of the types and in amounts based on the first material as stated above for the first -mentioned composition of the invention.
  • the second material preferably comprises one or more of polyvinyl chloride, polyethylene, polypropylene and , a polyethylene-polypropylene copolymer .
  • the second material and the carrier material are chosen for compatibility with each other, particularly upon co-extrusion, and are preferably the same material, more preferably polyvinyl chloride.
  • the composite product of the invention may take the form of a tube of multi-layer wall construction, the outer or inner layer of the tube wall being preferably of the first material.
  • Another preferred product is a tube having a wall construction which comprises a layer of the second material between first and second layers of the first material .
  • tubes constituting composite products according to the invention are pipes for gases or liquids and electrical and cable conduits.
  • Another example is a hose in which the second material is neoprene rubber and the carrier material is polyvinyl chloride, polyethylene, polypropylene or a polyethylene-polypropylene copolymer.
  • a further product according to this aspect of the invention comprises a tube of the second material which is filled completely with the first material.
  • Another product according to this aspect of the invention comprises a doorstrip or a door or window frame profile, in which the first material forms an intumescent element within the second element . It need not however be that the first material is fully enclosed in the extrusion of the second material: for example, U- and C-shaped and flat extrusions of the second material are also within the scope of the invention. Articles of these types all provide fire-stop and/or flame- or smoke-retardant functions when used in building construction.
  • the second material may be flexible or rigid according to its intended use, and may have its other physical properties also chosen to suit it to the intended use.
  • the tube wall construction comprises a layer (which may be an inner, outer or intermediate layer) of the first material
  • the tube when passed through an opening, for example in a wall or floor, in a building construction, acts as a smoke-stop, flame-stop and/or fire-stop component without any additional wrapping or collar being fitted around it to form a fire-stop.
  • the intumescent material When the tube is subjected to heat, the intumescent material intumesces and acts to block the bore of the tube . This is particularly advantageous for tubes used to convey flammable materials, for example gas pipes and fuel lines. It is desirable for the layer containing intumescent material to form the inner layer of the pipe or tube .
  • the present invention provides an electrical cable of which the insulation comprises an intumescent material comprising exfoliating graphite in a carrier material .
  • suitable cables are electrical cables generally, telecommunication cables, data transmission cables and coaxial cables .
  • the intumescent material preferably forms at least one tubular layer extending around at least one conductor of the cable.
  • the conductor may be a single strand or consist of a plurality of strands.
  • cable structures in which the intumescent material forms a tubular layer around each individual conductor, or at least those having their own insulating layers, and structures in which the intumescent material forms a tubular layer around all the conductors and within the sheathing layer of the cable are within the scope of the invention.
  • the invention also provides a cable in which a layer of intumescent material forms an outer tubular layer enclosing the sheathing layer of the cable.
  • the carrier material preferably comprises one or more of polyvinyl chloride, polyethylene, polypropylene, a polyethylene-polypropylene copolymer, an acrylic polymer or copolymer and a metallocene polymer; the insulation and sheathing layers of the cable are also preferably of one of these materials.
  • carrier material and exfoliating graphite are preferably as stated above, for the carrier material and exfoliating graphite of the first-mentioned composition according to the invention.
  • the intumescent material may contain one or more plasticisers and/or one or more stabilisers and/or an inert filler of the types and in the amounts based on the carrier material stated above for the first-mentioned composition according to the invention.
  • the intumescent material swells to enlarge the cable and perform a fire-stop, anti-smoke-spread and/or anti-flame-spread function when the cable is subjected to the heat of a fire.
  • this intumescence provides a fire-stop, anti-smoke- spread and/or anti-flame-spread, effect.
  • polyvinyl chloride and "PVC” are each used throughout this specification and its claims to cover plasticised and unplasticised polyvinyl chloride and also derivatives of both those materials.
  • polyethylene polypropylene
  • polyethylene- polypropylene copolymer are used to cover both these materials themselves and also derivatives thereof. The invention will be described further by way of the following examples 1 to 3.
  • compositions according to the invention were produced by introducing the following ingredients into the feed hopper of an extruder filled with a suitable extrusion die:
  • Figure 1 is a transverse sectional view of an electrical conduit having a twin-walled construction
  • Figure 2 is a transverse sectional view of an electrical conduit having a triple-walled construction
  • Figure 3 is a transverse sectional view of a fuel pipe having a twin-walled construction
  • Figure 4 is a transverse sectional view of a filled profile member according to the invention.
  • Figure 5 is a transverse sectional view of a first electrical cable
  • Figure 6 is a transverse sectional view of a second electrical cable
  • Figure 7 is a transverse sectional view of a third electrical cable.
  • Figure 8 is a transverse sectional view of a coupling which can act as a fire and smoke seal where electrical cables pass through a wall or similar part of a building.
  • Figure 1 of the drawings shows an electrical conduit having an outer layer 10 of rigid PVC material as in a conventional electrical conduit and an inner layer 12 of a composition made in accordance with any of examples 1 to 3.
  • the conduit is produced by co-extrusion through an extruder fitted with a suitable extrusion die of PVC granules to form the outer layer 10 and a blend of the ingredients listed in example 1 tc form the inner layer 12.
  • An electrical conduit as shown in figure 1 and having an inner layer of a composition in accordance with example 1 was tested for compliance with British Standard 476, Part 20 (see British Standards Institution document UDC 614.841.332: 620.1: 69.01: 6909.81) for fire penetration.
  • the conduit had an outside diameter of 20 mm.
  • the inner layer was 2 mm thick.
  • the test involved placing the conduit between opposed panels of mineral fibre slab each 50 mm thick and coated with a 1 mm ablative coacing. Heat transfer through the sample from a furnace at 1200°C heating one of the panels was measured. The sample produced an integrity rating of 186 mins, with an insulation rating of 75 mins.
  • Figure 2 shows a conduit having an intermediate layer 20 of the same material as the outer layer 10 of the conduit of figure 1 and inner and outer layers 22,24 of a composition made in accordance with any of examples 1 to 3 herein.
  • the conduit is produced by co-extrusion as above using a suitable extrusion die.
  • the fuel pipe shown in Figure 3 comprises an outer layer 30 of latex rubber and an inner layer 32 of a composition made in accordance with any of examples 1 to 3 herein.
  • the fuel pipe is made by co-extrusion of the rubber and the ingredients listed in the example using a suitable extrusion die.
  • Figure 4 of the drawings shows a filled, profiled element produced by co-extrusion of PVC and the ingredients of any of examples 1, 2 and 3 using a suitable extrusion die.
  • the outer part 40 of the extrusion is of circular cross-section and is filled completely with the composition of the respective example.
  • the outer part can be of any desired cross-section, for example that of a door, window or cladding component, or a door or window frame.
  • Another example is a rectangular-section which forms a doorstrip for insertion into the frame of a fire door.
  • the filed profiled element intumesces to produce a fire-stop effect when subjected to the heat of a fire.
  • the electrical cable of Figure 5 comprises insulated line and neutral conductors 50,52 and an uninsulated earth conductor 54.
  • the three conductors 50,52,54 are encased in a sheathing 56 of PVC which is itself covered by a layer 58 of a composition made in accordance with any of examples 1, 2 and 3.
  • the cable is produced by co-extrusion of PVC and the ingredients listed in the respective example, through a suitable extrusion die through which the conductors 50,52,54 are also fed.
  • the cable of Figure 6 comprises conductors 60,62,64 which correspond to the conductors 50,52,54 of the cable of Figure 5.
  • Each of the insulated conductors 60,62 has around it a respective layer 66,68 of a composition made in accordance with example 1, 2 or 3 , around which a sheathing 70 of PVC is formed.
  • the cable is produced by co-extrusion of PVC and the ingredients listed in the respective example, through a suitable extrusion die through which the conductors 60,62,64 are also fed.
  • Figure 7 shows a cable which comprises insulated line and 5 neutral conductors 72, 76 and an uninsulated earth conductor 74.
  • the three conductors 72, 74, 76 are encased in sheathing 71 made from a composition in accordance with any of examples 1, 2 and 3.
  • the sheathing 71 is covered by an outer layer 80 of PVC.
  • the cable is produced by co-extrusion of the
  • composition according to the invention and PVC through a suitable extrusion die through which the conductors 72, 74 and 76 are also fed.
  • Test 61034 relating to measurement of smoke density of electrical cables burning under defined conditions, produced a test rating of 62%, compared with a minimum test requirement of 50%.
  • Test 60754-1 relating to the amount of halogen gases
  • the coupling 82 shown in Figure 8 is made from a composition in accordance with any of examples 1, 2 and 3.
  • the coupling is extruded in sections of suitable length to allow coupling of conduits or pipes which are not rated for fire resistance where they pass through fire-rated walls or floors. A fire, flame and/or smoke seal is therefore produced and is effective when subjected to the heat of a fire.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Building Environments (AREA)

Abstract

L'invention concerne une composition de graphite exfolié et d'un support qui est, de préférence, un chlorure de polyvinyle, un polyéthylène ou un propylène. Cette composition peut être produite par extrusion d'un mélange approprié avec un matériau en plastique, de façon à former des produits composites de longueur continue. Les produits peuvent être des papiers, des tubes, des combustibles, des tuyaux, des bourrelets de porte, des conduits et des câbles électriques.
PCT/GB1999/001529 1998-05-15 1999-05-14 Composition intumescente WO1999060074A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CA2332147A CA2332147C (fr) 1998-05-15 1999-05-14 Composition intumescente
AU39414/99A AU3941499A (en) 1998-05-15 1999-05-14 Intumescent composition
EP99922308A EP1084210A1 (fr) 1998-05-15 1999-05-14 Composition intumescente

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9810529.9 1998-05-15
GBGB9810529.9A GB9810529D0 (en) 1998-05-15 1998-05-15 Intumescent composition

Publications (1)

Publication Number Publication Date
WO1999060074A1 true WO1999060074A1 (fr) 1999-11-25

Family

ID=10832177

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1999/001529 WO1999060074A1 (fr) 1998-05-15 1999-05-14 Composition intumescente

Country Status (6)

Country Link
EP (1) EP1084210A1 (fr)
CN (1) CN1305518A (fr)
AU (1) AU3941499A (fr)
CA (1) CA2332147C (fr)
GB (1) GB9810529D0 (fr)
WO (1) WO1999060074A1 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001034724A1 (fr) * 1999-11-12 2001-05-17 P.F.C. Surechem Limited Composition intumescente
WO2001040610A1 (fr) * 1999-11-30 2001-06-07 Lorient Polyproducts Limited Joint a l'epreuve du feu et impermeable a la fumee
WO2003000824A1 (fr) * 2001-06-22 2003-01-03 Royal Group Technologies Limited Composition pour coupe-feu moule
DE20205505U1 (de) * 2002-04-09 2003-08-28 HTI Maschinen- und Apparatebau GmbH, 76855 Annweiler Schutzhülle für langgestreckte Gegenstände wie elektrische Kabel, Rohrleitungen o.dgl. gegen Einwirkung oder Ausbreitung von Hitze und/oder Feuer
WO2013162911A1 (fr) * 2012-04-23 2013-10-31 Sabic Innovative Plastics Ip B.V. Feuille multicouche et procédés de fabrication et articles comprenant la feuille multicouche
EP2787036A1 (fr) * 2011-11-29 2014-10-08 Tokuyama Sekisui Co., Ltd. Composition de résine chlorée de chlorure de vinyle pour le moulage par extrusion
EP2787035A4 (fr) * 2011-11-29 2015-07-08 Sekisui Chemical Co Ltd Emballage thermo-expansible à couches multiples pour des matériaux de construction
CN107731365A (zh) * 2017-09-29 2018-02-23 惠州市鼎丰泰科技有限公司 一种新型导电排

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2002367872B2 (en) * 2002-04-16 2008-05-22 Prysmian Cavi E Sistemi Energia S.R.L. Electric cable and manufacturing process thereof
EP2199992A1 (fr) * 2008-12-19 2010-06-23 Gemalto SA Activation sécurisée avant transaction de carte intelligente bancaire sans contact
CN108565051B (zh) * 2017-12-29 2019-11-19 温州新马亚电器有限公司 一种防结冰柱电缆
CN110265185A (zh) * 2019-06-25 2019-09-20 晋源电气集团股份有限公司 一种耐高温阻燃计算机电缆及其制备方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4549041A (en) * 1983-11-07 1985-10-22 Fujikura Ltd. Flame-retardant cross-linked composition and flame-retardant cable using same
WO1988002019A1 (fr) * 1986-09-17 1988-03-24 Dixon International Limited Materiau intumescent
EP0302987A1 (fr) * 1987-08-14 1989-02-15 Dr. Wolman GmbH Compositions pour la préparation d'articles de moulage intumescents et produits semi-finis et leur utilisation comme éléments de construction ignifugeants
EP0745751A2 (fr) * 1995-06-02 1996-12-04 Reddiplex Group PLC Ruban intumescent
EP0787784A2 (fr) * 1996-01-31 1997-08-06 Friedhelm Schneider Pièces moulées à base de mélanges intumescents et procédé pour leur production
EP0824134A1 (fr) * 1996-08-13 1998-02-18 Tosoh Corporation Comprimé ignifuge, composition de polymère retardatrice de flamme et article moulé utilisant cette composition
WO1998030654A1 (fr) * 1997-01-10 1998-07-16 Reddiplex Group Plc Compositions intumescentes non halogenees
DE19705736C1 (de) * 1997-02-14 1998-10-01 Kuhn Ag Dr Kombiniertes Dichtungs/Brandschutzprofil und Verfahren zu dessen Herstellung durch Koextrusion

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4549041A (en) * 1983-11-07 1985-10-22 Fujikura Ltd. Flame-retardant cross-linked composition and flame-retardant cable using same
WO1988002019A1 (fr) * 1986-09-17 1988-03-24 Dixon International Limited Materiau intumescent
EP0302987A1 (fr) * 1987-08-14 1989-02-15 Dr. Wolman GmbH Compositions pour la préparation d'articles de moulage intumescents et produits semi-finis et leur utilisation comme éléments de construction ignifugeants
EP0745751A2 (fr) * 1995-06-02 1996-12-04 Reddiplex Group PLC Ruban intumescent
EP0787784A2 (fr) * 1996-01-31 1997-08-06 Friedhelm Schneider Pièces moulées à base de mélanges intumescents et procédé pour leur production
EP0824134A1 (fr) * 1996-08-13 1998-02-18 Tosoh Corporation Comprimé ignifuge, composition de polymère retardatrice de flamme et article moulé utilisant cette composition
WO1998030654A1 (fr) * 1997-01-10 1998-07-16 Reddiplex Group Plc Compositions intumescentes non halogenees
DE19705736C1 (de) * 1997-02-14 1998-10-01 Kuhn Ag Dr Kombiniertes Dichtungs/Brandschutzprofil und Verfahren zu dessen Herstellung durch Koextrusion

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001034724A1 (fr) * 1999-11-12 2001-05-17 P.F.C. Surechem Limited Composition intumescente
WO2001040610A1 (fr) * 1999-11-30 2001-06-07 Lorient Polyproducts Limited Joint a l'epreuve du feu et impermeable a la fumee
WO2003000824A1 (fr) * 2001-06-22 2003-01-03 Royal Group Technologies Limited Composition pour coupe-feu moule
WO2004041967A1 (fr) * 2001-06-22 2004-05-21 Royal Group Technologies Limited Composition pour coupe-feu moule
DE20205505U1 (de) * 2002-04-09 2003-08-28 HTI Maschinen- und Apparatebau GmbH, 76855 Annweiler Schutzhülle für langgestreckte Gegenstände wie elektrische Kabel, Rohrleitungen o.dgl. gegen Einwirkung oder Ausbreitung von Hitze und/oder Feuer
EP2787036A1 (fr) * 2011-11-29 2014-10-08 Tokuyama Sekisui Co., Ltd. Composition de résine chlorée de chlorure de vinyle pour le moulage par extrusion
EP2787035A4 (fr) * 2011-11-29 2015-07-08 Sekisui Chemical Co Ltd Emballage thermo-expansible à couches multiples pour des matériaux de construction
EP2787036A4 (fr) * 2011-11-29 2015-07-08 Tokuyama Sekisui Co Ltd Composition de résine chlorée de chlorure de vinyle pour le moulage par extrusion
WO2013162911A1 (fr) * 2012-04-23 2013-10-31 Sabic Innovative Plastics Ip B.V. Feuille multicouche et procédés de fabrication et articles comprenant la feuille multicouche
CN107731365A (zh) * 2017-09-29 2018-02-23 惠州市鼎丰泰科技有限公司 一种新型导电排

Also Published As

Publication number Publication date
CN1305518A (zh) 2001-07-25
EP1084210A1 (fr) 2001-03-21
CA2332147C (fr) 2010-05-04
AU3941499A (en) 1999-12-06
GB9810529D0 (en) 1998-07-15
CA2332147A1 (fr) 1999-11-25

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